ES2322729B1 - AUTOMATION OF THE MEASURES OF THE CONCENTRATIONS OF THE GERMICIDES (BIOCIDES) USED IN THE WATER DISINFECTION. - Google Patents
AUTOMATION OF THE MEASURES OF THE CONCENTRATIONS OF THE GERMICIDES (BIOCIDES) USED IN THE WATER DISINFECTION. Download PDFInfo
- Publication number
- ES2322729B1 ES2322729B1 ES200600422A ES200600422A ES2322729B1 ES 2322729 B1 ES2322729 B1 ES 2322729B1 ES 200600422 A ES200600422 A ES 200600422A ES 200600422 A ES200600422 A ES 200600422A ES 2322729 B1 ES2322729 B1 ES 2322729B1
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- Spain
- Prior art keywords
- water
- germicides
- biocides
- concentrations
- automation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 239000003139 biocide Substances 0.000 title claims abstract description 15
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 11
- 230000002070 germicidal effect Effects 0.000 claims abstract description 13
- 229910052709 silver Inorganic materials 0.000 claims abstract description 5
- 239000004332 silver Substances 0.000 claims abstract description 5
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 4
- 150000002367 halogens Chemical class 0.000 claims abstract description 4
- 125000000864 peroxy group Chemical group O(O*)* 0.000 claims abstract description 4
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000006243 chemical reaction Methods 0.000 claims abstract description 3
- 239000012286 potassium permanganate Substances 0.000 claims abstract description 3
- 238000001556 precipitation Methods 0.000 claims abstract description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 3
- 238000005259 measurement Methods 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical class [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052794 bromium Inorganic materials 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 229910052802 copper Chemical class 0.000 claims description 3
- 239000010949 copper Chemical class 0.000 claims description 3
- 229910052740 iodine Inorganic materials 0.000 claims description 3
- 239000011630 iodine Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 239000000443 aerosol Substances 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 238000004891 communication Methods 0.000 claims description 2
- 230000002262 irrigation Effects 0.000 claims description 2
- 238000003973 irrigation Methods 0.000 claims description 2
- 230000009182 swimming Effects 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims 2
- 238000011088 calibration curve Methods 0.000 claims 1
- 230000003115 biocidal effect Effects 0.000 abstract description 7
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 2
- 238000004458 analytical method Methods 0.000 abstract description 2
- 150000001879 copper Chemical class 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 abstract description 2
- 238000001139 pH measurement Methods 0.000 abstract 2
- 230000009918 complex formation Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 238000012387 aerosolization Methods 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004590 computer program Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical class [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
Abstract
Automatización de las medidas de las concentraciones de los germicidas (biocidas) usados en la desinfección del agua.Automation of the measures of concentrations of the germicides (biocides) used in the water disinfection
El análisis químico de germicidas (biocidas) residuales, usados en la desinfección del agua, como los halógenos y derivados, sales de amonio cuaternario, peroxicompuestos, permanganato potásico, fosfonatos, sales de plata y cobre, el fundamento son las reacciones químicas, ácido-base, formación de complejos, precipitación y Redox, en ellas se genera una diferencia de pH diferencia de potencial milivoltios) en el agua.The chemical analysis of germicides (biocides) waste, used in water disinfection, such as halogens and derivatives, quaternary ammonium salts, peroxy compounds, potassium permanganate, phosphonates, silver and copper salts, the foundation are chemical reactions, acid-base, complex formation, precipitation and redox, they generate a pH difference potential difference millivolts) in the Water.
Se desarrolla un aparato electrónico automático que realiza:An automatic electronic device is developed performing:
- Toma muestra, medida pH (milivoltios mv_{1})- Sample sample, pH measurement (millivolts mv_ {1})
- Toma reactivo, medida pH (milivoltios mv_{2}).- Reagent outlet, pH measurement (millivolts mv_ {2}).
Por diferencia de pH se obtiene la concentración del biocida en agua (ppm).By concentration difference the concentration is obtained of the biocide in water (ppm).
