ES2712324A1 - PROCESS OF TREATMENT OF PURINES AND PLANT TO CARRY OUT SUCH PROCESS (Machine-translation by Google Translate, not legally binding) - Google Patents
PROCESS OF TREATMENT OF PURINES AND PLANT TO CARRY OUT SUCH PROCESS (Machine-translation by Google Translate, not legally binding) Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/38—Treatment of water, waste water, or sewage by centrifugal separation
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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Abstract
Description
PROCESO DE TRATAMIENTO DE PURINES Y PLANTA PARA LLEVAR A CABO DICHO PROCESS OF TREATMENT OF PURINES AND PLANT TO CARRY OUT SAID
PROCESOPROCESS
D E S C R I P C I O ND E S C R I P C I O N
OBJETO DE LA INVENCIONOBJECT OF THE INVENTION
La invencion, tal como expresa el enunciado de la presente memoria descriptiva, se refiere a un proceso de tratamiento de purines y a una planta para llevar a cabo dicho proceso, aportando, ventajas y caracterfsticas, que se describen en detalle mas adelante, que suponen una novedad para el estado actual de la tecnica.The invention, as expressed in the statement of the present specification, refers to a slurry treatment process and a plant to carry out said process, providing advantages and characteristics, which are described in detail below, which represent a Novelty for the current state of the art.
Mas concretamente, el objeto de la invencion se centra en un proceso y una planta de tratamiento de purines consistente, esencialmente, en separar la parte solida del purfn de la lfquida y realizar un tratamiento individualizado de ambas partes, comprendiendo, el tratamiento de la parte lfquida un pre-tratamiento con centrifugado que reduce toda la materia organica y casi toda la inorganica y un tratamiento posterior del lfquido obtenido con inyeccion de ozono que hace que quede desodorizado, desinfectado y habiendo eliminado, casi en su totalidad, el amonfaco, el potasio y los fosfatos presentes en la fraccion lfquida. Por su parte, el tratamiento de la parte solida que sale del separador se mezcla con la materia organica del centrifugador y se envfan a un digestor en que, tras un perfodo de reaccion, producira biogas exento de sulfurosos y un fertilizante desodorizado, desinfectado y estabilizado, apto como abono.More specifically, the object of the invention is focused on a process and a slurry treatment plant consisting, essentially, in separating the solid part of the liquid from the liquid and carrying out an individualized treatment of both parts, including, the treatment of the part lfquida a pre-treatment with centrifugation that reduces all the organic matter and almost all the inorganica and a subsequent treatment of the liquid obtained with ozone injection that makes it deodorized, disinfected and having eliminated, almost in its entirety, ammonia, potassium and the phosphates present in the liquid fraction. For its part, the treatment of the solid part leaving the separator is mixed with the organic matter of the centrifuge and sent to a digester, which, after a period of reaction, will produce sulfur-free biogas and a deodorized, disinfected and stabilized fertilizer. , suitable as a subscription.
CAMPO DE APLICACION DE LA INVENCIONFIELD OF APPLICATION OF THE INVENTION
El campo de aplicacion de la presente invencion se enmarca dentro del sector de la industria de la industria dedicada al tratamiento de residuos, centrandose particularmente en el ambito de los residuos organicos procedentes de granjas ganaderas, y mas concretamente al de los purines animales.The field of application of the present invention is part of the sector of the industry dedicated to the treatment of waste, focusing particularly on the field of organic waste from livestock farms, and more specifically to the animal slurry.
ANTECEDENTES DE LA INVENCIONBACKGROUND OF THE INVENTION
Como es sabido, aunque segun el diccionario purfn es el lfquido formado por las orinas de los animales y lo que rezuma del estiercol, la expresion purines hace referencia a cualquiera de los residuos de origen organico, como aguas residuales y restos de vegetales, cosechas, semillas, concentraciones de animales muertos, pesca, comida, excrementos solidos o liquidos, o mezcla de ellos, con capacidad de fermentar o fermentados que tienen impacto medioambiental.As it is known, although according to the dictionary purfn is the liquid formed by the urine of animals and what oozes from manure, the expression purines refers to any of waste of organic origin, such as waste water and vegetable remains, crops, seeds, concentrations of dead animals, fishing, food, solid or liquid excrement, or a mixture of them, with the ability to ferment or ferment that have an environmental impact.
La presente invencion, sin embargo, esta enfocada principalmente a los purines de tipo animal que, generalmente, son residuos resultado de una mezcla de orina, la parte lfquida de eso que rezuma de todo tipo de estiercoles de animales.The present invention, however, is mainly focused on animal-type slurries which, generally, are residues resulting from a mixture of urine, the liquid part of that oozing from all types of animal manures.
Los purines de cerdos de criadero son los mas conocidos ya que son muy contaminantes, sobre todo debido a la concentracion porcina en diversos puntos, por lo cual su control es obligatorio. Tienen un contenido aproximado (en proporciones de Kg por tonelada) de 2 Kg de nitrogeno, 0'5 de fosforo y 3 de potasio.The slurry of pigs is the best known because they are very polluting, mainly due to the swine concentration in diverse points, for which its control is obligatory. They have an approximate content (in proportions of Kg per ton) of 2 Kg of nitrogen, 0.5 of phosphorus and 3 of potassium.
En la actualidad se esta estudiando el reciclaje de los purines de cerdos para diversos usos, siendo, por tanto, el objetivo de la presente invencion el desarrollo de un proceso y una planta de tratamiento para dicho fin.At present, the recycling of pig slurry for various uses is being studied, the objective of the present invention therefore being the development of a process and a treatment plant for that purpose.
