ES2673488B1 - PACKAGING APPLICABLE TO DEPOSIT AND CONSERVATION OF FOODSTUFFS AND USE OF A CONSERVATIVE AGENT - Google Patents

PACKAGING APPLICABLE TO DEPOSIT AND CONSERVATION OF FOODSTUFFS AND USE OF A CONSERVATIVE AGENT Download PDF

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ES2673488B1
ES2673488B1 ES201631650A ES201631650A ES2673488B1 ES 2673488 B1 ES2673488 B1 ES 2673488B1 ES 201631650 A ES201631650 A ES 201631650A ES 201631650 A ES201631650 A ES 201631650A ES 2673488 B1 ES2673488 B1 ES 2673488B1
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container
walls
faces
preservative
air
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ES2673488A1 (en
Inventor
Cuairan Joaquín Bastida
Llatas Guadalupe Garcia
Martinez Carlos Sayas
Rodriguez Susana Laza
Becerra Alexandre Cucala
Urdaneta Ricardo Daniel Machado
Mengual Jesús Cuenca
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Universitat de Valencia
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Universitat de Valencia
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/24Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
    • B65D81/26Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators
    • B65D81/266Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing gases, e.g. oxygen absorbers or desiccants
    • B65D81/268Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing gases, e.g. oxygen absorbers or desiccants the absorber being enclosed in a small pack, e.g. bag, included in the package

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  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Mechanical Engineering (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • Packages (AREA)

Description

DESCRIPCIONDESCRIPTION

Envase aplicable al deposito y conservacion de productos alimenticios y uso de un agente conservanteContainer applicable to the storage and preservation of food products and use of a preservative agent

Sector de la tecnicaSector of the technique

La presente invention concierne, en un primer aspecto, a un envase aplicable al deposito y conservacion de productos alimenticios, cuyas propiedades de conservacion incluyen la protection frente a la humedad.The present invention concerns, in a first aspect, a container applicable to the storage and preservation of food products, whose preservation properties include protection against moisture.

Un segundo aspecto de la invencion concierne al uso de un agente conservante, protector frente a la humedad y apto para contacto alimentario, para la conservacion de productos alimenticios depositados en el interior de un envase permeable al aire. A second aspect of the invention concerns the use of a preservative agent, protector against moisture and suitable for food contact, for the preservation of food products deposited inside an air permeable container.

La invencion es particularmente aplicable al deposito y conservacion de productos de panaderla y reposterla, preferentemente de piezas de pan de consumo diario para prolongar el mantenimiento de su crujibilidad.The invention is particularly applicable to the storage and preservation of bakery and pastry products, preferably pieces of bread for daily consumption to prolong the maintenance of its crispness.

Estado de la tecnica anteriorState of the prior art

Son conocidos en el estado de la tecnica diversos tipos de envase para el deposito y conservacion de productos alimenticios.Various types of packaging for the storage and preservation of food products are known in the state of the art.

Tal es el caso, por ejemplo, del envase descrito en ES1024959U, el cual constituye una bolsa flexible para el deposito y conservacion de piezas de pan, que incluye unas valvulas de aireacion, o de la solicitud de patente EP0878407A1 que propone una bolsa de plastico para contener pan u otros productos alimenticios, que incluye una serie de micro-perforaciones para airear su contenido.Such is the case, for example, of the package described in ES1024959U, which constitutes a flexible bag for the storage and preservation of pieces of bread, which includes aeration valves, or of the patent application EP0878407A1 proposing a plastic bag to contain bread or other food products, which includes a series of micro-perforations to aerate its contents.

Los envases descritos en dichos documentos de patente reunen las caracterlsticas del preambulo de la reivindicacion 1 de la presente invencion.The containers described in said patent documents meet the characteristics of the preamble of claim 1 of the present invention.

Si bien tales envases conservan en mayor o menor medida los productos alimenticios contenidos en los mismos, estos no estan concebidos para ambientes muy humedos. De hecho en tal clase de ambientes muy humedos, debido a las aberturas de aireacion incluidas en tales envases, la humedad del ambiente pasa al interior del envase y afecta a su contenido.Although such containers retain to a greater or lesser extent the food products contained therein, they are not designed for very humid environments. In fact in such a class of very humid environments, due to the aeration openings included in such containers, the humidity of the environment passes into the container and affects its contents.

Ello es especialmente crltico para las piezas de pan y similares. En este sentido cabe indicarse que el pan es el producto perecedero resultante de la coccion de una masa obtenida por la mezcla de harina de trigo, sal comestible y agua potable, fermentada por especies propias de la fermentation panaria, y que el pan comun procesado por tecnica tradicional experimenta perdida de crujibilidad (propiedad muy valorada por el consumidor) particularmente rapida (ya sensible tras dos horas despues del horneado) en ambientes de elevada humedad.This is especially critical for bread pieces and the like. In this sense it should be noted that bread is the perishable product resulting from the cooking of a dough obtained by the mixture of wheat flour, edible salt and drinking water, fermented by species typical of the fermentation panaria, and that the common bread processed by traditional technique experiences loss of crunchiness (property highly valued by the consumer) particularly fast (already sensitive after two hours after baking) in high humidity environments.

Esta perdida de crujibilidad deriva de la incorporation de un exceso de humedad a la corteza que en condiciones ordinarias de aireacion proviene de la atmosfera externa que se suma a la proveniente de la humedad de la miga que se dirige hacia el exterior, a traves de la corteza y que ocasiona una disminucion del comportamiento fragil de la corteza.This loss of crunchiness derives from the incorporation of an excess of moisture to the crust that under ordinary conditions of aeration comes from the external atmosphere that is added to that coming from the humidity of the crumb that is directed towards the outside, through the bark and that causes a decrease in the fragile behavior of the bark.

La crujibilidad del pan fresco es el atributo mas demandado por los consumidores; el problema consiste en que despues del horneado, dicha propiedad es percibida durante un corto periodo de tiempo y la perdida de la misma causa rechazo en los consumidores. La calidad del pan se pierde rapidamente debido al envejecimiento que empieza cuando las piezas de pan se sacan del horno y se almacenan. Este proceso dinamico es debido a multiples factores e implican mecanismos simultaneos que incluyen la perdida de "flavor” (olor, sabor y textura), un incremento de la dureza de la miga y perdida de la crujibilidad de la corteza. Esta ultima esta asociada al incremento del contenido de agua en la misma, ocasionando que los cristales de almidon polimericen en regiones amorfas ocasionando un cambio de comportamiento mecanico (Aguilera J.M ,2002. Temas en tecnologla de alimentos - Vol. 1. Programa Iberoamericano de Ciencia y Tecnologla para el Desarrollo (CYTED). Mesas, J.M.; Alegre, M.T., 2002, El pan y su proceso de elaboration. Ciencia y tecnologla alimentaria, Vol. 3, No. 5, pp. 307-313). En el pan almacenado, la "humedad” de la corteza se ve incrementada debido a la migration de vapor de agua desde la miga a la corteza y desde el ambiente exterior hacia ella procurando a la pieza un comportamiento gomoso.The crispness of fresh bread is the attribute most demanded by consumers; the problem is that after baking, this property is perceived for a short period of time and the loss of it causes rejection in consumers. The quality of the bread is quickly lost due to aging that begins when the pieces of bread are taken out of the oven and stored. This dynamic process is due to multiple factors and involves simultaneous mechanisms that include the loss of "flavor" (odor, taste and texture), an increase in the hardness of the crumb and loss of crunchiness of the crust. increase in water content in the same, causing the starch crystals to polymerize in amorphous regions causing a change in mechanical behavior (Aguilera JM, 2002. Topics in food technology - Vol. 1. Ibero-American Program of Science and Technology for Development (Tables, JM; Alegre, MT, 2002, Bread and its process of elaboration, Food science and technology, Vol 3, No. 5, pp. 307-313) In the stored bread, the "humidity "Of the bark is increased due to the migration of water vapor from the crumb to the bark and from the external environment towards it, giving the piece a gummy behavior.

