ES2076068B1 - PROCEDURE FOR PREPARING CATALYZERS BASED ON ZEOLITES TREATED WITH PHOSPHORIC ACID, USEFUL FOR APPLICATION IN CATALYTIC CRACHING UNITS. - Google Patents

PROCEDURE FOR PREPARING CATALYZERS BASED ON ZEOLITES TREATED WITH PHOSPHORIC ACID, USEFUL FOR APPLICATION IN CATALYTIC CRACHING UNITS.

Info

Publication number
ES2076068B1
ES2076068B1 ES9300560A ES9300560A ES2076068B1 ES 2076068 B1 ES2076068 B1 ES 2076068B1 ES 9300560 A ES9300560 A ES 9300560A ES 9300560 A ES9300560 A ES 9300560A ES 2076068 B1 ES2076068 B1 ES 2076068B1
Authority
ES
Spain
Prior art keywords
zeolite
preparing
procedure
useful
phosphoric acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES9300560A
Other languages
Spanish (es)
Other versions
ES2076068A1 (en
Inventor
Canos Avelino Corma
Maria Sol Casas
Triguero Joaquin Martinez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Universitat de Valencia
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Universitat de Valencia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior de Investigaciones Cientificas CSIC, Universidad Politecnica de Valencia, Universitat de Valencia filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Priority to ES9300560A priority Critical patent/ES2076068B1/en
Priority to PCT/ES1994/000028 priority patent/WO1994021378A1/en
Publication of ES2076068A1 publication Critical patent/ES2076068A1/en
Application granted granted Critical
Publication of ES2076068B1 publication Critical patent/ES2076068B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

PROCEDIMIENTO DE PREPARACION DE CATALIZADORES A BASE DE ZEOLITAS TRATADAS CON ACIDO FOSFORICO, UTILES PARA SU APLICACION EN UNIDADES DE CRAQUEO CATALITICO EN LA PRESENTE MEMORIA SE DESCRIBE UN PROCEDIMIENTO PARA PREPARAR UN CATALIZADOR QUE CONTIENE ZEOLITA, Y QUE MEJORA LA ACTIVIDAD Y SELECTIVIDAD A DESTILADOS MEDIOS, DISMINUYENDO LA PRODUCCION DE GAS SECO Y COQUE. EL CATALIZADOR SE PREPARA MODIFICANDO LA ZEOLITA CON UNA DISOLUCION ACUOSA DE ACIDO FOSFORICO. COMO ZEOLITA SE PREFIERE UNA USY ZEOLITA, QUE HA SIDO PARCIALMENTE DESALUMINIZADA POR UN TRATAMIENTO PREVIO DE CALCINACION-VAPOR, Y EN LA QUE EL TRATAMIENTO CON H3PO4 SE LLEVA A CABO EN SOLUCION ACUOSA CONTENIENDO ENTRE 0,5 Y 4 POR CIENTO EN PESO DE H3PO4 CON RESPECTO A LA ZEOLITA. LA ZEOLITA MODIFICADA SE COMBINA CON EL PRECURSOR DE LA MATRIZ Y SE ATOMIZA PARA DARLE LA FORMA Y EL TAMAÑO ADECUADO PARA SU USO EN UNIDADES DE FCC. EL CATALIZADOR ES UTIL PARA EL CRAQUEO DE GASOIL, ASI COMO DE ALIMENTACIONES MAS PESADAS.PROCEDURE FOR PREPARING CATALYZERS BASED ON ZEOLITES TREATED WITH PHOSPHORIC ACID, USEFUL FOR APPLICATION IN CATALYTIC CRAGING UNITS, A PROCEDURE FOR PREPARING A CATALYTIC CONTAINING ZEOLITE IS DESCRIBED IN THIS PRESENT MEMBERSHIP. DECREASING THE PRODUCTION OF DRY GAS AND COKE. THE CATALYST IS PREPARED BY MODIFYING THE ZEOLITE WITH AN AQUEOUS SOLUTION OF PHOSPHORIC ACID. AS A ZEOLITE, A USY ZEOLITE IS PREFERRED, WHICH HAS BEEN PARTIALLY DEALUMINIZED BY A PREVIOUS CALCINATION-STEAM TREATMENT, AND IN WHICH THE H3PO4 TREATMENT IS CARRIED OUT IN AN AQUEOUS SOLUTION CONTAINING BETWEEN 0.5 AND 4 PERCENT IN WEIGHT OF H4 WITH REGARD TO THE ZEOLITE. THE MODIFIED ZEOLITE COMBINES WITH THE MATRIX PRECURSOR AND IS ATOMIZED TO GIVE IT THE RIGHT SIZE AND SHAPE FOR USE IN FCC UNITS. THE CATALYST IS USEFUL FOR GASOIL CRAYING, AS WELL AS FOR HEAVIER FEEDING.