Por otra parte, y como referencia al estado actual de la tecnica, cabe senalar que, si bien se conocen otros procesos con el mismo objetivo, al menos por parte del solicitante, se desconoce la existencia de ningun proceso y planta de tratamiento de purines o invencion similar con caracterfsticas iguales o semejantes a las que presenta lo que aquf se reivindica.On the other hand, and as a reference to the current state of the art, it should be noted that, although other processes with the same objective are known, at least on the part of the applicant, the existence of any slurry treatment process or plant is unknown. similar invention with characteristics equal or similar to those presented by what is claimed herein.
En dicho sentido, cabe destacar que una de las principales ventajas que presenta el proceso y la planta aquf descritos se encuentra en el biodigestor, ya que, a diferencia de los procesos conocidos, en que se necesitan cuatro fases de funcionamiento para hacer reaccionar el producto con cuatro tipos distintos de ph, trabajando normalmente en proporciones de un 40% de materia solida y un 60% de agua, en la presente invencion el biodigestor trabaja en continuo y en proceso semiseco, ya que la proporcion es de un 98% de materia solida y solo un 2% de agua, utilizando para la fermentacion un tipo de bacteria especffica a la que no afectan eventuales antibioticos que pueda contener la materia a tratar, a excepcion de los anticonceptivos.In this regard, it should be noted that one of the main advantages of the process and the plant described here is found in the biodigester, since, unlike the known processes, four phases of operation are required to react the product with four different types of ph, working normally in proportions of 40% solid matter and 60% water, in the present invention the biodigester works continuously and semi-dry process, since the proportion is 98% of matter solid and only 2% of water, using for the fermentation a specific type of bacteria that does not affect any antibiotics that may contain the material to be treated, with the exception of contraceptives.
EXPLICACION DE LA INVENCION EXPLANATION OF THE INVENTION
El proceso de tratamiento de purines y la planta para llevar a cabo dicho proceso que la invencion propone se configuran, pues, como una destacable novedad dentro de su campo de aplicacion, ya que a tenor de su implementacion y de manera taxativa se alcanzan satisfactoriamente los objetivos anteriormente senalados, estando los detalles caracterizadores que lo hacen posible y los distinguen convenientemente recogidos en las reivindicaciones finales que acompanan a la presente descripcion.The slurry treatment process and the plant to carry out said process that the invention proposes are configured, therefore, as a remarkable novelty within its field of application, since according to its implementation and in a exhaustive manner, the objectives outlined above, the details that make it possible and distinguish them conveniently collected in the final claims that accompany the present description.
De manera concreta, lo que la invencion propone, como se ha apuntado anteriormente, es un proceso de tratamiento de purines que consiste, esencialmente, en las siguientes etapas:Specifically, what the invention proposes, as pointed out above, is a slurry treatment process consisting, essentially, of the following steps:
- separar la parte solida del purfn de la parte lfquida y realizar un tratamiento individualizado de ambas partes, donde:- separate the solid part of the purfn from the liquid part and carry out an individualized treatment of both parts, where:
- el tratamiento de la parte lfquida comprende, basicamente:- the treatment of the liquid part comprises, basically:
- un pre-tratamiento con centrifugado que reduce la materia organica e inorganica - y un tratamiento propiamente dicho del lfquido obtenido a base de inyeccion de ozono con el que queda desodorizado, desinfectado y sin amonfaco, potasio ni fosfatos,- a pre-treatment with centrifugation that reduces the organic and inorganic matter - and a proper treatment of the liquid obtained by means of ozone injection with which it is deodorized, disinfected and without ammonia, potassium or phosphates,
- y el tratamiento de la parte solida comprende, basicamente:- and the treatment of the solid part comprises, basically:
- su mezcla con la materia organica obtenida de la parte lfquida en el centrifugado - y su paso por un digestor de trabajo en continuo con solo dos camaras en que, tras un perfodo de reaccion bacteriana, produce biogas exento de sulfurosos y un fertilizante desodorizado, desinfectado y estabilizado, apto como abono.- its mixture with the organic matter obtained from the liquid part in the centrifuge - and its passage through a continuous working digester with only two chambers in which, after a period of bacterial reaction, it produces sulphurous-free biogas and a deodorized fertilizer, disinfected and stabilized, suitable as fertilizer.
Mas especfficamente, la etapa de separacion comprende lo siguiente:More specifically, the separation stage comprises the following:
De una arqueta de recogida de purines, donde estan instalados un agitador, un interruptor de nivel y una bomba submarina, el purfn se bombea a un separador, tipo compactador de cuatrocientas micras, donde se separa el 63% de la materia solida (materia organica) de la lfquida.From a slurry collection chamber, where an agitator, a level switch and an underwater pump are installed, the purfn is pumped to a separator, compactor type of four hundred microns, where 63% of the solid matter is separated (organic matter). ) of the liquid.
La etapa de tratamiento de la parte lfquida comprende:The treatment step of the liquid part comprises:
- Una etapa de pre-tratamiento: que contempla la mezcla de la parte lfquida con coagulante, aglutinante como pro-lamida lfquida, y antiespumante. - A pre-treatment step: which contemplates the mixing of the liquid part with coagulant, binder as liquid pro-lamida, and antifoam.
- Y una etapa de tratamiento: en que al ifquido obtenido en la etapa de pre-tratamiento, se le inyecta ozono.- And a treatment stage: in which the liquid obtained in the pre-treatment stage is injected with ozone.