\vskip1.000000\baselineskip\ vskip1.000000 \ baselineskip
pH_{1} (mv_{1}) - pH_{2} (mv_{2}) = f (ppm)pH1 (mv1) - pH2 (mv_ {2}) = f (ppm)
\vskip1.000000\baselineskip\ vskip1.000000 \ baselineskip
La función f, se obtiene como curva de calibrado, para concentraciones conocidas de germicida en el agua, y así, los diferentes puntos de la curva pH_{1} (mv_{1}) - pH_{2} (mv_{2})/ppm.The function f is obtained as a curve of calibrated, for known concentrations of germicide in water, and thus, the different points of the curve pH_ {1} (mv_ {1}) - pH2 (mv2) / ppm.
Description
Automatización de las medidas de las concentraciones de los germicidas (biocidas) usados en la desinfección del agua.Automation of the measures of concentrations of the germicides (biocides) used in the water disinfection
La presente solicitud de patente de invención tiene por objeto el registro de la medida de los biocidas residuales en la desinfección del agua: torres de refrigeración, condensadores evaporativos, piscinas, fuentes ornamentales, agua fría y caliente sanitaria, equipos de enfriamiento evaporativo, humidificadoras, instalaciones termales, sistema de agua contra incendios, sistemas de riego para aspersión, elementos de refrigeración por aerosolización, acumuladores de agua que puedan producir aerosoles y potabilizacion de agua.The present invention patent application Its purpose is the registration of the biocidal measure residuals in water disinfection: cooling towers, evaporative condensers, swimming pools, ornamental fountains, water Sanitary hot and cold, evaporative cooling equipment, humidifiers, thermal installations, water system against fires, sprinkler irrigation systems, elements of aerosolization cooling, water accumulators that can produce aerosols and water purification.
Existen numerosos procedimientos en el mercado para el tratamiento, desinfección y potabilización del agua. Para estos fines se han empleado los halógenos (cloro, bromo, yodo) y sus derivados, sales de amonio cuaternario, peroxicompuestos, permanganatos potásicos, fosfonatos, sales de plata y cobre.There are numerous procedures in the market for the treatment, disinfection and purification of water. For For these purposes, halogens (chlorine, bromine, iodine) and its derivatives, quaternary ammonium salts, peroxy compounds, potassium permanganates, phosphonates, silver and copper salts.
- --
- Composition haring desinfecting action EP0876762 A1 998.Composition haring disinfecting action EP0876762 A1 998.
- --
- Composición desinfectante a base de polímeros de amonio cuaternario e iones de cobre, plata y/o manganeso y procedimiento de desinfección correspondiente ES 2003749. 1998.Disinfectant composition based on quaternary ammonium polymers and ions of copper, silver and / or manganese and corresponding disinfection procedure ES 2003749. 1998.
- --
- Composition for treating suiming polls EPO494373 A1 1991.Composition for treating suiming polls EPO494373 A1 1991.
Automatización de las medidas de las concentraciones de los germicidas (biocidas) usados en la desinfección del agua.Automation of the measures of concentrations of the germicides (biocides) used in the water disinfection
El análisis químico de los germicidas (biocidas) residuales, usados en la desinfección del agua, como son los halógenos (cloro, bromo, yodo) y sus derivados, sales de amonio cuaternario, peroxicompuestos, permanganato potásico, sales de fosfonio y sales de plata y cobre, se fundamenta en las reacciones químicas de ácido base de formación de complejos de precipitación y de oxido reducción (Redox) en ellas se genera una diferencia de pH (diferencia de potencial en milivoltios) en el agua. Se ha desarrollado un aparato electrónico automático cuyo funcionamiento describimos a continuación.The chemical analysis of germicides (biocides) waste, used in water disinfection, such as halogens (chlorine, bromine, iodine) and their derivatives, ammonium salts quaternary, peroxy compounds, potassium permanganate, salts of phosphonium and salts of silver and copper, is based on the reactions Acid base chemical formation of precipitation complexes and of oxide reduction (Redox) in them a difference of pH is generated (potential difference in millivolts) in the water. It has been developed an automatic electronic device whose operation We describe below.
