ES2537588R1 - Alkaline ion battery and method to produce it - Google Patents

Alkaline ion battery and method to produce it Download PDF

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Publication number
ES2537588R1
ES2537588R1 ES201331793A ES201331793A ES2537588R1 ES 2537588 R1 ES2537588 R1 ES 2537588R1 ES 201331793 A ES201331793 A ES 201331793A ES 201331793 A ES201331793 A ES 201331793A ES 2537588 R1 ES2537588 R1 ES 2537588R1
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Spain
Prior art keywords
battery
ion battery
alkaline ion
alkaline
cathode
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ES201331793A
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Spanish (es)
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ES2537588A2 (en
ES2537588B1 (en
Inventor
Daniel CÍNTORA JUÁREZ
Shahzada Ahmad
Carlos PÉREZ VICENTE
José Luis TIRADO COELLO
Samrana KAZIM
Manuel Doblaré Castellano
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Abengoa Research SL
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Abengoa Research SL
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Priority to ES201331793A priority Critical patent/ES2537588B1/en
Priority to PCT/EP2014/076787 priority patent/WO2015082711A1/en
Publication of ES2537588A2 publication Critical patent/ES2537588A2/en
Publication of ES2537588R1 publication Critical patent/ES2537588R1/en
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0438—Processes of manufacture in general by electrochemical processing
    • H01M4/0464—Electro organic synthesis
    • H01M4/0466—Electrochemical polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/122—Ionic conductors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/04—Construction or manufacture in general
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/04—Construction or manufacture in general
    • H01M10/049—Processes for forming or storing electrodes in the battery container
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0567—Liquid materials characterised by the additives
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/137—Electrodes based on electro-active polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1399—Processes of manufacture of electrodes based on electro-active polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H01M4/602—Polymers
    • H01M4/606—Polymers containing aromatic main chain polymers
    • H01M4/608—Polymers containing aromatic main chain polymers containing heterocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/14—Side-groups
    • C08G2261/142—Side-chains containing oxygen
    • C08G2261/1424—Side-chains containing oxygen containing ether groups, including alkoxy
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
    • C08G2261/3223—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more sulfur atoms as the only heteroatom, e.g. thiophene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Abstract

La presente invención se refiere a métodos para producir una batería de iones alcalinos y a una batería de iones alcalinos secundaria. De acuerdo con el método de la invención, se monta una batería de iones alcalinos, en donde dicha batería comprende un electrolito que comprende monómeros polimerizables o un cátodo sobre el que pueden añadirse monómeros polimerizables antes de ponerlo en contacto con el electrolito. Cuando se carga la batería, se forma un revestimiento de polímero sobre el cátodo de la batería. En una realización preferida, el cátodo compuesto que comprende el polímero se forma in situ, es decir, en el interior de la batería de iones alcalinos montada. Las baterías alcalinas de la invención tienen unas capacidades más altas; adolecen de menos pérdida de capacidad a tasas de descarga más altas. Además, las baterías de la invención tienen una mayor fiabilidad de batería ya que el desvanecimiento de la capacidad disminuye y el rendimiento de tasa aumenta.The present invention relates to methods for producing an alkaline ion battery and a secondary alkaline ion battery. According to the method of the invention, an alkaline ion battery is mounted, wherein said battery comprises an electrolyte comprising polymerizable monomers or a cathode onto which polymerizable monomers can be added before contacting it with the electrolyte. When the battery is charged, a polymer coating forms on the cathode of the battery. In a preferred embodiment, the composite cathode comprising the polymer is formed in situ, that is, inside the mounted alkaline ion battery. The alkaline batteries of the invention have higher capacities; suffer from less loss of capacity at higher download rates. In addition, the batteries of the invention have greater battery reliability since the capacity fading decreases and the rate performance increases.

ES201331793A 2013-12-05 2013-12-05 Alkaline ion battery and method to produce it Active ES2537588B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
ES201331793A ES2537588B1 (en) 2013-12-05 2013-12-05 Alkaline ion battery and method to produce it
PCT/EP2014/076787 WO2015082711A1 (en) 2013-12-05 2014-12-05 Alkali ion battery and method for producing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES201331793A ES2537588B1 (en) 2013-12-05 2013-12-05 Alkaline ion battery and method to produce it

Publications (3)

Publication Number Publication Date
ES2537588A2 ES2537588A2 (en) 2015-06-09
ES2537588R1 true ES2537588R1 (en) 2015-12-18
ES2537588B1 ES2537588B1 (en) 2016-09-28

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ES201331793A Active ES2537588B1 (en) 2013-12-05 2013-12-05 Alkaline ion battery and method to produce it

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WO (1) WO2015082711A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10593946B2 (en) * 2016-12-11 2020-03-17 StoreDot Ltd. LFP as initiator of in-battery polymerization of conducting polymers for high-rate-charging cathodes
US9831488B1 (en) * 2016-12-11 2017-11-28 StoreDot Ltd. In-battery polymerization of conducting polymers for high-rate charging cathodes
CN109873199B (en) * 2017-12-01 2021-11-16 中国科学院大连化学物理研究所 Polymer dispersion liquid and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110294019A1 (en) * 2010-05-27 2011-12-01 Khalil Amine Electrode stabilizing materials
US20120136136A1 (en) * 2009-06-01 2012-05-31 Universite Du Quebec A Montreal Process to induce polymerization of an organic electronically conductive polymer
WO2013120376A1 (en) * 2012-02-17 2013-08-22 深圳新宙邦科技股份有限公司 Lithium ion battery and electrolyte thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120136136A1 (en) * 2009-06-01 2012-05-31 Universite Du Quebec A Montreal Process to induce polymerization of an organic electronically conductive polymer
US20110294019A1 (en) * 2010-05-27 2011-12-01 Khalil Amine Electrode stabilizing materials
WO2013120376A1 (en) * 2012-02-17 2013-08-22 深圳新宙邦科技股份有限公司 Lithium ion battery and electrolyte thereof

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
LEE K S et al. Improvement of high voltage cycling performance and thermal stability of lithium-ion cells by use of a thiophene additive. Electrochemistry communications, 01/10/2009, Vol.11, Nº: 10, páginas: 1900 - 1903. 2. Experimental. *
TRINH N D et al. Conductive polymer film supporting LiFePO4 as composite cathode for lithium ion batteries. Journal of power sources, 13/08/2012, Vol. 221, páginas: 284 - 289. 1. Introduction and 2. Material and methods. *
YOON-SUNG LEE et al. Effect of an organic additive on the cycling performance and thermal stability of lithium-ion cells assembled with carbon anode and LiNi1/3Co1/3Mn1/3O2 cathode. Journal of Power Sources, 18/10/2010, Vol.196, Nº: 16, páginas: 6997 - 7001. Páginas 6997-6999. *
YUAN L-X et al. Development and challenges of LiFePO4 cathode material for lithium-ion batteries. Energy and Environmental Science, 31/01/2011, Vol. 4, Nº 2, páginas: 269 - 284. 3.2 Electrochemical properties of LiFePO4 derivatives. *

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Publication number Publication date
WO2015082711A1 (en) 2015-06-11
ES2537588A2 (en) 2015-06-09
ES2537588B1 (en) 2016-09-28

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