Para ello, la parte liquida que sale del separador tipo compactador a un primer deposito. Dicho deposito es de fibra, de dos metros cubicos, y lleva incorporada una valvula de mariposa, un rociador de agua para la limpieza del mismo, para lo se utiliza agua tratada por propio el sistema, y un interruptor de nivel.To do this, the liquid part that leaves the compactor type separator to a first deposit. This deposit is fiber, two cubic meters, and has a butterfly valve incorporated, a water sprayer for cleaning it, for which water is used by the system itself, and a level switch.
A la salida del primer deposito de fibra hay una dosificadora de coagulante compuesto por un 70% de coagulante inorganico y un 30% de coagulante organico, una dosificadora de pro-lamida liquida y una bomba de husillo que impulsa la mezcla a una centrifuga desde la que, a su vez, es conducido a un segundo deposito donde se anade antiespumante y de ahf el producto va a una bomba de turbina que envfa el lfquido a un tercer deposito o deposito de tratamiento.At the exit of the first fiber deposit there is a coagulant dosing agent composed of 70% inorganic coagulant and 30% organic coagulant, a liquid pro-lamida dosing machine and a screw pump that drives the mixture to a centrifuge from the which, in turn, is conducted to a second tank where antifoam is added and from there the product goes to a turbine pump that sends the liquid to a third tank or treatment tank.
La centrifuga reduce el 100% de la materia organica que le llega y un 90% de la materia inorganica, separando tales elementos solidos del lfquido restante.The centrifuge reduces 100% of the organic matter that reaches it and 90% of the inorganic matter, separating these solid elements from the remaining liquid.
En el deposito de tratamiento al lfquido se le inyecta ozono haciendolo recircular con una bomba de ozono, anadiendo coagulante y regulador del ph. Para ello, el tercer deposito o deposito de tratamiento que es de mayor tamano, entre 10 y 60 m3, con un detector de nivel incorporado. Cuando se alcanza el nivel determinado, se recircula el lfquido, a traves de otra bomba con la que se inyecta el ozono, hasta la finalizacion del tratamiento.In the liquid treatment tank, ozone is injected, recirculating it with an ozone pump, adding coagulant and ph regulator. To do this, the third tank or tank of treatment that is larger, between 10 and 60 m3, with a built-in level detector. When the determined level is reached, the liquid is recirculated, through another pump with which the ozone is injected, until the end of the treatment.
Al recircular la parte liquida e inyectar ozono conseguimos la oxidacion del amonfaco formado por un atomo de nitrogeno (N) y tres atomos de hidrogeno (H) de acuerdo a la formula NH3. El amonfaco posee una gran solubilidad en el agua debido a su caracter polar y a que la molecula no es plana, sino que tiene forma tetraedrica, en el que cada atomo de hidrogeno ocupa un vertice y el cuarto es ocupado por el par electronico del orbital hfbrido sp3, ocupado en su totalidad.By recirculating the liquid part and injecting ozone we get the oxidation of the ammonia formed by a nitrogen atom (N) and three hydrogen atoms (H) according to the NH3 formula. The ammonia has a great solubility in water due to its polar character since the molecule is not flat, but has a tetrahedral shape, in which each atom of hydrogen occupies a vertex and the fourth is occupied by the electronic pair of the hybrid orbital sp3, occupied in its entirety.
Esta polaridad inherente a su estructura molecular le concede una buena solubilidad en el agua donde se comporta como una base al formar el ion amonio NH4+ (cada proton se situa en el vertice del tetraedro formado por la hibridacion sp3). This polarity inherent in its molecular structure gives it a good solubility in water where it behaves as a base when forming the ammonium ion NH4 + (each proton is located at the vertex of the tetrahedron formed by sp3 hybridization).
La solubilidad en el agua a 20°C alcanza el 34% en peso es decir, aproximadamente, 34gr /100 mL.The solubility in water at 20 ° C reaches 34% by weight, ie approximately 34 g / 100 mL.
Esta cantidad es muy superior a la existente en el agua procedente del tratamiento de la centrifugadora, por lo que permanecera en disolucion y no se “evaporara” ni se “desprendera” a la atmosfera hasta que su composicion qufmica se vea alterada, es decir hasta que se forme otro compuesto qufmico diferente que reaccione de forma diferente.This amount is much higher than that in the water from the centrifuge treatment, so it will remain in solution and will not "evaporate" or "release" to the atmosphere until its chemical composition is altered, that is to say until that a different chemical compound forms that reacts differently.
El anion nitruro sera transformado en nitrogeno molecular por medio de los oxidantes presentes en el agua y por tanto la unica especie qufmica que se desprendera sera nitrogeno molecular, N2.The nitride anion will be transformed into molecular nitrogen by means of the oxidants present in the water and therefore the only chemical species that will be released will be molecular nitrogen, N2.
Este proceso tambien reduce, practicamente en su totalidad, los compuestos fosfatados y potasicos que precipitan en la materia y que se separan mediante un proceso de flotacion con la utilizacion de un cepillo.This process also reduces, practically in its entirety, the phosphate and potassium compounds that precipitate in the matter and that are separated by a flotation process with the use of a brush.
El ozono reduce hasta su eliminacion toda la flora biologica, incluidas las bacterias coliformes.The ozone reduces until its elimination all the biological flora, including coliform bacteria.
Las propiedades del ozono hacen que la fraccion lfquida quede desodorizada, desinfectada y que se eliminen, casi en su totalidad, el amonfaco, el potasio y los fosfatos presentes.The properties of ozone cause the liquid fraction to be deodorized, disinfected and the ammonia, potassium and phosphates present are almost completely eliminated.
