ES8101629A1 - Solvent polymerization of carboxyl containing monomers. - Google Patents
Solvent polymerization of carboxyl containing monomers.Info
- Publication number
- ES8101629A1 ES8101629A1 ES486697A ES486697A ES8101629A1 ES 8101629 A1 ES8101629 A1 ES 8101629A1 ES 486697 A ES486697 A ES 486697A ES 486697 A ES486697 A ES 486697A ES 8101629 A1 ES8101629 A1 ES 8101629A1
- Authority
- ES
- Spain
- Prior art keywords
- carboxyl
- monomers
- solvent
- containing monomers
- carboxyl containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/04—Acids, Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/923—Ethylenic monomers containing at least one salt group
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/93—Water swellable or hydrophilic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Carboxyl or carboxyl salt containing polymers are prepared by polymerizing carboxyl containing monomers wherein greater than one percent of the carboxyl groups are neutralized with an alkali, ammonia or an amine, optionally copolymerized with other vinylidene monomers containing at least one terminal CH2=CH< group dissolved in a solvent for the monomers which is a non-solvent for the polymer with a free radical catalyst, so that the resulting polymer is obtained suspended as a fine, readily recoverable substantially non-swollen fine powder. The solvents used are moderately to strongly hydrogen bonded and have solubility parameters of from about 8 to 15.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/967,447 US4267103A (en) | 1978-12-07 | 1978-12-07 | Solvent polymerization of carboxyl containing monomers |
Publications (2)
Publication Number | Publication Date |
---|---|
ES486697A0 ES486697A0 (en) | 1980-12-16 |
ES8101629A1 true ES8101629A1 (en) | 1980-12-16 |
Family
ID=25512810
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES486697A Expired ES8101629A1 (en) | 1978-12-07 | 1979-12-07 | Solvent polymerization of carboxyl containing monomers. |
Country Status (14)
Country | Link |
---|---|
US (1) | US4267103A (en) |
EP (1) | EP0020680A4 (en) |
JP (1) | JPH0262561B2 (en) |
AU (1) | AU5300179A (en) |
BE (1) | BE880235A (en) |
CA (1) | CA1147898A (en) |
ES (1) | ES8101629A1 (en) |
GR (1) | GR69729B (en) |
IL (1) | IL58751A0 (en) |
IT (1) | IT1127279B (en) |
NO (1) | NO793966L (en) |
PT (1) | PT70554A (en) |
WO (1) | WO1980001164A1 (en) |
ZA (1) | ZA796373B (en) |
Families Citing this family (56)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE3872T1 (en) * | 1979-08-10 | 1983-07-15 | Coopervision U.K. Limited | PREPARATION OF NON-CROSSLINKED POLYMERS, METHOD OF SHAPING THEREOF, AND CONTACT LENSES MADE BY THIS METHOD. |
US4500693A (en) * | 1981-07-07 | 1985-02-19 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Water soluble copolymer method for manufacture therefore and use thereof |
US4470814A (en) * | 1981-12-21 | 1984-09-11 | Block Drug Company, Inc. | Method of adhering dentures |
US4420586A (en) * | 1982-11-29 | 1983-12-13 | Nalco Chemical Company | Non-aqueous dispersion polymerization of vinyl monomers |
US4542168A (en) * | 1983-09-02 | 1985-09-17 | Block Drug Co., Inc. | Denture fixative composition with partially neutralized and crosslinked polyacrylic acid |
JPH0625317B2 (en) * | 1986-08-26 | 1994-04-06 | 日本ペイント株式会社 | Spherical collapsible vinyl resin particles for antifouling paint |
DE3631070A1 (en) * | 1986-09-12 | 1988-03-24 | Basf Ag | METHOD FOR PRODUCING TERPOLYMERS |
US4758641A (en) * | 1987-02-24 | 1988-07-19 | The B F Goodrich Company | Polycarboxylic acids with small amount of residual monomer |