En hostelerla, el estado gomoso del pan obliga frecuentemente a la presentation del pan ordinario tostado que suele resultar mas apetecible para el cliente, lo cual conlleva destinar tiempo a la operation adicional de tueste.In hostelerla, the gummy state of the bread often forces the presentation of ordinary toasted bread that is usually more appetizing for the customer, which entails spending time for the additional roasting operation.

Las paneras tradicionales no resuelven el problema enunciado referente a mantenimiento de crujibilidad en ambiente humedo.The traditional bread boxes do not solve the problem stated regarding maintenance of crujibilidad in humid environment.

Hasta hace unos 20 anos se solla efectuar una sola coccion diaria, en la actualidad se efectuan sucesivas cocciones incluso utilizando la tecnica tradicional (procesamiento completo desde el amasado hasta el fin del horneado), y se emplean tambien otras tecnicas para la production del pan comun (principalmente empleo de masas congeladas, y tecnicas de precocido). Until about 20 years ago, only one daily cooking is done, nowadays, successive firings are carried out even using the traditional technique (complete processing from mixing until the end of baking), and other techniques for the production of common bread are also used (mainly use of frozen doughs, and precooked techniques).

El pan tradicional en hogazas o en piezas de mayor espesor de corteza, mantiene cierta crujibilidad durante un tiempo relativamente mayor, respecto a piezas de menor espesor de corteza. En areas caracterizadas por frecuencia de altas humedades relativas, el pan se conserva relativamente bien durante un cierto tiempo en congeladores, pero se pone de manifiesto una tendencia a la desagregacion mecanica entre corteza y miga, y por otra parte debe efectuarse descongelacion del mismo, o dejar transcurrir cierto tiempo hasta el consumo.The traditional bread in loaves or in pieces of greater thickness of crust, maintains certain crunchiness during a relatively greater time, with respect to pieces of smaller thickness of crust. In areas characterized by frequency of high relative humidities, the bread is relatively well preserved for a certain time in freezers, but a tendency to mechanical disaggregation between crusts and crumbs is evident, and on the other hand thawing must be carried out, or let some time pass until consumption.

Por su propia naturaleza, panes comunes de proceso tradicional y elaboration cuidadosa experimentan en ambiente humedo una degradation de propiedades flsicas que afectan a su aceptabilidad por el consumidor.By their very nature, common breads of traditional process and careful elaboration experience in humid environment a degradation of physical properties that affect their acceptability by the consumer.

Resulta, por tanto, necesario, ofrecer una alternativa al estado de la tecnica que cubra las lagunas halladas en el mismo, mediante la proportion de un envase que permita conservar los productos alimenticios dispuestos en su interior en entornos muy humedos.It is therefore necessary to offer an alternative to the state of the art that covers the gaps found therein, by providing a container that allows the preservation of food products disposed in its interior in very humid environments.

Explication de la inventionExplanation of the invention

Con tal fin, la presente invencion concierne, en un primer aspecto, a un envase aplicable al deposito y conservation de productos alimenticios que, de manera en si conocida, comprende unas paredes dispuestas de manera que definen un recinto con por lo menos una abertura para la introduction de productos alimenticios en su interior, donde al menos parte de dichas paredes permite que el aire atraviese la pared con el fin de airear el interior del envase.For this purpose, the present invention concerns, in a first aspect, a container applicable to the storage and storage of food products which, in a manner known per se, comprises walls arranged so as to define an enclosure with at least one opening for the introduction of food products inside, where at least part of said walls allows air to pass through the wall in order to aerate the interior of the container.

A diferencia de los envases conocidos en el estado de la tecnica aplicables al deposito y conservacion de productos alimenticios, en el propuesto por el primer aspecto de la presente invencion, de manera caracterlstica, al menos una de sus paredes, contiene en su interior o adosado a una de sus caras, al menos un agente conservante protector frente a la humedad y apto para contacto alimentario.Unlike the containers known in the state of the art applicable to the storage and preservation of food products, in the one proposed by the first aspect of the present invention, characteristically, at least one of its walls contains inside or attached on one of its faces, at least one preservative agent against moisture and suitable for food contact.

En funcion del ejemplo de realization, las paredes del envase del primer aspecto de la invencion son rlgidas o son flexibles.Depending on the embodiment example, the container walls of the first aspect of the invention are rigid or flexible.

De acuerdo a un ejemplo de realizacion, el envase del primer aspecto de la presente invencion comprende al menos un elemento que incluye al agente conservante y que se encuentra adosado a por lo menos una cara de la pared. Preferentemente, el envase comprende una pluralidad de dichos elementos adosados a algunas caras de algunas o todas las citadas paredes. According to an example of embodiment, the container of the first aspect of the present invention comprises at least one element that includes the preservative agent and which is attached to at least one side of the wall. Preferably, the package comprises a plurality of said elements attached to some faces of some or all of said walls.

En funcion del ejemplo de realization, la citada o citadas caras es o son una o unas caras internas o externas de las paredes del envase que delimitan a dicho recinto. As a function of the realization example, the cited or cited faces are or are one or some internal or external faces of the walls of the container that delimit said enclosure.

Por lo que se refiere al mencionado elemento, de acuerdo a un ejemplo de realizacion, este es un contenedor permeable al aire que aloja al agente conservante en su interior.As regards the mentioned element, according to an example of embodiment, this is an air-permeable container that houses the preservative agent inside it.

Para otro ejemplo de realizacion, el agente conservante se encuentra integrado en la pared o paredes del envase.For another embodiment, the preservative agent is integrated into the wall or walls of the container.

Segun otro ejemplo de realizacion, el agente conservante se encuentra incorporado en la composition que constituye la pared o paredes.According to another embodiment, the preservative agent is incorporated in the composition constituting the wall or walls.

Ventajosamente, para un ejemplo de realizacion, el envase del primer aspecto de la invention comprende unos medios de cierre para cerrar la citada abertura una vez los productos alimenticios se encuentran alojados en el interior del recinto.Advantageously, for an example of embodiment, the container of the first aspect of the invention comprises closing means for closing said opening once the food products are housed inside the enclosure.

Alternativamente, para otro ejemplo de realizacion, el envase del primer aspecto de la invencion no incluye medios de cierre. Tal es el caso, por ejemplo, de que el envase sea una bolsa de tamano suficiente como para no necesitar de una tapa propiamente dicha, sino que las paredes de la bolsa recubran suficientemente el contenido de la bolsa tapando la abertura.Alternatively, for another embodiment, the package of the first aspect of the invention does not include closure means. Such is the case, for example, that the package is a bag of sufficient size so as not to require a cover itself, but that the walls of the bag sufficiently cover the contents of the bag by covering the opening.

Para un ejemplo de realizacion, con el fin de permitir la aireacion del interior del recinto mencionada anteriormente, como mlnimo parte de las paredes estan hechas de un material permeable al aire permitiendo el paso del aire a traves de la pared.For an example of embodiment, in order to allow aeration of the interior of the enclosure mentioned above, as a minimum part of the walls are made of an air permeable material allowing the passage of air through the wall.

