ES272034A1 - New polyaddition resins - Google Patents

New polyaddition resins

Info

Publication number
ES272034A1
ES272034A1 ES0272034A ES272034A ES272034A1 ES 272034 A1 ES272034 A1 ES 272034A1 ES 0272034 A ES0272034 A ES 0272034A ES 272034 A ES272034 A ES 272034A ES 272034 A1 ES272034 A1 ES 272034A1
Authority
ES
Spain
Prior art keywords
pyran
dihydro
methyl
bis
ester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES0272034A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of ES272034A1 publication Critical patent/ES272034A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M3/00—Liquid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single liquid substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G67/00—Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing oxygen or oxygen and carbon, not provided for in groups C08G2/00 - C08G65/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G71/00—Macromolecular compounds obtained by reactions forming a ureide or urethane link, otherwise, than from isocyanate radicals in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/04—Polythioethers from mercapto compounds or metallic derivatives thereof
    • C08G75/045—Polythioethers from mercapto compounds or metallic derivatives thereof from mercapto compounds and unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/082—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/101—Condensation polymers of aldehydes or ketones and phenols, e.g. Also polyoxyalkylene ether derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2213/04—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions obtained from monomers containing carbon, hydrogen, halogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2213/06—Perfluoro polymers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/028—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2221/02—Macromolecular compounds obtained by reactions of monomers involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2221/04—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2221/043—Polyoxyalkylene ethers with a thioether group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/08—Hydraulic fluids, e.g. brake-fluids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/46—Textile oils