DE3875788D1 (en) * | 1987-04-11 | 1992-12-17 | Basf Ag | WATER-SOLUBLE COPOLYMERISATE, METHOD FOR THEIR PRODUCTION AND THEIR USE. |
ES2056848T3 (en) * | 1987-04-11 | 1994-10-16 | Basf Ag | WATER-SOLUBLE COPOLYMERS, A PROCEDURE FOR ITS OBTAINING AND EMPLOYMENT. |
US5073612A (en) * | 1987-12-28 | 1991-12-17 | Nippon Shokubai Kagaku Kogyo, Co., Ltd. | Hydrophilic polymer and method for production thereof |
US4923940A (en) * | 1988-02-19 | 1990-05-08 | The B.F. Goodrich Company | Polycarboxylic acids with higher thickening capacity and better clarity |
US4996274A (en) * | 1988-02-19 | 1991-02-26 | The B. F. Goodrich Company | Polycarboxylic acids with higher thickening capacity and better clarity |
DE3818426A1 (en) * | 1988-05-31 | 1989-12-07 | Basf Ag | METHOD FOR PRODUCING WATER-SOLUBLE POLYMERISATS AND THEIR USE |
US5059664A (en) * | 1988-06-22 | 1991-10-22 | Mitsubishi Petrochemical Company Limited | Process for the preparation of water absorptive resin |
US5021526A (en) * | 1988-07-05 | 1991-06-04 | The Standard Oil Company | Anionic polymeric stabilizers for oil-in-water emulsions |
CA2003808C (en) * | 1988-11-28 | 1999-11-09 | Eugene Joseph Sehm | Crosslinked polyacrylic acid |
US5173551A (en) * | 1990-03-09 | 1992-12-22 | Board Of Control Of Michigan Technological University | Free-radical retrograde precipitation-polymerization process |
US5270415A (en) * | 1990-12-21 | 1993-12-14 | Allergan Inc. | Balanced charge polymer and hydrophilic contact lens manufactured therefrom |
US5612429A (en) * | 1992-04-21 | 1997-03-18 | National Starch And Chemical Investment Holding Corporation | Process for the polymerization of polymers in non-aqueous liquid media |
US5336423A (en) * | 1992-05-05 | 1994-08-09 | The Lubrizol Corporation | Polymeric salts as dispersed particles in electrorheological fluids |
US5364581A (en) * | 1993-05-06 | 1994-11-15 | Kenneth Wilkinson | Process of making polyacrylonitrile fibers |
US5616292A (en) * | 1993-05-06 | 1997-04-01 | Wilkinson; Kenneth | Process of making PAN fibers |
US5523366A (en) * | 1993-05-06 | 1996-06-04 | Wilkinson; Kenneth | Process for the preparation of an acrylonitrile copolymer and product prepared therefrom |
US5399639A (en) * | 1993-07-12 | 1995-03-21 | National Starch And Chemical Investment Holding Corporation | Method for manufacturing of polymers |
US5342911A (en) * | 1993-08-25 | 1994-08-30 | 3V Inc. | Crosslinked polyacrylic acids having low solvent residue, a process for the preparation thereof and the use thereof as thickening agents |
IT1264989B1 (en) * | 1993-12-14 | 1996-10-17 | Sigma Prod Chim | SORBED ALKYL AND / OR ALKYLPHENYL POLY (OXYALKYLENE) COPOLYMERS AND THEIR USE AS THICKENERS |
US5663253A (en) * | 1996-06-20 | 1997-09-02 | 3V Inc. | Policarboxylic acids |
US6492488B1 (en) | 1998-08-02 | 2002-12-10 | Pmd Holdings Corp. | Controlled release polyacrylic acid granules and a process for preparing the same |
GB9903140D0 (en) | 1999-02-12 | 1999-04-07 | Basf Ag | Interpolymers |
US6297337B1 (en) | 1999-05-19 | 2001-10-02 | Pmd Holdings Corp. | Bioadhesive polymer compositions |
US6623756B1 (en) * | 2000-04-27 | 2003-09-23 | Noveon Ip Holdings Corp. | Directly compressed solid dosage articles |
EP1311275B1 (en) | 2000-06-29 | 2004-09-15 | Kopran Research Laboratories Limited | A synthetic bulk laxative |
US6433061B1 (en) | 2000-10-24 | 2002-08-13 | Noveon Ip Holdings Corp. | Rheology modifying copolymer composition |