Segun diferentes implementaciones de dicho ejemplo de realizacion, las paredes estan hechas de al menos un material permeable al aire, bien sea carton, papel, tela u otro tipo de material tambien permeable al aire y apto para el contacto alimentario.According to different implementations of said embodiment, the walls are made of at least one air-permeable material, whether cardboard, paper, cloth or other type of material also permeable to air and suitable for food contact.

De acuerdo a otro ejemplo de realizacion del envase del primer aspecto de la presente invencion, por lo menos parte de las paredes comprenden o definen unos orificios o huecos, que permiten el paso de aire a traves de la pared. Segun diferentes implementaciones de dicho ejemplo de realizacion, las paredes estan hechas de como mlnimo uno de los siguientes materiales: mimbre, tejido, metal, madera o plastico, todos ellos incluyendo orificios pasantes, ya sea en la forma de perforaciones (metal, madera) o en la forma de espacios intersticiales entre filamentos (mimbre, tejido). According to another example embodiment of the container of the first aspect of the present invention, at least part of the walls comprise or define holes or holes, which allow the passage of air through the wall. According to different implementations of said embodiment, the walls are made of at least one of the following materials: wicker, fabric, metal, wood or plastic, all of them including through holes, either in the form of perforations (metal, wood) or in the form of interstitial spaces between filaments (wicker, tissue).

En funcion del ejemplo de realizacion, el envase del primer aspecto de la invencion se presenta provisto en forma de caja, bolsa o saco. According to the embodiment, the package of the first aspect of the invention is provided in the form of a box, bag or bag.

Para un ejemplo de realization, el envase de la invention consiste en una caja de carton u otro material permeable al aire que encierra un volumen determinado por caras rectangulares de dimensiones adecuadas a la aplicacion para la que este disenado el envase: contenedor fijo de uso domestico, contenedor de uso comercial, etc.For an example of realization, the packaging of the invention consists of a box of cardboard or other air-permeable material that encloses a volume determined by rectangular faces of dimensions appropriate to the application for which the container is designed: fixed container for domestic use , container for commercial use, etc.

De acuerdo con una implementation de dicho ejemplo de realization, sobre las caras de la caja, en su parte interna, se incorpora el material activo, es decir el agente conservante, en bolsas o sobres permeables al aire, de material textil plisado o carton corrugado, cuyos pliegues o corrugaciones contienen el material activo (en forma de arido de granulometrla adecuada para el correcto relleno de los pliegues), de un espesor aproximado de 6 mm.According to an implementation of said embodiment, on the faces of the box, in its internal part, the active material, ie the preservative agent, is incorporated in air-permeable bags or envelopes of pleated textile or corrugated cardboard. , whose folds or corrugations contain the active material (in the form of an arid with a granulometry suitable for the correct filling of the folds), of a thickness of approximately 6 mm.

Para otros ejemplos de realization, el envase del primer aspecto de la invention esta constituido por una bolsa de tela, tejida o sin tejer, permeable al aire, para uso domestico y transporte de pequeno numero de piezas, o bien por un saco de papel, donde el material activo se incorpore a la composition del papel, o bien por un saco de un tejido permeable al aire que incorpore bolsas conteniendo el material activo.For other examples of embodiment, the packaging of the first aspect of the invention consists of a cloth bag, woven or non-woven, air permeable, for domestic use and transport of small number of pieces, or by a paper bag, where the active material is incorporated into the composition of the paper, or by a bag of an air-permeable fabric that incorporates bags containing the active material.

Otras modalidades de envase serlan cajas de mimbre, o de un tejido de cierta consistencia, que permiten la aireacion de su interior, a las que incorporase el material activo de modo similar al indicado para el ejemplo de realization anterior.Other packaging modalities will be wicker boxes, or a fabric of a certain consistency, which allow the aeration of its interior, to which the active material will be incorporated in a manner similar to that indicated for the previous embodiment.

Otras modalidades serlan cajas de madera o metalicas cuya aireacion se consigue por un numero adecuado de perforaciones, y en cuyas caras internas se incorpora el material activo de modo similar al indicado anteriormente.Other modalities will be wooden or metal boxes whose aeration is achieved by an adequate number of perforations, and in whose internal faces the active material is incorporated in a manner similar to that indicated above.

Preferentemente, el envase propuesto por el primer aspecto de la invention es aplicable al deposito y conservation de productos de panaderla y/o reposterla que tengan propiedades de crujibilidad (con al menos una capa externa crujiente), y de manera mas preferida de piezas de pan.Preferably, the package proposed by the first aspect of the invention is applicable to the storage and preservation of bakery and / or pastry products having crispiness properties (with at least one crunchy outer layer), and more preferably bread pieces. .

Por ello, de manera preferida, el alcance de los productos alimenticios considerados se refiere a pan y productos de composition y textura similar, entendiendo por tales los elaborados a partir de una masa inicial que se moldea plasticamente, y que posteriormente es sometida a un proceso que reduce el contenido en agua, y da lugar a una lamina externa de menor contenido en humedad y mayor consistencia mecanica en relation a la humedad y consistencia del volumen interior de la pieza, diferencia de humedad y consistencia que origina un comportamiento adecuado del producto (crujibilidad) que se pierde con mayor rapidez en ambiente de humedad elevada. Therefore, preferably, the scope of the food products considered refers to bread and products of similar composition and texture, understood as those made from an initial mass that is molded plastically, and that is subsequently subjected to a process that reduces the content in water, and gives rise to an external sheet of lower content in humidity and greater mechanical consistency in relation to the humidity and consistency of the internal volume of the piece, difference of humidity and consistency that originates an adequate behavior of the product ( crujibilidad) that is lost more quickly in high humidity environment.

En general, las propiedades de protection frente a la humedad del agente conservante son regenerables al someterlo a una temperatura inferior a 200 °C, es decir regenerables domesticamente (durante la vida util del envase), ya que para ello se puede utilizar un horno domestico, por ejemplo un horno microondas.In general, the properties of protection against humidity of the preservative agent are regenerable when subjected to a temperature below 200 ° C, that is to say regenerable domestically (during the useful life of the container), since for this a domestic oven can be used , for example a microwave oven.

Ventajosamente, el agente conservador (y el contenedor que lo aloja, cuando es el caso) es desechable o reciclable cuando el envase ya se ha degradado mucho, es decir al final de la vida util del envase.Advantageously, the preservative agent (and the container that houses it, when it is the case) is disposable or recyclable when the container has already degraded a lot, that is to say at the end of the useful life of the container.

El envase del primer aspecto de la invention constituye un envase activo e inteligente, segun lo establecido en el Reglamento CE/450/2009, que permite el transporte y almacenamiento de, entre otros productos alimenticios, piezas de pan y similares de consumo diario, manteniendolos tiernos y crujientes.The packaging of the first aspect of the invention constitutes an active and intelligent packaging, according to what is established in Regulation CE / 450/2009, which allows the transport and storage of, among other food products, pieces of bread and the like of daily consumption, maintaining them tender and crispy.

El envase propuesto por el primer aspecto de la presente invencion se destina principalmente al consumidor domestico de los productos alimenticios, tal como pan, pero tambien tiene otras aplicaciones (en general cuando adopta la forma de saco, caja, etc...), con el mismo fundamento (incorporation de un agente conservante adecuado), destinandola por ejemplo a distribuidores, transportistas, hostelerla, etc. The container proposed by the first aspect of the present invention is intended primarily for the domestic consumer of food products, such as bread, but also has other applications (in general when it adopts the form of sack, box, etc ...), with the same foundation (incorporation of a suitable preservative agent), assigning it for example to distributors, transporters, hostelerla, etc.

