ES2199024B1 - PROCEDURE FOR THE OBTAINING OF CHELATAN DERIVATIVES FROM FULLERENOS, PRODUCTS AS WELL OBTAINED AND APPLICATIONS OF THE SAME. - Google Patents
PROCEDURE FOR THE OBTAINING OF CHELATAN DERIVATIVES FROM FULLERENOS, PRODUCTS AS WELL OBTAINED AND APPLICATIONS OF THE SAME.Info
- Publication number
- ES2199024B1 ES2199024B1 ES200101466A ES200101466A ES2199024B1 ES 2199024 B1 ES2199024 B1 ES 2199024B1 ES 200101466 A ES200101466 A ES 200101466A ES 200101466 A ES200101466 A ES 200101466A ES 2199024 B1 ES2199024 B1 ES 2199024B1
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- ES
- Spain
- Prior art keywords
- derivatives
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- formula
- procedure
- products
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Procedimiento para la obtención de derivados quelatantes de fullerenos, productos así obtenidos y aplicaciones de los mismos. El procedimiento comprende la reacción fotoquímica entre un fullereno de fórmula (III) y un reactivo quelatante de fórmula (IV), seguido de aislamiento y purificación del aducto de fórmula (I) así obtenido. En el producto obtenido de fórmula (I), el agrupamiento F representa un agrupamiento fullereno, A representa un grupo quelatante y R{sub,1} y R{sub,2} representan independientemente un grupo alquilo C{sub,2}-C{sub,4}, fenilo o vinilo, sin sustituir o sustituidos. Los derivados de fullerenos de la invención tienen aplicación como materiales adsorbentes, como fase estacionaria para cromatografía, para la inmovilización de derivados de fullerenos sobre superficies sólidas, etc.Procedure for obtaining chelating derivatives of fullerenes, products thus obtained and applications thereof. The process comprises the photochemical reaction between a fullerene of formula (III) and a chelating reagent of formula (IV), followed by isolation and purification of the adduct of formula (I) thus obtained. In the product obtained from formula (I), the cluster F represents a fullerene cluster, A represents a chelating group and R {sub, 1} and R {sub, 2} independently represent a C {sub, 2} -C alkyl group {sub, 4}, phenyl or vinyl, unsubstituted or substituted. The fullerene derivatives of the invention have application as adsorbent materials, as a stationary phase for chromatography, for the immobilization of fullerene derivatives on solid surfaces, etc.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES200101466A ES2199024B1 (en) | 2001-06-25 | 2001-06-25 | PROCEDURE FOR THE OBTAINING OF CHELATAN DERIVATIVES FROM FULLERENOS, PRODUCTS AS WELL OBTAINED AND APPLICATIONS OF THE SAME. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES200101466A ES2199024B1 (en) | 2001-06-25 | 2001-06-25 | PROCEDURE FOR THE OBTAINING OF CHELATAN DERIVATIVES FROM FULLERENOS, PRODUCTS AS WELL OBTAINED AND APPLICATIONS OF THE SAME. |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2199024A1 ES2199024A1 (en) | 2004-02-01 |
ES2199024B1 true ES2199024B1 (en) | 2005-06-01 |
Family
ID=31198077
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES200101466A Expired - Fee Related ES2199024B1 (en) | 2001-06-25 | 2001-06-25 | PROCEDURE FOR THE OBTAINING OF CHELATAN DERIVATIVES FROM FULLERENOS, PRODUCTS AS WELL OBTAINED AND APPLICATIONS OF THE SAME. |
Country Status (1)
Country | Link |
---|---|
ES (1) | ES2199024B1 (en) |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5308481A (en) * | 1992-06-02 | 1994-05-03 | Analytical Bio-Chemistry Laboratories, Inc. | Chemically bound fullerenes to resin and silica supports and their use as stationary phases for chromatography |
-
2001
- 2001-06-25 ES ES200101466A patent/ES2199024B1/en not_active Expired - Fee Related
Non-Patent Citations (6)
Also Published As
Publication number | Publication date |
---|---|
ES2199024A1 (en) | 2004-02-01 |
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