ES2005250A6 - Phosphorous- and sulfur-containing lubricant and functional fluid compositions. - Google Patents
Phosphorous- and sulfur-containing lubricant and functional fluid compositions.Info
- Publication number
- ES2005250A6 ES2005250A6 ES8701681A ES8701681A ES2005250A6 ES 2005250 A6 ES2005250 A6 ES 2005250A6 ES 8701681 A ES8701681 A ES 8701681A ES 8701681 A ES8701681 A ES 8701681A ES 2005250 A6 ES2005250 A6 ES 2005250A6
- Authority
- ES
- Spain
- Prior art keywords
- compositions
- lubricating
- metal
- functional fluid
- containing composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 11
- 239000012530 fluid Substances 0.000 title abstract 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title 1
- 239000000314 lubricant Substances 0.000 title 1
- 229910052717 sulfur Inorganic materials 0.000 title 1
- 239000011593 sulfur Substances 0.000 title 1
- 239000002184 metal Chemical class 0.000 abstract 5
- 230000001050 lubricating effect Effects 0.000 abstract 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical class [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 3
- 150000001412 amines Chemical class 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000003921 oil Substances 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical class OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 abstract 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical compound OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 abstract 1
- QCJQWJKKTGJDCM-UHFFFAOYSA-N [P].[S] Chemical compound [P].[S] QCJQWJKKTGJDCM-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- -1 amine salts Chemical class 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 239000010687 lubricating oil Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 235000011007 phosphoric acid Nutrition 0.000 abstract 1
- 150000003016 phosphoric acids Chemical class 0.000 abstract 1
- 150000003141 primary amines Chemical class 0.000 abstract 1
- 239000001384 succinic acid Substances 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/10—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
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- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
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- C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
- C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
- C10M137/04—Phosphate esters
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- C10M173/00—Lubricating compositions containing more than 10% water
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
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- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
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- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C—CHEMISTRY; METALLURGY
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- C10N2040/26—Two-strokes or two-cycle engines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B75/00—Other engines
- F02B75/02—Engines characterised by their cycles, e.g. six-stroke
- F02B2075/022—Engines characterised by their cycles, e.g. six-stroke having less than six strokes per cycle
- F02B2075/025—Engines characterised by their cycles, e.g. six-stroke having less than six strokes per cycle two
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Lubricants (AREA)
Abstract
Lubricating and functional fluid compositions having improved extreme pressure properties and high temperature stability. The compositions contain at least one ammonium or metal salt of at least one phosphorus- and sulfur-containing composition and at least one soluble nitrogen-containing composition. More particularly, the oil-based lubricating and functional fluid compositions of the present invention comprise a major amount of oil and a minor amount of (A) at least one amine or metal salt of at least one monothiophosphoric acid of formulae (I) or (II) or mixtures thereof wherein R<1> and R<2> are each independently hydrocarbyl groups, X is a metal or an ammonium group, and when X is a metal, n is an integer equal to the valence of the metal, and when X is an ammonium group, n=1, and (B) at least one soluble nitrogen-containing composition prepared by the reaction of a hydrocarbon-substituted succinic acid-producing compound with at least about one-half equivalent, per equivalent of acid producing compound, of an amine containing at least one hydrogen attached to a nitrogen atom. Preferably, the amine salts of the phosphoric acids utilized in the lubricating compositions of the present invention are derived from primary or tertiary amines, and the soluble nitrogen-containing compositions (B) also contain boron. The lubricating compositions of the present invention are particularly useful as lubricating oils or greases. Aqueous systems, and a method for preparing O-hydrocarbyl-S-hydrocarbyl monothiophosphates also are described herein.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US87425486A | 1986-06-13 | 1986-06-13 |
Publications (1)
Publication Number | Publication Date |
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ES2005250A6 true ES2005250A6 (en) | 1989-03-01 |
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ID=25363331
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES8701681A Expired ES2005250A6 (en) | 1986-06-13 | 1987-06-08 | Phosphorous- and sulfur-containing lubricant and functional fluid compositions. |
Country Status (7)
Country | Link |
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EP (1) | EP0309486A1 (en) |
JP (1) | JPH01502988A (en) |
AU (1) | AU7870787A (en) |
ES (1) | ES2005250A6 (en) |
MX (1) | MX169456B (en) |
WO (1) | WO1987007638A2 (en) |
ZA (1) | ZA874206B (en) |
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US5210261A (en) * | 1988-12-19 | 1993-05-11 | Ethyl Petroleum Additives, Ltd. | Production of phosphorothioate salts |