La invencion permite prolongar la conservation de los atributos del pan en el domicilio del consumidor durante 12 - 24 horas en condiciones de alta humedad ambiental (hasta 90%) lo que supone una mejora respecto a envases convencionales actualmente en el mercado.The invention allows to prolong the conservation of bread attributes in the consumer's home during 12-24 hours in conditions of high humidity (up to 90%) which is an improvement over conventional packaging currently on the market.

Un segundo aspecto de la presente invencion concierne al uso de un agente conservante, protector frente a la humedad y apto para contacto alimentario, para la conservacion de productos alimenticios depositados en el interior de un envase permeable al aire, con preferencia de productos de panaderla y reposterla que tengan propiedades de crujibilidad.A second aspect of the present invention concerns the use of a preservative agent, protector against moisture and suitable for food contact, for the preservation of food products deposited inside an air permeable container, preferably bakery products and pastry that have crispness properties.

En general, el agente conservante comprende como mlnimo una sustancia con alta capacidad de sorcion (ab/adsorcion) de humedad.In general, the preservative comprises at least one substance with a high sorption capacity (ab / adsorption) of moisture.

De acuerdo a diferentes ejemplos de realization, dicha sustancia con alta capacidad de sorcion esta seleccionada de al menos uno de los siguientes grupos, que se enumeran a continuation de I a VII, y de los cuales unicamente seran aplicables aquellas aptas para el contacto alimentario:According to different embodiments, said substance with high sorption capacity is selected from at least one of the following groups, which are listed below from I to VII, and of which only those suitable for food contact are applicable:

I. Sustancias minerales con predominio de filosilicatos de los grupos de la clasificacion de filosilicatos de la AIPEA (Bailey, 1980), que a continuacion se indican: I. Mineral substances with predominance of phyllosilicates of the groups of the classification of phyllosilicates of the AIPEA (Bailey, 1980), which are indicated below:

1 - Grupo sepiolita - paligorskita, como la sepiolita, o la paligosrskita (en denomination norteamericana, attapulgita) o minerales de estructura intermedia entre la de estos minerales.1 - Sepiolite group - paligorskite, like sepiolite, or paligosrskite (in North American denomination, attapulgite) or minerals of intermediate structure between these minerals.

2- Grupo de las esmectitas, sean estas dioctaedricas (como montmorillonitas, o nontronitas) o trioctaedricas (como saponitas o hectoritas).2- Group of smectites, be these dioctaedricas (as montmorillonitas, or nontronitas) or trioctaedricas (as saponitas or hectoritas).

3- Grupo de las vermiculitas, sean dioctaedricas o trioctaedricas, cuando se presentan en tamano arcilla y con elevada superficie especlfica.3- Group of vermiculites, be they dioctahedral or trioctahedral, when they occur in clay size and with a high specific surface.

4- Grupos de minerales de la arcilla interestratificados, cuya estructura presenta laminas de esmectita.4- Groups of interstratified clay minerals, whose structure presents smectite sheets.

5. Illitas y sericitas, y minerales con estructura basica de laminas 2:1 asimilables al grupo de las micas en cuya estructura se presentan contenidos elevados de laminas de esmectita.5. Illitas and sericites, and minerals with basic structure of sheets 2: 1 assimilable to the group of micas in whose structure high contents of smectite sheets are presented.

Para los minerales del grupo 1 se emplean denominaciones comerciales o tradicionales como tierras de batan, o “fullers's earths”For group 1 minerals, commercial or traditional denominations are used as batan lands, or "fullers's earths"

Para los minerales del grupo 2 se suele emplear la denomination comercial de bentonitas.For the minerals of group 2, the commercial denomination of bentonites is usually used.

II. Sustancias minerales con predominio de diatomita (tambien denominada kieselguhr, o arena de diatomeas, o tierra de diatomeas), con o sin tratamiento termico.II. Mineral substances with a predominance of diatomite (also known as kieselguhr, or diatomaceous earth, or diatomaceous earth), with or without thermal treatment.

III. Arcillas pilareadas, sintetizadas por insertion mediante intercambio ionico de policationes metalicos voluminosos en espacios interlaminares de los minerales de la arcilla originales, normalmente del grupo de las esmectitas, aumentando mucho su espaciado basal, seguido de calcinacion estabilizando la estructura con un espaciado basal superior al inicial.III. Pillared clays, synthesized by insertion by ion exchange of voluminous metal polycations in interlaminar spaces of the original clay minerals, usually from the group of smectites, greatly increasing their basal spacing, followed by calcination stabilizing the structure with a basal spacing greater than the initial .

IV. Substancias minerales naturales o sinteticas del grupo de las zeolitas, en general, y predominantemente las clasificadas como 4 A y 3 A (cuyos tamanos maximos de poro son inferiores a esos tamanos).IV. Natural or synthetic mineral substances of the group of zeolites, in general, and predominantly those classified as 4 A and 3 A (whose maximum pore sizes are less than those sizes).

V. Geles de sllice y geles de alumina desecados.V. Gels of silica and dried alumina gels.

VI. Otros sorventes de humedad no higroscopicos.SAW. Other non-hygroscopic moisture absorbers.

El material activo puede emplearse en diferentes modos, bien como polvo fino, bien en forma granular o bien aglomerado, pudiendo ser suministrado como mineral bruto con solo clasificacion mecanica, o bien con tratamientos flsicos o qulmicos de activation. The active material can be used in different ways, either as fine powder, in granular or agglomerated form, and can be supplied as raw ore with only mechanical classification, or with physical or chemical treatments of activation.

Breve description de los dibujosBrief description of the drawings

Las anteriores y otras ventajas y caracteristicas se comprenderan mas plenamente a partir de la siguiente description detallada de unos ejemplos de realization con referencia a los dibujos adjuntos, que deben tomarse a trtulo ilustrativo y no limitativo, en los que:The foregoing and other advantages and features will be more fully understood from the following detailed description of some realization examples with reference to the accompanying drawings, which must be taken by way of illustration and not limitation, in which:

La Figura 1 es una vista en perspectiva que representa de manera esquematica al envase propuesto por el primer aspecto de la presente invention;Figure 1 is a perspective view schematically representing the package proposed by the first aspect of the present invention;

Las Figuras 2 y 3 muestra los tipos mas frecuentes de evolution de resistencia (kg/cm2) en ensayos de compresion-flexion, a diferentes tiempos contados a partir del fin del horneado de la pieza de pan (1:2 horas, 2:5 horas, 3:10 h, y 4:24 horas), en piezas de pan conservadas en condiciones de humedad extraordinaria (HR= 85%) utilizando envases convencionales (cuadros huecos) o envases como el propuesto por el primer aspecto de la invencion, es decir incorporando conservante (cuadros rellenos).Figures 2 and 3 show the most frequent types of evolution of resistance (kg / cm2) in compression-flexion tests, at different times counted from the end of the baking of the piece of bread (1: 2 hours, 2: 5 hours, 3:10 h, and 4:24 hours), in pieces of bread preserved in conditions of extraordinary humidity (HR = 85%) using conventional containers (hollow boxes) or containers as proposed by the first aspect of the invention, that is, incorporating preservative (filled boxes).

