ES455122A1 - Production of metallurgically pure alumina - Google Patents
Production of metallurgically pure aluminaInfo
- Publication number
- ES455122A1 ES455122A1 ES455122A ES455122A ES455122A1 ES 455122 A1 ES455122 A1 ES 455122A1 ES 455122 A ES455122 A ES 455122A ES 455122 A ES455122 A ES 455122A ES 455122 A1 ES455122 A1 ES 455122A1
- Authority
- ES
- Spain
- Prior art keywords
- attack
- liquor
- washing
- residue
- precipitate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title abstract 2
- 238000005406 washing Methods 0.000 abstract 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 3
- 239000012452 mother liquor Substances 0.000 abstract 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 2
- 239000002244 precipitate Substances 0.000 abstract 2
- 235000011149 sulphuric acid Nutrition 0.000 abstract 2
- 239000000725 suspension Substances 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 abstract 1
- 235000011130 ammonium sulphate Nutrition 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 238000002425 crystallisation Methods 0.000 abstract 1
- 230000008025 crystallization Effects 0.000 abstract 1
- 238000006073 displacement reaction Methods 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 abstract 1
- 239000010419 fine particle Substances 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910000358 iron sulfate Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910000348 titanium sulfate Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/20—Preparation of aluminium oxide or hydroxide from aluminous ores using acids or salts
- C01F7/26—Preparation of aluminium oxide or hydroxide from aluminous ores using acids or salts with sulfuric acids or sulfates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/48—Halides, with or without other cations besides aluminium
- C01F7/56—Chlorides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/02—Oxides; Hydroxides
- C01G49/06—Ferric oxide [Fe2O3]
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Silicon Compounds (AREA)
Abstract
Procedure for obtaining alumina of metallurgical purity, by treatment of silico-aluminous materials containing Ti and Fe and less than 0.1% K2O, which includes a sulfuric attack on the mineral, the separation of the attack residue and the liquor from attack, the treatment of the attack residue, firstly by a displacement wash with the reunification of the displaced mother liquor and the attack liquor, and then the washing with water of the precipitate, obtaining AlCl3, 6H2O by addition of gaseous HCl to a solution containing dissolved AP2 (SO4) 3, the calcination of the chloride and the recycling of the effluents, the treatment of the liquor resulting from the washing of the attack residue, characterized in that the starting silico-aluminous matter is introduced into fine particles in a recycled solution containing by weight 49 to 59% free H2SO4 and 6 to 8% (NH4) 2S04 and containing residual amounts of various sulfates, because the suspension thus obtained is heated for 1 to 5 hours between 135ºC and 125ºC, because the liquor resulting from the attack is concentrated and cooled to precipitate an aluminum acid sulfate of formula (Al) 2 (SO4) 3, 0.5 H2SO4, 11 to 12 H2O, because This precipitate, after washing, is contacted with a concentrated solution of HC1 to constitute the solution or suspension to which the HCl gas is added, because the mother liquor resulting from the crystallization of the acid sulfate is used in part to displace the mother liquor that impregnates the attack residue and is added, in the other part, to the liquor resulting from the washing of the attack residue with water, because the liquor mixture is subjected to evaporation and is then kept at 80ºC for 2 to 3 hours to cause the precipitation of a complex iron, titanium and ammonium sulfate, which then decomposes into solid elements that are eliminated and into gaseous elements that are recycled. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7602061A FR2338898A1 (en) | 1976-01-20 | 1976-01-20 | PROCESS FOR OBTAINING PURE ALUMINA FROM A SILICO-ALUMINOUS MATERIAL CONTAINING TITANIUM AND FREE OF POTASSIUM |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES455122A1 true ES455122A1 (en) | 1977-12-16 |
