ES2003533A6 - Procedimiento para la obtencion de enantiomeros de monoesteres de acido dicarboxilicos opticamente activos. - Google Patents

Procedimiento para la obtencion de enantiomeros de monoesteres de acido dicarboxilicos opticamente activos.

Info

Publication number
ES2003533A6
ES2003533A6 ES8603131A ES8603131A ES2003533A6 ES 2003533 A6 ES2003533 A6 ES 2003533A6 ES 8603131 A ES8603131 A ES 8603131A ES 8603131 A ES8603131 A ES 8603131A ES 2003533 A6 ES2003533 A6 ES 2003533A6
Authority
ES
Spain
Prior art keywords
enantiomers
preparation
subjecting
rotation
dicarboxylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES8603131A
Other languages
English (en)
Inventor
Michael Casutt
Eike Poetsch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Merck Patent GmbH
Original Assignee
Merck Patent GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Merck Patent GmbH filed Critical Merck Patent GmbH
Publication of ES2003533A6 publication Critical patent/ES2003533A6/es
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D233/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/28Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/30Oxygen or sulfur atoms
    • C07D233/32One oxygen atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PROCEDIMIENTO PARA LA OBTENCION DE ENANTIOMEROS DE MONOESTERES DE ACIDOS DICARBOXILICOS OPTICAMENTE ACTIVOS, BAJO SEPARACION DE UN ENANTIOMERO, CARACTERIZADO PORQUE SE SOMETE EL MONOESTER DE PARTIDA A UNA TRANSPOSICION INTRAMOLECULAR Y, EN CASO DADO, SE SEPARA EL ENANTIOMERO DESEADO, OBTENIENDOSE UNA INVERSION DEL SENTIDO DE ROTACION DEL MONOESTER EMPLEADO. LA TRANSPOSICION SE LLEVA A CABO BAJO LAS CONDICIONES DE UNA TRANESTERIFICACION Y EL ENANTIOMERO DESEADO SE SEPARA MEDIANTE CRISTALIZACION. LA CRISTALIZACION DEL ENANTIOMERO DESEADO SE LLEVA A CABO DURANTE LA TRANSESTERIFICACION, TRANSFORMANDOSE EL MONOESTER EMPLEADO COMPLETAMENTE EN EL ENANTIOMERO DESEADO.
ES8603131A 1985-11-23 1986-11-21 Procedimiento para la obtencion de enantiomeros de monoesteres de acido dicarboxilicos opticamente activos. Expired ES2003533A6 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19853541450 DE3541450A1 (de) 1985-11-23 1985-11-23 Verfahren zur herstellung von enantiomeren

Publications (1)

Publication Number Publication Date
ES2003533A6 true ES2003533A6 (es) 1988-11-01

Family

ID=6286649

Family Applications (1)

Application Number Title Priority Date Filing Date
ES8603131A Expired ES2003533A6 (es) 1985-11-23 1986-11-21 Procedimiento para la obtencion de enantiomeros de monoesteres de acido dicarboxilicos opticamente activos.

Country Status (7)

Country Link
US (1) US4739071A (es)
EP (1) EP0226043B1 (es)
JP (1) JPH07116062B2 (es)
AT (1) ATE50406T1 (es)
DE (2) DE3541450A1 (es)
ES (1) ES2003533A6 (es)
HU (1) HU209423B (es)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2491920A1 (fr) * 1980-10-10 1982-04-16 Roussel Uclaf Nouveaux esters methyliques derives de l'acide 2,2-dimethyl cyclopropane 1,3-dicarboxylique, leur preparation et les intermediaires nouveaux obtenus
EP0173185B1 (de) * 1984-08-25 1990-01-31 MERCK PATENT GmbH Verfahren zur Herstellung von (3a5,6aR)-und/oder(3aR,6a5)-1,3-Dibenzyl-hexahydro-1H-furo(3,4-d)imidazol-2,4-dion

Also Published As

Publication number Publication date
DE3541450A1 (de) 1987-05-27
EP0226043A1 (de) 1987-06-24
JPS62135436A (ja) 1987-06-18
JPH07116062B2 (ja) 1995-12-13
DE3669040D1 (de) 1990-03-22
ATE50406T1 (de) 1990-02-15
EP0226043B1 (de) 1990-02-14
HUT43550A (en) 1987-11-30
HU209423B (en) 1994-06-28
US4739071A (en) 1988-04-19

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Legal Events

Date Code Title Description
SA6 Expiration date (snapshot 920101)

Free format text: 2006-11-21

FD1A Patent lapsed

Effective date: 20010503