ES2189619B1 - 2,2- (VINYLENBIS (3-SULFONATE-4,1-PHENYLENE) IMINO (6- (IDB (2-HYDROXYPROPIL) AMINO) 1,3,5, -TRIAZINE-4,2-DIIL) IMINO)) BIS ( BENZENE-1,4-DISULFONATE) HEXASODY AND PROCEDURE FOR OBTAINING. - Google Patents

2,2- (VINYLENBIS (3-SULFONATE-4,1-PHENYLENE) IMINO (6- (IDB (2-HYDROXYPROPIL) AMINO) 1,3,5, -TRIAZINE-4,2-DIIL) IMINO)) BIS ( BENZENE-1,4-DISULFONATE) HEXASODY AND PROCEDURE FOR OBTAINING.

Info

Publication number
ES2189619B1
ES2189619B1 ES200100202A ES200100202A ES2189619B1 ES 2189619 B1 ES2189619 B1 ES 2189619B1 ES 200100202 A ES200100202 A ES 200100202A ES 200100202 A ES200100202 A ES 200100202A ES 2189619 B1 ES2189619 B1 ES 2189619B1
Authority
ES
Spain
Prior art keywords
imino
bis
obtaining
disulfonate
triazine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn - After Issue
Application number
ES200100202A
Other languages
Spanish (es)
Other versions
ES2189619A1 (en
Inventor
Jose Comas Carceller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Elaboracion De Colorantes S A
ELABORACION DE COLORANTES SA
Original Assignee
Elaboracion De Colorantes S A
ELABORACION DE COLORANTES SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Elaboracion De Colorantes S A, ELABORACION DE COLORANTES SA filed Critical Elaboracion De Colorantes S A
Priority to ES200100202A priority Critical patent/ES2189619B1/en
Priority to PCT/IB2001/001920 priority patent/WO2002060883A1/en
Publication of ES2189619A1 publication Critical patent/ES2189619A1/en
Application granted granted Critical
Publication of ES2189619B1 publication Critical patent/ES2189619B1/en
Anticipated expiration legal-status Critical
Withdrawn - After Issue legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/60—Optical bleaching or brightening
    • D06L4/614—Optical bleaching or brightening in aqueous solvents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/40—Nitrogen atoms
    • C07D251/54—Three nitrogen atoms
    • C07D251/68—Triazinylamino stilbenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C08K5/42—Sulfonic acids; Derivatives thereof
    • D06L3/1207—
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/60—Optical bleaching or brightening
    • D06L4/614—Optical bleaching or brightening in aqueous solvents
    • D06L4/621—Optical bleaching or brightening in aqueous solvents with anionic brighteners
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/30—Luminescent or fluorescent substances, e.g. for optical bleaching

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paper (AREA)

Abstract

2,2''-[vinilenbis[(3-sulfonato-4,1-fenilen)imino[6-[bis(2- hidroxipropil)amino]1,3,5-triazina-4,2-diil]imino]]bis(benceno- 1,4-disulfonato)de hexasodio y procedimiento para su obtención. Producto de fórmula general (I) donde X es un grupo diisopropanolamina y cuyo procedimiento de obtención comprende tres etapas sucesivas de condensación, bajo condiciones de pH determinadas. Dicho producto presenta un efecto blanqueante mejorado en papel ya que no presenta los problemas de saturación característicos de otros productos conocidos y presenta otras posibles utilizaciones en salsas de estuco que contienen una cantidad apreciable de almidón o carboximetilcelulosa y en el blanqueo de géneros de fibras celulósicas en la industria textil.2,2 '' - [Vinylenebis [(3-sulfonate-4,1-phenylene) imino [6- [bis (2- hydroxypropyl) amino] 1,3,5-triazine-4,2-diyl] imino]] hexasodium bis (benzene-1,4-disulfonate) and process for obtaining it. Product of general formula (I) where X is a diisopropanolamine group and whose process of obtaining comprises three successive stages of condensation, under certain pH conditions. Said product has an improved bleaching effect on paper since it does not present the saturation problems characteristic of other known products and has other possible uses in stucco sauces containing an appreciable amount of starch or carboxymethyl cellulose and in the bleaching of cellulosic fiber genera in The textile industry.