Al principio de la recirculacion y, junto a la bomba de ozono, se ponen en marcha dos bombas dosificadoras: una que inyecta coagulante con un porcentaje del 70% organico y el 30% inorganico y otra con un producto que regula el pH.At the beginning of the recirculation and, next to the ozone pump, two dosing pumps are started: one that injects coagulant with a percentage of 70% organic and 30% inorganic and another with a product that regulates the pH.
Cuando el detector de nivel senale el maximo, se detendran las dosificadoras, haciendo un barrido con un cepillo sobre el nivel del lfquido; este sistema aglutina por flotacion la materia organica e inorganica y la retira del proceso.When the level detector reaches the maximum, the dispensers will stop, sweeping with a brush over the level of the liquid; this system agglutinates the organic and inorganic matter by flotation and removes it from the process.
A continuacion del deposito de tratamiento se ha previsto un bypass que hace pasar el lfquido por un filtro de arena. Para ello una bomba de turbina abierta de 50 m3 vacfa el deposito de tratamiento y recircula el lfquido dividiendo el flujo en dos circuitos activados por dos valvulas de mariposas. Uno de ellos hace circular su caudal por un filtro de arena para, posteriormente, unirse al otro antes de la entrada en una valvula de tres vfas desde la que se puede llevar directamente a riego o a un cuarto deposito de agua tratada.Following the treatment tank, a bypass has been provided which passes the liquid through a sand filter. For this, an open turbine pump of 50 m3 empties the treatment tank and recirculates the liquid dividing the flow into two circuits activated by two butterfly valves. One of them circulates its flow through a sand filter to later join the other before entering a three-way valve from the that can be taken directly to irrigation or a fourth tank of treated water.
Para el vaciado del deposito de tratamiento, la bomba de turbina abierta de 50 m3 dispone, preferentemente, de dos valvulas motorizadas que actuan enviando el agua a dicho cuarto deposito de agua tratada, que puede consistir en una balsa para riego.For emptying the treatment tank, the 50 m3 open turbine pump preferably has two motorized valves that act by sending the water to said fourth tank of treated water, which may consist of a raft for irrigation.
En caso que se quiera obtener una mayor reduccion de los parametros disueltos, se puede enviar de nuevo el agua tratada al primer deposito, posterior al separador tipo compactador, para comenzar asf otra vez el proceso.In case you want to obtain a greater reduction of the dissolved parameters, you can send the treated water back to the first tank, after the compactor-type separator, to start the process again.
Ademas, opcionalmente, una parte del agua tratada servira para alimentar las necesidades del proceso en la planta: limpieza de filtros, depositos.., de forma que el sistema necesite de unas aportaciones mfnimas de agua procedente de la red.In addition, optionally, a part of the treated water will serve to feed the needs of the process in the plant: cleaning of filters, deposits ..., so that the system needs a minimum contributions of water from the network.
En caso que el agua obtenida no alcance los parametros deseados para su uso como agua de riego, opcionalmente se la hara circular por una nanofiltracion y, a continuacion, por un sistema de osmosis, de forma que se alcancen las condiciones requeridas para el proceso.In case the obtained water does not reach the desired parameters for its use as irrigation water, it will optionally be circulated by a nanofiltration and then by an osmosis system, so that the conditions required for the process are achieved.
Hay que senalar que el agua o fraccion liquida tratada que se va a utilizar para riego es posible que este un tiempo almacenada antes de ser usada. Para ello, opcionalmente, en el cuarto deposito o balsa de agua tratada donde se almacena, se instala un RMI o Reactor de Mezcla Instantaneo con la intencion de que se conserve en las mejores condiciones.It should be noted that the water or liquid fraction treated that is going to be used for irrigation may be stored for a while before being used. For this, optionally, in the fourth tank or treated water tank where it is stored, an RMI or Instant Mixing Reactor is installed with the intention of keeping it in the best conditions.
Por su parte, la etapa de tratamiento de la parte solida del purfn comprende lo siguiente:For its part, the treatment stage of the solid part of the purfn comprises the following:
- El envfo de la parte solida que sale del separador (compactador), preferentemente junto con la parte solida obtenida en la centrifuga de la parte liquida, a un bio-digestor que trabaja en continuo con solo dos compartimientos, donde permanece unos 21 dfas fermentando con una bacteria especffica.- The shipment of the solid part that leaves the separator (compactor), preferably together with the solid part obtained in the centrifuge of the liquid part, to a bio-digester that works continuously with only two compartments, where it remains about 21 days fermenting with a specific bacteria.
Para ello, dicha parte solida, cae en un cono que tiene un sinffn que lo introduce dentro del bio digestor.For this, the solid part falls into a cone that has a symphon that introduces it into the bio digester.
El digestor como se ha dicho tiene dos compartimentos, y una campana que recoge los gases sulfurosos a todo lo largo del deposito y los hace pasar por un filtro con lo cual se obtiene biogas exento de sulfurosos.The digester, as has been said, has two compartments, and a bell that collects the sulfurous gases along the entire length of the deposit and passes them through a filter, thereby obtains sulfur-free biogas.
El primer compartimiento recibe la materia solida e incorpora sensores de temperatura y de nivel. La materia introducida, por decantacion, al sobrepasar el tabique de separacion que no llega hasta el techo del deposito, pasa al segundo compartimento. Este segundo compartimento dispone de la misma cantidad de sensores y un segundo tornillo sinffn para extraer el producto una vez terminado el proceso.The first compartment receives the solid material and incorporates temperature and level sensors. The material introduced, by decanting, when passing the septum of separation that does not reach the roof of the deposit, passes to the second compartment. This second compartment has the same number of sensors and a second screw to extract the product once the process is finished.
