ES443820A1 - Pesticidal compositions containing tetrasubstituted organotin compounds - Google Patents
Pesticidal compositions containing tetrasubstituted organotin compoundsInfo
- Publication number
- ES443820A1 ES443820A1 ES443820A ES443820A ES443820A1 ES 443820 A1 ES443820 A1 ES 443820A1 ES 443820 A ES443820 A ES 443820A ES 443820 A ES443820 A ES 443820A ES 443820 A1 ES443820 A1 ES 443820A1
- Authority
- ES
- Spain
- Prior art keywords
- carbon atoms
- straight
- alkyl
- branched
- branched chain
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title 1
- 230000000361 pesticidal effect Effects 0.000 title 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 26
- 125000000217 alkyl group Chemical group 0.000 abstract 14
- -1 nitro, acetyl Chemical group 0.000 abstract 11
- 229910052739 hydrogen Inorganic materials 0.000 abstract 5
- 239000001257 hydrogen Substances 0.000 abstract 5
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 5
- 125000003545 alkoxy group Chemical group 0.000 abstract 4
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 abstract 4
- 125000001624 naphthyl group Chemical group 0.000 abstract 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 125000004453 alkoxycarbonyl group Chemical group 0.000 abstract 2
- 125000004414 alkyl thio group Chemical group 0.000 abstract 2
- 125000002947 alkylene group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 235000010290 biphenyl Nutrition 0.000 abstract 2
- 239000004305 biphenyl Substances 0.000 abstract 2
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- 125000002868 norbornyl group Chemical group C12(CCC(CC1)C2)* 0.000 abstract 2
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 abstract 2
- 125000002941 2-furyl group Chemical group O1C([*])=C([H])C([H])=C1[H] 0.000 abstract 1
- 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 abstract 1
- 125000000339 4-pyridyl group Chemical group N1=C([H])C([H])=C([*])C([H])=C1[H] 0.000 abstract 1
- 125000004171 alkoxy aryl group Chemical group 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 125000001188 haloalkyl group Chemical group 0.000 abstract 1
- 125000003106 haloaryl group Chemical group 0.000 abstract 1
- 125000000717 hydrazino group Chemical group [H]N([*])N([H])[H] 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 abstract 1
- UKHQRARQNZOXRL-UHFFFAOYSA-N trimethyltin Chemical compound C[SnH](C)C UKHQRARQNZOXRL-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2224—Compounds having one or more tin-oxygen linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
Procedure for the preparation of tetrasubstituted organotin compounds, of general formula: **(See formula)** wherein R'is hydrogen, hydroxyl, alkoxy, or a straight or branched chain alkyl group having 1 to 5 carbon atoms; X is (a) -SO2R1, where R'is hydrogen, and where R3 is a straight or branched chain alkyl group having 1 to 18 carbon atoms, cyclohexyl, benzyl, phenyl or phenyl substituted with 1 or more groups than they can be the same or different and it can be a straight chain or branched alkyl group with 1 to 20 carbon atoms, cycloaliphatic groups with 4 to 6 carbon atoms, straight or branched