ES200100202A 2001-01-30 2001-01-30 2,2- (VINYLENBIS (3-SULFONATE-4,1-PHENYLENE) IMINO (6- (IDB (2-HYDROXYPROPIL) AMINO) 1,3,5, -TRIAZINE-4,2-DIIL) IMINO)) BIS ( BENZENE-1,4-DISULFONATE) HEXASODY AND PROCEDURE FOR OBTAINING. Withdrawn - After Issue ES2189619B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
ES200100202A ES2189619B1 (en) 2001-01-30 2001-01-30 2,2- (VINYLENBIS (3-SULFONATE-4,1-PHENYLENE) IMINO (6- (IDB (2-HYDROXYPROPIL) AMINO) 1,3,5, -TRIAZINE-4,2-DIIL) IMINO)) BIS ( BENZENE-1,4-DISULFONATE) HEXASODY AND PROCEDURE FOR OBTAINING.
PCT/IB2001/001920 WO2002060883A1 (en) 2001-01-30 2001-10-15 2-2"-[vinylenebis[(3-sulphonate-4,1-phenylene) imino[6-[bis(2-hydroxypropyl)amino]-1,3,5-triazine-4,2-diyl]imino]]bis(benzene-1,4 -disulphonate) of hexadosium and method for making same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES200100202A ES2189619B1 (en) 2001-01-30 2001-01-30 2,2- (VINYLENBIS (3-SULFONATE-4,1-PHENYLENE) IMINO (6- (IDB (2-HYDROXYPROPIL) AMINO) 1,3,5, -TRIAZINE-4,2-DIIL) IMINO)) BIS ( BENZENE-1,4-DISULFONATE) HEXASODY AND PROCEDURE FOR OBTAINING.

Publications (2)

Publication Number Publication Date
ES2189619A1 ES2189619A1 (en) 2003-07-01
ES2189619B1 true ES2189619B1 (en) 2004-10-01

Family

ID=8496546

Family Applications (1)

Application Number Title Priority Date Filing Date
ES200100202A Withdrawn - After Issue ES2189619B1 (en) 2001-01-30 2001-01-30 2,2- (VINYLENBIS (3-SULFONATE-4,1-PHENYLENE) IMINO (6- (IDB (2-HYDROXYPROPIL) AMINO) 1,3,5, -TRIAZINE-4,2-DIIL) IMINO)) BIS ( BENZENE-1,4-DISULFONATE) HEXASODY AND PROCEDURE FOR OBTAINING.

Country Status (2)

Country Link
ES (1) ES2189619B1 (en)
WO (1) WO2002060883A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4179584B2 (en) 2001-03-22 2008-11-12 日本化薬株式会社 Aqueous liquid composition of fluorescent brightener with excellent dyeing properties
EP2192231A1 (en) 2008-11-27 2010-06-02 Clariant International Ltd. Improved optical brightening compositions for high quality inkjet printing
ES2390932T5 (en) † 2008-11-27 2020-09-14 Archroma Ip Gmbh Optical Brightening Compositions for High-Quality Inkjet Printing
KR20110089364A (en) 2008-11-27 2011-08-05 클라리언트 파이넌스 (비브이아이)리미티드 Improved optical brightening compositions for high quality ink jet printing
US20100129553A1 (en) * 2008-11-27 2010-05-27 International Paper Company Optical Brightening Compositions For High Quality Inkjet Printing
CN101429344B (en) * 2008-12-08 2012-07-04 浙江传化华洋化工有限公司 Process for producing hexa-sulphonic acid liquid fluorescent whitening agents
CN103436050B (en) * 2013-09-16 2014-12-03 山西青山化工有限公司 Liquid fluorescent whitening agent and preparation method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3479349A (en) * 1967-08-03 1969-11-18 Geigy Chem Corp Polysulfonated bis-s-triazinylamino-stilbene-2,2'-disulfonic acids
DE19500791C1 (en) * 1995-01-13 1996-08-01 Bayer Ag Substd. 4,4-di:amino-stilbene-2,2-di:sulphonic acid salts prodn.
DE19706238B4 (en) * 1997-02-18 2005-09-01 Bayer Chemicals Ag Process for the preparation of substituted 4,4'-diaminostilbene-2,2'-disulfonic acids
US6165973A (en) * 1999-02-05 2000-12-26 Ciba Specialty Chemicals Corporation Fluorescent whitening agent, its preparation and use

