ES330193A1 - A procedure of continuous copolimerization in constant condition to constitute a polymer. (Machine-translation by Google Translate, not legally binding) - Google Patents

A procedure of continuous copolimerization in constant condition to constitute a polymer. (Machine-translation by Google Translate, not legally binding)

Info

Publication number
ES330193A1
ES330193A1 ES0330193A ES330193A ES330193A1 ES 330193 A1 ES330193 A1 ES 330193A1 ES 0330193 A ES0330193 A ES 0330193A ES 330193 A ES330193 A ES 330193A ES 330193 A1 ES330193 A1 ES 330193A1
Authority
ES
Spain
Prior art keywords
monomers
polymer
weight
reaction zone
monomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES0330193A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
JR Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JR Geigy AG filed Critical JR Geigy AG
Publication of ES330193A1 publication Critical patent/ES330193A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1862—Stationary reactors having moving elements inside placed in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00162—Controlling or regulating processes controlling the pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00182—Controlling or regulating processes controlling the level of reactants in the reactor vessel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/08—Hydraulic fluids, e.g. brake-fluids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/015—Dispersions of solid lubricants
    • C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Lubricants (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

A continuous copolymerization process in a constant state to form a polymer, randomly improving the viscosity index, for lubricating oil, characterized in that it comprises: feeding to a reaction zone, on a constant average, at least two aliphatic alpha-olefinic monomers M1 and M2, of which M1 have the smallest number of carbon atoms, while M1 and M2 contain together at least 6 already sums 11 carbon atoms, and in the case of polymers of more than 2 monomers, the subsequent aliphatic alpha-olefin monomer M3, other than M1 and M2, containing at least as many carbon atoms as M2; and the monomers being chosen exclusively between and in the case of polymers derived from 2 monomers; - feed a diluent to said reaction zone, at a constant average; - feeding a stereospecific catalyst to said reaction zone, at a constant average; - maintaining in said reaction zone a pressure between approximately 100 and 1000 psig and a temperature between about 50º C and about 120º C, in order to copolymerize said monomers until a conversion (c) of 20 to 90% by weight of M1 is obtained, the composition being of the feeding of said monomers, the temperature inºC (t) and the inter-related conversion (c) according to the formula ** (See formula) ** with the proviso that b1 <= X <= bh, where X represents the percentage weight with respect to the total weight of the monomer feed, while cyt is the conversion and temperature and a1, ah, b1 and bh are chosen from the following values : (see graphic) the amount of M3 in the feed being from 0 to 15% by weight with respect to the total weight of the monomers fed, while constituting the rest of the composition of the feed; and continuously extracting unreacted polymer and monomer from the reaction zone, with an average such that a mass balance is maintained between the fed monomer and the monomer and polymer extracted from said zone; - deactivating the catalyst and, if necessary, further processing the polymer in solution, to reduce the average molecular weight of viscosity to the level of 200,000 to 1,000,000 and to extract the insoluble material in n-heptane at 60º C in excess of 0.5% by weight of the total weight, of polymer. (Machine-translation by Google Translate, not legally binding)
ES0330193A 1965-08-13 1966-08-12 A procedure of continuous copolimerization in constant condition to constitute a polymer. (Machine-translation by Google Translate, not legally binding) Expired ES330193A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US47941565A 1965-08-13 1965-08-13
US47941665A 1965-08-13 1965-08-13

Publications (1)

Publication Number Publication Date
ES330193A1 true ES330193A1 (en) 1967-06-01

Family

ID=27046235

Family Applications (1)

Application Number Title Priority Date Filing Date
ES0330193A Expired ES330193A1 (en) 1965-08-13 1966-08-12 A procedure of continuous copolimerization in constant condition to constitute a polymer. (Machine-translation by Google Translate, not legally binding)

Country Status (8)

Country Link
AT (1) AT283560B (en)
BE (1) BE685485A (en)
CH (1) CH484208A (en)
DE (1) DE1595760A1 (en)
ES (1) ES330193A1 (en)
GB (1) GB1146189A (en)
NL (1) NL6611408A (en)
SE (1) SE324853B (en)

Also Published As

Publication number Publication date
NL6611408A (en) 1967-02-14
GB1146189A (en) 1969-03-19
SE324853B (en) 1970-06-15
CH484208A (en) 1970-01-15
DE1595760A1 (en) 1970-04-23
BE685485A (en) 1967-02-13
AT283560B (en) 1970-08-10

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