ES2073132T3 - ANTISEPTIC GRAFT POLYMERIC MATERIAL WHICH HAS GRAFT COMPLEXED BY METAL IONS AND PREPARATION PROCEDURE. - Google Patents

ANTISEPTIC GRAFT POLYMERIC MATERIAL WHICH HAS GRAFT COMPLEXED BY METAL IONS AND PREPARATION PROCEDURE.

Info

Publication number
ES2073132T3
ES2073132T3 ES91400193T ES91400193T ES2073132T3 ES 2073132 T3 ES2073132 T3 ES 2073132T3 ES 91400193 T ES91400193 T ES 91400193T ES 91400193 T ES91400193 T ES 91400193T ES 2073132 T3 ES2073132 T3 ES 2073132T3
Authority
ES
Spain
Prior art keywords
graft
antiseptic
complexed
polymeric material
metal ions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91400193T
Other languages
Spanish (es)
Inventor
Roger Chatelin
Louis Gavet
Michel Bourgeois
Christine Darroux
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Institut Textile de France
Original Assignee
Institut Textile de France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institut Textile de France filed Critical Institut Textile de France
Application granted granted Critical
Publication of ES2073132T3 publication Critical patent/ES2073132T3/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
    • C08F251/02—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof on to cellulose or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/02—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin
    • D06M14/04—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
    • D06M14/20—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin
    • D06M14/22—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
    • D06M14/26—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of synthetic origin
    • D06M14/28—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of synthetic origin of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
    • D06M14/26—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of synthetic origin
    • D06M14/30—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of synthetic origin of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M14/34—Polyamides

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Toxicology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Biochemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

SEGUN LA INVENCION, EL MATERIAL, EN PARTICULAR TEXTIL, COMPRENDE EN SU ESTRUCTURA POLIMERICA INJERTOS QUE FORMAN COMPLEJOS CON AL MENOS UN ION METALICO QUE TIENE UNA ACTIVIDAD ANTISEPTICA RECONOCIDA. ESTOS INJERTOS ESTAN FORMADOS POR POLIMERIZACION DE MONOMEROS NO SATURADOS DE FUNCION ACOMPLEJANTE, ENTRE LOS QUE ESTA EL FOSFATO DE METACRILATO DE ETILENO GLICOL O UN DERIVADO POLIMERIZABLE DE LA QUINOLEINA COMO ES LA ACRIL HIDROXI 8 QUINOLEINA. EL PROCESO DE PREPARACION COMPRENDE UNA PRIMERA ETAPA DE INJERTO, POR EJEMPLO POR IRRADIACION ELECTRONICA DEL MATERIAL E IMPREGNACION DEL BAÑO DE MONOMEROS, Y UNA SEGUNDA ETAPA DE IMPREGNACION DEL MATERIAL INJERTADO POR UNO O VARIOS BAÑOS QUE CONTIENEN EL O LOS IONES METALICOS, COMO EL COBRE, EL ZINC, EL ESTAÑO, EL MERCURIO.ACCORDING TO THE INVENTION, THE MATERIAL, IN PARTICULAR TEXTILE, INCLUDES IN ITS POLYMERIC STRUCTURE GRAPES THAT FORM COMPLEXES WITH AT LEAST ONE METAL ION THAT HAS A RECOGNIZED ANTISEPTIC ACTIVITY. THESE GRAFTS ARE FORMED BY POLYMERIZATION OF NON-SATURATED MONOMERS OF COMPLEXING FUNCTION, AMONG WHICH IS ETHYLENE GLYCOL METHACRYLATE PHOSPHATE OR A POLYMERIZABLE DERIVATIVE OF QUINOLEIN, AS IS ACRYL HYDROXY 8 CHINOLEIN. THE PREPARATION PROCESS INCLUDES A FIRST STAGE OF GRAFTING, FOR EXAMPLE BY ELECTRONIC IRRADIATION OF THE MATERIAL AND IMPREGNATION OF THE BATHROOM OF MONOMERES, AND A SECOND STAGE OF IMPREGNATION OF THE MATERIAL GRAFTED BY ONE OR MULTIPLE BATHS THAT CONTAIN CONTAIN OR , THE ZINC, THE TIN, THE MERCURY.