Descripcion detallada de unos ejemplos de realizacionDetailed description of some examples of realization

En la Figura 1 se ilustra un ejemplo de realizacion para el que el envase 1 propuesto por el primer aspecto de la presente invencion, aplicable al deposito y conservation de productos alimenticios, es una caja que comprende unas paredes 1a, 1b, 1c, 1d, 1e, 1f que permiten el paso de aire a su traves (ya sea por estar hechas de un material permeable al aire, tal como carton, o porque incluyan perforaciones de aireacion) y que estan dispuestas de manera que definen un recinto con una abertura A para la introduction de productos alimenticios en su interior, en este caso piezas de pan, asi como unos medios de cierre 3a, 3b para cerrar dicha abertura A una vez los productos alimenticios se encuentran alojados en el interior del recinto.In Figure 1 is illustrated an embodiment for which the package 1 proposed by the first aspect of the present invention, applicable to the storage and storage of food products, is a box comprising walls 1a, 1b, 1c, 1d, 1e, 1f allowing the passage of air through it (either by being made of an air-permeable material, such as cardboard, or because they include aeration perforations) and which are arranged so as to define an enclosure with an opening A for introducing food products therein, in this case pieces of bread, as well as closing means 3a, 3b for closing said opening A Once the food products are housed inside the room.

Como puede apreciarse en la Figura 1, el envase 1 comprende unos contenedores 2 que son permeables al aire y que alojan en su interior un agente conservante protector frente a la humedad (desecante) apto para contacto alimentario, donde los contenedores 2 estan adosados a algunas de las paredes del envase, en el caso particular de la figura, adosados a las paredes 1a, 1b, 1c, 1d y 1e (en las dos ultimas, no se aprecian en la vista presentada).As can be seen in Figure 1, the container 1 comprises containers 2 that are permeable to air and that house inside a preservative agent protective against moisture (desiccant) suitable for food contact, where the containers 2 are attached to some of the walls of the container, in the particular case of the figure, attached to the walls 1a, 1b, 1c, 1d and 1e (in the last two, they are not seen in the view presented).

Los presentes inventores han efectuado experimentos, emulando unos prototipos del envase propuesto por el primer aspecto de la presente invencion, que se describiran a continuacion. The present inventors have carried out experiments, emulating prototypes of the package proposed by the first aspect of the present invention, which will be described below.

Dispositivos y procedimientos experimentales:Experimental procedures and devices:

i. Ensayos de medidas de humedad y de resistencia a la compresion:i. Testing of moisture measurements and resistance to compression:

La experimentation practicada incluye una amplia campana utilizando barras de pan tradicional de cierta calidad sobre las que se han practicado mediciones de variation de contenido de humedad de la miga y de la corteza asl como de resistencia mecanica a la compresion-flexion de las piezas de pan (mediante un ensayo puesto a punto para el caso), con el tiempo transcurrido desde el horneado, en ambientes de humedad controlada.The experimentation includes a wide bell using traditional bread bars of a certain quality on which measurements have been made of variation of moisture content of the crumb and of the crust as well as of mechanical resistance to the compression-flexion of the pieces of bread (by means of a test set up for the case), with the time elapsed since the baking, in controlled humidity environments.

Equipamiento y materiales utilizados: caja de plastico o de porespan impermeabilizado, con ambientes de humedad variable en el intervalo 30-90%, mediante soluciones salinas saturadas procurando humedades de equilibrio determinadas, termo-higrometro digital para control de humedad relativa en el dispositivo, penetrometro de mano (marca Fachini, indentador cillndrico de 6.65 mm de diametro) para medicion de resistencia a la compresion (en el rango de 0,1 a 1,8 Kg/cm2), bolsas de tela, sobres conteniendo material activo seco, analizador de humedad (modelo Ohaus, MB35).Equipment and materials used: plastic or waterproofed porespan box, with variable humidity environments in the range 30-90%, by means of saturated saline solutions, providing certain equilibrium humidities, digital thermo-hygrometer to control relative humidity in the device, penetrometer (Fachini brand, cylindrical indentation of 6.65 mm in diameter) for measurement of resistance to compression (in the range of 0.1 to 1.8 Kg / cm2), cloth bags, envelopes containing dry active material, analyzer of humidity (Ohaus model, MB35).

En cajas de porespan (de 20x20x25 cm3), con impermeabilizacion exterior y de cierre hermetico, se establecio una humedad prefijada, incorporando un receptaculo que contenla solution saturada de una sal cuya humedad de equilibrio era la deseada para el experimento. Durante la realization del experimento la temperatura y humedad fueron medidas mediante termo-higrometro digital residente en la caja de porespan. In porespan boxes (20x20x25 cm3), with external waterproofing and hermetic sealing, a pre-set humidity was established, incorporating a receptacle containing saturated solution of a salt whose equilibrium moisture was the desired for the experiment. During the realization of the experiment the temperature and humidity were measured by thermo-hygrometer digital resident in the box of porespan.

Cada caja contenla una jaula de 14 x 22 x 6 cm3, es decir de volumen aproximadamente igual a la mitad del volumen util de una bolsa convencional utilizada para alojar tres o cuatro barras de “cuarto” (aprox. 4000 cm3), en la que se acoplo una bolsa de tela conteniendo en su interior media barra de pan. La caja de ensayo con humedad controlada tenia un volumen interno de 10000 cm3. Para cada condition de humedad, y para cada agente activo, se realizo el experimento con media barra en bolsa situada en la jaula, en la parte inferior de la bolsa de tela y dentro de la jaula, se coloco un sobre de papel conteniendo el agente activo, es decir el agente conservante, y sobre la bolsa de tela y en contacto con ella, se situo tambien otro sobre de papel conteniendo el agente activo. El peso inicial del material activo fue prefijado (75 g, para el caso de la sepiolita), comprobandose en todos los casos que la sorcion de vapor de agua en el agente activo a tres horas del inicio del experimento habla sido igual o superior al 9 % en peso. En las mismas condiciones se realizo el experimento en blanco, con otra caja de porespan analoga, pero sin incorporar el agente activo. Each box contains a cage of 14 x 22 x 6 cm3, that is to say of volume approximately equal to half the useful volume of a conventional bag used to house three or four "quarter" bars (approximately 4000 cm3), in which a cloth bag containing half a loaf of bread inside it was attached. The test box with controlled humidity had an internal volume of 10000 cm3. For each condition of humidity, and for each active agent, the experiment was carried out with half a bar in a bag located in the cage, in the lower part of the cloth bag and inside the cage, a paper envelope containing the agent was placed active agent, that is to say the preservative agent, and on the cloth bag and in contact with it, another paper envelope containing the active agent was also placed. The initial weight of the active material was preset (75 g, for the case of sepiolite), and it was verified in all cases that the sorption of water vapor in the active agent at three hours after the start of the experiment had been equal to or greater than 9 hours. % in weigh. Under the same conditions the experiment was carried out in white, with another box of analogous porespan, but without incorporating the active agent.

Desarrollo experimental realizado:Experimental development carried out:

Se utilizaron dos agente activos formados por minerales de la arcilla seleccionados entre dos grupos: el de las esmectitas y el de la paligorskita-sepiolita (con amplia production en Espana) y se realizaron experimentos a dos humedades representativas de condiciones muy desfavorables para el mantenimiento de la crujibilidad. Con mediciones sucesivas a los cuatro tiempos indicados arriba.Two active agents were used, formed by clay minerals selected from two groups: the smectites and the paligorskite-sepiolite (with extensive production in Spain) and experiments were carried out at two humidities representative of very unfavorable conditions for the maintenance of the crunchiness. With successive measurements at the four times indicated above.