US6623754B2 (en) * | 2001-05-21 | 2003-09-23 | Noveon Ip Holdings Corp. | Dosage form of N-acetyl cysteine |
JP3940009B2 (en) * | 2002-03-18 | 2007-07-04 | 住友精化株式会社 | Method for producing carboxyl group-containing water-soluble polymer |
US20080193405A1 (en) * | 2005-01-28 | 2008-08-14 | Basf Aktiengesellschaft | Use of a Water-In-Water Emulsion Polymers in the Form of a Thickener for Cosmetic Preparations |
CN101405304A (en) * | 2006-01-23 | 2009-04-08 | 巴斯夫欧洲公司 | Process for preparing polymers in aqueous solvents |
CN101410418B (en) * | 2006-03-31 | 2011-11-09 | 巴斯夫欧洲公司 | Process for preparing acrylate copolymers |
EP2023892A1 (en) * | 2006-05-04 | 2009-02-18 | Basf Se | Neutralized acid group-containing polymers and the use thereof |
KR100844181B1 (en) * | 2007-02-15 | 2008-07-04 | 애경정밀화학 주식회사 | Composition for manufacturing a carboxylic group containing polymer and a polymer prepared thereof |
WO2010059765A1 (en) * | 2008-11-21 | 2010-05-27 | Hercules Incorporated | Non-hydrocarbyl hydrophobically modified polycarboxylic polymers |
CA2781185A1 (en) | 2009-11-26 | 2011-06-03 | Basf Se | Use of highly-branched polyesters in cosmetic and dermatological formulations |
US20110123473A1 (en) * | 2009-11-26 | 2011-05-26 | Basf Se | Use of highly-branched polycarbonates in cosmetic and dermatological formulations |
CN102665669B (en) | 2009-11-26 | 2014-04-16 | 巴斯夫欧洲公司 | Use of hyperbranched polycarbonates in cosmetic and dermatological formulations |
KR20130036188A (en) | 2010-03-02 | 2013-04-11 | 바스프 에스이 | Block copolymers and their use |
US8673275B2 (en) | 2010-03-02 | 2014-03-18 | Basf Se | Block copolymers and their use |
US20110218295A1 (en) * | 2010-03-02 | 2011-09-08 | Basf Se | Anionic associative rheology modifiers |
MY176354A (en) | 2014-05-05 | 2020-07-30 | Lubrizol Advanced Mat Inc | Homogenous film compositions |
MX2017000368A (en) | 2014-07-09 | 2017-05-12 | Lubrizol Advanced Mat Inc | Hydrogel compositions. |
US20180311358A1 (en) | 2015-11-05 | 2018-11-01 | Lubrizol Advanced Materials, Inc. | Thermoformable dual network hydrogel compositions |
WO2018175237A1 (en) | 2017-03-23 | 2018-09-27 | Particle Sciences, Inc. | Implantable and removable drug delivery device |
US20200069533A1 (en) | 2017-03-23 | 2020-03-05 | Lubrizol Advanced Materials, Inc. | Denture adhesives |
CA3062158A1 (en) | 2017-05-02 | 2018-11-08 | Lubrizol Advanced Materials, Inc. | Improved extended release highly loaded drug compositions |
FR3111899A1 (en) * | 2020-06-25 | 2021-12-31 | Snf Sa | Crosslinked copolymer, preparation process and printing paste comprising said copolymer |
EP4301806A1 (en) | 2021-03-05 | 2024-01-10 | Lubrizol Advanced Materials, Inc. | Method for wetting and dispersion of acrylic acid polymers |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2244703A (en) * | 1938-04-16 | 1941-06-10 | Du Pont | Water soluble salts of interpolymers containing methacrylic acid |
US2878237A (en) * | 1955-06-15 | 1959-03-17 | American Cyanamid Co | Mercapto dibasic acids as regulators for the polymerization of acrylic acids, amidesand salts |
US3025219A (en) * | 1956-12-28 | 1962-03-13 | Ciba Ltd | Aerosol hair dressing composition |
US3336269A (en) * | 1964-04-07 | 1967-08-15 | Hercules Inc | Preparation of acrylamide-type water-soluble polymers |
US3379702A (en) * | 1965-06-14 | 1968-04-23 | Dow Chemical Co | Method for preparing terpolymers of ethylene, acrylic acids and salts of acrylic acids |
JPS453979Y1 (en) * | 1966-04-08 | 1970-02-24 | ||