ES91400193T 1990-02-05 1991-01-29 ANTISEPTIC GRAFT POLYMERIC MATERIAL WHICH HAS GRAFT COMPLEXED BY METAL IONS AND PREPARATION PROCEDURE. Expired - Lifetime ES2073132T3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9001621A FR2657895A1 (en) 1990-02-05 1990-02-05 ANTISEPTIC MATERIAL WITH METALLIC ION COMPLEX GRAFT AND PROCESS FOR PREPARING THE SAME.

Publications (1)

Publication Number Publication Date
ES2073132T3 true ES2073132T3 (en) 1995-08-01

Family

ID=9393608

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91400193T Expired - Lifetime ES2073132T3 (en) 1990-02-05 1991-01-29 ANTISEPTIC GRAFT POLYMERIC MATERIAL WHICH HAS GRAFT COMPLEXED BY METAL IONS AND PREPARATION PROCEDURE.

Country Status (7)

Country Link
US (1) US5194454A (en)
EP (1) EP0446082B1 (en)
JP (1) JP2833245B2 (en)
DE (1) DE69108428T2 (en)
DK (1) DK0446082T3 (en)
ES (1) ES2073132T3 (en)
FR (1) FR2657895A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6039964A (en) * 1997-04-11 2000-03-21 Omni Manufacturing, Inc. Germicidally protected conveyor components
RU2618738C2 (en) * 2011-07-26 2017-05-11 Киото Прифекчурал Паблик Юниверсити Корпорэйшн Inhibitory fiber with anti-virulence factor and its manufacturing method
CN112227064A (en) * 2020-10-28 2021-01-15 上海威露美生物科技有限公司 Aldehyde nucleophilic addition complexing antibacterial fiber, preparation method and application
FR3136674A1 (en) 2022-06-17 2023-12-22 Ouvry Radiological decontamination wipe.

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA910233A (en) * 1972-09-19 Y. Kabanov Vitaly Method of modifying polymeric materials wood and articles made therefrom by radiation-initiated graft copolymerization thereof
CA641174A (en) * 1962-05-15 E.I. Du Pont De Nemours And Company Modification of shaped polymeric structures by irradiation
US2998329A (en) * 1957-08-05 1961-08-29 Dow Chemical Co Modification of cellulosic articles
US3297525A (en) * 1962-10-19 1967-01-10 Merck & Co Inc Fungicidal compositions comprising salicylates of 8 hydroxy quinoline carboxylic esters
BE681379A (en) * 1966-05-20 1966-10-31
FR1499358A (en) * 1966-09-12 1967-10-27 Mo Tekstilny I Process for obtaining antimicrobial fibrous materials
US4001150A (en) * 1970-11-25 1977-01-04 Kansai Paint Company, Ltd. Composition for preparing electroconductive resin comprising an unsaturated polyester and phosphoric or sulfonic unsaturated ester
US3814703A (en) * 1971-05-31 1974-06-04 Kansai Paint Co Ltd Composition for forming an electrically conductive resin film
US4179401A (en) * 1971-07-08 1979-12-18 Garnett John L Preparation of heterogeneous catalysts including the steps of radiation grafting of an alpha unsaturated monomer to a metal or to an organic polymer
US3814676A (en) * 1971-10-07 1974-06-04 Stevens & Co Inc J P Radiation process of preparing grafted elastomeric fibers wherein post-decrystallization is employed
US3872128A (en) * 1972-03-08 1975-03-18 Union Carbide Corp Antimicrobial hydroxy quinoline, ethylene-acrylic polymer compositions
US4072640A (en) * 1976-01-29 1978-02-07 Instituto Venezolano De Investigaciones Cientificas Copolymerization of vinyl monomers with cellulose and starch in copper ammonium solutions
SU608813A1 (en) * 1977-01-11 1978-05-30 Московский Ордена Ленина И Ордена Трудового Красного Знамени Государственный Университет Имени М.В.Лононосова Method of obtaining graft copolymers
DE2905531A1 (en) * 1979-02-14 1981-01-08 Boehringer Mannheim Gmbh DIAGNOSTIC AGENT FOR DETECTING LEUCOCYTES IN BODY LIQUIDS
US4340057A (en) * 1980-12-24 1982-07-20 S. C. Johnson & Son, Inc. Radiation induced graft polymerization
DD207740A1 (en) * 1982-06-07 1984-03-14 Bitterfeld Chemie METHOD FOR THE MICROBICIDAL EQUIPMENT OF CELLULOSIC TEXTILE FIBERS AND FABRIC FIBERS
DE3248505A1 (en) * 1982-12-29 1984-07-05 Bayer Ag, 5090 Leverkusen 1-CYCLOPROPYL-6-FLUOR-1,4-DIHYDRO-4-OXO-7 (4- (OXOALKYL) -1-PIPERAZINYL / -3-QUINOLINE CARBONIC ACIDS AND THEIR DERIVATIVES, METHOD FOR THE PRODUCTION THEREOF, AND THEIR CONTAINERS
DE3318145A1 (en) * 1983-05-18 1984-11-22 Bayer Ag, 5090 Leverkusen 7-AMINO-1-CYCLOPROPYL-6,8-DIFLUOR-1,4-DIHYDRO-4-OXO-3-CHINOLINE CARBONIC ACIDS, METHOD FOR THE PRODUCTION THEREOF AND THEIR CONTAINING ANTIBACTERIAL AGENTS