Este segundo compartimento esta calefactado por un serpentfn interior alimentado por placas solares y, en el caso de que fuera necesario, por un acumulador electrico. La temperatura permanecera estable entre 50 y 60°C. Los digestores de poliester pueden tener un volumen desde 10 hasta 60 m3.This second compartment is heated by an indoor serpentine fed by solar panels and, if necessary, by an electric accumulator. The temperature will remain stable between 50 and 60 ° C. Polyester digesters can have a volume from 10 to 60 m3.
Puesta en marcha y funcionamiento del digestor es la siguiente:Start-up and operation of the digester is as follows:
Se procede a introducir unos 300 litros de agua, se anaden los cultivos bacterianos y, a partir de ese momento, comienza la introduccion de la materia organica procedente del sistema. La produccion es continua y se adapta tanto a las fluctuaciones de temperatura y Ph como a los restos de antibioticos que puedan permanecer en la materia organica introducida.We proceed to introduce about 300 liters of water, bacterial cultures are added and, from that moment, the introduction of organic matter from the system begins. The production is continuous and adapts to fluctuations in temperature and Ph as well as to the remains of antibiotics that can remain in the organic matter introduced.
Despues de este llenado inicial, Cuando los sensores de nivel detectan que ambos compartimientos estan llenos, el proceso de funcionamiento de la planta se detiene durante 21 dfas para que se produzca la fermentacion, y la planta deja de introducir materia en el primer compartimiento. El sistema permanece durante, al menos, dichos 21 dfas en reaccion, sabiendo que el tiempo medio de procesado en continuo puede oscilar, segun las temperaturas y caracterfsticas especificas de los purines a tratar, entre los 17 y los 27 dfas.After this initial filling, when the level sensors detect that both compartments are full, the process of operation of the plant stops for 21 days for the fermentation to take place, and the plant stops introducing matter into the first compartment. The system remains for at least 21 days in reaction, knowing that the average time of continuous processing can vary, according to the temperatures and specific characteristics of the slurry to be treated, between 17 and 27 days.
Tras los 21 dfas de reaccion, se procede a introducir de nuevo las cantidades agua, cultivos bacterianos y materia organica que se determine a traves del primer compartimiento para convertir el proceso en un proceso continuo.After 21 days of reaction, the amounts of water, bacterial cultures and organic matter determined through the first compartment are again introduced to convert the process into a continuous process.
Durante este proceso de reaccion se produce un biogas, que esta exento de elementos sulfurosos, que se eliminan con la campana de gases filtrados. El producto obtenido es un fertilizante desodorizado, desinfectado y estabilizado, apto para su utilizacion como abono ecologico en el caso de ser aprobado.During this reaction process a biogas is produced, which is free of sulfur elements, which are removed with the filtered gas hood. The product obtained is a deodorized, disinfected and stabilized fertilizer, suitable for use as fertilizer ecological in the case of being approved.
El descrito proceso de tratamiento de purines y planta para llevar a cabo dicho proceso representan, pues, innovaciones de caractensticas desconocidas hasta ahora, razones que unidas a su utilidad practica, les dotan de fundamento suficiente para obtener el privilegio de exclusividad que se solicita.The described process of treatment of slurry and plant to carry out this process represent, therefore, innovations of characteristics unknown until now, reasons that together with their practical utility, provide them with sufficient grounds to obtain the privilege of exclusivity that is requested.
DESCRIPCION DE LOS DIBUJOSDESCRIPTION OF THE DRAWINGS
Para complementar la descripcion que se esta realizando y con objeto de ayudar a una mejor comprension de las caractensticas de la invencion, se acompana a la presente memoria descriptiva, como parte integrante de la misma, de un juego de planos, en los que con caracter ilustrativo y no limitativo se ha representado lo siguiente:To complement the description that is being made and in order to help a better understanding of the characteristics of the invention, the descriptive specification is included, as an integral part thereof, of a set of plans, in which illustrative and not limitative the following has been represented:
La figura numero 1.- Muestra una representacion esquematica de la planta para llevar a cabo el proceso de tratamiento de purines, objeto de la invencion, apreciandose en ella las principales partes y elementos que comprende.Figure 1 shows a schematic representation of the plant to carry out the process of treatment of slurry, object of the invention, appreciating in it the main parts and elements comprising.
La figura numero 2.- Muestra una representacion esquematica del deposito de tratamiento de inyeccion de ozono de la parte lfquida y los principales elementos asociados al mismo.Figure 2 shows a schematic representation of the ozone injection treatment tank of the liquid part and the main elements associated thereto.
La figura numero 3.- Muestra una representacion esquematica de la campana extractora con maquina de ozono que comprende el deposito de tratamiento de la parte lfquida de los purines.Figure 3 shows a schematic representation of the extractor hood with ozone machine that comprises the treatment tank of the liquid part of the slurry.
Y la figura numero 4.- Muestra una representacion esquematica del bio-digestor en que se trata la parte solida de los purines.And the figure number 4.- It shows a schematic representation of the bio-digester in which the solid part of the slurry is treated.
