ES2144364B1 - METHOD FOR PRODUCING SYNTHETIC OILS AND STORAGE PRODUCTS OF HEATING ENERGY THROUGH CO-PROCESSING OF MATERIALS OF RUBBER OF RUBBER AND CARBON. - Google Patents

METHOD FOR PRODUCING SYNTHETIC OILS AND STORAGE PRODUCTS OF HEATING ENERGY THROUGH CO-PROCESSING OF MATERIALS OF RUBBER OF RUBBER AND CARBON.

Info

Publication number
ES2144364B1
ES2144364B1 ES009800650A ES9800650A ES2144364B1 ES 2144364 B1 ES2144364 B1 ES 2144364B1 ES 009800650 A ES009800650 A ES 009800650A ES 9800650 A ES9800650 A ES 9800650A ES 2144364 B1 ES2144364 B1 ES 2144364B1
Authority
ES
Spain
Prior art keywords
rubber
synthetic oils
heat energy
materials
producing synthetic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
ES009800650A
Other languages
Spanish (es)
Other versions
ES2144364A1 (en
Inventor
Lamarca Ana Maria Mastral
Villuendas Ramon Murillo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior de Investigaciones Cientificas CSIC filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Publication of ES2144364A1 publication Critical patent/ES2144364A1/en
Application granted granted Critical
Publication of ES2144364B1 publication Critical patent/ES2144364B1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

Método para producir aceites sintéticos y productos almacenables de energía calorífica mediante coprocesado de materiales de caucho de desecho y carbón. Un método para producir aceites sintéticos y productos almacenables de energía calorífica coprocesando materiales de caucho de desecho y carbón, eventualmente con un catalizador que contiene Fe, consistente en las etapas de: mezclar el material de caucho triturado, carbón y, opcionalmente, el catalizador hasta obtener una mezcla; calentar la mezcla en un reactor a una temperatura entre 300ºC a 500ºC, durante 3-180 minutos, a una presión entre la presión atmosférica y 10 MPa, seguidas de un procesado consistente en una pirólisis/hidropirólisis, durante la que se generan gases con un 50% de hidrocarburos C sub,1 -C sub,4 y una energía calorífica de 6000 a 8000 kcal/Nm sup,3 , que se recogen. El material resultante de la reacción es una mezcla de sólidos y líquidos de la cual se obtienen un extracto y un primer residuo sólido con una energía calorífica de 4500 a 5000 kcal/kg, mientras que mediante fraccionación del extracto, se obtienen un residuo de asfalteno de elevada energía calorífica, y aceites sintéticos.Method for producing synthetic oils and storable products of heat energy by coprocessing waste rubber and coal materials. A method for producing synthetic oils and storable heat energy products by coprocessing waste rubber and carbon materials, possibly with a catalyst containing Fe, consisting of the steps of: mixing the crushed rubber material, coal and, optionally, the catalyst up to get a mixture; heating the mixture in a reactor at a temperature between 300 ° C to 500 ° C, for 3-180 minutes, at a pressure between atmospheric pressure and 10 MPa, followed by a process consisting of a pyrolysis / hydropyrolysis, during which gases are generated with a 50% of hydrocarbons C sub, 1 -C sub, 4 and a calorific energy of 6000 to 8000 kcal / Nm sup, 3, which are collected. The material resulting from the reaction is a mixture of solids and liquids from which an extract and a first solid residue with a heat energy of 4500 to 5000 kcal / kg are obtained, while by fractionation of the extract, an asphaltene residue is obtained high heat energy, and synthetic oils.

ES009800650A 1997-03-26 1998-03-26 METHOD FOR PRODUCING SYNTHETIC OILS AND STORAGE PRODUCTS OF HEATING ENERGY THROUGH CO-PROCESSING OF MATERIALS OF RUBBER OF RUBBER AND CARBON. Expired - Fee Related ES2144364B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/824,297 US5936134A (en) 1997-03-26 1997-03-26 Method for obtaining storable products of calorific energy and synthetical oils, by processing waste rubber materials with coal

Publications (2)

Publication Number Publication Date
ES2144364A1 ES2144364A1 (en) 2000-06-01
ES2144364B1 true ES2144364B1 (en) 2001-01-01

Family

ID=25241054

Family Applications (1)

Application Number Title Priority Date Filing Date
ES009800650A Expired - Fee Related ES2144364B1 (en) 1997-03-26 1998-03-26 METHOD FOR PRODUCING SYNTHETIC OILS AND STORAGE PRODUCTS OF HEATING ENERGY THROUGH CO-PROCESSING OF MATERIALS OF RUBBER OF RUBBER AND CARBON.

Country Status (2)

Country Link
US (1) US5936134A (en)
ES (1) ES2144364B1 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020020112A1 (en) * 2000-07-25 2002-02-21 Scotlund Stivers Process and apparatus for manufacturing fuel gas and liquid fuels from trash, other waste materials and solid fuels
US20020020363A1 (en) * 2000-07-25 2002-02-21 Scotlund Stivers Pressure relief system
ES2190752B1 (en) * 2001-12-19 2005-10-16 Consejo Superior De Investigaciones Cientificas CATALYST FOR THE IMPROVEMENT OF SYNTHETIC OILS GENERATED FROM POLYMER WASTE MATERIAL.
US6933849B2 (en) 2002-07-09 2005-08-23 Fred Sawyer Method and apparatus for tracking objects and people
KR100519802B1 (en) * 2002-07-18 2005-10-10 금호타이어 주식회사 Method for Mesurement of Polycyclic Aromatics in Tire
US7803201B2 (en) * 2005-02-09 2010-09-28 Headwaters Technology Innovation, Llc Organically complexed nanocatalysts for improving combustion properties of fuels and fuel compositions incorporating such catalysts
US7856992B2 (en) * 2005-02-09 2010-12-28 Headwaters Technology Innovation, Llc Tobacco catalyst and methods for reducing the amount of undesirable small molecules in tobacco smoke
US7357903B2 (en) * 2005-04-12 2008-04-15 Headwaters Heavy Oil, Llc Method for reducing NOx during combustion of coal in a burner
US7758660B2 (en) * 2006-02-09 2010-07-20 Headwaters Technology Innovation, Llc Crystalline nanocatalysts for improving combustion properties of fuels and fuel compositions incorporating such catalysts
US7951271B2 (en) * 2006-06-12 2011-05-31 David Brent Thompson System for recovering oil from used automobile tires
US10745629B2 (en) 2017-01-16 2020-08-18 Council Of Scientific And Industrial Research Process for upgradation of heavy crude oil/residue using waste plastic as hydrogen donating agent
CN109201063B (en) * 2018-11-07 2020-09-11 中国科学院过程工程研究所 Red mud-based semi-coke catalyst and preparation method and application thereof
CN114525149A (en) * 2022-01-11 2022-05-24 钟永康 Method for preparing biological coal

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4077866A (en) * 1976-10-01 1978-03-07 Mobil Oil Corporation Process for producing low-sulfur liquid and solid fuels from coal
US4303497A (en) * 1978-09-25 1981-12-01 Mobil Oil Corporation Desulfurization, demetalation and denitrogenation of coal
US5061363A (en) * 1990-10-09 1991-10-29 The United States Of America As Represented By The United States Department Of Energy Method for co-processing waste rubber and carbonaceous material

Also Published As

Publication number Publication date
ES2144364A1 (en) 2000-06-01
US5936134A (en) 1999-08-10

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