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
BASE DE DATOS CHEMLIST [en línea] [recuperado el 27.05.2003] Recuperado de: STN Internacional AN:56551. Supplement to Canada Gazette, Part I, January 26, 1991. *
PAULSSON, M. et al. Chemical modification of lignin-rich paper. Part 7. Photostabilizing high-brightness aspen CTMP by combining various classes of additives and acetylation. Nord. Pulp Pap. Res. J., 1998, 13 (2), páginas 124-131. *

Also Published As

Publication number Publication date
WO2002060883A1 (en) 2002-08-08
ES2189619A1 (en) 2003-07-01

Similar Documents

Publication Publication Date Title
CN100564670C (en) Triazinylaminostilbedisulphonic disulphonic acid mixtures
ES2189619B1 (en) 2,2- (VINYLENBIS (3-SULFONATE-4,1-PHENYLENE) IMINO (6- (IDB (2-HYDROXYPROPIL) AMINO) 1,3,5, -TRIAZINE-4,2-DIIL) IMINO)) BIS ( BENZENE-1,4-DISULFONATE) HEXASODY AND PROCEDURE FOR OBTAINING.
JP2003509416A (en) Triazinylaminostilbene derivatives as optical brighteners
FI102623B1 (en) Procedure and apparatus in a paper machine
CA2425235A1 (en) Improved creping adhesive modifier and process for producing paper products
US3018287A (en) Optical brighteners for use with paper
US8092649B2 (en) Method of decreasing the rate of photoyellowing with thiocyanic acid
BR9609008A (en) Pulp production process from fibrous plant materials, apparatus for pulping fibrous plant materials and pulp.
BR0215015A (en) Mono azo acid dyes
IL206268A (en) Storage stable solutions of optical brighteners
FI20030769A0 (en) Starch derivatives, their preparation and use
ATE306537T1 (en) FLUORESCENT BRIGHTENING PIGMENT COMPOSITIONS
BR0317786A (en) Process for the production of wrinkled and twisted fibers
JP2006045761A (en) Alkanol-ammonium containing triazinylflavonate brightener
MXPA03008248A (en) N-heteroarylmethyl-m-phenylenediamine derivative-containing dyes for keratin fibers and novel n-heteroarylmethyl-m-phenylenediamine derivatives.
GB896533A (en) New stilbene derivatives and process for their manufacture
EP2933253A1 (en) Stilbene optical brighteners
ITMI20121220A1 (en) STYLBENIC COMPOUNDS
BRPI0600247A (en) chemical pulp unsaturated uranic acid removal process for papermaking
TW200516193A (en) Composition for the fluorescent whitening of paper
TR200503591T1 (en) A method of dyeing a mixture comprising two or more different fibers.
US9109331B2 (en) Fluorescent brighter #71 used for the papermaking process
US5844101A (en) Light-fast disazo dyestuffs
ES2038076B1 (en) PROCEDURE FOR OBTAINING PRODUCTS USEFUL AS AUXILIARIES FOR THE DYEING OF SUBSTRATES OF CELLULOSE OR POLYAMID MATERIAL.
Berry Progress in paper coloration

Legal Events

Date Code Title Description
EC2A Search report published

Date of ref document: 20030701

Kind code of ref document: A1

FG2A Definitive protection

Ref document number: 2189619B1

Country of ref document: ES

FA2A Application withdrawn

Effective date: 20050301