ES2325048B1 - DETERGENT COMPOSITION OF SOAP CONSISTENCY, AND PROCESS FOR ITS OBTAINANCE. - Google Patents

DETERGENT COMPOSITION OF SOAP CONSISTENCY, AND PROCESS FOR ITS OBTAINANCE. Download PDF

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Publication number
ES2325048B1
ES2325048B1 ES200800494A ES200800494A ES2325048B1 ES 2325048 B1 ES2325048 B1 ES 2325048B1 ES 200800494 A ES200800494 A ES 200800494A ES 200800494 A ES200800494 A ES 200800494A ES 2325048 B1 ES2325048 B1 ES 2325048B1
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Prior art keywords
water
dilution
detergent composition
tilose
preservative
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Expired - Fee Related
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ES200800494A
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ES2325048A1 (en
Inventor
Francisco Cutillas Gregorio
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Palc Chemical Espanola SL
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Palc Chemical Espanola SL
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00Special methods for preparing compositions containing mixtures of detergents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/02Compositions of detergents based essentially on soap on alkali or ammonium soaps
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/06Inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/06Inorganic compounds
    • C11D9/08Water-soluble compounds
    • C11D9/10Salts
    • C11D9/12Carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/06Inorganic compounds
    • C11D9/08Water-soluble compounds
    • C11D9/10Salts
    • C11D9/14Phosphates; Polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

Composición detergente de consistencia esponjosa y proceso para su obtención consistente en incorporar, en un recipiente no superior a los 500 litros, previsto de un agitador lateral dotado de tres discos en su eje central:Detergent composition of spongy consistency and process for obtaining it consisting of incorporating, in a container not exceeding 500 liters, provided with a stirrer lateral endowed with three discs in its central axis:

- agua descalcificada, 63,8%,- decalcified water, 63.8%,

- Alcohol Graso 7 Moles, 1%,- 7 Moles Fatty Alcohol, 1%,

- Potasa Cáustica Líquida al 50%, 1%,- 50% Liquid Caustic Potash, 1%,

- 7% de dilución, (20% de Acido Dodecilbenzeno, 78% de
{}\hskip0,18cm agua y 2% de Sosa Cáustica)
- 7% dilution, (20% Dodecylbenzene Acid, 78% of
{} \ hskip0.18cm water and 2% Caustic Soda)

- 10,6% de dilución (97% de agua, 3% de Tilose, y 0,25%
{}\hskip0,18cm de conservante)
- 10.6% dilution (97% water, 3% Tilose, and 0.25%
{} \ hskip0.18cm of preservative)

- jabón Potásico, 10,6%- Potassium soap, 10.6%

- y el perfume, 0,03%- and perfume, 0.03%

agitándose durante 20 minutos,stirring for 20 minutes,

- a continuación se añade:- then add:

- 3,5% del Triton en polvo,- 3.5% Triton powder,

- el Carbonato Sódico, en un 0,7%- Sodium Carbonate, 0.7%

- Tripolifosfato, 0,7%- Tripolyphosphate, 0.7%

- y Metasilicato, 0,7%- and Metasilicate, 0.7%

y se somete a otro ciclo de agitación de 20 minutos.and undergoes another stirring cycle of 20 minutes

Description

Composición detergente de consistencia esponjosa, y proceso para su obtención.Consistency detergent composition spongy, and process to obtain it.

Objeto de la invenciónObject of the invention

La presente patente invención se refiere, tal como indica el enunciado, a una composición detergente de consistencia esponjosa, y al proceso para su obtención.The present invention patent relates, such as stated in the statement, to a detergent composition of spongy consistency, and the process for obtaining it.

Explicación de la invenciónExplanation of the invention.

En particular, el objeto de la invención consiste en una composición detergente, esencialmente destinada a ser aplicada para el lavado de la ropa, que presenta la particularidad de que los componentes de que consta junto al especifico proceso que requiere su elaboración le otorgan un aspecto y una consistencia esponjosa, tal como el aspecto y consistencia que presenta una "mousse" (postre de crema suave y espumosa), convirtiéndola en una innovadora alternativa a los detergentes tradicionales actualmente conocidos en el mercado, aportando varias ventajas que se describirán en detalle más adelante.In particular, the object of the invention It consists of a detergent composition, essentially intended for be applied to the laundry, which presents the particularity that the components of which consists next to specific process that requires its elaboration give it a appearance and a spongy consistency, such as appearance and consistency that presents a "mousse" (soft cream dessert and foamy), making it an innovative alternative to traditional detergents currently known in the market, providing several advantages that will be described in more detail ahead.

