ES468490A1 - Fixation of radioactive materials in a glass matrix - Google Patents

Fixation of radioactive materials in a glass matrix

Info

Publication number
ES468490A1
ES468490A1 ES468490A ES468490A ES468490A1 ES 468490 A1 ES468490 A1 ES 468490A1 ES 468490 A ES468490 A ES 468490A ES 468490 A ES468490 A ES 468490A ES 468490 A1 ES468490 A1 ES 468490A1
Authority
ES
Spain
Prior art keywords
composition
glass
radioactive materials
glass matrix
sio2
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES468490A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/884,371 external-priority patent/US4224177A/en
Application filed by Individual filed Critical Individual
Publication of ES468490A1 publication Critical patent/ES468490A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
    • C03C23/0095—Solution impregnating; Solution doping; Molecular stuffing, e.g. of porous glass
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00—Compositions for glass with special properties
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/28—Treating solids
    • G21F9/30—Processing
    • G21F9/301—Processing by fixation in stable solid media
    • G21F9/302—Processing by fixation in stable solid media in an inorganic matrix
    • G21F9/305—Glass or glass like matrix

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Glass Compositions (AREA)

Abstract

The new nonporous glass composition contains a radioactive material in the form of oxides or elements which is embedded and immobilised in the glass matrix. The said composition contains at least 75 moles per cent of SiO2, in addition to a radiation activity higher than 1 millicurie per cm<3> of the composition and a high chemical durability in aqueous solution. The composition may be in the form of a glass article showing an outer enclosure or glass skin comprising at least 90 moles per cent of SiO2 and substantially free from radioactive material, and an inner core formed by the said composition. The composition is used for binding radioactive materials. The attached figure is a graphic representation of the fraction of waste released into the environment after 20,000 years' storage.
ES468490A 1977-04-04 1978-04-03 Fixation of radioactive materials in a glass matrix Expired ES468490A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US78443277A 1977-04-04 1977-04-04
US83677877A 1977-09-26 1977-09-26
US05/884,371 US4224177A (en) 1978-03-09 1978-03-09 Fixation of radioactive materials in a glass matrix

Publications (1)

Publication Number Publication Date
ES468490A1 true ES468490A1 (en) 1980-12-16

Family

ID=27419815

Family Applications (2)

Application Number Title Priority Date Filing Date
ES468490A Expired ES468490A1 (en) 1977-04-04 1978-04-03 Fixation of radioactive materials in a glass matrix
ES474004A Expired ES474004A1 (en) 1977-04-04 1978-10-06 Fixation of radioactive materials in a glass matrix

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES474004A Expired ES474004A1 (en) 1977-04-04 1978-10-06 Fixation of radioactive materials in a glass matrix

Country Status (17)

Country Link
JP (1) JPS53146715A (en)
AT (1) AT367237B (en)
AU (1) AU524260B2 (en)
BR (1) BR7802066A (en)
CA (1) CA1110051A (en)
CH (1) CH633499A5 (en)
DE (1) DE2814204A1 (en)
DK (1) DK146878A (en)
ES (2) ES468490A1 (en)
FR (1) FR2386889B1 (en)
GB (1) GB1591703A (en)
IE (1) IE46863B1 (en)
IL (1) IL54316A (en)
IT (1) IT1094315B (en)
LU (1) LU79365A1 (en)
NL (1) NL7803533A (en)
SE (1) SE7803744L (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA786514B (en) * 1978-11-09 1980-07-30 Litovitz T Immobilization of radwastes in glass containers and products formed thereby
GB2050681B (en) * 1978-11-09 1982-08-04 Litovitz Theodore A Fixation by ion exchange of toxic materials in a glass matrix
DE3045878C2 (en) * 1980-12-05 1986-01-23 Rheinisch-Westfälisches Elektrizitätswerk AG, 4300 Essen Process for solidifying liquid waste containing boric acid from the primary cooling circuit of nuclear power plants
DE3214242A1 (en) * 1982-04-17 1983-10-20 Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe METHOD FOR IMPROVING THE PROPERTIES OF RADIOACTIVE WASTE REINFORCEMENTS REQUIRED FOR LONG TERM STORAGE
FR2563936B1 (en) * 1984-05-04 1989-04-28 Sgn Soc Gen Tech Nouvelle PROCESS FOR COATING AND STORING DANGEROUS MATERIALS, PARTICULARLY RADIOACTIVE, IN A MONOLITHIC CONTAINER, DEVICE FOR IMPLEMENTING THE PROCESS AND PRODUCT OBTAINED
JPH0721556B2 (en) * 1988-03-28 1995-03-08 動力炉・核燃料料開発事業団 Method for melting and solidifying glass of radioactive waste liquid with suppressed formation of gaseous ruthenium
JPH10272459A (en) * 1997-03-31 1998-10-13 Power Reactor & Nuclear Fuel Dev Corp Environmental purifying body, environmental purifying method and environmental purifying device
JP4649670B2 (en) * 2006-06-06 2011-03-16 国立大学法人 新潟大学 Method for measuring radon and thoron in air
JP2011128083A (en) * 2009-12-18 2011-06-30 Central Res Inst Of Electric Power Ind Method for preparing sample for observing insoluble substance of platinum group element inside solidified glass body
RU2746985C1 (en) * 2020-10-05 2021-04-23 Федеральное государственное автономное образовательное учреждение высшего образования «Дальневосточный федеральный университет» (ДВФУ) Method for immobilizing strontium radionuclides in ceramics
CN115424757B (en) * 2022-08-17 2024-06-11 西南科技大学 Method for solidifying iodine-containing waste with high iodine retention rate

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3116131A (en) * 1960-08-01 1963-12-31 Victor Comptometer Corp Method and materials for disposing of radioactive waste
US3114716A (en) * 1962-12-28 1963-12-17 Thomas C Quinby Method of preparing radioactive cesium sources
DE2343241A1 (en) * 1973-08-28 1975-03-06 Bayer Ag METHOD FOR CONSOLIDATING RADIOACTIVE WASTE SOLUTIONS

Also Published As

Publication number Publication date
DE2814204A1 (en) 1978-10-19
JPS53146715A (en) 1978-12-20
IL54316A (en) 1982-01-31
IT1094315B (en) 1985-07-26
DK146878A (en) 1978-10-05
BR7802066A (en) 1978-12-05
IT7821927A0 (en) 1978-04-03
AU524260B2 (en) 1982-09-09
LU79365A1 (en) 1979-11-07
ATA232778A (en) 1981-10-15
ES474004A1 (en) 1979-11-16
AT367237B (en) 1982-06-11
CA1110051A (en) 1981-10-06
IL54316A0 (en) 1978-06-15
CH633499A5 (en) 1982-12-15
SE7803744L (en) 1978-10-05
IE46863B1 (en) 1983-10-19
GB1591703A (en) 1981-06-24
NL7803533A (en) 1978-10-06
IE780653L (en) 1978-10-04
AU3438878A (en) 1979-09-27
FR2386889B1 (en) 1986-01-03
JPS6120840B2 (en) 1986-05-23
FR2386889A1 (en) 1978-11-03

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 20010301