La toma de muestra recibe una tensión de alimentación de 220 V AC 50 Hz. Estos son aplicados a un diferencial y un magnetotérmico, con el objeto de proteger el circuito diferencial a personas, y a su vez proteger los diferentes elementos en caso de fuga y el magnetotérmico posibles cortocircuitos.The sampling receives a voltage of 220 V AC power supply 50 Hz. These are applied to a differential and a circuit breaker, in order to protect the differential circuit to people, and in turn protect the different elements in case of leakage and the possible circuit breaker short circuits
La toma de muestras dispone de una toma de tensión de 220 V AC 16 A para la realización de tomar datos y mantenimiento (ordenador).The sampling has a voltage of 220 V AC 16 A for the realization of taking data and maintenance (computer).
- --
- Dispone de un relé de vigilancia de tensión indicada en el frontal del cuadro, mediante un led permanentemente encendido.It has a monitoring relay voltage indicated on the front of the panel, by means of a led permanently on.
- --
- Dispone de una fuente de alimentación para alimentar toda la instrumentación asociada a la toma de muestra, así como al controlador principal de 220 V AC / 24 V DC 2 A.It has a power supply to feed all the instrumentation associated with making Sample, as well as the main controller 220V AC / 24V DC 2 TO.
- --
- Mediante un SOFTWARE DE CONTROL se pone en marcha una bomba que aporta la muestra de biocida a analizar en un vaso. Un transmisor detector de la solución hace la primera medida del biocida residual en pH, medida 1 (diferencia de potencial mv_{1}).Through a CONTROL SOFTWARE you put a pump is in progress that provides the biocidal sample to be analyzed in a glass. A solution detector transmitter makes the first measurement of residual biocide in pH, measure 1 (difference of potential mv_ {1}).
Pasado un tiempo el software pone de nuevo en marcha la bomba, aspirando una cantidad de reactivo depositándola en el vaso de la muestra, realizando la segunda medida pH_{2}, medida 2 (diferencia de potencial mv_{2}). Esta medida aplicada al programa informático, mediante una ecuación interna refleja la cantidad de biocida residual de la muestra, aporta una lectura en p.p.m. guardándola en memoria el controlador.After a while the software puts back on start the pump, aspirating a quantity of reagent by depositing it in the sample vessel, making the second measurement pH2, measure 2 (potential difference mv_ {2}). This measure applied to the computer program, through an internal equation reflects the amount of residual biocide of the sample, provides a reading in p.p.m. keeping it in memory the controller.
La ecuación que se desarrolla es la siguiente:The equation that develops is the next:
- Toma muestra, medida de pH_{1} (milivoltios mv_{1})- Sample taken, measurement of pH1 (millivolts mv_ {1})
- Toma reactivo, medida de pH_{2} (milivoltios mv_{2})- Reagent sample, pH2 measurement (millivolts mv_ {2})
Por diferencia de pH_{1} (mv_{1}) - pH_{2} (mv_{2}) obtenemos la concentración del biocida residual en el agua en (p.p.m.)By difference of pH1 (mv1) - pH2 (mv_ {2}) we obtain the concentration of the residual biocide in the water in (p.p.m.)
pH_{1} (mv_{1}) - pH_{2} (mv_{2}) = f (p.p.m.)pH1 (mv_ {1}) - pH2 (mv_2) = f (p.p.m.)
La función f, se obtiene como curva de calibrado, para concentraciones conocidas de germicida en el agua, y así, los diferentes puntos de la curva pH_{1} (mv_{1}) - pH_{2} (mv_{2}) / p.p.m.The function f is obtained as a curve of calibrated, for known concentrations of germicide in water, and thus, the different points of the curve pH_ {1} (mv_ {1}) - pH2 (mv2) / p.p.m.