Antecedentes de la invenciónBackground of the invention

En la actualidad, y como referencia al estado de la técnica, debe mencionarse que, aunque son conocidos múltiples tipos de composiciones detergentes, con diferentes consistencias más o menos líquidas, tales como pastillas de jabón sólidas, pastas cremosas, geles, polvos atomizados etc., por parte del peticionario, se desconoce la existencia de ninguna que presente unas características semejantes a las que incorpora la que aquí se preconiza, cuyos ingredientes y especifico proceso de elaboración permiten su obtención con una innovadora consistencia esponjosa que la hace destacar como evidente novedad dentro de su campo de aplicación.Currently, and as a reference to the state of the technique, it should be mentioned that, although multiple are known types of detergent compositions, with different consistencies more or less liquid, such as solid soap bars, pastes creamy, gels, atomized powders etc., by the petitioner, it is unknown the existence of any that present similar characteristics to those incorporated here advocates, whose ingredients and specific manufacturing process they allow their obtaining with an innovative spongy consistency that makes it stand out as obvious novelty within its field of application.

Explicación de la invenciónExplanation of the invention.

De forma concreta, los componentes químicos que intervienen en la fórmula de la composición detergente que se propone son los siguientes:Specifically, the chemical components that involved in the formula of the detergent composition that proposed are the following:

--
H_{2}O-D (desionizada)H 2 O-D (deionized)

--
Ácido Dodecilbenzeno DBS/EAcid Dodecilbenzeno DBS / E

--
Potasa cáustica líquida al 50%Potash 50% liquid caustic

--
Alcohol graso 7 Moles7 Moles fatty alcohol

--
Perfume ("marsella" o cualquier otro, según se desee)Perfume ("marseille" or any other, as desired)

--
TiloseTilose

--
Jabón potásicoSoap potassium

--
MetasilicatoMetasilicate

--
Tripolifosfato sosa LDSoda tripolyphosphate LD

--
Trilón B polvo (secuestrante, coservante)Trilon B powder (sequestrant, coservant)

--
Sosa líquida al 50%bland 50% liquid

En cuanto al proceso para su obtención, éste requiere en primer lugar de sendos pasos previos para la preparación de dos prediluciones que posteriormente se utilizarán el en preparado de la composición detergente definitiva.As for the process to obtain it, it it requires first of all two previous steps for the preparation of two predilutions that will later be used the preparation of the final detergent composition.

En primer lugar, en un depósito se vierte un 20% de Ácido Dodecilbenzeno (según cantidad a elaborar), y un 78% de agua. Se mezcla y a continuación se le incorpora un 2% de Sosa cáustica para la neutralización del producto obtenido (se entiende por neutralización el hecho de elevar el pH de un producto ácido, como es el Ácido Dodecilbenzeno a un estado neutro (5.5 pH)).First, 20% is poured into a deposit of Dodecylbenzene Acid (depending on the amount to be made), and 78% of Water. Mix and then add 2% Sosa Caustic for the neutralization of the product obtained (it is understood by neutralizing the fact of raising the pH of an acid product, such as Dodecylbenzene Acid at a neutral state (5.5 pH)).

Por otra parte, en un recipiente independiente al anterior, se vierte un 97% de H_{2}O, donde se podrán diluir un 3% de espesante especial (TILOSE), añadiendo a la mezcla obtenida un 0,25% de conservante.Moreover, in a separate container to the previous one, 97% of H2O is poured, where they can be diluted 3% special thickener (TILOSE), adding to the mixture obtained 0.25% preservative.

Con estos dos procesos de preparación previa, se está en condiciones de proceder a la elaboración del producto final, es decir, la composición detergente con consistencia esponjosa, objeto de la invención.With these two pre-preparation processes, you is in a position to proceed to product development final, that is, the detergent composition with consistency spongy, object of the invention.

