ES2153138T3 - PROCEDURE FOR REACTIONING CARBON MONOXIDE WITH A CARBONABLE REACTANT AND / OR AN ESTER DERIVED FROM IT. - Google Patents

PROCEDURE FOR REACTIONING CARBON MONOXIDE WITH A CARBONABLE REACTANT AND / OR AN ESTER DERIVED FROM IT.

Info

Publication number
ES2153138T3
ES2153138T3 ES97104832T ES97104832T ES2153138T3 ES 2153138 T3 ES2153138 T3 ES 2153138T3 ES 97104832 T ES97104832 T ES 97104832T ES 97104832 T ES97104832 T ES 97104832T ES 2153138 T3 ES2153138 T3 ES 2153138T3
Authority
ES
Spain
Prior art keywords
procedure
carbon monoxide
carbonable
reactioning
reactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97104832T
Other languages
Spanish (es)
Inventor
Kirsten Everald Clode
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Application granted granted Critical
Publication of ES2153138T3 publication Critical patent/ES2153138T3/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/54—Preparation of carboxylic acid anhydrides
    • C07C51/573—Separation; Purification; Stabilisation; Use of additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4092—Regeneration or reactivation of catalysts containing metals involving a stripping step, with stripping gas or solvent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Confectionery (AREA)
  • Alcoholic Beverages (AREA)
  • Dairy Products (AREA)

Abstract

UN PROCEDIMIENTO PARA HACER REACCIONAR MONOXIDO DE CARBONO CON UN REACTIVO QUE SE PUEDE CARBONILAR Y/O UN DERIVADO DE ESTER DEL MISMO EN UNA COMPOSICION DE REACCION LIQUIDA QUE COMPRENDE UN CATALIZADOR DE CARBONILACION DE IRIDIO, UN PROMOTOR DE CARBONILACION DE HALURO DE HIDROCARBILO, AGUA Y UN PRODUCTO DE REACCION DE CARBONILACION, CARACTERIZADO EN QUE LA COMPOSICION DE REACCION LIQUIDA COMPRENDE AGUA A UNA CONCENTRACION DE ALREDEDOR EL 2 AL 8% DE PESO, PROMOTOR DE CARBONILACION DE HALURO DE HIDROCARBILO A UNA CONCENTRACION EN EL RANGO DEL 1 AL 20% DE PESO Y DERIVADO DE ESTER DEL REACTIVO QUE SE PUEDE CARBONILAR A UNA CONCENTRACION EN EL RANGO DEL 1,0 AL 60% DE PESO.A PROCEDURE TO MAKE CARBON MONOXIDE REACT WITH A REAGENT THAT CAN BE CARBONY AND / OR AN ESTER DERIVATIVE OF THE SAME IN A LIQUID REACTION COMPOSITION THAT INCLUDES AN IRIDIO CARBONILATION CATALYST, A CARBON CARBON HUB A CARBONILATION REACTION PRODUCT, CHARACTERIZED IN WHICH THE LIQUID REACTION COMPOSITION INCLUDES WATER TO A CONCENTRATION AROUND 2 TO 8% WEIGHT, CARBONILATION PROMOTER OF HYDROCARBON HALIDE AT A CONCENTRATION 1 TO 20% RANGE AND DERIVED FROM ESTER OF THE REAGENT THAT CAN BE CARBONED TO A CONCENTRATION IN THE RANGE OF 1.0 TO 60% WEIGHT.

ES97104832T 1993-03-26 1994-03-09 PROCEDURE FOR REACTIONING CARBON MONOXIDE WITH A CARBONABLE REACTANT AND / OR AN ESTER DERIVED FROM IT. Expired - Lifetime ES2153138T3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB939306409A GB9306409D0 (en) 1993-03-26 1993-03-26 Process

Publications (1)

Publication Number Publication Date
ES2153138T3 true ES2153138T3 (en) 2001-02-16

Family

ID=10732866

Family Applications (2)

Application Number Title Priority Date Filing Date
ES97104832T Expired - Lifetime ES2153138T3 (en) 1993-03-26 1994-03-09 PROCEDURE FOR REACTIONING CARBON MONOXIDE WITH A CARBONABLE REACTANT AND / OR AN ESTER DERIVED FROM IT.
ES94301645T Expired - Lifetime ES2108376T3 (en) 1993-03-26 1994-03-09 PROCESS FOR THE RECOVERY OF A CARBONILATION PRODUCT.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES94301645T Expired - Lifetime ES2108376T3 (en) 1993-03-26 1994-03-09 PROCESS FOR THE RECOVERY OF A CARBONILATION PRODUCT.

