ES352710A1 - Catalyst preparation - Google Patents
Catalyst preparationInfo
- Publication number
- ES352710A1 ES352710A1 ES352710A ES352710A ES352710A1 ES 352710 A1 ES352710 A1 ES 352710A1 ES 352710 A ES352710 A ES 352710A ES 352710 A ES352710 A ES 352710A ES 352710 A1 ES352710 A1 ES 352710A1
- Authority
- ES
- Spain
- Prior art keywords
- silica
- aqueous medium
- urea
- carrier material
- medium containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 24
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 18
- 239000012736 aqueous medium Substances 0.000 abstract 13
- 239000000377 silicon dioxide Substances 0.000 abstract 12
- 239000004202 carbamide Substances 0.000 abstract 10
- 239000012876 carrier material Substances 0.000 abstract 9
- -1 hydroxyl ions Chemical class 0.000 abstract 7
- 229910052751 metal Inorganic materials 0.000 abstract 6
- 239000002184 metal Substances 0.000 abstract 6
- 239000002244 precipitate Substances 0.000 abstract 6
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 abstract 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 4
- 239000011149 active material Substances 0.000 abstract 4
- 230000003197 catalytic effect Effects 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 4
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 abstract 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- PHFQLYPOURZARY-UHFFFAOYSA-N chromium trinitrate Chemical compound [Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PHFQLYPOURZARY-UHFFFAOYSA-N 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 239000002243 precursor Substances 0.000 abstract 2
- 235000010288 sodium nitrite Nutrition 0.000 abstract 2
- 239000000725 suspension Substances 0.000 abstract 2
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 abstract 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N SnO2 Inorganic materials O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 abstract 1
- 229910052770 Uranium Inorganic materials 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 238000013019 agitation Methods 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 abstract 1
- 229940010552 ammonium molybdate Drugs 0.000 abstract 1
- 235000018660 ammonium molybdate Nutrition 0.000 abstract 1
- 239000011609 ammonium molybdate Substances 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052797 bismuth Inorganic materials 0.000 abstract 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract 1
- 229910000416 bismuth oxide Inorganic materials 0.000 abstract 1
- 239000012018 catalyst precursor Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 abstract 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 229960002089 ferrous chloride Drugs 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 abstract 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000002609 medium Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 abstract 1
- 229910000480 nickel oxide Inorganic materials 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000005049 silicon tetrachloride Substances 0.000 abstract 1
- 239000007790 solid phase Substances 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 abstract 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 abstract 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 abstract 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/18—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/26—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/42—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/882—Molybdenum and cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/393—Metal or metal oxide crystallite size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
- B01J37/035—Precipitation on carriers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
A supported metal-containing catalyst is prepared by a process which comprises pre- 'paring an aqueous medium comprising a soluble compound of a catalytic metal in solution and particulate carrier material in the solid phase e.g. alumina, titania or, silica, which compound forms a precipitate of catalytically-active material or precursor therefor on reaction with a hydroxyl ion, agitating the medium thereby to obtain a suspension of the carrier material, making available hydroxyl ions in the agitated suspension by an in situ generation of hydroxyl ions thereby to form a precipitate of catalytically-active material or precursor therefor, the rate at which the hydroxyl ions are made available being controlled at such a low rate that the precipitate is formed on the carrier material and not in the body of the aqueous medium and the agitation being controlled so that the concentration of hydroxyl ions is uniform throughout the aqueous medium thereby to provide a homogeneous distribution of precipitate in finely divided form on the carrier material, separating carrier material loaded with precipitate from the aqueous medium, and