Se dispondrá de un recipiente de acero inoxidable, cuya capacidad no sea superior a los 500 litros, en orden a conseguir una adecuada emulsión de los líquidos y sólidos que en dicho proceso se incorporan, dado que la mezcla no se producirá mediante reactor químico, sino mediante agitación, y el manejo de un volumen mayor no resultaría adecuado.A steel container will be available stainless, whose capacity does not exceed 500 liters, in order to get an adequate emulsion of liquids and solids that in this process are incorporated, since the mixture is not will produce by chemical reactor, but by agitation, and the handling a larger volume would not be adequate.

Para realizar dicha agitación, este recipiente cuenta con un agitador de 1500 r.p.m., dotado de tres discos en su eje central con los que tritura y compacta la materia, siendo importante destacar que el agitador se hallará ubicado lateralmente, y no en el centro del recipiente, ya que la acción del agitador, es comparable, en términos culinarios, al modo de obtención de la nata montada.To perform such agitation, this vessel It has a 1500 rpm agitator, equipped with three discs in its central axis with which it crushes and compacts matter, being important to note that the agitator will be located laterally, and not in the center of the container, since the action of the agitator, it is comparable, in culinary terms, to the mode of Obtaining whipped cream.

En dicho recipiente se incorporan en primer lugar los siguientes ingredientes, cuyas proporciones son aproximadas:In said container they are incorporated first place the following ingredients, whose proportions are approximate:

--
el agua descalcificada, en un 63,8%,he decalcified water, at 63.8%,

--
el Alcohol Graso 7 Moles, en un 1%,he 7 Moles Fatty Alcohol, by 1%,

--
la Potasa Cáustica Líquida al 50%, en un 1%,the 50% Liquid Caustic Potash, by 1%,

--
un 7% de la primera dilución anteriormente descrita, es decir, (20% de Ácido Dodecilbenzeno, 78% de agua y 2% de Sosa Cáustica)7% of the first dilution described above, that is, (20% of Dodecylbenzene Acid, 78% water and 2% Caustic Soda)

--
un 10,6% de la segunda dilución, igualmente descrita (97% de agua, 3% de Tilose, y 0,25% de conservante)a 10.6% of the second dilution, also described (97% water, 3% of Tilose, and 0.25% preservative)

--
el jabón Potásico, en un 10,6%he Potassium soap, 10.6%

--
y el perfume, en un 0,03%and the perfume, at 0.03%

agitándose todo ello durante un tiempo aproximado de 20 minutos, tras los cuales se añade, igualmente en proporciones aproximadas:shaking all this for a approximate time of 20 minutes, after which it is added, also in proportions approximate:

--
un 3,5% del Triton en polvo, es decir, de secuestrante (cuya función es evitar la deposición de la suciedad en la ropa durante el proceso de lavado)a 3.5% Triton powder, that is, sequestrant (whose function is avoid the deposition of dirt on clothes during the process of washed)

--
el Carbonato Sódico, en un 0,7%he Sodium Carbonate, 0.7%

--
el Tripolifosfato, en un 0,7%he Tripolyphosphate, 0.7%

--
y el Metasilicato, en un 0,7%and the Metasilicate, 0.7%

Tras otro ciclo de agitación de 20 minutos se obtiene el producto final, el cual adquiere la consistencia esponjosa tipo "mousse" que se preconiza.After another 20 minute stirring cycle, obtains the final product, which acquires consistency fluffy type "mousse" that is recommended.

Dicha consistencia otorga a la composición detergente que se preconiza la ventajosa capacidad de constituirse en una masa estable, es decir, que no se decanta, y en consecuencia, no salpica, no se derrama y tampoco levanta polvo o causa grumos en la ropa. Además se puede dispensar en envases de boca grande con tapa, tal como tarrinas o recipientes similares, permitiendo su consumo total, es decir, evitando tener que dejar restos en el fondo del envase, lo que supone un importante ahorro.This consistency gives the composition detergent that is recommended the advantageous ability to constitute in a stable mass, that is, it does not decant, and in Consequently, it does not splash, does not spill and does not lift dust or It causes lumps in clothes. It can also be dispensed in containers of large mouth with lid, such as tubs or similar containers, allowing its total consumption, that is, avoiding having to leave remains in the bottom of the container, which is an important saving.