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

In examples: (16( adipic acid-bis-(2,3-dihydro-4H-pyran-2-yl-methyl ester is prepared from the corresponding alcohol and adipic acid dichloride. (18) Bis-(2,3-dihydro-4H-pyran-2-yl) formal is prepared from divinyl formal and acrolein (19) Ethylene glycol-bis-(2,3-dihydro-4H-pyran-2-yl) ether is prepared from ethylene glycol divinyl ether and acrolein (22) Oxalic acid - bis - (2,3 - dihydro - 4H - pyran - 2 - yl-methyl) ester is prepared from oxalalyl chloride and the corresponding methanol derivation (23) and (24) The succinic acid di-ester and the tri-phosphate are similarly prepared (25) Bis - (2,3 - dihydro - 4H - pyran - 2 - yl - methyl) carbonate is prepared from phosgene and the appropriate methanol derivative (28) Toluene-2,4 - bis - (carbamic acid - 21,31 - dihydro - 41H-pyran-21-yl-methyl ester) is prepared from toluene-2,4-diisocyanate and 2,3-dihydro-4H-pyran-2-yl-methanol (29) Ethylene diamine-bis-(2,3-dihydro - 4H - pyran - 2 - methyl - 2 - carboxylic acid) amide is prepared from ethylene diamine and 2,3 - dihydro - 4H - pyran - 2 8 methyl - 2-carboxylic acid methyl ester (30) and (31) Ethylene glycol - bis - (2,3 - dihydro - 4H - pyran-2-methyl-2-carboxylic acid) ester is prepared from ethylene glycol and 2,3-dihydro-4H-pyran-2-methyl-2-carboxyli acid methyl ester, and Hexanetriol - bis - (2,3 - dihydro - 4H - pyran-2-methyl-2-carboxylic acid) ester and pentaery-thritol - bis - (2,3 - dihydro - 4H - pyran - 2 - methyl-2-carboxylic acid) ester are prepared from hexanetriol or pentaerythritol and the same methyl ester.ALSO:Polyaddition resins are prepared by reacting (1) a compound of the general formula <FORM:0996705/C3/1> in which R is H or CH3 n=2 to 6 and Z is either -COOCH2- (in which case n=2) or -[-COO-]-nY, where Y is the hydrocarbon residue of a polyol or -[-CH2O-]-nX, where X is the ester residue of a polycarboxylic or inorganic acid of basicity n, or an alkylidene group (in which case n=2), or the hydrocarbon residue of a polyol or -[-O-]-nR1, where R1 is the hydrocarbon residue of a polyol or an alkylidene group (in which case n=2) or -[-OCONH-]-nR2, or -[-CH2OCONH-]-nR2, where R2 is a hydrocarbon radical of valency n, with (2) a compound containing at least two groups chosen from hydroxyl, mercapto, carboxyl, amide, acetal and ortho-ester groups. Preferably, an acid catalyst is used, unless compound (2) above is strongly acidic. Suitable starting materials are listed. If desired, a precondensate may first be formed, and cured by further reaction, e.g. with polyols, polyesters, phenolic or epoxy resins. Products may be linear or cross-linked. Conventional additives, e.g. fillers, plasticizers or colouring matters may be added before curing. In Examples 1-15, 20, 21, compound (1) is 2,3-dihydro - 4H - pyran - 2 - carboxylic acid-(21,31-dihydro - 41H - pyran - 21 - yl) - methyl ester. It is reacted with: Example 1. Ethylene glycol. 2. Glycerol. 3. A polyester from glycerol and phthalic anhydride. 4. Oxalic acid. 5. A polyester from adipic acid and glycol. 6. A hexanetriol-phthalate resin. 7. A mixture of 1,2,6-hexanetriol and phenol. 8. A mixture of trimethylolpropane and 1,1 - bis - (41 - hydroxyphenyl) ethane. 9. A hydroxylated ester from ethylene glycol, trimethylol ethane, and succinic anhydride. 10. A mixture of 1,4-bis-(hydroxymethyl) - benzene, phenol and diglycerol. 11. A mixture of glyoxal-tetramethylacetal and trimethylolpropane. 12. A mixture of a hydroxylated ester from ethylene glycol, trimethylol ethane, and succinic anhydride, with a liquid polymeric polysulphide known as "Thiokol LP-3" (Registered Trade Mark). 13. A mixture of thiourea and glycerol. 14. A mixture of trimethylolpropane and e -caprolactam. 15. A mixture of trimethylolpropane and an epoxy resin from 2,2-bis-(p-hydroxyphenyl)-propane and epichlorhydrin. 20. A mixture of trimethylol propane and e -caprolactone. 21. Polyvinyl alcohol. The other examples are as follows: 16. Adipic acid-bis-(2,3-dihydro-4H -pyran-2-yl-methyl ester) is reacted with e -caprolactone and trimethylolpropane. 17. Excess 2,3 - dihydro - 4H - pyran - 2 - carboxylic acid - (21,31 - hydro - 41H - pyran - 21 - yl) methyl ester is reacted with ethylene glycol-di-(2 -hydroxypropyl) ether. The product may be subsequently reacted with the hydroxylated ester of Example 9. 18. Bis-(2,3-dihydro-4H -pyran-2-yl)-formal is reacted with the hydroxylated ester of Example 9. 19. Ethylene glycolbis - (2,3 - dihydro - 4H - pyran - 2 - yl) ether is reacted with a mixture of phenol and 1,2,6-hexanetriol. 22. Oxalic acid bis-(2,3-dihydro - 4H - pyran - 2 - yl - methyl) ester is reacted with (a) 1,2,6-hexanetriol, or (b) trimethylolpropane. Other examples use succinic acid-bis -(2,3 - dihydro - 4H - pyran - 2 - yl - methyl) ester tri - (2,3 - dihydro - 4H - pyran - 2 - yl - methyl) phosphate bis - (2,3 - dihydro - 4H - pyran - 2 - yl - methyl) carbonate diphenyl-di -(2,3 - dihydro - 4H - pyran - 2 - yl - methyl) orthosilicate (prepared from 2,3-dihydro-4H -pyran-2-yl-methanol and diphenoxy dichlorosilane a urethane prepared from an adduct of hexanetriol and m-phenylene diisocyanate, and 2,3 - dihydro - 4H - pyran - 2 - yl - methanol toluene - 2,4 - bis - (carbamic acid - 21,31 - di - hydro - 41H - pyran - 21 - yl - methyl ester) Ethylene diamine - bis - (2,3 - dihydro - 4H - pyran - 2 - methyl - 2 - carboxylic acid)-amide ethylene glycol - bis - (2,3 - dihydro - 4H-pyran -2 - methyl - 2 - carboxylic acid) ester hexane triol - bis - (2,3 - dihydro - 4H - pyran - 2 - methyl - 2 - carboxylic acid) ester and pentaerythritol - bis - (2,3 - dihydro - 4H - pyran - 2 - methyl - 2 - carboxylic acid) ester.ALSO:In Example 3, a glycerol-phthalic anhydride resin is dissolved in isobutyl acetate and 213-dihydro-4H-pyran-2-carboxylic acid-[2131-dihydro-41H-pyran-21-yl] -methyl ester and hydrochloric acid is added. The solution is distributed over an aluminium sheet, solvent evaporated and the lacquer coat stoved.
ES0272034A 1960-11-16 1961-11-15 New polyaddition resins Expired ES272034A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH1281960A CH428234A (en) 1960-11-16 1960-11-16 Curable mixtures