Also Published As

Publication number Publication date
DE69108428T2 (en) 1995-09-07
FR2657895B1 (en) 1994-04-22
JPH073651A (en) 1995-01-06
DK0446082T3 (en) 1995-05-01
US5194454A (en) 1993-03-16
JP2833245B2 (en) 1998-12-09
EP0446082A1 (en) 1991-09-11
EP0446082B1 (en) 1995-03-29
FR2657895A1 (en) 1991-08-09
DE69108428D1 (en) 1995-05-04

Similar Documents

Publication Publication Date Title
ES2059411T5 (en) BIFUNCTIONAL CHELATING AGENTS.
GB1465884A (en) Process for radiation grafting hydrogels onto organic polymeric substrates
ES468124A1 (en) Process for bleaching textiles
ES8207440A1 (en) Process for preparing ethylcellulose microcapsules.
ES2053534T3 (en) A COPOLYMERIC COMPOSITION.
AR005287A1 (en) DETERGENT COMPOSITIONS INCLUDING IMMOBILIZED ENZYMES.
FR2423500A1 (en) POLYMER SEQUENCES AND THEIR MANUFACTURING PROCESS
ATE174538T1 (en) HYDROPHILIC FILMS BY PLASMA POLYMERIZATION
ATE221905T1 (en) STRUCTURED COPOLYMERS AS METAL ION SUPPORTS
GB1304153A (en)
EP0653491A4 (en) Process for introducing foreign dna into cell.
ES2108706T3 (en) COMPOSITIONS OF FLUORESCENT BLEACHES OF PAIRS OF SURFACE IONS.
ES2073132T3 (en) ANTISEPTIC GRAFT POLYMERIC MATERIAL WHICH HAS GRAFT COMPLEXED BY METAL IONS AND PREPARATION PROCEDURE.
NL1002246A1 (en) Laser gun irradiated by electron gun.
IT1184428B (en) HYDROGEN ABSORBENT COMPOSITION FOR CABLES AND ELECTRIC CABLES, FIBER OPTIC CABLES AND THEIR INCORPORATING COMPONENTS SAID COMPOSITION
DE60010072D1 (en) STEREO COMPLEX HYDROGELS
GB1557226A (en) Corpuscular beam microscopes
ES352529A1 (en) Grafted copolymers
ES2151121T3 (en) COMPLEXES, FORMED BY HEAVY METAL IONS AND BY A POLYMER, AS WELL AS THEIR USE FOR THE SELECTIVE DISPOSAL OF LIQUID COMPOUNDS.
ATE236216T1 (en) ACRYLIC POLYMER THAT CAN BE STERILIZED WITH GAMMA RADIATION
BR8405886A (en) PROCESS AND COMPOSITIONS RELATING TO THE ACTIVATION OF FLUORESCENT WHITENING AGENTS
GB1413410A (en) Process for the polymerisation of allyl amines
NL166576C (en) DEFLECTOR FOR THE ELECTRON BEAM IN AN ELECTRON MICROSCOPE.
ES2033621T1 (en) A METHOD FOR DISINFECTING AND CLEANING CONTACT LENSES.
SE7907850L (en) PROCEDURE FOR COMPLETE WHITE CELLULOSA

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 446082

Country of ref document: ES