Ejemplo de una realización preferidaExample of a preferred embodiment

Como ejemplo de una realización concreta, se describe a continuación los ingredientes y cantidades para la obtención de unos 282 kilogramos de la composición detergente con consistencia esponjosa que se propone:As an example of a specific embodiment, Describe below the ingredients and quantities for obtaining about 282 kilograms of the detergent composition with spongy consistency that is proposed:

Para ello, en primer lugar se agitarán, en el recipiente dotado de agitador lateral y durante 20 minutos:To do this, they will first be agitated, in the vessel equipped with side stirrer and for 20 minutes:

--
180 Litros de agua180 Liters of water

--
3 Litros de Potasa3 Liters of Potash

--
0,6 Gramos de perfume "marsella", por ejemplo.0.6 Grams of perfume "marseille", for example.

--
20 Kg de un primer prediluido (formado por 20% de Ácido Dodecilbenzeno y 78% de agua, con 2% de Sosa Cáustica añadida tras su mezcla)20 kg of a first prediluted (formed by 20% of Dodecilbenzeno Acid and 78% water, with 2% Caustic Soda added after mixture)

--
30 Kg de Jabón Potásico30 kg Potassium Soap

--
3 Kg de Alcohol Graso 7 Moles3 kg of 7 Moles Fatty Alcohol

--
y 30 Kg de un segundo prediluido (formado por 97% de agua, y 3% de Tilose, con 0,25% de conservante añadido tras su mezcla)and 30 Kg of a second prediluted (formed by 97% of water, and 3% of Tilose, with 0.25% preservative added after mixing)

       \vskip1.000000\baselineskip\ vskip1.000000 \ baselineskip
    

Tras la citada agitación de dichos componentes durante los mencionados 20 minutos, se añadirán los siguientes ingredientes:After said agitation of said components during the mentioned 20 minutes, the following will be added ingredients:

--
10 Kg de Tritón B polvo, disuelto en 10 litros de agua10 kg of Triton B powder, dissolved in 10 liters of water

--
2 Kg de Tripolifosfato de Sosa D.2 kg of Sosa D Tripolyphosphate.

--
2 Kg de Metasilicato2 kg of Metasilicate

--
y 2 Kg de Carbonato Sódicoand 2 kg of sodium carbonate

agitándose todo durante otros 20 minutos más.stirring everything for another 20 minutes plus.

Descrita suficientemente la naturaleza de la presente invención, así como la manera de ponerla en práctica, no se considera necesaria hacer más extensa su explicación para que cualquier experto en la materia comprenda su alcance y las ventajas que de ella se derivan, haciendo constar que, dentro de su esencialidad, podrá ser llevada a la práctica en otras formas de realización que difieran en detalle de la indicada a título de ejemplo, y a las cuales alcanzará igualmente la protección que se recaba siempre que no se altere, cambie o modifique su principio fundamental.Describe sufficiently the nature of the present invention, as well as the way of putting it into practice, not it is considered necessary to extend its explanation so that any subject matter expert understands its scope and advantages that derive from it, stating that, within its essentiality, may be implemented in other forms of embodiment that differ in detail from that indicated by way of example, and which will also achieve the protection that collects as long as it does not alter, change or modify its principle fundamental.

Claims (2)