Family
ID=9168382
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES455122A Expired ES455122A1 (en) | 1976-01-20 | 1977-01-18 | Production of metallurgically pure alumina |
Country Status (28)
| Country | Link |
|---|---|
| JP (1) | JPS5288599A (en) |
| AR (1) | AR220674A1 (en) |
| AT (1) | AT354980B (en) |
| AU (1) | AU505965B2 (en) |
| BE (1) | BE850569A (en) |
| CA (1) | CA1103462A (en) |
| CH (1) | CH599902A5 (en) |
| CS (1) | CS207377B2 (en) |
| DD (1) | DD127918A5 (en) |
| DE (1) | DE2701710C3 (en) |
| DK (1) | DK16877A (en) |
| EG (1) | EG13209A (en) |
| ES (1) | ES455122A1 (en) |
| FR (1) | FR2338898A1 (en) |
| GB (1) | GB1569033A (en) |
| HU (1) | HU175517B (en) |
| IL (1) | IL51265A (en) |
| IT (1) | IT1091558B (en) |
| MX (1) | MX144469A (en) |
| NL (1) | NL7700592A (en) |
| NO (1) | NO149626C (en) |
| NZ (1) | NZ183097A (en) |
| OA (1) | OA05532A (en) |
| PL (1) | PL104344B1 (en) |
| RO (1) | RO78297A (en) |
| SE (1) | SE423707B (en) |
| SU (1) | SU747412A3 (en) |
| ZA (1) | ZA77292B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2426019A1 (en) * | 1978-05-18 | 1979-12-14 | Pechiney Aluminium | CONTINUOUS PROCESS FOR OBTAINING PURE ALUMINA FROM AN ACIDIC LIQUOR FROM THE CHLOROSULFURIC ATTACK OF AN ALUMINOUS ORE AND FOR PURIFYING THE LIQUEUR CLEANED FROM THE ALUMINA |
| NO790460L (en) * | 1979-02-13 | 1980-08-14 | Elkem Spigerverket As | PREPARATION OF A PURE ALUMINUM OXIDE FROM SOLUTIONS CONTAINING DISSOLVED ALUMINUM AND IRON IONS |
| NO147516C (en) * | 1979-02-13 | 1983-04-27 | Elkem Spigerverket As | PROCEDURE FOR THE DEPOSIT OF A PURE ALUMINUM CHLORIDE FROM SOLUTIONS CONTAINING ALUMINUM AND MAGNESIUM IONS. |
| CA2321000C (en) | 1998-12-17 | 2005-05-24 | Nippon Light Metal Co., Ltd. | Method of producing highly pure aluminum primary base metal |
| CN102849765B (en) * | 2012-04-10 | 2014-05-21 | 沈阳金博新技术产业有限公司 | Method for preparing alumina from low-grade bauxite by acid leaching |
-
1976
- 1976-01-20 FR FR7602061A patent/FR2338898A1/en active Granted
- 1976-12-30 OA OA56034A patent/OA05532A/en unknown
-
1977
- 1977-01-13 CS CS77202A patent/CS207377B2/en unknown
- 1977-01-13 AR AR266183A patent/AR220674A1/en active
- 1977-01-14 SU SU772438251A patent/SU747412A3/en active
- 1977-01-14 IL IL51265A patent/IL51265A/en unknown
- 1977-01-15 RO RO7789064A patent/RO78297A/en unknown
- 1977-01-15 EG EG31/77A patent/EG13209A/en active
- 1977-01-17 DD DD7700196972A patent/DD127918A5/en unknown
- 1977-01-17 DE DE2701710A patent/DE2701710C3/en not_active Expired
- 1977-01-17 CH CH52677A patent/CH599902A5/xx not_active IP Right Cessation
- 1977-01-17 SE SE7700441A patent/SE423707B/en not_active IP Right Cessation
- 1977-01-17 NZ NZ183097A patent/NZ183097A/en unknown
- 1977-01-17 IT IT19360/77A patent/IT1091558B/en active
- 1977-01-17 DK DK16877A patent/DK16877A/en unknown
- 1977-01-18 PL PL1977195383A patent/PL104344B1/en unknown
- 1977-01-18 HU HU77PE1006A patent/HU175517B/en not_active IP Right Cessation
- 1977-01-18 ES ES455122A patent/ES455122A1/en not_active Expired
- 1977-01-18 CA CA269,979A patent/CA1103462A/en not_active Expired
- 1977-01-18 AU AU21406/77A patent/AU505965B2/en not_active Expired
- 1977-01-19 AT AT28577A patent/AT354980B/en not_active IP Right Cessation
- 1977-01-19 GB GB2141/77A patent/GB1569033A/en not_active Expired
- 1977-01-19 JP JP481077A patent/JPS5288599A/en active Granted
- 1977-01-19 ZA ZA00770292A patent/ZA77292B/en unknown
- 1977-01-19 NO NO770162A patent/NO149626C/en unknown
- 1977-01-19 MX MX167751A patent/MX144469A/en unknown
- 1977-01-20 BE BE174234A patent/BE850569A/en not_active IP Right Cessation
- 1977-01-20 NL NL7700592A patent/NL7700592A/en not_active Application Discontinuation
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19931029 |