A tiempos 1, 2,3 y 4 (correspondientes a 2, 5, 10 y 24 horas tras el horneado) se efectuaron medidas de humedad en miga y corteza, asl como de resistencia a compresion. Para cada tiempo se efectuaron 4 mediciones de humedad (tres en corteza y una en miga, en porciones de 0,7 g), y 12 de resistencia a compresion. Las determinaciones de humedad de obtuvieron por perdida de peso a 130°C durante 20 minutos, en porciones de 0,55 g.At times 1, 2, 3 and 4 (corresponding to 2, 5, 10 and 24 hours after baking) moisture measurements were made in crumb and bark, as well as compression resistance. For each time, 4 moisture measurements were made (three in crust and one in crumb, in 0.7 g portions), and 12 in compression resistance. The moisture determinations obtained by weight loss at 130 ° C for 20 minutes, in portions of 0.55 g.

Se puso a punto un procedimiento de medicion de resistencia a la penetration, por medida de resistencia a la compresion de la pieza de pan, con una distancia entre apoyos adecuada. La medida obtenida no corresponde en sentido estricto a una resistencia a la compresion sino a compresion - flexion con baja deformation.A procedure for measuring resistance to penetration, by measuring the resistance to compression of the piece of bread, with a suitable distance between supports was developed. The measurement obtained does not correspond in a strict sense to a resistance to compression but to compression - flexion with low deformation.

Esta medicion de resistencia a penetracion se efectuo utilizando un penetrometro de bolsillo en la parte plana la pieza, en su parte central, alejada de los extremos, efectuando las perforaciones a lo largo de 15-18 cm, apoyando la pieza a una distancia conveniente (2 cm), y manteniendose la pieza aguantada con una mano durante la realizacion del ensayo.This measurement of resistance to penetration was made using a pocket penetrometer in the flat part, in its central part, away from the ends, making the perforations along 15-18 cm, supporting the piece at a convenient distance ( 2 cm), and keeping the piece supported with one hand during the performance of the test.

La pieza de pan con un comportamiento gomoso (inadecuado) se caracteriza por un elevado contenido en humedad de la miga, asl como por dejar de percibirse el sonido crujiente durante la perforation con el penetrometro y por adquirir, la pieza, una alta resistencia a la perforacion (al tiempo 4) ocasionada por la perdida del comportamiento fragil de la corteza (deformacion previa a la perforacion).The piece of bread with a gummy (inadequate) behavior is characterized by a high content of moisture in the crumb, as well as by not perceiving the crispy sound during the perforation with the penetrometer and by acquiring, the piece, a high resistance to perforation (at time 4) caused by the loss of the fragile behavior of the crust (deformation prior to perforation).

Despues de realizar ensayos de puesta a punto del dispositivo de compresion, se realizaron diferentes ensayos. Las figuras 2 y 3 ejemplifican los tipos mas frecuentes de evolution de resistencia a la compresion Rc (kg/cm2) con el tiempo trascurrido despues del horneado, t (1, 2, 3 y 4 correspondientes a 2, 5, 10 y 24 horas respectivamente) reconocidos en una amplia campana de ensayos (30). En ambas figuras se comparan resistencias a tiempo variable, con agente conservante (Rc_cort_c) y sin agente conservante (Rc_cor_s), en condition de humedad extremada (HR=85%), para diferentes piezas de pan. A tiempo 3 se percibe organolepticamente (oldo y tacto) mantenimiento de crujibilidad de la pieza, pudiendo el valor de Rc ser inferior o superior al de tiempo 2 (con adicion, siempre superior, sin adicion, no siempre). A tiempo 4 siempre se aprecia el aumento de valor de Rc respecto al valor medido en tiempo 3, en experiencia sin agente activo mientras que en piezas con agente activo ocurre lo contrario.After carrying out testing of the compression device, different tests were carried out. Figures 2 and 3 exemplify the most frequent types of evolution of resistance to compression Rc (kg / cm2) with the time elapsed after baking, t (1, 2, 3 and 4 corresponding to 2, 5, 10 and 24 hours respectively) recognized in a wide range of tests (30). In both figures, resistances are compared to variable time, with preservative agent (Rc_cort_c) and without preservative agent (Rc_cor_s), in extreme humidity condition (HR = 85%), for different pieces of bread. At time 3 it is perceived organoleptically (oldo and touch) maintenance of the piece's crispness, the value of Rc may be lower or higher than time 2 (with addition, always higher, without addition, not always). At time 4 the increase in value of Rc with respect to the value measured at time 3 is always appreciated, in experience without active agent while in pieces with active agent the opposite occurs.

En estos experimentos, los valores de humedad de miga son decrecientes, y los de corteza crecientes (esto ultimo en mayor medida en las muestras sin agente activo), lo que justifica el aumento de resistencia medida que traduce el comportamiento elasticono fragil de la pieza.In these experiments, moisture values of crumb are decreasing, and those of bark increasing (this last in greater measure in the samples without active agent), which justifies the increase in measured resistance that translates the fragile elastic behavior of the piece.

Las diferencias de comportamiento mecanico son bastante claras.The differences in mechanical behavior are quite clear.

ii. Ensayos de crujibilidad:ii. Crucibility tests:

Adicionalmente, en un conjunto de barras, conservadas en condiciones de humedad extraordinaria (HR = 85%) y de humedad normal (HR=40%), en dispositivos ubicados en el laboratorio (incorporando o no el agente conservante), y a distintos tiempos desde el horneado, se ha practicado un test de crujibilidad mediante el ensayo simultaneo de puncion dinamica y medicion de sonido (equipo TA XTplus, Stable Micro Systems).Additionally, in a set of bars, preserved under conditions of extraordinary humidity (HR = 85%) and normal humidity (HR = 40%), in devices located in the laboratory (incorporating or not the preservative agent), and at different times from the baking, a crujibilidad test has been practiced by the simultaneous test of dynamic puncture and sound measurement (TA XTplus equipment, Stable Micro Systems).

Los experimentos se han realizado para un envase constituido por una caja de carton que encierra un volumen determinado por caras rectangulares de dimensiones aproximadas A: 30 cm x 45 cm (2 caras), B: 7 cm x 45 cm (2 caras) y C: 7 cm x 30 cm (2 caras), para disposicion horizontal paralelamente a las caras A, y con dosificacion de 300 g de sepiolita.The experiments have been carried out for a container consisting of a cardboard box enclosing a volume determined by rectangular faces of approximate dimensions A: 30 cm x 45 cm (2 faces), B: 7 cm x 45 cm (2 faces) and C : 7 cm x 30 cm (2 sides), for horizontal arrangement parallel to the A faces, and with 300 g of sepiolite.