Publications (1)

Publication Number Publication Date
ES272034A1 true ES272034A1 (en) 1962-04-16

Family

ID=4386656

Family Applications (1)

Application Number Title Priority Date Filing Date
ES0272034A Expired ES272034A1 (en) 1960-11-16 1961-11-15 New polyaddition resins

Country Status (6)

Country Link
BE (1) BE610417A (en)
CH (1) CH428234A (en)
DE (1) DE1445315B2 (en)
ES (1) ES272034A1 (en)
GB (1) GB996705A (en)
NL (2) NL271416A (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1101343A (en) * 1963-12-30 1968-01-31 Ici Ltd Isocyanate-containing vinyl ether foams
US3429853A (en) * 1964-07-24 1969-02-25 Shell Oil Co Process for preparing prepolymers of unsaturated heterocyclic compounds and resulting products
DE2861226D1 (en) * 1977-06-28 1981-12-10 Univ Strathclyde A pharmaceutical composition for tropical diseases
EP0475107B1 (en) * 1990-08-30 1995-02-15 Th. Goldschmidt AG Use of 2-(2'-propenyl)-3,4-dihydro-2H-pyranes
DE4042353C2 (en) * 1990-08-30 1995-04-06 Goldschmidt Ag Th Use of 2- (2'-propenyl) -3,4-dihydro-2H-pyrans

Also Published As

Publication number Publication date
NL134014C (en) 1900-01-01
DE1445315A1 (en) 1968-12-19
GB996705A (en) 1965-06-30
NL271416A (en) 1900-01-01
DE1445315B2 (en) 1972-04-13
CH428234A (en) 1967-01-15
BE610417A (en) 1900-01-01

Similar Documents

Publication Publication Date Title
US3298981A (en) Polyhydroxyethers of 1, 4-cyclohexane-dimethanol
US3535287A (en) Polyurethanes based on three-component polyester oligomers
JPS60156781A (en) Two component polyurethane adhesive
GB694978A (en) Diisocyanate-modified polyester or polyesteramide elastomers
GB1072956A (en) Esters of diisocyanato carboxylic acids and reaction products thereof
CH646428A5 (en) COMPOUNDS HAVING ALDIMINE AND OXAZOLIDING GROUPS, METHOD FOR THE PRODUCTION THEREOF AND THE USE THEREOF AS A HARDENER FOR POLYISOCYANATE.
US4102862A (en) Application of cumylphenol and derivatives thereof in plastic compositions
US3458527A (en) Certain epoxy-containing 2-oxazolidinones
ES272034A1 (en) New polyaddition resins
DE2428408A1 (en) MIXED ESTERS OF MULTI BASIC SATURATED ACIDS, GLYCOLS AND GLYCIDYLESTERS
US4602071A (en) Process for the production of oligourethanes containing mercapto groups and their use as binders for coating and sealing compositions hardenable by oxidation and as additives for epoxide resins
US4742125A (en) Process for the production of mercapto group-containing oligourethanes, oligourethanes obtainable by this process and their use in various polymer systems
US3634306A (en) Moisture-curing polyurethanes soluble in mineral spirits
US3282896A (en) Linear polyurethanes formed by reacting dimethylol phenol with a diisocyanate
JPS6232119A (en) Polyhydroxyl compound having ether group and ester group andits use in production of polyurethane plastic
DE1570382B2 (en) USE OF A MERCAPTOCARBON ACID ESTER IN MASSES BASED ON EPOXY RESIN AS A FLEXIBILIZER
US2907745A (en) Polyurethane of a polyisocyanate, an active hydrogen compound, and a hydroxyaryl aliphatic acid
US3591590A (en) Diisocyanates
GB921041A (en) Resins prepared from polyspiranes and an isocyanate material
DE69011372T2 (en) Diester and ketoester derivatives of polyhydroxy compounds and their production.
US3225065A (en) Diester compositions formed by the reaction of pyromellitic dianhydride and polyhydric alcohols
EP0510674B1 (en) Urea-superacid salts and their use as a curing catalyst of epoxy resins
EP0738741A2 (en) Epoxy(meth)acrylates, a process for their preparation and their use
US3284487A (en) Adducts of orthocarboxylates and isocyanates and their preparation
JP2884149B2 (en) Epoxy resin curing agent and one-pack type epoxy resin composition