ES2179727A1 - Preparation of nitro aromatic oxidized derivatives involves treatment with nucleophilic reagents for electrochemical oxidation - Google Patents

Preparation of nitro aromatic oxidized derivatives involves treatment with nucleophilic reagents for electrochemical oxidation

Info

Publication number
ES2179727A1
ES2179727A1 ES200000489A ES200000489A ES2179727A1 ES 2179727 A1 ES2179727 A1 ES 2179727A1 ES 200000489 A ES200000489 A ES 200000489A ES 200000489 A ES200000489 A ES 200000489A ES 2179727 A1 ES2179727 A1 ES 2179727A1
Authority
ES
Spain
Prior art keywords
preparation
electrochemical oxidation
nucleophilic reagents
oxidized derivatives
involves treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES200000489A
Other languages
Spanish (es)
Other versions
ES2179727B1 (en
Inventor
Garcia Iluminada Gallardo
Lopez Gonzalo Guirado
Cortes Jordi Marquet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universitat Autonoma de Barcelona UAB
Universitat de Barcelona UB
Original Assignee
Universitat Autonoma de Barcelona UAB
Universitat de Barcelona UB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universitat Autonoma de Barcelona UAB, Universitat de Barcelona UB filed Critical Universitat Autonoma de Barcelona UAB
Priority to ES200000489A priority Critical patent/ES2179727B1/en
Publication of ES2179727A1 publication Critical patent/ES2179727A1/en
Application granted granted Critical
Publication of ES2179727B1 publication Critical patent/ES2179727B1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The preparation of nitro-aromatic oxidized derivatives involves functionalization of nitro-aromatic derivatives by nucleophilic reagents, through formation of the corresponding Meisenheimer complexes. These then undergo electrochemical oxidation.
ES200000489A 2000-03-01 2000-03-01 ELECTROCHEMICAL PREPARATION OF NITRO-, DINITRO AND SUBSTITUTED TRINITRO-DERIVATIVES. Expired - Fee Related ES2179727B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
ES200000489A ES2179727B1 (en) 2000-03-01 2000-03-01 ELECTROCHEMICAL PREPARATION OF NITRO-, DINITRO AND SUBSTITUTED TRINITRO-DERIVATIVES.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES200000489A ES2179727B1 (en) 2000-03-01 2000-03-01 ELECTROCHEMICAL PREPARATION OF NITRO-, DINITRO AND SUBSTITUTED TRINITRO-DERIVATIVES.

Publications (2)

Publication Number Publication Date
ES2179727A1 true ES2179727A1 (en) 2003-01-16
ES2179727B1 ES2179727B1 (en) 2004-06-16

Family

ID=8492518

Family Applications (1)

Application Number Title Priority Date Filing Date
ES200000489A Expired - Fee Related ES2179727B1 (en) 2000-03-01 2000-03-01 ELECTROCHEMICAL PREPARATION OF NITRO-, DINITRO AND SUBSTITUTED TRINITRO-DERIVATIVES.

Country Status (1)

Country Link
ES (1) ES2179727B1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114507156A (en) * 2021-10-22 2022-05-17 浙江巍华新材料股份有限公司 Preparation method of cyanophenyl compound
CN114507156B (en) * 2021-10-22 2024-06-07 浙江巍华新材料股份有限公司 Preparation method of benzonitrile compound

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1051614A (en) * 1962-06-02

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1051614A (en) * 1962-06-02

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
I.M. SOSONKIN et al. "Mechanism of the electrochemical oxidation of anionic sigma-complexes, derivatives of m-dinitrobenzene", Zhur. Org. Khimii, (1979), Vol. 19, Nö 9, páginas 1895-1898 (resumen), CAPLUS [en línea] [recuperado el 09.12.2002]. Recuperado de: STN International, Columbus, Ohio (EE.UU.). Nö de acceso 1979:601040. *
M. MAKOSZA et al. "Oxidative Nucleophilic Substitution of Hydrogen in Nitroarenes. A Short Review", Polish J. Chem., 1999, Vol. 73, pßginas 151-161. *
M. MIR et al. "Reductively Activated Polar Nucleophilic Aromatic Substitution. II. The Reaction of p-Dinitrobenzene and p-Nitrobenzonitrile with Charged and Neutral Nucleophiles", Tetrahedron Letters, 1994, Vol. 35, Nö 48, páginas 9055-9058. *
R. BACALOGLU et al. "Single-Electron Transfer in Aromatic Nucleophilic Substitution on Dinitrobenzonitriles", J. Am. Chem. Soc., 1992, Vol. 114, Nö 20, páginas 7708-7718. *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114507156A (en) * 2021-10-22 2022-05-17 浙江巍华新材料股份有限公司 Preparation method of cyanophenyl compound
CN114507156B (en) * 2021-10-22 2024-06-07 浙江巍华新材料股份有限公司 Preparation method of benzonitrile compound

Also Published As

Publication number Publication date
ES2179727B1 (en) 2004-06-16

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