ES2075132T3 - USE OF METAL-PORPHYRINS AS BLEACHING CATALYSTS. - Google Patents

USE OF METAL-PORPHYRINS AS BLEACHING CATALYSTS.

Info

Publication number
ES2075132T3
ES2075132T3 ES90200228T ES90200228T ES2075132T3 ES 2075132 T3 ES2075132 T3 ES 2075132T3 ES 90200228 T ES90200228 T ES 90200228T ES 90200228 T ES90200228 T ES 90200228T ES 2075132 T3 ES2075132 T3 ES 2075132T3
Authority
ES
Spain
Prior art keywords
metal
porphyrins
bleaching catalysts
iii
bleaching
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90200228T
Other languages
Spanish (es)
Inventor
Marion Frances Gregory
Jean Hypolites Koek
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever NV
Original Assignee
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26294997&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2075132(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from GB898904062A external-priority patent/GB8904062D0/en
Priority claimed from GB898905993A external-priority patent/GB8905993D0/en
Application filed by Unilever NV filed Critical Unilever NV
Application granted granted Critical
Publication of ES2075132T3 publication Critical patent/ES2075132T3/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3932—Inorganic compounds or complexes

Abstract

SE REVELA LAS METALO-PORFIRINAS CON UNA MEJORADA ESTABILIDAD FRENTE A LA OXIDACION, PARA USARLAS COMO CATALIZADORAS BLANQUEADORES PERACIDAS EN EL BLANQUEAMIENTO DE TEJIDOS. LAS METALO-PORFIRINAS SON PROFIRINAS MN(III) O FE(III) CON AR SUSTITUYENTES EN LA POSICION MESO, ELEGIDAS ENTRE: (FORMULAS A, B Y C); DONDE N Y M PUEDEN SER 0 O 1, A PUEDE SER UN GRUPO SULFATO, FOSFATO O CARBOXILATO: B ES UN ALQUIL C1-C10, POLIETOXIALQUIL O HIDROXIALQUIL Y X1 Y X2 SON CL, BR, CH3, C2H5 O CH3O.METAL-PORPHYRINES WITH AN IMPROVED STABILITY AGAINST OXIDATION ARE REVEALED FOR USE AS PERCIDENT BLEACHING CATALYZERS IN TISSUE WHITENING. THE METAL-PORPHYRINS ARE PROFIRINES MN (III) OR FAITH (III) WITH AR SUBSTITUTES IN THE MESO POSITION, CHOSEN BETWEEN: (FORMULAS A, B AND C); WHERE N AND M MAY BE 0 OR 1, A MAY BE A GROUP OF SULPHATE, PHOSPHATE OR CARBOXYLATE: B IS A C1-C10 ALKYL, POLYETOXIALKYL OR HYDROXIALKYL AND X1 AND X2 ARE CL, BR, CH3, C2H5 OR CH3O.

ES90200228T 1989-02-22 1990-01-31 USE OF METAL-PORPHYRINS AS BLEACHING CATALYSTS. Expired - Lifetime ES2075132T3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB898904062A GB8904062D0 (en) 1989-02-22 1989-02-22 Metall-porphyrins for use as bleach catalyst
GB898905993A GB8905993D0 (en) 1989-03-15 1989-03-15 Metallo-porphyrins for use as bleach catalyst

Publications (1)

Publication Number Publication Date
ES2075132T3 true ES2075132T3 (en) 1995-10-01

Family

ID=26294997

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90200228T Expired - Lifetime ES2075132T3 (en) 1989-02-22 1990-01-31 USE OF METAL-PORPHYRINS AS BLEACHING CATALYSTS.

