ES430503A1 - Procedure for treating metallic sulfurs containing iron. (Machine-translation by Google Translate, not legally binding) - Google Patents
Procedure for treating metallic sulfurs containing iron. (Machine-translation by Google Translate, not legally binding)Info
- Publication number
- ES430503A1 ES430503A1 ES74430503A ES430503A ES430503A1 ES 430503 A1 ES430503 A1 ES 430503A1 ES 74430503 A ES74430503 A ES 74430503A ES 430503 A ES430503 A ES 430503A ES 430503 A1 ES430503 A1 ES 430503A1
- Authority
- ES
- Spain
- Prior art keywords
- sulfur
- sulphides
- acid
- production
- iron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
Procedure for treating iron containing metal sulphides, for the massive separation of the iron content thereof and so that the non-ferrous metal values are susceptible of recovery separately, characterized by comprising the steps of: heating said iron content metal sulphides at a high temperature in a practically antioxidant atmosphere to eliminate labile sulfur; contacting said destabilized sulphides with a reducing gas capable of accepting sulfur to convert the sulphitic iron from said sulphides into an acid leachable form, said reducing gas being contacted, in countercurrent, with said destabilized sulphides, whereby the reaction products Fuels and the labile sulfur thereof can be burned in an adjustable way with sufficient oxygen to provide heat for said heating phase and to convert the sulfur values into SO2 that is discharged from said heating phase, subjecting said sulfides to leaching acidic in aqueous sulfuric acid to produce a solution of ferrous sulfate and a solid residue containing copper and iron in a molar ratio of at least about 1: 1, with simultaneous evolution of H2S gas; discharge said ferrous sulfate and solid residue for the subsequent separation, as well as the recovery of non-ferrous metal values and the production of sulfuric acid for recycling to said acid leaching; burn a part of said H2S gas; combining the burnt H2S with SO2 from the heating phase for the production of at least part of the sulfuric acid necessary in said acid leaching; and combine the remaining H2S with the remaining SO2 from said heating phase for the production of elemental sulfur, controlling the production of sulfuric acid and elemental sulfur to supply the acid needs of the acid leaching phase with excess sulfur produced as sulfur elemental, thereby practically eliminating the discharge of sulfur values into the atmosphere. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA182368 | 1973-08-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES430503A1 true ES430503A1 (en) | 1976-10-01 |
Family
ID=4097965
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES74430503A Expired ES430503A1 (en) | 1973-08-28 | 1974-09-28 | Procedure for treating metallic sulfurs containing iron. (Machine-translation by Google Translate, not legally binding) |
Country Status (1)
Country | Link |
---|---|
ES (1) | ES430503A1 (en) |
-
1974
- 1974-09-28 ES ES74430503A patent/ES430503A1/en not_active Expired
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