ES2575829T3 - Vitrocerámica y vidrio de silicato de litio con contenido en ZrO2 - Google Patents
Vitrocerámica y vidrio de silicato de litio con contenido en ZrO2 Download PDFInfo
- Publication number
- ES2575829T3 ES2575829T3 ES11162840.0 ES2575829T3 ES 2575829 T3 ES2575829 T3 ES 2575829T3 ES 2575829 T3 ES2575829 T3 ES 2575829T3
- Authority
- ES
- Spain
- Prior art keywords
- vitroceramic
- silicate glass
- lithium silicate
- zro2 content
- zro2
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 title description 8
- PAZHGORSDKKUPI-UHFFFAOYSA-N Lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 title 1
- 229910052912 lithium silicate Inorganic materials 0.000 title 1
- 239000005368 silicate glass Substances 0.000 title 1
- 229910001556 Li2Si2O5 Inorganic materials 0.000 description 9
- 229910007562 Li2SiO3 Inorganic materials 0.000 description 7
- 229910001386 lithium phosphate Inorganic materials 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 4
- 229910052681 coesite Inorganic materials 0.000 description 3
- 229910052906 cristobalite Inorganic materials 0.000 description 3
- 238000001483 high-temperature X-ray diffraction Methods 0.000 description 3
- 229910052904 quartz Inorganic materials 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 229910052682 stishovite Inorganic materials 0.000 description 3
- 229910052905 tridymite Inorganic materials 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- WMWLMWRWZQELOS-UHFFFAOYSA-N Bismuth(III) oxide Chemical compound O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 description 2
- OFJATJUUUCAKMK-UHFFFAOYSA-N Cerium(IV) oxide Chemical compound [O-2]=[Ce+4]=[O-2] OFJATJUUUCAKMK-UHFFFAOYSA-N 0.000 description 2
- VQCBHWLJZDBHOS-UHFFFAOYSA-N Erbium(III) oxide Chemical compound O=[Er]O[Er]=O VQCBHWLJZDBHOS-UHFFFAOYSA-N 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N Manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- 229910007530 Li2Si2O3 Inorganic materials 0.000 description 1
- 229910000949 MnO2 Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- CWBWCLMMHLCMAM-UHFFFAOYSA-M rubidium(1+);hydroxide Chemical compound [OH-].[Rb+].[Rb+] CWBWCLMMHLCMAM-UHFFFAOYSA-M 0.000 description 1
- 229910001953 rubidium(I) oxide Inorganic materials 0.000 description 1
Description
Tabla III
- 17
- 18 19 20
- SiO2
- 61,3 62,6 64,9 64,9
- K2O
- 3,3 5,0 3,5 3,5
- Li2O
- 12,7 12,7 13,5 13,5
- CaO
- 3,0
- Al2O3
- 2,9 2,9 3,1 3,1
- P2O5
- 7,0 3,5 3,0 3,0
- ZrO2
- 9,0 11,3 10,4 10,9
- F
- 0,5
- MnO2
- 0,2
- Fe2O3
- 0,1
- V2O5
- 0,1
- Tb4O7
- 0,4 0,5 0,5
- CeO2
- 1,3 1,0 0,6
- Er2O3
- 0,3
- 100,0
- 100,0
- 100,0
- 100,0
Tabla IV
- 21
- 22 23 24
- SiO2
- 66,4 63,8 64,5 63,8
- K2O
- 3,0 3,2 3,0
- Li2O
- 13,6 13,6 13,8 13,6
- Rb2O
- 4,0
- BaO
- 2,0
- Al2O3
- 3,0 3,0 3,0 3,0
- Bi2O3
- 4,0
- P2O5
- 3,0 3,0 3,5 3,0
- ZrO2
- 10,0 9,6 10,0 9,6
- WO3
- 4,0
- 100,0
- 100,0
- 100,0
- 100,0
Tabla V
- Vitrocerámica, no.
- Tratamiento térmico (ºC/min) o HT-XRD Fases cristalinas FP=Fase principalFS=Fase(s) secundaria(s)
- 2
- 500/100, 650/20, 840/7 FP: Li2Si2O5 FS: Li3PO4, Li2SiO3
- 3
- 500/100, 650/20, 840/7 FP: Li2Si2O5 FS: Li3PO4, Li2SiO3; Li4SiO4
- 4
- 540/10, 690/20 FP: Li2SiO3 FS: ninguna
- 4
- 540/10, 650/20, 840/7 FP: Li2Si2O5 FS: Li2SiO3; Li4SiO4
- 5
- 540/10, 710/20 FP: Li2SiO3 FS: ninguna
- 5
- 540/10, 650/20, 840/7 FP: Li2Si2O3 FS: Li4SiO4
- 6
- 560/10 y HT-XRD con corte a 860 FP: Li2Si2O5 FS: Li3PO4, Li2SiO3
- 7
- 560/10 y HT-RXD con corte a 900 FP: Li2Si2O5 FS: SiO2, ZrO2
- 8
- 560/10 y HT-RXD con corte a 920 FP:Li2Si2O5 FS:Li3PO4
- 13
- 520/10, 6500/20, 800/10 FP:Li2Si2O5 FS:Li3PO4
- 21
- 520/10, 650/20, 800/10 FP:Li2Si2O5 FS:Li3PO4
- 22
- 520/10, 650/20, 850/10 FP:Li2Si2O5 FS:Li3PO4, Li2SiO3
10 En el análisis por HT-XRD, se utilizó una velocidad de calentamiento de aproximadamente 2 K/min. 11
Claims (1)
-
imagen1 imagen2
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP10160222 | 2010-04-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2575829T3 true ES2575829T3 (es) | 2016-07-01 |
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