ES2558804T3 - Method to produce graphene layers - Google Patents

Method to produce graphene layers Download PDF

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Publication number
ES2558804T3
ES2558804T3 ES08801827.0T ES08801827T ES2558804T3 ES 2558804 T3 ES2558804 T3 ES 2558804T3 ES 08801827 T ES08801827 T ES 08801827T ES 2558804 T3 ES2558804 T3 ES 2558804T3
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Spain
Prior art keywords
graphene layers
monolayer
molecular weight
low molecular
group
Prior art date
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Active
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ES08801827.0T
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Spanish (es)
Inventor
Armin GÖLZHÄUSER
Andrey Turchanin
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Universitaet Bielefeld
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Universitaet Bielefeld
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00Manufacture or treatment of nanostructures
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/182Graphene
    • C01B32/184Preparation
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/20Graphite
    • C01B32/21After-treatment
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2204/00Structure or properties of graphene
    • C01B2204/02Single layer graphene
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2204/00Structure or properties of graphene
    • C01B2204/04Specific amount of layers or specific thickness

Abstract

Procedimiento para preparar capas de grafeno consistentes en 1 a 3 estratos atómicos, que comprende el paso de calentar al menos una monocapa con compuestos aromáticos de bajo peso molecular y/o compuestos heteroaromáticos de bajo peso molecular reticulados en dirección lateral, bajo vacío o gas inerte, a una temperatura 5 de >1.000 K, estando la monocapa seleccionada de compuestos aromáticos, seleccionados del grupo consistente en fenilo, bifenilo, terfenilo, naftaleno y antraceno, y/o compuestos heteroaromáticos, seleccionados del grupo consistente en bipiridina, terpiridina, tiofeno, bitienilo, tertienilo y pirrol.Method for preparing graphene layers consisting of 1 to 3 atomic layers, comprising the step of heating at least one monolayer with low molecular weight aromatic compounds and / or low molecular weight heteroaromatic compounds crosslinked in the lateral direction, under vacuum or inert gas , at a temperature 5 of> 1,000 K, the monolayer being selected from aromatic compounds, selected from the group consisting of phenyl, biphenyl, terphenyl, naphthalene and anthracene, and / or heteroaromatic compounds, selected from the group consisting of bipyridine, terpiridine, thiophene, Bitienyl, tertienyl and pyrrole.

Description

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Claims (1)

imagen1image 1
ES08801827.0T 2007-09-03 2008-09-03 Method to produce graphene layers Active ES2558804T3 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102007041820 2007-09-03
DE102007041820A DE102007041820A1 (en) 2007-09-03 2007-09-03 graphite layers
PCT/EP2008/007203 WO2009030473A1 (en) 2007-09-03 2008-09-03 Graphite layers

Publications (1)

Publication Number Publication Date
ES2558804T3 true ES2558804T3 (en) 2016-02-08

Family

ID=39988102

Family Applications (1)

Application Number Title Priority Date Filing Date
ES08801827.0T Active ES2558804T3 (en) 2007-09-03 2008-09-03 Method to produce graphene layers

Country Status (6)

Country Link
US (2) US20100209330A1 (en)
EP (1) EP2188212B1 (en)
JP (1) JP5627460B2 (en)
DE (1) DE102007041820A1 (en)
ES (1) ES2558804T3 (en)
WO (1) WO2009030473A1 (en)

