ES2070736A1 - Stable, free-flowing granulate of alkaline cleaning additive - contg. (meth)acrylic] acid (co)polymer, sodium silicate, sodium carbonate or sodium sulphate, sequestering agent and water - Google Patents

Stable, free-flowing granulate of alkaline cleaning additive - contg. (meth)acrylic] acid (co)polymer, sodium silicate, sodium carbonate or sodium sulphate, sequestering agent and water

Info

Publication number
ES2070736A1
ES2070736A1 ES09300825A ES9300825A ES2070736A1 ES 2070736 A1 ES2070736 A1 ES 2070736A1 ES 09300825 A ES09300825 A ES 09300825A ES 9300825 A ES9300825 A ES 9300825A ES 2070736 A1 ES2070736 A1 ES 2070736A1
Authority
ES
Spain
Prior art keywords
sodium
free
meth
polymer
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES09300825A
Other languages
Spanish (es)
Other versions
ES2070736B1 (en
Inventor
Lothar Pioch
Wolfgang Seiter
Hans-Friedrich Kruse
Jochen Jacobs
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of ES2070736A1 publication Critical patent/ES2070736A1/en
Application granted granted Critical
Publication of ES2070736B1 publication Critical patent/ES2070736B1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
    • C11D11/02—Preparation in the form of powder by spray drying
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C11D17/065—High-density particulate detergent compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/361—Phosphonates, phosphinates or phosphonites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/364—Organic compounds containing phosphorus containing nitrogen

Abstract

A granular, alkaline cleaning additive, free from phosphate, contains (a) 20-40 wt.% of the Na salt of a (meth)acrylic acid (co)polymer, (b) 8-25% of Na silicate with Na20:Si02 = 1:1-3.4, (c) 15-50% of Na2CO3 and/or Na2SO4 (calc. as anhydrous), 0-15% of aminopolycarboxylate and/or polyphosphonate sequestering agent, and (e) 5-15% of water. The amts. are (a) 23-35 wt.%, (b) 12-20%, (c) 18-45%, pref. of Na2CO3, (d) 0-12% and (e) 8-12%. The average grain size is 0.2-1.2 mm, with not more than 2 wt.% of grains of below 0.1 mm, and not more than 20% above 2 mm. Esp., at least 80% (at least 90%) of the grains are 0.2-1.6 mm, with not more than 3% (not more than 1%) of 0.1-0.05 mm, and not more than 20% (not more than 10%) of 1.6-2.4 mm. USE/ADVANTAGE - The mixt. is used as component in washing, cleaning and watersoftening agents (claimed). Appln. is esp. in dishwaster rinses. The granulate is free-flowing, and is stable even in a moist atmos.
ES9300825A 1992-04-21 1993-04-20 CLEANING ADDITIVE ALKALINE PHOSPHATE FREE, GRANULAR. Expired - Fee Related ES2070736B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19924213036 DE4213036A1 (en) 1992-04-21 1992-04-21 Stable, free-flowing granulate of alkaline cleaning additive - contg. (meth)acrylic] acid (co)polymer, sodium silicate, sodium carbonate or sodium sulphate, sequestering agent and water

Publications (2)

Publication Number Publication Date
ES2070736A1 true ES2070736A1 (en) 1995-06-01
ES2070736B1 ES2070736B1 (en) 1996-02-16

Family

ID=6457117

Family Applications (1)

Application Number Title Priority Date Filing Date
ES9300825A Expired - Fee Related ES2070736B1 (en) 1992-04-21 1993-04-20 CLEANING ADDITIVE ALKALINE PHOSPHATE FREE, GRANULAR.

Country Status (2)

Country Link
DE (1) DE4213036A1 (en)
ES (1) ES2070736B1 (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0726932A1 (en) * 1993-11-01 1996-08-21 The Procter & Gamble Company Spray drying process for making a low or nil phosphate automatic dishwashing detergent composition
EP0678572A1 (en) * 1994-04-20 1995-10-25 The Procter & Gamble Company Detergent powder compositions
FR2726002B1 (en) * 1994-10-21 1997-01-17 Rhone Poulenc Chimie BUILDER COMPOSITION WITHOUT ZEOLITHS OR PHOSTATES COMPRISING A SYSTEM REDUCING CALCIUM INCRUST, USE THEREOF IN DETERGENT COMPOSITIONS AND DETERGENT COMPOSITIONS
EP0791095A4 (en) * 1994-11-10 1997-10-15 Procter & Gamble Method of cleaning carpets
FR2732355B1 (en) * 1995-03-29 1997-04-30 Rhone Poulenc Chimie COMPACT DETERGENT POWDER FORMULA FOR LAUNDRY WASHING
GB2318584A (en) * 1996-10-25 1998-04-29 Procter & Gamble Process for preparing detergent compositions by spray drying
DE19651072A1 (en) * 1996-12-09 1998-06-10 Henkel Kgaa Additive for detergents or cleaning agents
EP1228185A1 (en) * 1999-08-10 2002-08-07 The Procter & Gamble Company Non-aqueous liquid detergents with water-soluble low-density particles
US6770615B1 (en) 1999-08-10 2004-08-03 The Procter & Gamble Company Non-aqueous liquid detergents with water-soluble low-density particles
US6492320B2 (en) * 1999-09-24 2002-12-10 Rohm And Hass Company Multifunctional, granulated pellet aid and process
GB0111043D0 (en) * 2001-05-08 2001-06-27 Ineos Silicas Ltd Granular compositions
WO2004055150A1 (en) * 2002-12-18 2004-07-01 Henkel Kommanditgesellschaft Auf Aktien Fine particulate agent
US7459422B2 (en) 2004-08-11 2008-12-02 The Procter & Gamble Company Process for making a granular detergent composition having improved solubility
GB201214558D0 (en) 2012-08-15 2012-09-26 Reckitt Benckiser Nv Detergent granule
US11441107B2 (en) 2018-06-26 2022-09-13 Ecolab Usa Inc. Powder and solid alkaline cleaning compositions and use thereof for removing greasy soils
WO2024088878A1 (en) * 2022-10-24 2024-05-02 Unilever Ip Holdings B.V. Spray-dried laundry particle

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0432437A1 (en) * 1989-11-10 1991-06-19 Henkel Kommanditgesellschaft auf Aktien Granular, alkaline and phosphate-free detergent additive
EP0445852A1 (en) * 1990-02-05 1991-09-11 Sara Lee/DE N.V. Detergent composition
WO1991015568A1 (en) * 1990-04-02 1991-10-17 Henkel Kommanditgesellschaft Auf Aktien Stable, bifunctional, phosphate-free detergent tablets for use in dishwashing machines

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0432437A1 (en) * 1989-11-10 1991-06-19 Henkel Kommanditgesellschaft auf Aktien Granular, alkaline and phosphate-free detergent additive
EP0445852A1 (en) * 1990-02-05 1991-09-11 Sara Lee/DE N.V. Detergent composition
WO1991015568A1 (en) * 1990-04-02 1991-10-17 Henkel Kommanditgesellschaft Auf Aktien Stable, bifunctional, phosphate-free detergent tablets for use in dishwashing machines

Also Published As

Publication number Publication date
DE4213036A1 (en) 1993-10-28
ES2070736B1 (en) 1996-02-16

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 20041102