Country Status (8)

Country Link
EP (1) EP0384503B1 (en)
JP (1) JPH02261547A (en)
AU (1) AU612538B2 (en)
BR (1) BR9000786A (en)
CA (1) CA2010271A1 (en)
DE (1) DE69020380T2 (en)
ES (1) ES2075132T3 (en)
NO (1) NO900787L (en)

Families Citing this family (52)

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Publication number Priority date Publication date Assignee Title
ES2114536T3 (en) * 1991-10-14 1998-06-01 Procter & Gamble DETERGENT COMPOSITIONS THAT INHIBIT THE TRANSFER OF DYES IN THE WASH.
TR26870A (en) * 1991-10-14 1994-08-22 Procter & Gamble Detergent compositions to prevent dye transfer during washing
EP0553607B1 (en) * 1992-01-31 1998-03-18 The Procter & Gamble Company Detergent compositions inhibiting dye transfer in washing
US5445651A (en) * 1992-01-31 1995-08-29 The Procter & Gamble Company Detergent compositions inhibiting dye transfer in washing
EP0553608B1 (en) * 1992-01-31 1998-06-17 The Procter & Gamble Company Detergent compositions inhibiting dye transfer in washing
EP0596184B1 (en) * 1992-11-06 1998-04-15 The Procter & Gamble Company Detergent compositions inhibiting dye transfer
US5599924A (en) * 1992-08-14 1997-02-04 Trustees Of The University Of Pennsylvania Electron-deficient porphyrins and processes and intermediates for preparing same
US5371199B1 (en) * 1992-08-14 1995-12-26 Univ Pennsylvania Substituted porphyrins porphyrin-containing polymers and synthetic methods therefor
US5493017A (en) * 1992-08-14 1996-02-20 The Trustees Of The University Of Pennsylvania Ring-metalated porphyrins
US5817830A (en) * 1992-08-14 1998-10-06 Trustees Of The University Of Pennsylvania Pyrrolic compounds
EP0596187A1 (en) * 1992-11-06 1994-05-11 The Procter & Gamble Company Detergent compositions inhibiting dye transfer in washing
EP0596186A1 (en) * 1992-11-06 1994-05-11 The Procter & Gamble Company Detergent compositions inhibiting dye transfer in washing
US5288746A (en) * 1992-12-21 1994-02-22 The Procter & Gamble Company Liquid laundry detergents containing stabilized glucose/glucose oxidase as H2 O2 generation system
EP0693116B1 (en) * 1993-04-08 1998-01-07 The Procter & Gamble Company Composition and process for inhibiting dye transfer
EP0692947A4 (en) * 1993-04-09 1996-03-13 Procter & Gamble Machine dishwashing method employing a metallo catalyst and enzymatic source of hydrogen peroxide
EP0622447A1 (en) * 1993-04-26 1994-11-02 The Procter & Gamble Company Enzymatic detergent compositions inhibiting dye transfer
ATE170553T1 (en) * 1994-04-07 1998-09-15 Procter & Gamble BLEACH CONTAINING METAL BLEACH CATALYSTS AND ANTIOXIDANTS
US5686014A (en) * 1994-04-07 1997-11-11 The Procter & Gamble Company Bleach compositions comprising manganese-containing bleach catalysts
US5908821A (en) * 1994-05-11 1999-06-01 Procter & Gamble Company Dye transfer inhibiting compositions with specifically selected metallo catalysts
GB2294268A (en) 1994-07-07 1996-04-24 Procter & Gamble Bleaching composition for dishwasher use
US5578136A (en) 1994-08-31 1996-11-26 The Procter & Gamble Company Automatic dishwashing compositions comprising quaternary substituted bleach activators
DE69608541T2 (en) * 1995-02-02 2001-01-18 Procter & Gamble MACHINE DISHWASHER COMPOSITIONS WITH COBALT CHELATE CATALYSTS
US5968881A (en) * 1995-02-02 1999-10-19 The Procter & Gamble Company Phosphate built automatic dishwashing compositions comprising catalysts
ES2163006T3 (en) * 1995-02-02 2002-01-16 Procter & Gamble METHOD FOR ELIMINATING TE STAINS IN AUTOMATIC DISHWASHERS USING COMPOSITIONS THAT INCLUDE COBALT CATALYSTS (III).
BR9609384A (en) * 1995-06-16 1999-05-18 Procter & Gamble Bleaching compositions comprising cobalt catalysts
DE69613842T2 (en) * 1995-06-16 2002-04-04 Procter & Gamble MACHINE DISHWASHER CONTAINING COBALT CATALYSTS
US5703034A (en) * 1995-10-30 1997-12-30 The Procter & Gamble Company Bleach catalyst particles