ES9300560A 1993-03-17 1993-03-17 PROCEDURE FOR PREPARING CATALYZERS BASED ON ZEOLITES TREATED WITH PHOSPHORIC ACID, USEFUL FOR APPLICATION IN CATALYTIC CRACHING UNITS. Expired - Lifetime ES2076068B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
ES9300560A ES2076068B1 (en) 1993-03-17 1993-03-17 PROCEDURE FOR PREPARING CATALYZERS BASED ON ZEOLITES TREATED WITH PHOSPHORIC ACID, USEFUL FOR APPLICATION IN CATALYTIC CRACHING UNITS.
PCT/ES1994/000028 WO1994021378A1 (en) 1993-03-17 1994-03-17 Process for the preparation of catalysts based on zeolites treated with phosphoric acid, useful for catalytic cracking units

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES9300560A ES2076068B1 (en) 1993-03-17 1993-03-17 PROCEDURE FOR PREPARING CATALYZERS BASED ON ZEOLITES TREATED WITH PHOSPHORIC ACID, USEFUL FOR APPLICATION IN CATALYTIC CRACHING UNITS.

Publications (2)

Publication Number Publication Date
ES2076068A1 ES2076068A1 (en) 1995-10-16
ES2076068B1 true ES2076068B1 (en) 1996-06-16

Family

ID=8281163

Family Applications (1)

Application Number Title Priority Date Filing Date
ES9300560A Expired - Lifetime ES2076068B1 (en) 1993-03-17 1993-03-17 PROCEDURE FOR PREPARING CATALYZERS BASED ON ZEOLITES TREATED WITH PHOSPHORIC ACID, USEFUL FOR APPLICATION IN CATALYTIC CRACHING UNITS.

Country Status (2)

Country Link
ES (1) ES2076068B1 (en)
WO (1) WO1994021378A1 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5470810A (en) * 1994-02-02 1995-11-28 Mobil Oil Corporation Catalyst and method of manufacture
EP1797951A1 (en) * 2005-12-15 2007-06-20 Total Petrochemicals Research Feluy Catalytic cracking catalyst additive
CN100425534C (en) * 2005-05-31 2008-10-15 中国石油化工股份有限公司 Modified beta zeolite
EP1931468B1 (en) * 2005-10-07 2018-04-18 SK Innovation Co., Ltd. Hydrothermally stable microporous molecular sieve catalyst and preparation method thereof
CN100406416C (en) * 2006-07-03 2008-07-30 中国石油化工集团公司 Method of preparing ethylene and propylene and catalyst used in said method
WO2011090124A1 (en) 2010-01-20 2011-07-28 Ｊｘ日鉱日石エネルギー株式会社 Catalyst for production of hydrocarbons and process for production of hydrocarbons
CN104556122B (en) * 2013-10-23 2017-05-17 中国石油化工股份有限公司 Molecular sieve supported nanocrystal Y-type molecular sieve and synthesis method thereof
US9895680B2 (en) 2013-12-19 2018-02-20 Basf Corporation FCC catalyst compositions containing boron oxide
US20150174559A1 (en) 2013-12-19 2015-06-25 Basf Corporation Phosphorus-Modified FCC Catalysts
US9796932B2 (en) 2013-12-19 2017-10-24 Basf Corporation FCC catalyst compositions containing boron oxide and phosphorus
US9441167B2 (en) 2013-12-19 2016-09-13 Basf Corporation Boron oxide in FCC processes

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ178543A (en) * 1974-09-23 1978-04-03 Mobil Oil Corp Conversion catalyst, crystalline alumin osilicate zeolite containing phosphorus
US4454241A (en) * 1982-05-24 1984-06-12 Exxon Research And Engineering Co. Phosphorus-containing catalyst
CA1297861C (en) * 1986-07-11 1992-03-24 William L. Schuette Hydrocarbon cracking catalysts and processes utilizing the same
CA2015335A1 (en) * 1989-05-12 1990-11-12 Terry G. Roberie Catalytic compositions

Also Published As

Publication number Publication date
ES2076068A1 (en) 1995-10-16
WO1994021378A1 (en) 1994-09-29

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Legal Events

Date Code Title Description
FA2A Application withdrawn

Effective date: 19970218