ES2179727A1 - Preparation of nitro aromatic oxidized derivatives involves treatment with nucleophilic reagents for electrochemical oxidation - Google Patents
Preparation of nitro aromatic oxidized derivatives involves treatment with nucleophilic reagents for electrochemical oxidationInfo
- Publication number
- ES2179727A1 ES2179727A1 ES200000489A ES200000489A ES2179727A1 ES 2179727 A1 ES2179727 A1 ES 2179727A1 ES 200000489 A ES200000489 A ES 200000489A ES 200000489 A ES200000489 A ES 200000489A ES 2179727 A1 ES2179727 A1 ES 2179727A1
- Authority
- ES
- Spain
- Prior art keywords
- preparation
- electrochemical oxidation
- nucleophilic reagents
- oxidized derivatives
- involves treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The preparation of nitro-aromatic oxidized derivatives involves functionalization of nitro-aromatic derivatives by nucleophilic reagents, through formation of the corresponding Meisenheimer complexes. These then undergo electrochemical oxidation.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES200000489A ES2179727B1 (en) | 2000-03-01 | 2000-03-01 | ELECTROCHEMICAL PREPARATION OF NITRO-, DINITRO AND SUBSTITUTED TRINITRO-DERIVATIVES. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES200000489A ES2179727B1 (en) | 2000-03-01 | 2000-03-01 | ELECTROCHEMICAL PREPARATION OF NITRO-, DINITRO AND SUBSTITUTED TRINITRO-DERIVATIVES. |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2179727A1 true ES2179727A1 (en) | 2003-01-16 |
ES2179727B1 ES2179727B1 (en) | 2004-06-16 |
Family
ID=8492518
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES200000489A Expired - Fee Related ES2179727B1 (en) | 2000-03-01 | 2000-03-01 | ELECTROCHEMICAL PREPARATION OF NITRO-, DINITRO AND SUBSTITUTED TRINITRO-DERIVATIVES. |
Country Status (1)
Country | Link |
---|---|
ES (1) | ES2179727B1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114507156A (en) * | 2021-10-22 | 2022-05-17 | 浙江巍华新材料股份有限公司 | Preparation method of cyanophenyl compound |
CN114507156B (en) * | 2021-10-22 | 2024-06-07 | 浙江巍华新材料股份有限公司 | Preparation method of benzonitrile compound |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1051614A (en) * | 1962-06-02 |
-
2000
- 2000-03-01 ES ES200000489A patent/ES2179727B1/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1051614A (en) * | 1962-06-02 |
Non-Patent Citations (4)
Title |
---|
I.M. SOSONKIN et al. "Mechanism of the electrochemical oxidation of anionic sigma-complexes, derivatives of m-dinitrobenzene", Zhur. Org. Khimii, (1979), Vol. 19, Nö 9, páginas 1895-1898 (resumen), CAPLUS [en línea] [recuperado el 09.12.2002]. Recuperado de: STN International, Columbus, Ohio (EE.UU.). Nö de acceso 1979:601040. * |
M. MAKOSZA et al. "Oxidative Nucleophilic Substitution of Hydrogen in Nitroarenes. A Short Review", Polish J. Chem., 1999, Vol. 73, pßginas 151-161. * |
M. MIR et al. "Reductively Activated Polar Nucleophilic Aromatic Substitution. II. The Reaction of p-Dinitrobenzene and p-Nitrobenzonitrile with Charged and Neutral Nucleophiles", Tetrahedron Letters, 1994, Vol. 35, Nö 48, páginas 9055-9058. * |
R. BACALOGLU et al. "Single-Electron Transfer in Aromatic Nucleophilic Substitution on Dinitrobenzonitriles", J. Am. Chem. Soc., 1992, Vol. 114, Nö 20, páginas 7708-7718. * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114507156A (en) * | 2021-10-22 | 2022-05-17 | 浙江巍华新材料股份有限公司 | Preparation method of cyanophenyl compound |
CN114507156B (en) * | 2021-10-22 | 2024-06-07 | 浙江巍华新材料股份有限公司 | Preparation method of benzonitrile compound |
Also Published As
Publication number | Publication date |
---|---|
ES2179727B1 (en) | 2004-06-16 |
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