chain alkenyl groups with 2 to 20 carbon atoms, alkoxy groups with 1 to 8 carbon atoms, alkylthio groups with 1 to 8 carbon atoms, phenoxy, halogen, nitro, acetyl, acetanido, carboxy, alkoxycarbonyl, carbamoyl, cyano, hydroxy, trifluoromethyl, benzyl, naphthyl or norbornyl; naphthyl, biphenyl, piperidinoethylmethiodide, -R2Sn (CH3) 3 where R2 is polymethylene with 2 to 11 carbon atoms, -R4S02R5Sn (CH3) 3 where R4 is ethylene and R5 is defined as above for R2; (b) -OR7, where R7 is a straight or branched chain alkyl with 1 to 20 carbon atoms, haloalkyl, aryl, haloaryl, alkaryl, alkoxyaryl, ethoxyalkylene where the alkylene group has 2 to 4 carbon atoms, N, N-dialkylamino-alkyl, tetrahydro-1,1-dioxo-3-thienyl, -R8Sn (CH3) 3 where r8 is alkylene with 2 to 11 carbon atoms, cycloaliphatic with 4 to 6 carbon atoms or aryl; (c) -SR-10 where R'is hydrogen, where R10 is a straight or branched chain alkyl with 1 to 18 carbon atoms, cyclohexyl, benzyl, phenyl or phenyl substituted with 1 or more groups that may be the same or different and which can be a linear or Branched alkyl with 1 to 20 carbon atoms, cycloaliphatic with 4 to 6 carbon atoms, straight or branched chain alkenyl with 2 to 20 carbon atoms, alkoxy with 1 to 8 carbon atoms, alkylthio with 1 to 8 carbon atoms, halogen, nitro, acetyl, acetamido, carboxy, alkoxycarbonyl, carbamyl, cyano, hydroxy, trifluoromethyl, benzyl, naphthyl or norbornyl; naphthyl, biphenyl, piperidinoethylmethiodide, -R2Sn (CH3) 3 where R2 is polymethylene with 2 to 11 carbon atoms, -R4SO2R5Sn (CH3) 3 where R4 is ethylene and R5 is defined as above for R2; (d) -C0R11 where R11 is -NH2, NHNH2, -NHCH2OH, -NHR12 where R12 is a straight or branched chain alkyl with 1 to 12 carbon or aryl atoms; -NHCH2NHCOR2Sn (CH3) 3, -OR13 where R13 is a straight chain or branched alkyl with 1 to 15 carbon atoms, - (CH2) m0H where m is an integer from 2 to 4, - (CH2) pN (R14) 2 where p is an integer from 2 to 4 and R14 is a straight or branched chain alkyl with 1 to 5 carbon atoms, - (CH2) qOCOR2Sn (CH3) 3 where q is defined internally for p, - (CH2) 5N (CH3) 3I where s is defined as above for p; (e) -NHCONH2; (f) -NHCSNH2; (g) 2-pyridyl; (h) 4-pyridyl; (i) 2-alkyl-5-pyridyl; (j) 9-carbazolyl; (k) 1-imidazolyl; (1) n-2-oxopyrrolidinyl; (m) -OCOR17 where R17 is -NHR18 where R18 is a straight chain or branched alkyl with 1 to 5 carbon or aryl atoms; 2-furyl; and -O (CH2) tSn (CH3) 3 where t is an integer from 2 to 11; (n) -PO (OR20) 2 where R20 is a straight chain or branched alkyl with 1 to 5 carbon atoms; (o) tetrahydro-1,1-dioxo-2-tenyl; (p) -Si (OR21) 3 where R21 is a straight chain or branched alkyl with 1 to 5 carbon atoms; (q) **(See formula)** (r) cyano; (s) OH; (t) **(See formula)** and n is an integer from 1 to 10; characterized in that it comprises reacting trimethyltin hydride with a compound containing an olefinic moiety and the structure **(See formula)** where X is defined as above, R'can be hydrogen, a straight chain or branched alkyl group with 1 to 5 carbon atoms or an alkoxy group with 1 to 5 carbon atoms, R''can be hydrogen, hydroxyl or an alkyl group with 1 to 5 carbon atoms and m is 0 to 9, the reaction being carried out in such a way that approximately equimolar amounts of the compound containing an olefinic moiety are mixed under an inert atmosphere, in a glass reaction vessel, after which is irradiated by a mercury vapor lamp for a time of approximately 4 to 232 hours, at a temperature of approximately 0 to 502ºC. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US53667974A | 1974-12-26 | 1974-12-26 | |