Country Status (21)

Country Link
US (2) US5750007A (en)
EP (2) EP0786447B1 (en)
JP (2) JP4233122B2 (en)
KR (1) KR100288997B1 (en)
CN (2) CN1047588C (en)
BR (1) BR9401281A (en)
CA (1) CA2119609C (en)
DE (2) DE69406167T2 (en)
ES (2) ES2153138T3 (en)
FI (1) FI941395A (en)
GB (1) GB9306409D0 (en)
ID (1) ID16946A (en)
IN (2) IN188047B (en)
MY (1) MY121550A (en)
NO (1) NO300768B1 (en)
NZ (1) NZ260174A (en)
RU (1) RU2133731C1 (en)
SG (2) SG70019A1 (en)
TW (1) TW268939B (en)
UA (2) UA41279C2 (en)
YU (2) YU49305B (en)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9306409D0 (en) * 1993-03-26 1993-05-19 Bp Chem Int Ltd Process
FR2703351A1 (en) * 1993-03-31 1994-10-07 Rhone Poulenc Chimie Process for the preparation of carboxylic acids or the corresponding esters in the presence of a catalyst based on rhodium and iridium.
CN1070167C (en) * 1994-05-13 2001-08-29 派蒂斯艾西提克公司 Method for the preparation of carboxylic acids or corresponding esters in the presence of a soluble iridium and iodide-based catalyst
GB9503385D0 (en) * 1995-02-21 1995-04-12 Bp Chem Int Ltd Process
US5696284A (en) * 1995-06-21 1997-12-09 Bp Chemicals Limited Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof
EP0851851B1 (en) * 1995-11-03 2001-02-21 Ineos Acrylics UK Limited Carbonylation reactions
US5831120A (en) * 1996-11-19 1998-11-03 Watson; Derrick John Process for the production of acetic acid
GB9626317D0 (en) * 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
GB9626324D0 (en) * 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
GB9626428D0 (en) * 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
GB9816385D0 (en) 1998-07-29 1998-09-23 Bp Chem Int Ltd Process
GB9819079D0 (en) 1998-09-03 1998-10-28 Bp Chem Int Ltd Carbonylation process
GB9819606D0 (en) 1998-09-08 1998-11-04 Bp Chem Int Ltd Carbonylation process
US6552221B1 (en) 1998-12-18 2003-04-22 Millenium Petrochemicals, Inc. Process control for acetic acid manufacture
FR2795410B1 (en) * 1999-06-22 2002-12-27 Acetex Chimie PROCESS FOR IMPROVING THE STABILITY AND / OR AVOIDING THE DEACTIVATION OF THE CATALYST DURING THE MANUFACTURE OF ACETIC ACID AND / OR METHYL ACETATE
DE19946545B4 (en) 1999-09-28 2006-05-04 W.C. Heraeus Gmbh Process for the preparation of tris (acetylacetonato) iridium (III)
GB9926855D0 (en) * 1999-11-12 2000-01-12 Bp Chem Int Ltd Process
NL1013682C2 (en) * 1999-11-26 2001-05-30 Purac Biochem Bv Method and device for purifying an aqueous solution of lactic acid.
JP5069827B2 (en) 2001-02-28 2012-11-07 株式会社ダイセル Reaction control method and control apparatus
JP4245298B2 (en) 2002-02-27 2009-03-25 ダイセル化学工業株式会社 Gas reaction component supply control method and control apparatus
GB0212974D0 (en) * 2002-06-06 2002-07-17 Bp Chem Int Ltd Process
GB0213485D0 (en) * 2002-06-12 2002-07-24 Bp Chem Int Ltd Process
CA2496839A1 (en) 2004-07-19 2006-01-19 Woodland Chemical Systems Inc. Process for producing ethanol from synthesis gas rich in carbon monoxide
CN100363321C (en) * 2005-12-29 2008-01-23 西南化工研究设计院 Rectification method in acetic acid synthesis process by low-pressure methanol carbonylation
BRPI0710578B1 (en) * 2006-04-05 2016-11-29 Woodland Biofuels Inc Ethanol production method from synthesis gas
DE102007014914B4 (en) 2007-03-26 2013-09-12 Heraeus Precious Metals Gmbh & Co. Kg Catalytically highly effective noble metal carboxylate compounds of Ir, Ru, Rh, Pd, Pt and Au
US7902397B2 (en) * 2007-10-11 2011-03-08 Celanese International Corporation Method and apparatus for making acetic acid with improved productivity
EP2093209A1 (en) 2008-02-19 2009-08-26 BP Chemicals Limited Process for the production of acetic acid
US7820855B2 (en) 2008-04-29 2010-10-26 Celanese International Corporation Method and apparatus for carbonylating methanol with acetic acid enriched flash stream
WO2012014393A1 (en) 2010-07-26 2012-02-02 Daicel Chemical Industries, Ltd. Process for producing acetic acid
MY161203A (en) 2010-12-15 2017-04-14 Daicel Corp Process for producing acetic acid
AR094541A1 (en) * 2013-01-25 2015-08-12 Daicel Corp PROCEDURE TO PRODUCE CARBOXYL ACID
CN106170467B (en) 2013-12-24 2020-05-12 英国石油有限公司 Process for the production of ethanol by hydrogenation of methyl acetate