         \global\parskip0.870000\baselineskip\ global \ parskip0.870000 \ baselineskip
      
1. Composición detergente de consistencia esponjosa, esencialmente aplicable para el lavado de la ropa, caracterizada por el hecho de comprender los siguientes ingredientes y proporciones:1. Detergent composition of spongy consistency, essentially applicable for washing clothes, characterized by the fact that it comprises the following ingredients and proportions:
--
Agua descalcificada, en un 63,8%,Water descaled, at 63.8%,
--
Alcohol Graso 7 Moles, en un 1%,7 Moles Fatty Alcohol, in a one%,
--
Potasa Cáustica Líquida al 50%, en un 1%,Potash Liquid Caustic at 50%, by 1%,
--
Una dilución compuesta por un 20% de Ácido Dodecilbenzeno, 78% de agua y 2% de Sosa Cáustica, en un 7%,A dilution composed of 20% Dodecylbenzene Acid, 78% water and 2% Caustic Soda, 7%,
--
Otra dilución, compuesta por 97% de agua, 3% de Tilose, y 0,25% de conservante, en un 10,6%Other dilution, consisting of 97% water, 3% Tilose, and 0.25% of preservative, at 10.6%
--
Jabón Potásico, en un 10,6%Soap Potassium, 10.6%
--
perfume, en un 0,03%perfume, at 0.03%
--
secuestrante Triton en polvo, en un 3,5%Triton sequestrant powder, in a 3.5%
--
Carbonato Sódico, en un 0,7%Sodium Carbonate, 0.7%
--
Tripolifosfato, en un 0,7%Tripolyphosphate, 0.7%
--
y Metasilicato, en un 0,7%.Y Metasilicate, at 0.7%.
2. Proceso para la obtención de una composición detergente de consistencia esponjosa, según la primera reivindicación, caracterizado por el hecho de consistir en:2. Process for obtaining a detergent composition of spongy consistency, according to the first claim, characterized in that it consists of: - El vertido y mezcla en un depósito, un 20% de Ácido Dodecilbenzeno y un 78% de agua- The pouring and mixing in a deposit, 20% of Dodecylbenzene acid and 78% water - Se incorpora un 2% de Sosa cáustica para la neutralización del producto obtenido.- 2% of caustic soda is incorporated for neutralization of the product obtained. - En recipiente independiente al anterior, se vierte un 97% de H_{2}O, en la que se diluye 3% de espesante especial (TILOSE)- In a separate container from the previous one, pour 97% H2O, in which 3% thickener is diluted special (TILOSE) - Se añade a la mezcla obtenida un 0,25% de conservante.- 0.25% of the added mixture is added to the obtained mixture preservative - A continuación, en un recipiente de acero inoxidable, cuya capacidad no sea superior a los 500 litros, previsto de un agitador lateral de 1500 r.p.m., dotado de tres discos en su eje central se incorporan:- Then in a steel container stainless, whose capacity does not exceed 500 liters, planned for a side shaker of 1500 r.p.m., equipped with three discs in its central axis are incorporated:
--
el agua descalcificada, en un 63,8%,he decalcified water, at 63.8%,
--
el Alcohol Graso 7 Moles, en un 1%,he 7 Moles Fatty Alcohol, by 1%,
--
la Potasa Cáustica Líquida al 50%, en un 1%,the 50% Liquid Caustic Potash, by 1%,
--
un 7% de la primera dilución, es decir, (20% de Ácido Dodecilbenzeno, 78% de agua y 2% de Sosa Cáustica)7% of the first dilution, that is, (20% Dodecylbenzene Acid, 78% of water and 2% of Caustic Soda)
--
un 10,6% de la segunda dilución (97% de agua, 3% de Tilose, y 0,25% de conservante)a 10.6% of the second dilution (97% water, 3% Tilose, and 0.25% of preservative)
--
el jabón Potásico, en un 10,6%he Potassium soap, 10.6%
--
y el perfume, en un 0,03%and the perfume, at 0.03%
agitándose durante un tiempo aproximado de 20 minutos,stirring for a while about 20 minutes - a continuación se añade:- then add:
--
un 3,5% del Triton en polvo, es decir, de secuestrantea 3.5% Triton powder, that is, sequestrant
--
el Carbonato Sódico, en un 0,7%he Sodium Carbonate, 0.7%
--
el Tripolifosfato, en un 0,7%he Tripolyphosphate, 0.7%
--
y el Metasilicato, en un 0,7%and the Metasilicate, 0.7%
y se somete a otro ciclo de agitación de 20 minutos.and undergoes another stirring cycle of 20 minutes
ES200800494A 2008-02-21 2008-02-21 DETERGENT COMPOSITION OF SOAP CONSISTENCY, AND PROCESS FOR ITS OBTAINANCE. Expired - Fee Related ES2325048B1 (en)

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DE3271270D1 (en) * 1981-11-16 1986-06-26 Unilever Nv Liquid detergent composition
DE69830723T2 (en) * 1997-05-02 2006-04-20 The Procter & Gamble Company, Cincinnati CLEANING COMPOSITION, METHOD AND / OR ARTICLE FOR HARD SURFACES
WO2000018868A1 (en) * 1998-09-25 2000-04-06 Unilever N.V. Detergent composition

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