ES259578A1 - Process for the manufacture of epoxy resins - Google Patents
Process for the manufacture of epoxy resinsInfo
- Publication number
- ES259578A1 ES259578A1 ES0259578A ES259578A ES259578A1 ES 259578 A1 ES259578 A1 ES 259578A1 ES 0259578 A ES0259578 A ES 0259578A ES 259578 A ES259578 A ES 259578A ES 259578 A1 ES259578 A1 ES 259578A1
- Authority
- ES
- Spain
- Prior art keywords
- phenol
- bisphenol
- reacting
- vanillyl alcohol
- epichlorohydrin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/22—Di-epoxy compounds
- C08G59/24—Di-epoxy compounds carbocyclic
- C08G59/245—Di-epoxy compounds carbocyclic aromatic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Epoxy Resins (AREA)
Abstract
The invention comprises a thermosetting resin comprising the reaction product of epichlorohydrin or a dihalogen hydrin and a bisphenol of the formula <FORM:0920520/IV(a)/1> in which R is an aromatic nucleus which may contain unreactive substituents and a process for the production of thermosetting synthetic resins which comprises reacting vanillyl alcohol in acid medium with at least an equimolar amount of a phenol and reacting the bisphenol thus obtained with epichlorohydrin at elevated temperature in the presence of alkali. The epoxy resins are hardened with the usual catalysts, e.g. acids, acid anhydrides, primary and secondary aliphatic and aromatic monovalent and polyfunctional amines or polyamides. In examples vanillyl alcohol is heated with phenol or o-cresol in the presence of hydrochloric acid with removal of water and the bisphenol obtained is heated with epichlorhydrin in the presence of sodium hydroxide. The products are mixed with phthalic anhydride and allowed to set at elevated temperature.ALSO:Bisphenols for use in the preparation of thermosetting resins (see Group IV(a)) are prepared by reacting vanillyl alcohol in acid medium with at least an equimolar amount of a phenol e.g. phenol or o-cresol.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH7721059A CH378043A (en) | 1959-08-21 | 1959-08-21 | Method for producing a curable epoxy resin |
Publications (1)
Publication Number | Publication Date |
---|---|
ES259578A1 true ES259578A1 (en) | 1960-12-01 |
Family
ID=4535493
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES0259578A Expired ES259578A1 (en) | 1959-08-21 | 1960-07-11 | Process for the manufacture of epoxy resins |
Country Status (7)
Country | Link |
---|---|
BE (1) | BE592732A (en) |
CH (1) | CH378043A (en) |
DE (1) | DE1145361B (en) |
ES (1) | ES259578A1 (en) |
FR (1) | FR1262420A (en) |
GB (1) | GB920520A (en) |
NL (1) | NL253751A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015183892A1 (en) * | 2014-05-27 | 2015-12-03 | Reno Kaleigh Havery | Bisphenol alternatives derived from renewable susbstituted phenolics and their industrial application |
EP3002303A1 (en) | 2014-10-03 | 2016-04-06 | Université de Bordeaux | New phenolic polymers and preparation processes thereof |
-
0
- NL NL253751D patent/NL253751A/xx unknown
- BE BE592732D patent/BE592732A/xx unknown
-
1959
- 1959-08-21 CH CH7721059A patent/CH378043A/en unknown
-
1960
- 1960-07-01 DE DEJ18385A patent/DE1145361B/en active Pending
- 1960-07-11 ES ES0259578A patent/ES259578A1/en not_active Expired
- 1960-07-13 FR FR832963A patent/FR1262420A/en not_active Expired
- 1960-08-04 GB GB27076/60A patent/GB920520A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
CH378043A (en) | 1964-05-31 |
DE1145361B (en) | 1963-03-14 |
GB920520A (en) | 1963-03-06 |
FR1262420A (en) | 1961-05-26 |
NL253751A (en) | |
BE592732A (en) |
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