- --
- En el caso de detectar bajo nivel de biocida p.p.m. el sistema activará una alarma, este valor será almacenado en la memoria del controlador y se visualiza en el frontal del armario, el sistema también emite un contacto libre de potencial de la anomalía detectada pudiendo actuar este un sistema óptico y sonoro.At case of detecting low level of biocide p.p.m. the system will activate an alarm, this value will be stored in the memory of the controller and is displayed on the front of the cabinet, the system also emits a potential free contact of the anomaly detected being able to act this an optical and sound system.
- --
- Una vez realizada la medida el sistema de SOFTWARE pone en marcha la bomba procediendo a vaciar el vaso de la solución más reactivo, después de un tiempo de vaciado el SOFTWARE de nuevo pone en funcionamiento la bomba, aportando H_{2}O limpia al vaso para la limpieza de éste.A Once the measurement is made, the SOFTWARE system starts the pump proceeding to empty the vessel of the most reactive solution, after a time of emptying the SOFTWARE again puts on operation of the pump, providing H2O clean to the vessel for cleaning of this one.
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- Al iniciarse el siguiente ciclo el vaso se vaciará procediéndose a la realización del ciclo descrito anteriormente.To the start the next cycle the glass will empty by proceeding to the completion of the cycle described above.
El controlador almacena diariamente las medidas realizadas, estas pueden ser almacenadas en su memoria interna, enviarlas a un ordenador mediante RS232 o RS485 a una base central o bien a través de un sistema de comunicación GSM, Internet o telefónico.The controller stores the measurements daily made, these can be stored in its internal memory, send them to a computer via RS232 or RS485 to a central base or through a GSM communication system, Internet or telephone.
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES200600422A ES2322729B1 (en) | 2006-02-22 | 2006-02-22 | AUTOMATION OF THE MEASURES OF THE CONCENTRATIONS OF THE GERMICIDES (BIOCIDES) USED IN THE WATER DISINFECTION. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES200600422A ES2322729B1 (en) | 2006-02-22 | 2006-02-22 | AUTOMATION OF THE MEASURES OF THE CONCENTRATIONS OF THE GERMICIDES (BIOCIDES) USED IN THE WATER DISINFECTION. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2322729A1 ES2322729A1 (en) | 2009-06-25 |
| ES2322729B1 true ES2322729B1 (en) | 2010-04-21 |
Family
ID=40791757
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES200600422A Expired - Fee Related ES2322729B1 (en) | 2006-02-22 | 2006-02-22 | AUTOMATION OF THE MEASURES OF THE CONCENTRATIONS OF THE GERMICIDES (BIOCIDES) USED IN THE WATER DISINFECTION. |
Country Status (1)
| Country | Link |
|---|---|
| ES (1) | ES2322729B1 (en) |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5149354A (en) * | 1991-01-10 | 1992-09-22 | Delaney Brendan J | Composition for treating swimming pools |
| US5405541A (en) * | 1992-06-17 | 1995-04-11 | Baltimore Aircoil Company, Inc. | Water treatment process |
| DE29715378U1 (en) * | 1997-08-27 | 1998-02-12 | Dinotec GmbH, 63477 Maintal | Measuring, control and dosing station |
| ES1042714Y (en) * | 1999-03-26 | 2000-02-16 | Tecnicas De Dosificacion Y Fil | AUTOMATIC DOSING STATION. |
| JP2001070943A (en) * | 1999-09-07 | 2001-03-21 | Matsushita Electric Ind Co Ltd | Alkali ionized water maker |
| ES2185491B1 (en) * | 2001-06-22 | 2004-08-01 | Novedades Agricolas, S.A. | WATER DISINFECTION SYSTEM FOR AGRICULTURAL AND SIMILAR USE. |
| JP2006110443A (en) * | 2004-10-14 | 2006-04-27 | Nippon Kosan Kk | Water-quality monitoring system |
-
2006
- 2006-02-22 ES ES200600422A patent/ES2322729B1/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ES2322729A1 (en) | 2009-06-25 |
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