REALIZACION PREFERENTE DE LA INVENCIONPREFERRED EMBODIMENT OF THE INVENTION
A la vista de las mencionadas figuras y de acuerdo con la numeracion adoptada, se puede observar en ellas un ejemplo de realizacion no limitativo de la planta para llevar a cabo el proceso de tratamiento de purines de la invencion, la cual comprende las partes y elementos que se indican y describen en detalle a continuacion siguiendo la siguiente lista de referencias: In view of the mentioned figures and in accordance with the numeration adopted, an example of a non-limiting embodiment of the plant can be observed in them to carry out the slurry treatment process of the invention, which comprises the parts and elements which are indicated and described in detail below by following the following list of references:
1. planta1 floor
2. arqueta, o fosa aseptica2. chest, or aseptic pit
3. agitador3. agitator
4. sensor de nivel4. level sensor
5. bomba submarina5. underwater pump
6. separador, compactador6. separator, compactor
7. primer deposito, de fibra7. first deposit, fiber
8. valvulas de mariposa, o electrovalvula8. Butterfly valves, or electrovalve
9. rociador9. sprayer
10. dosificadoras10. dosing
11. bomba de husillo11. spindle pump
12. centrffuga12. centripetal
13. segundo deposito13. second deposit
14. bomba de turbina14. turbine pump
15. tercer deposito de tratamiento15. third treatment tank
16. maquina de ozono16. ozone machine
17. campana, de la maquina de ozono17. bell, from the ozone machine
18. extractor, de la campana de la maquina de ozono 19. segunda bomba de turbina, abierta18. extractor, of the hood of the ozone machine 19. second turbine pump, open
20. primer circuito, bypass20. first circuit, bypass
21. segundo circuito, bypass21. second circuit, bypass
22. filtro arena22. sand filter
23. valvula de tres vfas23. Three-way valve
24. cuarto deposito, de agua tratada24. fourth tank, of treated water
25. bomba de riego25. irrigation pump
26. sistema de nanofiltracion y/o de osmosis26. nanofiltration and / or osmosis system
27. reactor de mezcla instantaneo27. instantaneous mixing reactor
28. digestor28. digester
29. cono de entrada, al digestor29. input cone, to the digester
30. tornillos sinffn30. sinffn screws
31. bocas de hombre31. man mouths
32. primer compartimiento, de entrada32. first compartment, entry
33. segundo compartimiento de fermentacion y salida 34. tabique de decantacion 33. Second fermentation compartment and exit 34. Decantation partition
35. campana extractora con filtro, de sulfurosos35. Extractor hood with filter, sulfur
36. placas solares36. solar panels
37. acumulador electrico37. electric accumulator
38. deposito mezclador, adicional38. mixer tank, additional
Asf, tal como se observa en la figura 1, dicha planta (1) comprende, esencialmente, una arqueta (2) o fosa septica de recogida de purines, donde estan instalados un agitador (3), un sensor de nivel (4) y una bomba submarina (5) que comunica, a traves de una conduccion, con un separador (6), tipo compactador en el que se vierte el producto para separar la parte lfquida de la parte solida.Thus, as seen in Figure 1, said plant (1) essentially comprises a pit (2) or septic tank to collect slurry, where are installed an agitator (3), a level sensor (4) and an underwater pump (5) that communicates, through a conduction, with a separator (6), a compactor type in which the product is poured to separate the liquid part from the solid part.
A continuacion del separador (6), se ha previsto un primer deposito (7) en que se lleva a cabo el pre-tratamiento de la parte lfquida el cual es de fibra, de dos metros cubicos, con valvula de mariposa (8) o electrovalvula, un rociador (9) para limpieza con agua, preferentemente procedente del propio el sistema a traves de una conduccion que comunica con el deposito de agua tratada (24) que se describe mas adelante, contando, ademas tambien con sensor de nivel (4), elemento con que cuentan todos los depositos.Following the separator (6), a first tank (7) is provided in which the pre-treatment of the liquid part which is fiber, of two cubic meters, with butterfly valve (8) or electrovalve, a sprayer (9) for cleaning with water, preferably from the system itself through a conduit that communicates with the treated water tank (24) described below, counting, also with a level sensor (4). ), element that all deposits have.
En la conduccion de salida este primer deposito (7) hay dos dosificadoras (10), a traves de las que se anade al producto lfquido coagulante y aglutinante, y una bomba de husillo (11) que impulsa el flujo hacia una centrifuga (12) en que se reduce y separa materia organica e inorganica solidas del lfquido restante.In the outlet pipe this first tank (7) there are two dosing units (10), through which is added to the liquid product coagulant and binder, and a screw pump (11) that drives the flow to a centrifuge (12) in which solid and inorganic matter is reduced and separated solid from the remaining liquid.
Tras la centrifuga (12), otra conduccion comunica con un segundo deposito (13), tambien de dos metros cubicos, igualmente provisto de sensor de nivel (4) y rociador (9) con valvula de mariposa (8), para limpieza con agua procedente del propio el sistema a traves de una conduccion que comunica con el deposito de agua tratada (24), al que llega el producto lfquido y donde, mediante otra dosificadora (10), se le anade antiespumante.After the centrifuge (12), another conduit communicates with a second tank (13), also of two cubic meters, also provided with level sensor (4) and sprinkler (9) with butterfly valve (8), for cleaning with water coming from the system itself through a conduit that communicates with the treated water tank (24), where the liquid product arrives and where, through another dosing device (10), antifoam is added.
Tras este segundo deposito (13) se ha previsto una bomba de turbina (14) que envfa el lfquido a un tercer deposito (15) que es el deposito de tratamiento de ozono.After this second tank (13) there is provided a turbine pump (14) which sends the liquid to a third tank (15) which is the ozone treatment tank.
Tal como se observa en el esquema de la figura 2, dicho tercer deposito (15) o deposito de tratamiento, es de mayor tamano, entre 10 y 60 m3, y cuenta con un sensor de nivel (4) incorporado que, cuando se alcanza el nivel determinado, acciona una maquina de ozono (16) que inyecta ozono en dicho deposito (15) al tiempo que se recircula el ifquido ayudado de una bomba submarina (5).As seen in the diagram of figure 2, said third tank (15) or tank of treatment, is larger, between 10 and 60 m3, and has a built-in level sensor (4) that, when it is reached the determined level, activates an ozone machine (16) which injects ozone into said tank (15) while recirculating the liquid assisted by an underwater pump (5).