drying the separated carrier material loaded with precipitate to provide a catalyst which subsequently may be moulded to form artefacts having a predetermined shape and size. The artefacts may include thermostable filler material. The catalyst and/or the artefacts moulded therefrom may be calcined alternatively or subsequently, the catalyst and/or the artefacts moulded therefrom may be heated under reducing conditions, for example in a stream of hydrogen. The catalytically-active material supported by the carrier material preferably has a particle size not greater than 50 the weight ratio of catalytically-active material to carrier material may be between 0À1 to 1 and 3 to 1 and preferably is not more than 2 to 1. The hydroxyl ions may be made available by the provision in the aqueous medium of urea and/or nitrite ions, which nitrite ions may be provided by the use of a nitrite as the soluble compound of the catalytic metal alternatively, such soluble compound may be a chloride, a nitrate or a sulphate. The carrier material, preferably has a specific surface area of about 150 m.2/g. The catalytic metal may be tin, lead, vanadium, antimony, bismuth, chromium, uranium, manganese, iron, cobalt or nickel and may be present in the form of elemental metal or an oxide thereof the catalyst may contain two or more catalytic metals or oxides thereof which may be in the form of a salt, for example a vanadate, a molybdate or a tungstate. Catalysts referred to include silica-elemental nickel obtained by reduction, for example with hydrogen, of a silicanickel oxide catalyst precursor prepared from an aqueous medium containing silica, nickel nitrate, sodium nitrite and urea (Example 1) or silica, nickel nitrate and urea (Example 2) or silica, nickel nitrate and sodium nitrite (Example 10) silica-bismuth oxide prepared from an aqueous medium containing silica, bismuth nitrate and urea (Example 3) silica-cobalt molybdate prepared from an aqueous medium containing silica, cobalt nitrate, ammonium molybdate and urea (Example 4) silicachromium oxide prepared from an aqueous medium containing silica, chromium nitrate and urea (Example 5) silica-stannic oxide prepared from an aqueous medium containing silica, stannic chloride and urea (Example 6) silicaplatinum prepared from an aqueous medium containing silica chloroplatinic acid and urea (Example 7) titania-nickel oxide prepared from an aqueous medium containing titania, nickel nitrate and urea (Example 8) and silica-ferric oxide prepared from an aqueous medium containing silica, ferrous chloride and urea (Example 9). The silica used is a commerciallyavailable highly-porous silica obtained from silicon tetrachloride by flame hydrolysis.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL676705259A NL143139B (en) | 1967-04-14 | 1967-04-14 | PROCESS FOR PREPARING A CARRIER CATALYST BY TREATING A CARRIER WITH A SOLUTION OF A SALT OF A CATALYTIC ACTIVE ELEMENT. |
| NL676712004A NL145778B (en) | 1967-04-14 | 1967-08-31 | IMPROVEMENT OF A METHOD FOR PREPARING A CATALYST. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES352710A1 true ES352710A1 (en) | 1970-04-16 |
Family
ID=26644180
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES352710A Expired ES352710A1 (en) | 1967-04-14 | 1968-03-13 | Catalyst preparation |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS502398B1 (en) |
| AT (1) | AT289040B (en) |
| BE (1) | BE713656A (en) |
| CH (1) | CH517522A (en) |
| DE (1) | DE1767202C3 (en) |
| DK (1) | DK124925B (en) |
| ES (1) | ES352710A1 (en) |
| FR (1) | FR1569895A (en) |
| GB (1) | GB1220105A (en) |
| NL (2) | NL143139B (en) |
| SE (1) | SE345393B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112619659A (en) * | 2020-12-18 | 2021-04-09 | 齐鲁工业大学 | Nickel oxide nanosheet and bismuth molybdate nanofiber heterojunction photocatalytic material as well as preparation method and application thereof |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4113658A (en) * | 1967-04-14 | 1978-09-12 | Stamicarbon, N.V. | Process for homogeneous deposition precipitation of metal compounds on support or carrier materials |
| FR1573174A (en) * | 1968-04-10 | 1969-07-04 | ||
| LU57716A1 (en) * | 1968-12-30 | 1970-07-01 | ||
| LU58391A1 (en) * | 1969-04-09 | 1970-11-09 | ||
| US4077912A (en) * | 1972-10-12 | 1978-03-07 | Standard Oil Company | Catalysts useful for exothermic reactions |
| US3853791A (en) * | 1973-02-06 | 1974-12-10 | American Cyanamid Co | Oxide and molybdenum oxide on an alumina support and catalyst obtained |
| US4073750A (en) * | 1976-05-20 | 1978-02-14 | Exxon Research & Engineering Co. | Method for preparing a highly dispersed supported nickel catalyst |
| NL7703762A (en) * | 1977-04-06 | 1978-10-10 | Stamicarbon | PROCEDURE FOR PREPARING CATALYST ON SUPPORT SYSTEMS. |
| HU177860B (en) * | 1979-05-22 | 1982-01-28 | Mta Koezponti Hivatala | Method for producing carrier metal catalyzers |
