ES2199024B1 - PROCEDURE FOR THE OBTAINING OF CHELATAN DERIVATIVES FROM FULLERENOS, PRODUCTS AS WELL OBTAINED AND APPLICATIONS OF THE SAME. - Google Patents

PROCEDURE FOR THE OBTAINING OF CHELATAN DERIVATIVES FROM FULLERENOS, PRODUCTS AS WELL OBTAINED AND APPLICATIONS OF THE SAME.

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Publication number
ES2199024B1
ES2199024B1 ES200101466A ES200101466A ES2199024B1 ES 2199024 B1 ES2199024 B1 ES 2199024B1 ES 200101466 A ES200101466 A ES 200101466A ES 200101466 A ES200101466 A ES 200101466A ES 2199024 B1 ES2199024 B1 ES 2199024B1
Authority
ES
Spain
Prior art keywords
derivatives
sub
formula
procedure
products
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
ES200101466A
Other languages
Spanish (es)
Other versions
ES2199024A1 (en
Inventor
Josefa Rodriguez Baena
Mercedes Gallego Fernandez
Miguel Valcarcel Cases
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universidad de Cordoba
Original Assignee
Universidad de Cordoba
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universidad de Cordoba filed Critical Universidad de Cordoba
Priority to ES200101466A priority Critical patent/ES2199024B1/en
Publication of ES2199024A1 publication Critical patent/ES2199024A1/en
Application granted granted Critical
Publication of ES2199024B1 publication Critical patent/ES2199024B1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

Procedimiento para la obtención de derivados quelatantes de fullerenos, productos así obtenidos y aplicaciones de los mismos. El procedimiento comprende la reacción fotoquímica entre un fullereno de fórmula (III) y un reactivo quelatante de fórmula (IV), seguido de aislamiento y purificación del aducto de fórmula (I) así obtenido. En el producto obtenido de fórmula (I), el agrupamiento F representa un agrupamiento fullereno, A representa un grupo quelatante y R{sub,1} y R{sub,2} representan independientemente un grupo alquilo C{sub,2}-C{sub,4}, fenilo o vinilo, sin sustituir o sustituidos. Los derivados de fullerenos de la invención tienen aplicación como materiales adsorbentes, como fase estacionaria para cromatografía, para la inmovilización de derivados de fullerenos sobre superficies sólidas, etc.Procedure for obtaining chelating derivatives of fullerenes, products thus obtained and applications thereof. The process comprises the photochemical reaction between a fullerene of formula (III) and a chelating reagent of formula (IV), followed by isolation and purification of the adduct of formula (I) thus obtained. In the product obtained from formula (I), the cluster F represents a fullerene cluster, A represents a chelating group and R {sub, 1} and R {sub, 2} independently represent a C {sub, 2} -C alkyl group {sub, 4}, phenyl or vinyl, unsubstituted or substituted. The fullerene derivatives of the invention have application as adsorbent materials, as a stationary phase for chromatography, for the immobilization of fullerene derivatives on solid surfaces, etc.

ES200101466A 2001-06-25 2001-06-25 PROCEDURE FOR THE OBTAINING OF CHELATAN DERIVATIVES FROM FULLERENOS, PRODUCTS AS WELL OBTAINED AND APPLICATIONS OF THE SAME. Expired - Fee Related ES2199024B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
ES200101466A ES2199024B1 (en) 2001-06-25 2001-06-25 PROCEDURE FOR THE OBTAINING OF CHELATAN DERIVATIVES FROM FULLERENOS, PRODUCTS AS WELL OBTAINED AND APPLICATIONS OF THE SAME.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES200101466A ES2199024B1 (en) 2001-06-25 2001-06-25 PROCEDURE FOR THE OBTAINING OF CHELATAN DERIVATIVES FROM FULLERENOS, PRODUCTS AS WELL OBTAINED AND APPLICATIONS OF THE SAME.

Publications (2)

Publication Number Publication Date
ES2199024A1 ES2199024A1 (en) 2004-02-01
ES2199024B1 true ES2199024B1 (en) 2005-06-01

Family

ID=31198077

Family Applications (1)

Application Number Title Priority Date Filing Date
ES200101466A Expired - Fee Related ES2199024B1 (en) 2001-06-25 2001-06-25 PROCEDURE FOR THE OBTAINING OF CHELATAN DERIVATIVES FROM FULLERENOS, PRODUCTS AS WELL OBTAINED AND APPLICATIONS OF THE SAME.

Country Status (1)

Country Link
ES (1) ES2199024B1 (en)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5308481A (en) * 1992-06-02 1994-05-03 Analytical Bio-Chemistry Laboratories, Inc. Chemically bound fullerenes to resin and silica supports and their use as stationary phases for chromatography

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
CH. HUANG et al. "Photoelectrochemical Properties of a New C60 Derivative: C60-Glycine Ester C60(C6H9NO4)", J. Chem. Soc., Faraday Trans., 1997, Vol. 93, Nº 17, páginas 3115-3117. *
K.-F. LIOU et al. "Photoinduced Reactions of Tertiary Amines with [60]Fullerene: Addition of an alpha-C-H Bond of Amines to [60]Fullerene", Chem. Commun., 1996, Vol. 12, páginas 1423-1424. *
L. GANG et al. "Synthesis of Fullerene Amino Acid Derivatives by Direct Interaction of Amino Acid Ester with C60", J. Org. Chem., 1996, Vol. 61, páginas 1954-1961. *
L. GANG et al. "Synthesis of Pyrrolidine Ring-Fused Fullerene Multicarboxylates by Photoreaction", J. Org. Chem., 1998, Vol. 63, páginas 4240-4247. *
M. MAGGINI et al. "Synthesis of N-Acylated Fulleropyrrolidines: New Materials for the Preparation of Langmuir-Blodgett Films Containing Fullerenes", Tetrahedron Letters, 1994, Vol. 35, Nº 18, páginas 2985-2988. *
M. VALCARCEL et al. "Fullerenes as Sorbent Materials for Metal Preconcentration", Anal. Chem., 1994, Vol. 66, páginas 4074-4078. *

Also Published As

Publication number Publication date
ES2199024A1 (en) 2004-02-01

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