ES2033514T3 - PROCEDURE FOR STEREO-SPECIFIC POLYMERIZATION OF ALPHA-OLEFINS AND CATALYTIC SYSTEM USABLE FOR SUCH POLYMERIZATION. - Google Patents

PROCEDURE FOR STEREO-SPECIFIC POLYMERIZATION OF ALPHA-OLEFINS AND CATALYTIC SYSTEM USABLE FOR SUCH POLYMERIZATION.

Info

Publication number
ES2033514T3
ES2033514T3 ES198989200469T ES89200469T ES2033514T3 ES 2033514 T3 ES2033514 T3 ES 2033514T3 ES 198989200469 T ES198989200469 T ES 198989200469T ES 89200469 T ES89200469 T ES 89200469T ES 2033514 T3 ES2033514 T3 ES 2033514T3
Authority
ES
Spain
Prior art keywords
polymerization
olefins
alpha
compound
stereo
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES198989200469T
Other languages
Spanish (es)
Inventor
Paul Fiasse
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay SA
Original Assignee
Solvay SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay SA filed Critical Solvay SA
Application granted granted Critical
Publication of ES2033514T3 publication Critical patent/ES2033514T3/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Process for the polymerisation of alpha-olefins, carried out in the presence of a catalyst system comprising: (1) a solid based on complexed titanium trichloride, (2) an organometallic compound of metals of groups IA, IIA, IIB and IIIB of the Periodic Table, (3) an electron-donating organic compound, the solid (1) based on complexed titanium trichloride having been preactivated by being placed in contact with a preactivator comprising the product of reaction of an organoaluminium compound (a) and of a compound (b) chosen from hydroxyaromatic compounds whose hydroxyl group is sterically blocked. This process enables propylene to be polymerised with an improved stereospecificity without significant decrease in the catalyst activity.
ES198989200469T 1988-03-09 1989-02-27 PROCEDURE FOR STEREO-SPECIFIC POLYMERIZATION OF ALPHA-OLEFINS AND CATALYTIC SYSTEM USABLE FOR SUCH POLYMERIZATION. Expired - Lifetime ES2033514T3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8803160A FR2628430B1 (en) 1988-03-09 1988-03-09 PROCESS FOR THE STEREOSPECIFIC POLYMERIZATION OF ALPHA-OLEFINS AND CATALYTIC SYSTEM FOR USE IN THIS POLYMERIZATION
CN90100037A CN1053070A (en) 1988-03-09 1990-01-06 The cocatalyst composition that is used for alpha-olefine polymerizing

Publications (1)

Publication Number Publication Date
ES2033514T3 true ES2033514T3 (en) 1993-03-16

Family

ID=36754126

Family Applications (1)

Application Number Title Priority Date Filing Date
ES198989200469T Expired - Lifetime ES2033514T3 (en) 1988-03-09 1989-02-27 PROCEDURE FOR STEREO-SPECIFIC POLYMERIZATION OF ALPHA-OLEFINS AND CATALYTIC SYSTEM USABLE FOR SUCH POLYMERIZATION.

Country Status (12)

Country Link
EP (1) EP0334411B1 (en)
JP (1) JP2776481B2 (en)
KR (1) KR0137775B1 (en)
CN (1) CN1053070A (en)
AT (1) ATE78265T1 (en)
CA (1) CA1340314C (en)
DE (1) DE68902073T2 (en)
ES (1) ES2033514T3 (en)
FR (1) FR2628430B1 (en)
GR (1) GR3005618T3 (en)
HK (1) HK38793A (en)
SG (1) SG112192G (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE1004563A3 (en) * 1990-08-30 1992-12-15 Solvay COMPOSITION FOR CURING cocatalytic USE OF ALPHA-OLEFINS.
BE1006080A3 (en) * 1992-07-17 1994-05-10 Solvay SOLID CATALYST USED FOR stereospecific polymerization ALPHA-OLEFINS, METHOD OF MAKING AND METHOD FOR POLYMERIZATION OF ALPHA-OLEFINS IN HIS PRESENCE.
US5264590A (en) * 1993-04-01 1993-11-23 Ethyl Corporation Preparation of titanium (III) coordination complexes
BE1009962A3 (en) * 1995-12-21 1997-11-04 Solvay Compositions propylene polymers and their use.
BE1012364A3 (en) * 1998-12-22 2000-10-03 Solvay Method for preparing a catalyst composition for polymerization of alpha-olefins, catalyst composition obtained and method of using the polymerization catalyst composition
US6586528B1 (en) 2000-11-15 2003-07-01 Polypropylene Belgium (Naamlose Vennootshap) Composition based on propylene polymers and process for obtaining same
US6642317B1 (en) 2000-11-15 2003-11-04 Polypropylene Belgium Naamlose Vennootschap Composition based on propylene polymers and process for obtaining same

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IE40215B1 (en) * 1973-12-04 1979-04-11 Ici Ltd Olefine polymer, olefine polymerisation process and catalyst
US4529780A (en) * 1981-11-19 1985-07-16 Northern Petrochemical Company Process for polymerizing alpha olefins with phenolic compound containing catalysts
FR2604439B1 (en) * 1986-09-26 1989-07-28 Solvay CATALYTIC SOLID FOR USE IN THE STEREOSPECIFIC POLYMERIZATION OF ALPHA-OLEFINS, PROCESS FOR PREPARING THE SAME, AND METHOD FOR POLYMERIZING ALPHA-OLEFINS IN ITS PRESENCE

Also Published As

Publication number Publication date
DE68902073T2 (en) 1993-02-25
DE68902073D1 (en) 1992-08-20
EP0334411A1 (en) 1989-09-27
JPH01275607A (en) 1989-11-06
JP2776481B2 (en) 1998-07-16
KR890014591A (en) 1989-10-24
HK38793A (en) 1993-04-30
ATE78265T1 (en) 1992-08-15
SG112192G (en) 1993-02-19
CN1053070A (en) 1991-07-17
EP0334411B1 (en) 1992-07-15
FR2628430B1 (en) 1992-04-17
KR0137775B1 (en) 1998-05-01
CA1340314C (en) 1999-01-12
GR3005618T3 (en) 1993-06-07
FR2628430A1 (en) 1989-09-15

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