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KR101344493B1 (en) * 2007-12-17 2013-12-24 삼성전자주식회사 Single crystalline graphene sheet and process for preparing the same
DE102009034575A1 (en) * 2009-07-24 2011-01-27 Universität Bielefeld Perforated membranes
DE102011006344B4 (en) * 2010-03-31 2020-03-12 Joyson Safety Systems Acquisition Llc Occupant measurement system
US9005565B2 (en) * 2010-06-24 2015-04-14 Hamid-Reza Jahangiri-Famenini Method and apparatus for forming graphene
US20110314840A1 (en) * 2010-06-24 2011-12-29 Hamid-Reza Jahangiri-Famenini Various methods for industrial scale production of graphene and new devices/instruments to achieve the latter
US9561964B2 (en) * 2010-06-24 2017-02-07 Hamid-Reza Jahangiri-Famenini Method and apparatus for forming graphene
DE102010031767A1 (en) 2010-07-21 2012-01-26 Universität Bielefeld Use of graphite layer for e.g. piezoresistive element obtained by heating at least one monolayer along lateral direction of interlaced low-molecular aromatics and/or low-molecular hetero aromatics under vacuum or inert gas atmosphere
KR101403989B1 (en) 2010-11-09 2014-06-10 포항공과대학교 산학협력단 Graphene coated steel and method for preparing thereof
DE102011054103A1 (en) * 2011-09-30 2013-04-04 MAX-PLANCK-Gesellschaft zur Förderung der Wissenschaften e.V. Method of making graphene nanoribbons
KR101348925B1 (en) * 2012-03-15 2014-01-10 한국수력원자력 주식회사 Fabrication method of organic material-derived graphene using radiation technique and the fabrication of the graphene using the same
US10653824B2 (en) 2012-05-25 2020-05-19 Lockheed Martin Corporation Two-dimensional materials and uses thereof
US10980919B2 (en) 2016-04-14 2021-04-20 Lockheed Martin Corporation Methods for in vivo and in vitro use of graphene and other two-dimensional materials
KR101937517B1 (en) 2012-06-21 2019-01-10 테슬라 나노코팅스, 인크. Coating composition
JP2015534535A (en) * 2012-09-20 2015-12-03 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se Method for producing graphene nanoribbon
WO2014164621A1 (en) 2013-03-12 2014-10-09 Lockheed Martin Corporation Method for forming filter with uniform aperture size
US9572918B2 (en) 2013-06-21 2017-02-21 Lockheed Martin Corporation Graphene-based filter for isolating a substance from blood
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SG11201609272TA (en) * 2014-05-08 2016-12-29 Lockheed Corp Stacked two-dimensional materials and methods for producing structures incorporating same
GB2527561B (en) 2014-06-26 2021-06-16 Cnm Tech Gmbh Multilayer structure
US10586651B2 (en) 2014-06-26 2020-03-10 Cnm Technologies Gmbh Method of manufacture of a multilayer structure
KR20170095804A (en) 2014-09-02 2017-08-23 록히드 마틴 코포레이션 Hemodialysis and hemofiltration membranes based upon a two-dimensional membrane material and methods employing same
US9735366B2 (en) 2014-09-30 2017-08-15 Cnm Technologies Gmbh Heterostructure comprising a carbon nanomembrane
US10017649B2 (en) 2014-12-19 2018-07-10 Tesla Nanocoatings, Inc. Tunable materials
JP2018528144A (en) 2015-08-05 2018-09-27 ロッキード・マーチン・コーポレーション Perforable sheet of graphene-based material
AU2016303049A1 (en) 2015-08-06 2018-03-01 Lockheed Martin Corporation Nanoparticle modification and perforation of graphene
US20180286598A1 (en) * 2015-09-29 2018-10-04 Rohm And Haas Electronic Materials Llc A method of making a multilayer structure
CN108028178A (en) * 2015-09-29 2018-05-11 罗门哈斯电子材料有限责任公司 The method for preparing graphitic carbon thin slice
EP3368197B8 (en) 2015-10-28 2021-09-15 CNM Technologies GmbH Method for manufacturing of a carbon nanomembrane
JP2019521055A (en) 2016-04-14 2019-07-25 ロッキード・マーチン・コーポレーション Selective interface relaxation of graphene defects
WO2017180135A1 (en) 2016-04-14 2017-10-19 Lockheed Martin Corporation Membranes with tunable selectivity
KR20190018410A (en) 2016-04-14 2019-02-22 록히드 마틴 코포레이션 Two-dimensional membrane structures with flow passages
KR20190019907A (en) 2016-04-14 2019-02-27 록히드 마틴 코포레이션 Handling graphene sheets for large-scale transport using the free-floating method
EP3443329A4 (en) 2016-04-14 2020-04-08 Lockheed Martin Corporation Methods for in situ monitoring and control of defect formation or healing
CN107460021B (en) * 2017-08-07 2021-07-30 泉州师范学院 Preparation method of low-temperature graphene-based nano borate composite material
CN111875961B (en) * 2020-08-12 2021-05-07 西北大学 High-dispersion graphene composite material with short-chain polymer adsorbed on surface and preparation method thereof

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US3900540A (en) * 1970-06-04 1975-08-19 Pfizer Method for making a film of refractory material having bi-directional reinforcing properties
GB1292534A (en) * 1970-06-04 1972-10-11 Pfizer Method for making a continuous film of pyrolytic graphite having bi-directional reinforcing properties
DE3675080D1 (en) * 1985-05-30 1990-11-29 Matsushita Electric Ind Co Ltd METHOD FOR PRODUCING GRAPHITE FILMS.
US4761308A (en) * 1987-06-22 1988-08-02 General Electric Company Process for the preparation of reflective pyrolytic graphite
EP0312146B1 (en) * 1987-10-15 1993-03-31 Philips Patentverwaltung GmbH Process for the production of shaped articles from pyrolitic graphite
AU5963990A (en) * 1989-06-14 1991-01-08 Temple University Process for production of graphite flakes and films via low temperature pyrolysis
CN1826288A (en) * 2003-09-02 2006-08-30 株式会社钟化 Filmy graphite and process for producing the same

Also Published As

Publication number Publication date
JP5627460B2 (en) 2014-11-19
EP2188212B1 (en) 2015-12-02
US20100209330A1 (en) 2010-08-19
DE102007041820A1 (en) 2009-03-05
US20150274530A1 (en) 2015-10-01
EP2188212A1 (en) 2010-05-26
WO2009030473A1 (en) 2009-03-12
US9458019B2 (en) 2016-10-04
JP2010537923A (en) 2010-12-09

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