| US53667874A | 1974-12-26 | 1974-12-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES443820A1 true ES443820A1 (en) | 1977-11-16 |
Family
ID=27065218
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES443820A Expired ES443820A1 (en) | 1974-12-26 | 1975-12-23 | Pesticidal compositions containing tetrasubstituted organotin compounds |
| ES457899A Expired ES457899A1 (en) | 1974-12-26 | 1977-04-16 | Pesticidal compositions containing tetrasubstituted organotin compounds |
| ES457898A Expired ES457898A1 (en) | 1974-12-26 | 1977-04-16 | Pesticidal compositions containing tetrasubstituted organotin compounds |
| ES457897A Expired ES457897A1 (en) | 1974-12-26 | 1977-04-16 | Pesticidal compositions containing tetrasubstituted organotin compounds |
Family Applications After (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES457899A Expired ES457899A1 (en) | 1974-12-26 | 1977-04-16 | Pesticidal compositions containing tetrasubstituted organotin compounds |
| ES457898A Expired ES457898A1 (en) | 1974-12-26 | 1977-04-16 | Pesticidal compositions containing tetrasubstituted organotin compounds |
| ES457897A Expired ES457897A1 (en) | 1974-12-26 | 1977-04-16 | Pesticidal compositions containing tetrasubstituted organotin compounds |
Country Status (18)
| Country | Link |
|---|---|
| JP (1) | JPS51125220A (en) |
| AU (1) | AU507615B2 (en) |
| BG (6) | BG26397A3 (en) |
| BR (1) | BR7508582A (en) |
| CH (1) | CH613364A5 (en) |
| DD (2) | DD134323A5 (en) |
| DE (2) | DE2554790A1 (en) |
| DK (1) | DK588675A (en) |
| EG (1) | EG12249A (en) |
| ES (4) | ES443820A1 (en) |
| FR (1) | FR2355850A1 (en) |
| GB (2) | GB1542282A (en) |
| IL (1) | IL48716A (en) |
| LU (1) | LU74105A1 (en) |
| NL (1) | NL7514734A (en) |
| PL (3) | PL99515B1 (en) |
| SE (1) | SE7514546L (en) |
| SU (1) | SU594884A3 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1598451A (en) * | 1977-01-17 | 1981-09-23 | Netherlands Central Org Scient | Antifungal and/or antibacterial organotin compounds there preparation and uses |
| US4178382A (en) * | 1978-06-19 | 1979-12-11 | Uniroyal, Inc. | N-substituted triorganostannylhydro-carbylcarboxylic acid hydrazides |
| EP0077296B1 (en) * | 1981-10-08 | 1985-08-28 | Ciba-Geigy Ag | Organotin compounds |
| US5882356A (en) * | 1992-10-21 | 1999-03-16 | Courtaulds Fibres (Holdings) Limited | Fibre treatment |
| GB9304887D0 (en) * | 1993-03-10 | 1993-04-28 | Courtaulds Plc | Fibre treatment |
| GB9410912D0 (en) * | 1994-06-01 | 1994-07-20 | Courtaulds Plc | Fibre treatment |
| DE19726340C2 (en) * | 1996-08-16 | 1999-05-06 | Schering Ag | Tin dendrimers, their use as X-ray contrast media and process for their preparation |