| GB2080135B (en) * | 1980-07-16 | 1984-05-10 | Dyson Refractories | A method of preparing a supported catalyst |
| GB2080136B (en) * | 1980-07-16 | 1984-05-16 | Dyson Refractories | Coprecipitated modified nickel catalysts |
| DE3131257C2 (en) * | 1981-08-07 | 1986-10-30 | VEG-Gasinstituut N.V., Apeldoorn | Process for removing hydrogen sulfide from gases |
| DE3131255C2 (en) * | 1981-08-07 | 1986-02-13 | VEG-Gasinstituut N.V., Apeldoorn | Process for the preparation of a ferric oxide catalyst or absorbent |
| NL8200544A (en) * | 1982-02-12 | 1983-09-01 | Veg Gasinstituut Nv | METHOD FOR PREPARING METHANE FROM CARBON MONOXIDE-CONTAINING GAS MIXTURES USING CATALYSTS USING NICKEL |
| DE3228482C2 (en) * | 1982-07-30 | 1986-09-11 | VEG-Gasinstituut N.V., Apeldoorn | Process for the reaction of carbon monoxide with water vapor to form carbon dioxide and hydrogen and the use of a catalyst therefor |
| DE3228481A1 (en) * | 1982-07-30 | 1984-02-02 | VEG-Gasinstituut N.V., 7300 Apeldoorn | REACTION MEASURES, METHOD FOR THEIR PRODUCTION AND THEIR USE |
| GB2144446A (en) * | 1983-08-04 | 1985-03-06 | Veg Gasinstituut Nv | Process for the production of methane rich gases |
| DE3347676A1 (en) * | 1983-12-31 | 1985-07-11 | VEG-Gasinstituut N.V., Apeldoorn | COPPER-NICKEL CATALYST, METHOD FOR PRODUCING THE SAME AND THE USE THEREOF |
| DE3347677C2 (en) * | 1983-12-31 | 1987-02-26 | VEG-Gasinstituut N.V., Apeldoorn | Process for producing a catalyst |
| SE8402916L (en) * | 1984-01-30 | 1985-07-31 | Eka Ab | CATALYTIC EXHAUST CLEANER AND WAY TO MAKE IT |
| BR8504994A (en) * | 1984-01-30 | 1986-01-21 | Eka Ab | LOAD OR SUPPORT FOR CATALYTICALLY ACTIVE SUBSTANCES, A PROCESS TO PRODUCE THAT LOAD OR SUPPORT, A CATALYST PRODUCED FROM THAT SUPPORT, AND THE USE OF THAT CATALYST |
| SE8400426L (en) * | 1984-01-30 | 1985-07-31 | Eka Ab | SET TO MAKE FINE PARTICLES WITH A COATING OF METAL OR METAL COMPOUND, SPECIFICALLY A CATALYTIC ACTIVE SUBSTANCE |
| EP1101734A3 (en) * | 1999-11-19 | 2003-01-15 | Praxair Technology, Inc. | Purification of argon |
| DE10054457A1 (en) * | 2000-11-03 | 2002-05-08 | Sued Chemie Ag | Catalyst for oxidation of methane to formaldehyde and methanol comprises a silica support having a specified iron content |
| GB0214383D0 (en) * | 2002-06-21 | 2002-07-31 | Isis Innovation | Catalyst |
| WO2005056164A1 (en) * | 2003-12-05 | 2005-06-23 | Jayalekshmy Ayyer | A catalyst useful for h2s removal from gas stream preparation thereof and use thereof |
| CA2887849A1 (en) | 2012-11-06 | 2014-05-15 | H R D Corporation | Reactor and catalyst for converting natural gas to organic compounds |
| US10626064B2 (en) | 2018-05-30 | 2020-04-21 | Exxonmobil Chemical Patents Inc. | Processes to make neopentane using shell and tube reactors |
| US10994264B2 (en) | 2018-05-30 | 2021-05-04 | Exxonmobil Chemical Patents Inc. | Catalysts and processes for making catalysts for producing neopentane |
| JP7194629B2 (en) * | 2019-03-29 | 2022-12-22 | 日揮触媒化成株式会社 | Nickel catalyst and its production method |
-
1967
- 1967-04-14 NL NL676705259A patent/NL143139B/en not_active IP Right Cessation
- 1967-08-31 NL NL676712004A patent/NL145778B/en unknown
-
1968
- 1968-03-13 ES ES352710A patent/ES352710A1/en not_active Expired
- 1968-04-10 DK DK161368AA patent/DK124925B/en not_active IP Right Cessation
- 1968-04-10 CH CH537168A patent/CH517522A/en not_active IP Right Cessation
- 1968-04-11 AT AT361568A patent/AT289040B/en not_active IP Right Cessation
- 1968-04-11 GB GB07620/68A patent/GB1220105A/en not_active Expired
- 1968-04-11 DE DE1767202A patent/DE1767202C3/en not_active Expired
- 1968-04-12 BE BE713656D patent/BE713656A/xx not_active IP Right Cessation
- 1968-04-12 FR FR1569895D patent/FR1569895A/fr not_active Expired
- 1968-04-13 JP JP43024721A patent/JPS502398B1/ja active Pending
- 1968-04-16 SE SE5075/68A patent/SE345393B/xx unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112619659A (en) * | 2020-12-18 | 2021-04-09 | 齐鲁工业大学 | Nickel oxide nanosheet and bismuth molybdate nanofiber heterojunction photocatalytic material as well as preparation method and application thereof |
| CN112619659B (en) * | 2020-12-18 | 2022-09-16 | 齐鲁工业大学 | Nickel oxide nanosheet and bismuth molybdate nanofiber heterojunction photocatalytic material as well as preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| AT289040B (en) | 1971-03-25 |
| NL143139B (en) | 1974-09-16 |
| NL6712004A (en) | 1969-03-04 |
| BE713656A (en) | 1968-10-14 |
| SE345393B (en) | 1972-05-29 |
| GB1220105A (en) | 1971-01-20 |
| FR1569895A (en) | 1969-06-06 |
| DE1767202B2 (en) | 1974-09-05 |
| DE1767202C3 (en) | 1975-05-22 |
| CH517522A (en) | 1972-01-15 |
| DK124925B (en) | 1972-12-11 |
| NL145778B (en) | 1975-05-15 |
| DE1767202A1 (en) | 1971-03-18 |
| JPS502398B1 (en) | 1975-01-25 |
| NL6705259A (en) | 1968-10-15 |
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