US5254272A (en) * | 1989-12-22 | 1993-10-19 | Ethyl Petroleum Additives Limited | Lubricant compositions with metal-free antiwear or load-carrying additives and amino succinate esters |
ATE134701T1 (en) * | 1990-01-05 | 1996-03-15 | Lubrizol Corp | UNIVERSAL POWER TRANSMISSION FLUID |
US5328619A (en) * | 1991-06-21 | 1994-07-12 | Ethyl Petroleum Additives, Inc. | Oil additive concentrates and lubricants of enhanced performance capabilities |
EP0684298A3 (en) | 1994-05-23 | 1996-04-03 | Lubrizol Corp | Compositions for extending seal life, and lubricants and functional fluids containing the same. |
TW425425B (en) | 1994-08-03 | 2001-03-11 | Lubrizol Corp | Lubricating compositions, concentrates, and greases containing the combination of an organic polysulfide and an overbased composition or a phosphorus or boron compound |
AU717747B2 (en) | 1995-10-18 | 2000-03-30 | Lubrizol Corporation, The | Antiwear enhancing composition for lubricants and functional fluids |
GB9521352D0 (en) * | 1995-10-18 | 1995-12-20 | Exxon Chemical Patents Inc | Power transmitting fluids of improved antiwear performance |
WO1998008919A2 (en) | 1996-08-30 | 1998-03-05 | Solutia Inc. | Novel water soluble metal working fluids |
US6277794B1 (en) | 1998-12-28 | 2001-08-21 | Infineum Usa L.P. | Lubricant compositions |
US6617287B2 (en) | 2001-10-22 | 2003-09-09 | The Lubrizol Corporation | Manual transmission lubricants with improved synchromesh performance |
US6573223B1 (en) | 2002-03-04 | 2003-06-03 | The Lubrizol Corporation | Lubricating compositions with good thermal stability and demulsibility properties |
US6689723B2 (en) | 2002-03-05 | 2004-02-10 | Exxonmobil Chemical Patents Inc. | Sulfide- and polysulfide-containing lubricating oil additive compositions and lubricating compositions containing the same |
US6534451B1 (en) * | 2002-04-05 | 2003-03-18 | Infineum International Ltd. | Power transmission fluids with improved extreme pressure lubrication characteristics and oxidation resistance |
US6586375B1 (en) | 2002-04-15 | 2003-07-01 | The Lubrizol Corporation | Phosphorus salts of nitrogen containing copolymers and lubricants containing the same |
US20050026791A1 (en) * | 2003-07-30 | 2005-02-03 | Ethyl Corporation | Low sulfur, low ash, and low phosphorus lubricant additive package using an alkylamine salt of dialkylmonothiophosphate |
US8299003B2 (en) | 2005-11-09 | 2012-10-30 | Afton Chemical Corporation | Composition comprising a sulfur-containing, phosphorus-containing compound, and/or its salt, and uses thereof |
US20070142660A1 (en) | 2005-11-09 | 2007-06-21 | Degonia David J | Salt of a sulfur-containing, phosphorus-containing compound, and methods thereof |
EP2132281B1 (en) * | 2007-03-30 | 2019-06-12 | Dorf Ketal Chemicals (I) Private Limited | High temperature naphthenic acid corrosion inhibition using organophosphorous sulphur compounds and combinations thereof |
JP2008280536A (en) | 2007-05-09 | 2008-11-20 | Afton Chemical Corp | Composition comprising at least one friction improving compound, and use of the same |
US8349778B2 (en) | 2007-08-16 | 2013-01-08 | Afton Chemical Corporation | Lubricating compositions having improved friction properties |
US8722594B2 (en) | 2010-03-19 | 2014-05-13 | Jx Nippon Oil & Energy Corporation | Lubricating oil composition |
JP5462682B2 (en) * | 2010-03-26 | 2014-04-02 | Jx日鉱日石エネルギー株式会社 | Lubricating oil composition |
JP5523885B2 (en) * | 2010-03-19 | 2014-06-18 | Jx日鉱日石エネルギー株式会社 | Lubricating oil composition |
US9896640B2 (en) | 2012-11-28 | 2018-02-20 | Dow Corning Corporation | Method of reducing friction and wear between surfaces under a high load condition |
CA2948138C (en) | 2014-05-06 | 2022-10-04 | The Lubrizol Corporation | Anti-corrosion additives |
CA3004417A1 (en) | 2015-11-06 | 2017-05-11 | The Lubrizol Corporation | Low viscosity gear lubricants |
US20190062666A1 (en) | 2016-03-03 | 2019-02-28 | The Lubrizol Corporation | Lubricating Oil Composition Having Improved Air Release |
US10640723B2 (en) | 2018-03-16 | 2020-05-05 | Afton Chemical Corporation | Lubricants containing amine salt of acid phosphate and hydrocarbyl borate |
US11066622B2 (en) | 2019-10-24 | 2021-07-20 | Afton Chemical Corporation | Synergistic lubricants with reduced electrical conductivity |
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DE2363388C2 (en) * | 1973-12-20 | 1982-08-19 | Hoechst Ag, 6000 Frankfurt | Process for the preparation of dialkyl thiophosphates |
GB1493965A (en) * | 1974-02-04 | 1977-12-07 | Lubrizol Corp | Method for working metal and metal workpieces with lubricants thereon |
US4472288A (en) * | 1980-08-29 | 1984-09-18 | Chevron Research Company | Lubricant composition containing alkali metal borate and an oil-soluble amine salt of a phosphorus compound |
US4431552A (en) * | 1982-11-26 | 1984-02-14 | Chevron Research Company | Lubricant composition containing an alkali-metal borate and a mixture of phosphates, monothiophosphates and dithiophosphates in a critical ratio |
-
1987
- 1987-06-05 EP EP87905673A patent/EP0309486A1/en not_active Ceased
- 1987-06-05 AU AU78707/87A patent/AU7870787A/en not_active Abandoned
- 1987-06-05 WO PCT/US1987/001327 patent/WO1987007638A2/en not_active Application Discontinuation
- 1987-06-05 JP JP62505208A patent/JPH01502988A/en active Pending
- 1987-06-08 ES ES8701681A patent/ES2005250A6/en not_active Expired
- 1987-06-09 MX MX006833A patent/MX169456B/en unknown
- 1987-06-11 ZA ZA874206A patent/ZA874206B/en unknown
Also Published As
Publication number | Publication date |
---|---|
EP0309486A1 (en) | 1989-04-05 |
WO1987007638A3 (en) | 1988-03-10 |
MX169456B (en) | 1993-07-05 |
JPH01502988A (en) | 1989-10-12 |
WO1987007638A2 (en) | 1987-12-17 |
ZA874206B (en) | 1987-12-15 |
AU7870787A (en) | 1988-01-11 |
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