La maquina de ozono (16), como muestra la figura 3, se monta con una campana (17) provista de un extractor (18).The ozone machine (16), as shown in figure 3, is assembled with a hood (17) provided with an extractor (18).
Ademas, el tercer deposito (15) o deposito de tratamiento tambien comunica, mediante las correspondientes conducciones, con dos dosificadoras (10) que inyectan, una coagulante y la otra un producto que regula el pH.In addition, the third tank (15) or tank of treatment also communicates, by means of the corresponding pipes, with two dosing units (10) that inject a coagulant and the other a product that regulates the pH.
En las figuras 1 y 2, se observa como a continuacion del tercer deposito (15) de tratamiento, la conduccion de salida del mismo, que incorpora una segunda bomba de turbina abierta (19) de mayor capacidad, de 50 m3, para su vaciado, se divide en dos circuitos (20, 21) que forman un bypass con respectivas valvulas de mariposa (8), haciendo que el producto pase por un filtro de arena (22), tras lo cual, mediante una valvula de tres vfas (23) se distribuye el liquido, que ya esta convertido en agua tratada, y sirve preferentemente para riego, siendo preferentemente enviado a un cuarto deposito (24) de agua tratada desde el que se puede utilizar directamente y/o hacer recircular para limpieza de la planta en los rociadores (9) de los diferentes depositos.In Figures 1 and 2, it is observed as following the third tank (15) of treatment, the outlet conduction thereof, which incorporates a second open turbine pump (19) of greater capacity, 50 m3, for emptying , is divided into two circuits (20, 21) that form a bypass with respective butterfly valves (8), causing the product to pass through a sand filter (22), after which, by means of a three-way valve (23). ) the liquid is distributed, which is already converted into treated water, and preferably serves for irrigation, preferably being sent to a fourth tank (24) of treated water from which it can be used directly and / or recirculated for cleaning the plant in the sprinklers (9) of the different deposits.
Preferentemente, la bomba de turbina abierta (19) de 50 m3 para vaciar el tercer deposito (15) dispone de dos valvulas motorizadas que actuan enviando el agua al mencionado cuarto deposito (24) de agua tratada que puede ser una balsa para riego o conectar con ella o con una bomba de riego (25).Preferably, the open turbine pump (19) of 50 m3 for emptying the third tank (15) has two motorized valves that act by sending the water to said fourth tank (24) of treated water that can be a raft for irrigation or to connect with it or with an irrigation pump (25).
Opcionalmente, este cuarto deposito (24), comunica, a traves de otra conduccion con bomba (14), con el primer deposito (7) posterior al separador (6), para repetir otra vez el proceso.Optionally, this fourth tank (24), communicates, through another pump conduit (14), with the first tank (7) subsequent to the separator (6), to repeat the process again.
Opcionalmente, tras el cuarto deposito (24) de agua tratada, se incorpora un sistema de nanofiltracion y/o un sistema de osmosis (26).Optionally, after the fourth tank (24) of treated water, a nanofiltration system and / or an osmosis system (26) is incorporated.
Asimismo, de modo optativo, el cuarto deposito (24) incorpora un Reactor de Mezcla Instantaneo (27) para la conservacion del agua tratada en las mejores condiciones. Also, optionally, the fourth tank (24) incorporates an Instant Mixing Reactor (27) for the conservation of treated water in the best conditions.
En el esquema de la figura 2 se aprecian con mayor detalle los elementos asociados al tercer deposito (17) que es el deposito de tratamiento de la parte lfquida.In the scheme of figure 2 the elements associated with the third tank (17) which is the treatment tank of the liquid part are appreciated in greater detail.
Opcionalmente, la planta contempla un deposito mezclador (38) adicional donde se efectua la mezcla de los componentes coagulantes y/o aglutinantes que se anaden al producto lfquido en su etapas de tratamiento tras su paso por el primer deposito (7) y en la centrffuga (12).Optionally, the plant contemplates an additional mixer tank (38) where the mixture of the coagulating and / or binding components that are added to the liquid product in its treatment stages after passing through the first tank (7) and in the centrifuge is made. (12)
Finalmente, la planta comprende un digestor (28), apreciable esquematicamente en la figura 4, al que se envfa la parte solida que sale del separador (6) y, opcionalmente, tambien la parte solida obtenida en la centrifuga (12), para lo cual comunica con dichos elementos, por ejemplo mediante cinta transportadora (no representada).Finally, the plant comprises a digester (28), which can be seen schematically in figure 4, to which the solid part coming out of the separator (6) and, optionally, also the solid part obtained in the centrifuge (12), is sent. which communicates with said elements, for example by conveyor belt (not shown).
Para la introduccion de dichos solidos, el digestor (28) cuenta con un cono de entrada (29) dotado en su interior de un tornillo sinffn (30).For the introduction of said solids, the digester (28) has an inlet cone (29) provided inside it with a sintered screw (30).
El digestor (28), preferentemente, es un recipiente con un volumen de unos 60 m3 de doble camara con capa aislante de 100 milfmetros y bocas de hombre (31).The digester (28), preferably, is a container with a volume of about 60 m3 of double chamber with insulating layer of 100 millimeters and manholes (31).
En cualquier caso, el digestor (28) trabaja en continuo y es donde se mezcla el material solido con una bacteria que provoca su fermentacion para convertir el producto en estiercol.In any case, the digester (28) works continuously and is where the solid material is mixed with a bacterium that causes its fermentation to convert the product into manure.