Para una description mas completa del fenomeno se efectuaron los ensayos de crujibilidad aqul descritos (realizados en piezas conservadas con o sin conservante, y en ambiente de humedad normal o de humedad extraordinaria) con penetration dinamica y medicion simultanea de senales acusticas en un texturometro TA.XT Plus, trabajando con una sonda cillndrica (area de contacto 3 mm2), segun procedimiento basado en el trabajo de Van Hecke E., Alaf A.K., y Bouvier J.M., 1998. Texture and structure of crispy - puffed food products, part II: Mechanical properties in puncture. Journal of Texture Studies 29 (1998) 617-632. Los resultados obtenidos se exponen en las dos tablas siguientes, para dos barras, identificadas como barra A, con una corteza de grosor superior a 1 mm, y barra B, con una corteza de grosor inferior a 1 mm, para ocho ensayos E N° 1 a E N° 8, referenciados respectivamente como A0, A5S, A5C, B5S, B10C, B10C, A24S, B24S. For a more complete description of the phenomenon, the crustability tests described here (carried out in conserved pieces with or without a preservative, and in an environment of normal humidity or extraordinary humidity) were carried out with dynamic penetration and simultaneous measurement of acoustic signals in a TA texturometer. XT Plus, working with a cylindrical probe (contact area 3 mm2), according to the procedure based on the work of Van Hecke E., Alaf AK, and Bouvier JM, 1998. Texture and structure of crispy - puffed food products, part II: Mechanical properties in puncture. Journal of Texture Studies 29 (1998) 617-632. The results obtained are shown in the following two tables, for two bars, identified as bar A, with a bark thicker than 1 mm, and bar B, with a bark thicker than 1 mm, for eight tests EN ° 1 to EN ° 8, referenced respectively as A0, A5S, A5C, B5S, B10C, B10C, A24S, B24S.

Tabla 1aTable 1a

Figure imgf000013_0001
Figure imgf000013_0001

Tabla 1bTable 1b

Figure imgf000014_0001
Figure imgf000014_0001

La tabla 1a incluye caracterlsticas de pieza de pan ensayada, y la tabla 1b resume los efectos sonicos registrados en el ensayo de penetracion dinamica, al medir la carga de rotura (cuyo valor no se incluye en la tabla).Table 1a includes characteristics of bread piece tested, and table 1b summarizes the sonic effects recorded in the dynamic penetration test, when measuring the breaking load (whose value is not included in the table).

La tabla 1b incluye el valor de la intensidad en decibelios del efecto sonico principal registrado hasta 5 segundos (S a AT =5 sg), as! como si se registraron o no, efectos sonicos adicionales diferenciables del fondo (cuya intensidad en decibelios se incluye en la columna Fondo).Table 1b includes the value of the intensity in decibels of the main sonic effect recorded up to 5 seconds (S to AT = 5 sg), as! as if they were recorded or not, additional distinguishable sonic effects of the fund (whose intensity in decibels is included in the Fund column).

Con este experimento se pone de manifiesto mediante los ensayos 2 y 3 (referencias A5S y A5C) que a 5 horas, con agente activo, y ambiente de humedad extraordinaria (ensayo 3), se mantiene la crujibilidad con humedad extraordinaria (ya que se presenta efecto sonico principal claramente resuelto respecto al fondo, apreciandose tambien efectos secundarios diferenciables del fondo) similar a la reconocida en el ensayo 2 para barra analoga con humedad normal.With this experiment, it is shown by tests 2 and 3 (references A5S and A5C) that at 5 hours, with active agent, and extraordinary humidity environment (test 3), the crunchiness is maintained with extraordinary humidity (since it is presented main sonic effect clearly resolved with respect to the background, also appreciable secondary effects differentiable from the background) similar to that recognized in the test 2 for analogous bar with normal humidity.

Por otra parte los ensayos 5 y 6 permitieron apreciar mantenimiento de efectos sonicos, secundarios diferenciables del fondo, mas manifiestos en la barra con mayor espesor de corteza (ensayo 5).On the other hand, tests 5 and 6 allowed us to appreciate the maintenance of sonic effects, secondary differentiable from the bottom, more evident in the bar with greater bark thickness (essay 5).

Los resultados obtenidos validan la eficacia del agente activo en el mantenimiento de la crujibildad de la pieza de pan, manteniendo una humedad de la miga admisible (obviamente resecando el pan fresco hasta pan “duro”, se desecan tanto corteza como miga, la corteza aumenta su resistencia mecanica pero tambien la miga, y se cambia la naturaleza del producto). La comparacion de ensayos 2 y 5, o de 4 y 6, en cuanto a datos de humedad, muestra una reduccion del contenido en humedad de la corteza, con escasa variacion del contenido en humedad de la miga, lo que traduce una cierta constancia composicional durante el intervalo de 12 horas en que se suele realizar el consumo (desayuno, comida, merienda, cena) del pan diario.The results obtained validate the efficacy of the active agent in the maintenance of the crujibildad of the piece of bread, maintaining a moisture of the admissible crumb (obviously drying the fresh bread until bread "hard", dry both bark and crumb, the crust increases its mechanical resistance but also the crumb, and the nature of the product is changed). The comparison of tests 2 and 5, or 4 and 6, in terms of moisture data, shows a reduction in the moisture content of the crust, with little variation in the moisture content of the crumb, which translates a certain compositional constancy during the 12-hour interval in which consumption is usually made (breakfast, lunch, snack, dinner) of daily bread.

Un experto en la materia podrla introducir cambios y modificaciones en los ejemplos de realization descritos sin salirse del alcance de la invention segun esta definido en las reivindicaciones adjuntas. A person skilled in the art could introduce changes and modifications in the described embodiment examples without departing from the scope of the invention as defined in the appended claims.

Claims (20)