US3479284A (en) * | 1967-03-30 | 1969-11-18 | Hercules Inc | Separation of finely divided solids from liquid suspensions thereof |
US3509113A (en) * | 1967-08-14 | 1970-04-28 | Hercules Inc | Preparation of acrylamide-type water-soluble polymers |
NL7303593A (en) * | 1972-03-16 | 1973-09-18 | ||
US3872063A (en) * | 1972-08-29 | 1975-03-18 | American Cyanamid Co | Polymerization process |
US3919140A (en) * | 1972-08-31 | 1975-11-11 | Sumitomo Chemical Co | Process for producing acrylamide polymers in an acetone-water solvent system |
US3970633A (en) * | 1973-05-16 | 1976-07-20 | Rohm And Haas Company | Thermosetting powder coatings composition |
JPS5539170B2 (en) * | 1975-01-16 | 1980-10-08 | ||
US4138539A (en) * | 1975-06-19 | 1979-02-06 | American Cyanamid Company | Process for water-soluble synthetic polymer in powder form |
US4028290A (en) * | 1975-10-23 | 1977-06-07 | Hercules Incorporated | Highly absorbent modified polysaccharides |
JPS6024122B2 (en) * | 1977-01-05 | 1985-06-11 | 三菱化学株式会社 | Method for producing bead-like polymer |
US4062817A (en) * | 1977-04-04 | 1977-12-13 | The B.F. Goodrich Company | Water absorbent polymers comprising unsaturated carboxylic acid, acrylic ester containing alkyl group 10-30 carbon atoms, and another acrylic ester containing alkyl group 2-8 carbon atoms |
US4237253A (en) * | 1977-04-21 | 1980-12-02 | L'oreal | Copolymers, their process of preparation, and cosmetic compounds containing them |
US4066583A (en) * | 1977-05-16 | 1978-01-03 | The B. F. Goodrich Company | Flexible water absorbent polymer compositions comprising (a) unsaturated carboxylic acid, acrylic ester containing alkyl group 10-30 carbon atoms, additional monomer plus (b) aliphatic diol |
JPS5548212A (en) * | 1978-10-02 | 1980-04-05 | Nippon Junyaku Kk | Preparation of novel water-soluble crosslinked copolymer |
US4167464A (en) * | 1978-10-16 | 1979-09-11 | The B. F. Goodrich Company | Photopolymerized hydrophilic interpolymers of unsaturated carboxylic acid and esters |
-
1978
- 1978-12-07 US US05/967,447 patent/US4267103A/en not_active Expired - Lifetime
-
1979
- 1979-11-13 WO PCT/US1979/001013 patent/WO1980001164A1/en not_active Application Discontinuation
- 1979-11-13 JP JP55500086A patent/JPH0262561B2/ja not_active Expired - Lifetime
- 1979-11-15 CA CA000339890A patent/CA1147898A/en not_active Expired
- 1979-11-20 GR GR60556A patent/GR69729B/el unknown
- 1979-11-20 AU AU53001/79A patent/AU5300179A/en not_active Abandoned
- 1979-11-20 IL IL58751A patent/IL58751A0/en unknown
- 1979-11-23 BE BE0/198264A patent/BE880235A/en unknown
- 1979-11-23 ZA ZA00796373A patent/ZA796373B/en unknown
- 1979-12-04 IT IT27843/79A patent/IT1127279B/en active
- 1979-12-05 NO NO793966A patent/NO793966L/en unknown
- 1979-12-06 PT PT70554A patent/PT70554A/en unknown
- 1979-12-07 ES ES486697A patent/ES8101629A1/en not_active Expired
-
1980
- 1980-06-17 EP EP19800900030 patent/EP0020680A4/en not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
BE880235A (en) | 1980-03-17 |
JPS55500941A (en) | 1980-11-13 |
CA1147898A (en) | 1983-06-07 |
IT1127279B (en) | 1986-05-21 |
US4267103A (en) | 1981-05-12 |
ZA796373B (en) | 1980-11-26 |
IL58751A0 (en) | 1980-02-29 |
GR69729B (en) | 1982-07-09 |
PT70554A (en) | 1980-01-01 |
NO793966L (en) | 1980-06-10 |
ES486697A0 (en) | 1980-12-16 |
IT7927843A0 (en) | 1979-12-04 |
AU5300179A (en) | 1980-06-12 |
EP0020680A4 (en) | 1981-01-28 |
EP0020680A1 (en) | 1981-01-07 |
WO1980001164A1 (en) | 1980-06-12 |
JPH0262561B2 (en) | 1990-12-26 |
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