Para ello, dicho digestor (28) tiene dos compartimentos, un primer compartimiento (32) de entrada y un segundo compartimiento (33) de fermentacion y salida, separados por un tabique de decantacion (34) abierto superiormente, de manera que, el segundo compartimiento (33) se llena por rebose del material por encima de dicho tabique (34) tras el llenado del primer compartimiento (32).For this, said digester (28) has two compartments, a first compartment (32) of entrance and a second compartment (33) of fermentation and exit, separated by a septum of decantation (34) open superiorly, so that, the second compartment (33) is filled by overflowing the material above said partition (34) after filling of the first compartment (32).
Ademas, el digestor (28) tiene una campana extractora con filtro (35), que se prolonga a todo lo largo del mismo, que recoge los gases sulfurosos de la fermentacion y los filtra permitiendo obtener biogas sin sulfuros.In addition, the digester (28) has an extractor hood with filter (35), which extends throughout its length, which collects sulfurous gases from the fermentation and filters them allowing to obtain biogas without sulphides.
Ambos compartimientos (32, 33) del digestor (28) incorporan sensores de temperatura y sensores de nivel (4), de manera que, cuando detecta que estan llenos, el llenado de producto se detiene durante unos 21 dfas para que se produzca la fermentacion. Y, una vez transcurrido ese tiempo, el producto ya convertido en estiercol, es extrafdo a traves de otro sinffn (30) previsto al efecto.Both compartments (32, 33) of the digester (28) incorporate temperature sensors and level sensors (4), so that, when it detects that they are full, the product filling stops for about 21 days for the fermentation to take place. . And once after that time, the product that has already been turned into manure is extracted through another sync (30) provided for that purpose.
Preferentemente, el segundo compartimento (33) esta calefactado por un serpentfn interior (no representado) alimentado por placas solares (36) y, opcionalmente, por un acumulador electrico (37).Preferably, the second compartment (33) is heated by an indoor serpentine (not shown) powered by solar panels (36) and, optionally, by an electric accumulator (37).
Descrita suficientemente la naturaleza de la presente invencion, asf como la manera de ponerla en practica, no se considera necesario hacer mas extensa su explicacion para que cualquier experto en la materia comprenda su alcance y las ventajas que de ella se derivan, haciendose constar que, dentro de su esencialidad, podra ser llevada a la practica en otras formas de realizacion que difieran en detalle de la indicada a tftulo de ejemplo, y a las cuales alcanzara igualmente la proteccion que se recaba siempre que no se altere, cambie o modifique su principio fundamental. Having sufficiently described the nature of the present invention, as well as the way of putting it into practice, it is not considered necessary to make its explanation more extensive so that any expert in the field understands its scope and the advantages derived from it, stating that, within its essentiality, it may be carried out in other forms of realization that differ in detail from the one indicated by way of example, and to which it will also reach the protection that is sought provided it is not altered, changes or modifies its fundamental principle .
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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ES2845275A1 (en) * | 2020-01-24 | 2021-07-26 | Munoz Antonio Cuenca | PROCEDURE FOR THE RECOVERY OF EFFLUENTS FROM THE AGRI-FOOD INDUSTRY AND LIVESTOCK DEJECTIONS, AND PLANT TO CARRY OUT SUCH PROCEDURE (Machine-translation by Google Translate, not legally binding) |
WO2023017193A1 (en) * | 2021-08-09 | 2023-02-16 | Descontaminación Y Medioambiente, S.L. | Assembly for separating the solid and liquid fraction of slurry and converting them into organic fertilisers that are deodorised, sterilised and sanitised |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2153739A1 (en) * | 1998-07-10 | 2001-03-01 | Riera Molist Ricardo | Purines separation consists of ozone based oxidation, and neutralization of the separated liquid, for simplified distillation |
ES2157779A1 (en) * | 1999-04-13 | 2001-08-16 | Servicios De Gestion Tecnologi | Purines purification and drying technique consists of anaerobic biological digestion, centrifugation decomposition and concentration with thermoelectric heat cogeneration |
ES2198219A1 (en) * | 2002-07-05 | 2004-01-16 | Netporc Xxi S L | Purification of purines consists of mechanical separation of solids, for oxidation neutralization, and distillation and filtration |
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2017
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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ES2153739A1 (en) * | 1998-07-10 | 2001-03-01 | Riera Molist Ricardo | Purines separation consists of ozone based oxidation, and neutralization of the separated liquid, for simplified distillation |
ES2157779A1 (en) * | 1999-04-13 | 2001-08-16 | Servicios De Gestion Tecnologi | Purines purification and drying technique consists of anaerobic biological digestion, centrifugation decomposition and concentration with thermoelectric heat cogeneration |
ES2198219A1 (en) * | 2002-07-05 | 2004-01-16 | Netporc Xxi S L | Purification of purines consists of mechanical separation of solids, for oxidation neutralization, and distillation and filtration |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2845275A1 (en) * | 2020-01-24 | 2021-07-26 | Munoz Antonio Cuenca | PROCEDURE FOR THE RECOVERY OF EFFLUENTS FROM THE AGRI-FOOD INDUSTRY AND LIVESTOCK DEJECTIONS, AND PLANT TO CARRY OUT SUCH PROCEDURE (Machine-translation by Google Translate, not legally binding) |
WO2023017193A1 (en) * | 2021-08-09 | 2023-02-16 | Descontaminación Y Medioambiente, S.L. | Assembly for separating the solid and liquid fraction of slurry and converting them into organic fertilisers that are deodorised, sterilised and sanitised |
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