ES332202A1 - A procedure for the recyclation of ammonia and carbon dioxide not converted in urea, to the autoclave of synthesis, in the urea synthesis. (Machine-translation by Google Translate, not legally binding) - Google Patents

A procedure for the recyclation of ammonia and carbon dioxide not converted in urea, to the autoclave of synthesis, in the urea synthesis. (Machine-translation by Google Translate, not legally binding)

Info

Publication number
ES332202A1
ES332202A1 ES0332202A ES332202A ES332202A1 ES 332202 A1 ES332202 A1 ES 332202A1 ES 0332202 A ES0332202 A ES 0332202A ES 332202 A ES332202 A ES 332202A ES 332202 A1 ES332202 A1 ES 332202A1
Authority
ES
Spain
Prior art keywords
ammonia
expansion
urea
carbon dioxide
synthesis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES0332202A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Inventa AG fuer Forschung und Patentverwertung
Original Assignee
Inventa AG fuer Forschung und Patentverwertung
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inventa AG fuer Forschung und Patentverwertung filed Critical Inventa AG fuer Forschung und Patentverwertung
Publication of ES332202A1 publication Critical patent/ES332202A1/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/02Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds
    • C07C273/04Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A procedure for the recycling of ammonia and carbon dioxide not converted to urea, to the synthesis autoclave, in the synthesis of urea from ammonia and carbon dioxide carried out with excess ammonia at elevated pressure and at elevated temperature, characterized in that the mixture of urea, water, ammonium carbamate and excess ammonia, which exits, from the synthesis autoclave that is under high pressure, is expanded in (at least) two stages of pressure for the separation of the exhaust gases not converted to urea , so that the expansion gases of ammonia and carbon dioxide that result in the first expansion stage, together with the gases expelled from the melt remaining by heating at the same pressure, which consist of excess ammonia and ammonia and carbon dioxide from decomposed ammonium carbamate, are conducted to a condenser that is under the same pressure, and because the expansion and decomposition resulting in a second stage of expansion under lower pressure, are absorbed in aqueous solution of ammonium carbonate, solution that is then brought to the pressure of the first stage of expansion and is released by heating the absorbed ammonia and carbon dioxide , after which the expelled gases, considerably dehydrated, are conducted to the condenser which is under the same pressure as the first stage of expansion and there they are condensed together with the expansion and decomposition gases of the first stage of expansion to obtain a Very concentrated solution of ammonia and carbon dioxide in little water, solution that is then pumped back to the synthesis reactor. (Machine-translation by Google Translate, not legally binding)
ES0332202A 1965-10-15 1966-10-13 A procedure for the recyclation of ammonia and carbon dioxide not converted in urea, to the autoclave of synthesis, in the urea synthesis. (Machine-translation by Google Translate, not legally binding) Expired ES332202A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH1427665A CH456569A (en) 1965-10-15 1965-10-15 Process for the separation and recycling of starting gases not converted in the synthesis of urea from ammonia and carbon dioxide into the synthesis reactor

Publications (1)

Publication Number Publication Date
ES332202A1 true ES332202A1 (en) 1967-11-16

Family

ID=4399474

Family Applications (1)

Application Number Title Priority Date Filing Date
ES0332202A Expired ES332202A1 (en) 1965-10-15 1966-10-13 A procedure for the recyclation of ammonia and carbon dioxide not converted in urea, to the autoclave of synthesis, in the urea synthesis. (Machine-translation by Google Translate, not legally binding)

Country Status (4)

Country Link
CH (1) CH456569A (en)
DE (1) DE1568879A1 (en)
ES (1) ES332202A1 (en)
NL (1) NL6614496A (en)

Also Published As

Publication number Publication date
CH456569A (en) 1968-07-31
DE1568879A1 (en) 1970-04-02
NL6614496A (en) 1967-04-17

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