REIVINDICACIONES 1. - Envase (1) aplicable al deposito y conservation de productos alimenticios, que comprende unas paredes (1a, 1b, 1c, 1d, 1e, 1f) dispuestas de manera que definen un recinto con al menos una abertura (A) para la introduction de productos alimenticios en su interior, donde al menos parte de dichas paredes (1a, 1b, 1c, 1d, 1e, 1f) permiten el paso de aire a traves de la pared para airear el envase, estando el envase caracterizado porque al menos una de sus paredes (1a, 1b, 1c, 1d, 1e, 1f), contiene en su interior o adosado a una de sus caras, al menos un agente conservante protector frente a la humedad y apto para contacto alimentario.1. - Container (1) applicable to the deposit and conservation of food products, comprising walls (1a, 1b, 1c, 1d, 1e, 1f) arranged so as to define an enclosure with at least one opening (A) for the introduction of food products inside, where at least part of said walls (1a, 1b, 1c, 1d, 1e, 1f) allow the passage of air through the wall to aerate the container, the container being characterized in that at least one of its walls (1a, 1b, 1c, 1d, 1e, 1f) contains, in its interior or attached to one of its faces, at least one preservative agent that protects against moisture and is suitable for food contact. 2. - Envase (1) segun la revindication 1, que comprende al menos un elemento (2) que incluye a dicho agente conservante y que se encuentra adosado a al menos una cara de dicha pared (1a, 1b, 1c, 1d, 1e, 1f), que es al menos una.2. - Container (1) according to claim 1, comprising at least one element (2) including said preservative and which is attached to at least one side of said wall (1a, 1b, 1c, 1d, 1e) , 1f), which is at least one. 3. - Envase (1) segun la revindication 2, que comprende una pluralidad de dichos elementos (2) adosados a unas caras de algunas o todas dichas paredes (1a, 1b, 1c, 1d, 1e, 1f).3. - Container (1) according to claim 2, comprising a plurality of said elements (2) attached to faces of some or all said walls (1a, 1b, 1c, 1d, 1e, 1f). 4. - Envase (1) segun la revindication 2 o 3, en el que dicha o dichas caras son unas caras internas de las paredes (1a, 1b, 1c, 1d, 1e, 1f) del envase (1) que delimitan a dicho recinto. 4. - Container (1) according to re v indication 2 or 3, wherein said or said faces are internal faces of the walls (1a, 1b, 1c, 1d, 1e, 1f) of the container (1) that delimit to said enclosure. 5. - Envase (1) segun la revindication 2 o 3, en el que dicha o dichas caras son unas caras externas de las paredes (1a, 1b, 1c, 1d, 1e, 1f) del envase (1). 5. - Container (1) according to re v indication 2 or 3, wherein said or said faces are external faces of the walls (1a, 1b, 1c, 1d, 1e, 1f) of the container (1). 6. - Envase (1) segun una cualquiera de las reivindicaciones 2 a 5, en el que dicho elemento (2) es un contenedor permeable al aire que aloja a dicho agente conservante en su interior.6. - Container (1) according to any one of claims 2 to 5, wherein said element (2) is an air-permeable container that houses said preservative agent inside. 7. - Envase (1) segun la revindication 1, en el que dicho agente conservante se encuentra integrado en dicha pared (1a, 1b, 1c, 1d, 1e, 1f), que es al menos una. 7. - Container (1) according to re v indication 1, wherein said preservative agent is integrated into said wall (1a, 1b, 1c, 1d, 1e, 1f), which is at least one. 8. - Envase (1) segun la revindication 7, en el que el agente conservante se encuentra incorporado en la composition o en la estructura de dicha pared (1a, 1b, 1c, 1d, 1e, 1f), que es al menos una. 8. - Container (1) according to re v indication 7, in which the preservative agent is incorporated in the composition or structure of said wall (1a, 1b, 1c, 1d, 1e, 1f), which is the minus one. 9. - Envase (1) segun una cualquiera de las reivindicaciones anteriores, que comprende unos medios de cierre (3a, 3b) para cerrar dicha abertura (A) una vez los productos alimenticios se encuentran alojados en el interior de dicho recinto. 9. - Container (1) according to any one of the preceding claims, comprising closing means (3a, 3b) to close said opening (A) once the food products are housed inside said enclosure. 10. - Envase (1) segun una cualquiera de las reivindicaciones anteriores, en el que al menos parte de dichas paredes (1a, 1b, 1c, 1d, 1e, 1f) estan hechas de un material permeable al aire permitiendo el paso del aire a traves de la pared.10. - Container (1) according to any one of the preceding claims, wherein at least part of said walls (1a, 1b, 1c, 1d, 1e, 1f) are made of an air permeable material allowing the passage of air through the wall. 11. - Envase (1) segun la reivindicacion 10, en el que dichas paredes (1a, 1b, 1c, 1d, 1e, 1f) estan hechas de al menos uno de los siguientes materiales: carton, papel o tela.11. - Container (1) according to claim 10, wherein said walls (1a, 1b, 1c, 1d, 1e, 1f) are made of at least one of the following materials: cardboard, paper or cloth. 12. - Envase (1) segun una cualquiera de las reivindicaciones 1 a 9, en el que al menos parte de dichas paredes (1a, 1b, 1c, 1d, 1e, 1f) comprenden o definen unos orificios o huecos que permitan el paso de aire a traves de la pared.12. - Container (1) according to any one of claims 1 to 9, wherein at least part of said walls (1a, 1b, 1c, 1d, 1e, 1f) comprise or define orifices or holes that allow the passage of air through the wall. 13. - Envase (1) segun la reivindicacion 12, en el que dichas paredes (1a, 1b, 1c, 1d, 1e, 1f) estan hechas de al menos uno de los siguientes materiales: mimbre, tejido, metal, madera o plastico.13. - Container (1) according to claim 12, wherein said walls (1a, 1b, 1c, 1d, 1e, 1f) are made of at least one of the following materials: wicker, woven, metal, wood or plastic . 14. - Envase (1) segun una cualquiera de las reivindicaciones anteriores, en el que dicho agente conservante comprende al menos una sustancia microporosa con elevada capacidad de sorcion de vapor de agua para ambientes de humedad relativa superiores al 50%, resultando suficientes valores superiores al 11% en peso.14. - Package (1) according to any one of the preceding claims, wherein said preservative comprises at least one microporous substance with high water vapor sorption capacity for environments of relative humidity greater than 50%, resulting in sufficient values higher to 11% by weight. 15. - Envase (1) segun la reivindicacion 14, en el que dicha sustancia con alta capacidad de sorcion esta seleccionada de al menos uno de los siguientes grupos: 15. - Package (1) according to claim 14, wherein said substance with high sorption capacity is selected from at least one of the following groups: I. Sustancias minerales con predominio de filosilicatos de los siguientes grupos de la clasificacion de filosilicatos de la AIPEA: sepiolita - paligorskita, esmectitas, vermiculitas, cuando presentan tamano arcilla y elevada superficie especlfica, minerales de la arcilla interestratificados con laminas de esmectita, en tamano arcilla y elevada superficie especlfica, e illitas, sericitas, y minerales con estructura basica de laminas 2:1 presentando contenidos elevados de laminas de esmectita y elevada superficie especlfica;I. Mineral substances with predominance of phyllosilicates of the following groups of the classification of phyllosilicates of the AIPEA: sepiolite - paligorskite, smectites, vermiculites, when they present clay size and high specific surface, minerals of clay interbedded with smectite sheets, in size clay and high specific surface, and illites, sericites, and minerals with basic structure of sheets 2: 1 presenting high contents of smectite sheets and high specific surface; II. Sustancias minerales con predominio de diatomita, con o sin tratamiento termico; II. Mineral substances with a predominance of diatomite, with or without thermal treatment; III. Arcillas pilareadas, sintetizadas por insercion mediante intercambio ionico de policationes metalicos voluminosos y tratamiento adicional;III. Pillared clays, synthesized by insertion by ion exchange of voluminous metal polycations and additional treatment; IV. Sustancias minerales naturales o sinteticas del grupo de las zeolitas, preferentemente las clasificadas como 4 A y 3 A;IV. Natural or synthetic mineral substances from the group of zeolites, preferably those classified as 4 A and 3 A; V. Geles de sllice y geles de alumina desecados; V. Gels of silica and dried alumina gels; VI. Otros sorbentes de humedad no higroscopicos.SAW. Other non-hygroscopic moisture sorbents. 16.- Envase (1) segun una cualquiera de las reivindicaciones anteriores, aplicable al deposito y conservacion de productos de panaderla y reposterla que tengan propiedades de crujibilidad.16. Container (1) according to any one of the preceding claims, applicable to the storage and preservation of bakery and pastry products that have crispness properties. 17.- Envase (1) segun la reivindicacion 16, aplicable al deposito y conservacion de piezas de pan.17. Container (1) according to claim 16, applicable to the storage and preservation of pieces of bread. 18. - Envase (1) segun una cualquiera de las reivindicaciones anteriores, provisto en forma de caja, bolsa o saco.18. - Packaging (1) according to any one of the preceding claims, provided in the form of a box, bag or sack. 19. Envase (1) segun una cualquiera de las reivindicaciones anteriores, en el que las propiedades de proteccion frente a la humedad de dicho agente conservante son regenerables al someterlo a una temperatura inferior a 200 ° C.19. Container (1) according to any one of the preceding claims, wherein the moisture protection properties of said preservative are regenerable when subjected to a temperature below 200 ° C. 20. - Uso de un agente conservante, protector frente a la humedad y apto para contacto alimentario, para la conservacion de productos alimenticios depositados en el interior de un envase permeable al aire definido de acuerdo con una cualquiera de las reivindicaciones anteriores. 20. - Use of a preservative agent, protector against moisture and suitable for food contact, for the preservation of food products deposited inside an air permeable container defined according to any one of the preceding claims.
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