ES2098776T3 - Metodo mejorado para la regeneracion de un catalizador desactivado. - Google Patents

Metodo mejorado para la regeneracion de un catalizador desactivado.

Info

Publication number
ES2098776T3
ES2098776T3 ES93920491T ES93920491T ES2098776T3 ES 2098776 T3 ES2098776 T3 ES 2098776T3 ES 93920491 T ES93920491 T ES 93920491T ES 93920491 T ES93920491 T ES 93920491T ES 2098776 T3 ES2098776 T3 ES 2098776T3
Authority
ES
Spain
Prior art keywords
deactivated catalyst
regeneration
improved method
depuration
reduction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93920491T
Other languages
English (en)
Inventor
Yao-Jyh Robert Huang
Shun Chong Fung
Gary Brice Mcvicker
Jar-Lin Kao
John Francis Walsh
Kenneth Ray Clem
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Application granted granted Critical
Publication of ES2098776T3 publication Critical patent/ES2098776T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B01J29/61—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing iron group metals, noble metals or copper
    • B01J29/62—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/90—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/42—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using halogen-containing material
    • B01J38/44—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using halogen-containing material and adding simultaneously or subsequently free oxygen; using oxyhalogen compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

UN PROCESO PARA REGENERAR UN CATALIZADOR DESACTIVADO O REDISPERSAR METALES CATALITICOS EN UN CATALIZADOR PURO QUE COMPRENDE AL MENOS UN METAL CATALITICO DEL GRUPO VIII Y ZEOLITA QUE CONTIENE FUNDIDO DE COQUE, OXIHALOGENACION, PRESION INFERIOR, DEPURACION A TEMPERATURA REDUCIDA, Y REDUCCION DEL HIDROGENO FINAL A BAJA PRESION, CON PRESIONES PARCIALES CONTROLADAS DE HALURO DE HIDROGENO EN LAS FASES DE DEPURACION Y REDUCCION.
ES93920491T 1992-09-04 1993-09-01 Metodo mejorado para la regeneracion de un catalizador desactivado. Expired - Lifetime ES2098776T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/940,579 US5756414A (en) 1983-11-10 1992-09-04 Method of regenerating deactivated catalyst

Publications (1)

Publication Number Publication Date
ES2098776T3 true ES2098776T3 (es) 1997-05-01

Family

ID=25475083

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93920491T Expired - Lifetime ES2098776T3 (es) 1992-09-04 1993-09-01 Metodo mejorado para la regeneracion de un catalizador desactivado.

Country Status (9)

Country Link
US (1) US5756414A (es)
EP (1) EP0671978B1 (es)
JP (1) JP3553934B2 (es)
KR (2) KR0136402B1 (es)
CA (1) CA2143826C (es)
DE (1) DE69307154T2 (es)
ES (1) ES2098776T3 (es)
SG (1) SG48224A1 (es)
WO (1) WO1994005418A1 (es)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19723949A1 (de) † 1997-06-06 1998-12-10 Basf Ag Verfahren zur Regenerierung eines Zeolith-Katalysators
US6121180A (en) * 1998-01-09 2000-09-19 Uop Llc Precombustion of halogen-containing compounds in catalyst regeneration processes
US6294492B1 (en) * 1999-06-30 2001-09-25 Philips Petroleum Company Catalytic reforming catalyst activation
WO2003000415A1 (en) 2001-06-22 2003-01-03 Phillips Petroleum Company Catalytic reforming catalyst activation
US7037871B1 (en) * 2001-11-21 2006-05-02 Uop Llc Low-temperature regeneration of zeolite L using ozone
TWI294415B (en) * 2004-02-10 2008-03-11 Maruzen Petrochemical Company Ltd Process for producing alcohols and/or ketones from alkenes using oxide catalysts
US7745675B2 (en) * 2006-12-20 2010-06-29 Saudi Basic Industries Corporation Regeneration of platinum-germanium zeolite catalyst
US20100160702A1 (en) 2008-12-23 2010-06-24 Chevron Phillips Chemical Company Lp Methods of Preparing an Aromatization Catalyst
WO2011136765A1 (en) 2010-04-28 2011-11-03 Exxonmobil Chemical Patents Inc. Regeneration of oligomerisation catalysts and their use
US8912108B2 (en) 2012-03-05 2014-12-16 Chevron Phillips Chemical Company Lp Methods of regenerating aromatization catalysts
US8716161B2 (en) 2012-03-05 2014-05-06 Chevron Phillips Chemical Company Methods of regenerating aromatization catalysts
US9387467B2 (en) 2012-09-26 2016-07-12 Chevron Phillips Chemical Company Lp Aromatization catalysts with high surface area and pore volume
CN104226379B (zh) * 2013-06-20 2017-11-28 中国石油化工股份有限公司 一种连续重整催化剂的再生方法
CN110225796A (zh) 2016-12-20 2019-09-10 环球油品有限责任公司 用于管理轻质石蜡脱氢方法中催化剂上的硫的方法
WO2018118721A1 (en) 2016-12-20 2018-06-28 Uop Llc Process for managing sulfur on catalyst in a light paraffin dehydrogenation process
US10118167B2 (en) * 2016-12-20 2018-11-06 Chevron Phillips Chemical Company Lp Methods for regenerating sulfur-contaminated aromatization catalysts
US20190054427A1 (en) * 2017-08-15 2019-02-21 Georgia Tech Research Corporation Methods for regenerating aged carbon molecular sieve membranes
US10799858B2 (en) 2018-03-09 2020-10-13 Uop Llc Process for managing sulfur compounds on catalyst

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1436622A (en) * 1973-06-21 1976-05-19 British Petroleum Co Regeneration of zeolite catalysts
GB1565313A (en) * 1977-05-04 1980-04-16 British Petroleum Co Activation of platinum group metal catalysts
FR2395069A1 (fr) * 1977-06-20 1979-01-19 Inst Francais Du Petrole Procede de recyclage des reactifs gazeux utilises pour la regeneration d'un catalyseur d'hydroconversion d'hydrocarbures
ES8606023A1 (es) * 1983-11-10 1986-04-16 Exxon Research Engineering Co Un procedimiento para reactivar un catalizador de zeolita tipo l que contiene coque
US4925819A (en) * 1983-11-10 1990-05-15 Exxon Research & Engineering Company Method of regenerating a deactivated catalyst
US4855269A (en) * 1986-12-19 1989-08-08 Chevron Research Company Process for regenerating a monofunctional large-pore zeolite catalyst having high selectivity for paraffin dehydrocyclization
US4914068A (en) * 1988-03-21 1990-04-03 Exxon Chemical Patents Inc. Process for the dispersion of Group VIII metals in large pore zeolite catalysts
US5256612A (en) * 1990-07-12 1993-10-26 Exxon Research And Engineering Company Method for treating a catalyst
US5106798A (en) * 1990-07-12 1992-04-21 Exxon Research And Engineering Company Method for regenerating a Group VIII noble metal deactivated catalyst

Also Published As

Publication number Publication date
JPH08501019A (ja) 1996-02-06
WO1994005418A1 (en) 1994-03-17
DE69307154T2 (de) 1997-04-30
DE69307154D1 (de) 1997-02-13
EP0671978B1 (en) 1997-01-02
EP0671978A1 (en) 1995-09-20
KR0136402B1 (ko) 1998-04-25
US5756414A (en) 1998-05-26
SG48224A1 (en) 1998-04-17
KR950702870A (ko) 1995-08-23
CA2143826C (en) 1999-04-20
CA2143826A1 (en) 1994-03-17
JP3553934B2 (ja) 2004-08-11

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