EP0778342A1 (en) 1995-12-06 1997-06-11 The Procter & Gamble Company Detergent compositions
DE19620267A1 (en) * 1996-05-20 1997-11-27 Henkel Kgaa Catalytically active activator complexes with N¶4¶ ligands for peroxygen compounds
AU6857996A (en) * 1996-08-26 1998-03-19 Procter & Gamble Company, The Cellulase activity control by a terminator
DE19721886A1 (en) 1997-05-26 1998-12-03 Henkel Kgaa Bleaching system
CN1283968A (en) 1997-11-21 2001-02-14 宝洁公司 Product applicator
GB9725614D0 (en) 1997-12-03 1998-02-04 United States Borax Inc Bleaching compositions
GB0114155D0 (en) * 2001-06-11 2001-08-01 Unilever Plc Complex for catalytically bleaching a substrate
DE10163331A1 (en) 2001-12-21 2003-07-10 Henkel Kgaa Support-fixed bleach catalyst complex compounds are suitable as catalysts for peroxygen compounds
EP1590426B1 (en) 2003-02-03 2014-01-08 Unilever PLC Laundry cleansing and conditioning compositions
US20070138674A1 (en) 2005-12-15 2007-06-21 Theodore James Anastasiou Encapsulated active material with reduced formaldehyde potential
JP5401034B2 (en) 2007-12-19 2014-01-29 ライオン株式会社 Bleaching aid and bleaching aid particles containing the bleaching aid
CN101922111B (en) * 2010-09-14 2012-05-09 东华大学 Low-temperature activating and bleaching method by using water-soluble metalloporphyrin
GB2498265B (en) 2012-01-04 2015-04-08 Procter & Gamble Fibrous structures comprising particles and methods for making same
EP3075832B1 (en) 2015-03-30 2021-04-14 Dalli-Werke GmbH & Co. KG Manganese-amino acid compounds in cleaning compositions
JP6790257B2 (en) 2016-11-01 2020-11-25 ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ Leuco colorants as bluish agents in laundry care compositions, their packaging, kits and methods
US20180119057A1 (en) 2016-11-01 2018-05-03 The Procter & Gamble Company Methods of using leuco colorants as bluing agents in laundry care compositions
US11697905B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles that exhibit consumer acceptable article in-use properties
US11697906B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles and product-shipping assemblies for containing the same
US11697904B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles that exhibit consumer acceptable article in-use properties
GB2572720B (en) 2017-01-27 2022-06-22 Procter & Gamble Active agent-containing articles that exhibit consumer acceptable article in-use properties
EP3444328A1 (en) 2017-08-18 2019-02-20 The Procter & Gamble Company Cleaning agent
US20200190433A1 (en) 2018-12-14 2020-06-18 The Procter & Gamble Company Foaming Fibrous Structures Comprising Particles and Methods for Making Same
US11485934B2 (en) 2019-08-02 2022-11-01 The Procter & Gamble Company Foaming compositions for producing a stable foam and methods for making same
US20210148044A1 (en) 2019-11-15 2021-05-20 The Procter & Gamble Company Graphic-Containing Soluble Articles and Methods for Making Same
US20220403558A1 (en) 2021-05-28 2022-12-22 The Procter & Gamble Company Natural polymer-based fibrous elements comprising a surfactant and methods for making same

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1541576A (en) * 1975-06-20 1979-03-07 Procter & Gamble Ltd Inhibiting dye ltransfer in washing
US4892941A (en) * 1987-04-17 1990-01-09 Dolphin David H Porphyrins
WO1988007988A1 (en) * 1987-04-17 1988-10-20 Dolphin David H Porphyrins, their syntheses and uses thereof
GB8720863D0 (en) * 1987-09-04 1987-10-14 Unilever Plc Metalloporphyrins

Also Published As

Publication number Publication date
JPH02261547A (en) 1990-10-24
AU4992790A (en) 1990-08-30
EP0384503B1 (en) 1995-06-28
AU612538B2 (en) 1991-07-11
NO900787D0 (en) 1990-02-19
BR9000786A (en) 1991-01-22
CA2010271A1 (en) 1990-08-22
DE69020380T2 (en) 1995-12-07
EP0384503A1 (en) 1990-08-29
NO900787L (en) 1990-08-23
DE69020380D1 (en) 1995-08-03

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