| US6417366B2 (en) | 1999-06-24 | 2002-07-09 | Abbott Laboratories | Preparation of quinoline-substituted carbonate and carbamate derivatives |
-
1975
- 1975-12-05 DE DE19752554790 patent/DE2554790A1/en active Pending
- 1975-12-18 FR FR7538885A patent/FR2355850A1/en active Granted
- 1975-12-18 NL NL7514734A patent/NL7514734A/en not_active Application Discontinuation
- 1975-12-22 SE SE7514546A patent/SE7514546L/en unknown
- 1975-12-22 DD DD75198309A patent/DD134323A5/en unknown
- 1975-12-22 DD DD190457A patent/DD125544A5/xx unknown
- 1975-12-23 ES ES443820A patent/ES443820A1/en not_active Expired
- 1975-12-23 IL IL48716A patent/IL48716A/en unknown
- 1975-12-23 DK DK588675A patent/DK588675A/en unknown
- 1975-12-23 DE DE19752558163 patent/DE2558163A1/en not_active Withdrawn
- 1975-12-23 BR BR7508582*A patent/BR7508582A/en unknown
- 1975-12-23 CH CH1671875A patent/CH613364A5/en not_active IP Right Cessation
- 1975-12-24 AU AU87838/75A patent/AU507615B2/en not_active Expired
- 1975-12-24 LU LU74105A patent/LU74105A1/xx unknown
- 1975-12-24 PL PL1975186046A patent/PL99515B1/en unknown
- 1975-12-24 PL PL1975198721A patent/PL99516B1/en unknown
- 1975-12-24 PL PL1975198722A patent/PL99518B1/en unknown
- 1975-12-24 EG EG759/75A patent/EG12249A/en active
- 1975-12-25 JP JP50155747A patent/JPS51125220A/en active Pending
- 1975-12-26 BG BG7532848A patent/BG26397A3/xx unknown
- 1975-12-26 GB GB75@@3480778A patent/GB1542282A/en not_active Expired
- 1975-12-26 BG BG7500035346A patent/BG25229A3/en unknown
- 1975-12-26 SU SU752303951A patent/SU594884A3/en active
- 1975-12-26 GB GB7549030A patent/GB1542281A/en not_active Expired
- 1975-12-26 BG BG7531926A patent/BG26352A3/xx unknown
- 1975-12-26 BG BG7535348A patent/BG26672A4/xx unknown
- 1975-12-26 BG BG7500035347A patent/BG25520A3/en unknown
- 1975-12-26 BG BG7400035349A patent/BG25097A3/en unknown
-
1977
- 1977-04-16 ES ES457899A patent/ES457899A1/en not_active Expired
- 1977-04-16 ES ES457898A patent/ES457898A1/en not_active Expired
- 1977-04-16 ES ES457897A patent/ES457897A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EG12249A (en) | 1978-09-30 |
| AU507615B2 (en) | 1980-02-21 |
| JPS51125220A (en) | 1976-11-01 |
| FR2355850A1 (en) | 1978-01-20 |
| GB1542282A (en) | 1979-03-14 |
| DE2554790A1 (en) | 1976-07-01 |
| LU74105A1 (en) | 1976-11-11 |
| ES457898A1 (en) | 1978-11-01 |
| AU8783875A (en) | 1977-06-30 |
| ES457897A1 (en) | 1978-10-16 |
| CH613364A5 (en) | 1979-09-28 |
| DK588675A (en) | 1976-06-27 |
| IL48716A0 (en) | 1976-02-29 |
| IL48716A (en) | 1980-06-30 |
| BR7508582A (en) | 1976-08-24 |
| NL7514734A (en) | 1976-06-29 |
| ES457899A1 (en) | 1978-08-01 |
| GB1542281A (en) | 1979-03-14 |
| BG25097A3 (en) | 1978-07-12 |
| BG26352A3 (en) | 1979-03-15 |
| SU594884A3 (en) | 1978-02-25 |
| PL99516B1 (en) | 1978-07-31 |
| DD125544A5 (en) | 1977-05-04 |
| DE2558163A1 (en) | 1976-07-08 |
| BG25229A3 (en) | 1978-08-10 |
| DD134323A5 (en) | 1979-02-21 |
| BG25520A3 (en) | 1978-10-10 |
| PL99515B1 (en) | 1978-07-31 |
| BG26397A3 (en) | 1979-03-15 |
| FR2355850B1 (en) | 1981-10-23 |
| SE7514546L (en) | 1976-06-27 |
| PL99518B1 (en) | 1978-07-31 |
| BG26672A4 (en) | 1979-05-15 |
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