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CA837644A (en) * 1970-03-24 E. Paulik Frank Production of carboxylic acids and esters
GB203385A (en) * 1922-06-06 1923-09-06 John Edward Thornton Improved spindle for winding yarns
SE364255B (en) * 1967-04-05 1974-02-18 Monsanto Co
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US3772380A (en) * 1970-03-12 1973-11-13 Monsanto Co Production of carboxylic acids and esters
US3845121A (en) * 1971-11-10 1974-10-29 Monsanto Co Process for separating carbonylation products from reaction mixture without catalyst decomposition
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CA2035426A1 (en) * 1990-02-09 1991-08-10 David W. Smith Catalytic carbonylation process
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GB9211671D0 (en) * 1992-06-02 1992-07-15 Bp Chem Int Ltd Process
GB9306409D0 (en) * 1993-03-26 1993-05-19 Bp Chem Int Ltd Process
BR9401362A (en) * 1993-03-31 1994-11-01 Rhone Poulenc Chimie Process for the preparation of carboxylic acids, or the corresponding esters
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US5599976A (en) * 1995-04-07 1997-02-04 Hoechst Celanese Corporation Recovery of acetic acid from dilute aqueous streams formed during a carbonylation process

Also Published As

Publication number Publication date
NO941115L (en) 1994-09-27
EP0786447B1 (en) 2000-12-20
EP0616997B1 (en) 1997-10-15
IN188047B (en) 2002-08-10
KR940021500A (en) 1994-10-19
GB9306409D0 (en) 1993-05-19
NZ260174A (en) 1996-11-26
CN1099378A (en) 1995-03-01
JP2009073846A (en) 2009-04-09
UA43843C2 (en) 2002-01-15
FI941395A0 (en) 1994-03-25
US5874610A (en) 1999-02-23
US5750007A (en) 1998-05-12
BR9401281A (en) 1994-11-01
DE69426467D1 (en) 2001-01-25
ID16946A (en) 1997-11-27
CA2119609A1 (en) 1994-09-27
RU2133731C1 (en) 1999-07-27
SG46155A1 (en) 1998-02-20
YU49301B (en) 2005-06-10
DE69406167T2 (en) 1998-02-12
CN1047588C (en) 1999-12-22
MY121550A (en) 2006-02-28
DE69406167D1 (en) 1997-11-20
IN191080B (en) 2003-09-13
TW268939B (en) 1996-01-21
YU49305B (en) 2005-06-10
EP0616997A1 (en) 1994-09-28
ES2108376T3 (en) 1997-12-16
EP0786447A1 (en) 1997-07-30
YU14594A (en) 1996-10-09
KR100288997B1 (en) 2001-05-02
JPH06321847A (en) 1994-11-22
NO300768B1 (en) 1997-07-21
YU38504A (en) 2004-07-15
CA2119609C (en) 2005-05-17
UA41279C2 (en) 2001-09-17
CN1073543C (en) 2001-10-24
SG70019A1 (en) 2000-01-25
DE69426467T2 (en) 2001-04-19
NO941115D0 (en) 1994-03-25
FI941395A (en) 1994-09-27
JP4233122B2 (en) 2009-03-04
CN1136033A (en) 1996-11-20

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