EP4695354A1 - Processes for blending two or more streams of liquified hydrocarbons - Google Patents
Processes for blending two or more streams of liquified hydrocarbonsInfo
- Publication number
- EP4695354A1 EP4695354A1 EP24714523.8A EP24714523A EP4695354A1 EP 4695354 A1 EP4695354 A1 EP 4695354A1 EP 24714523 A EP24714523 A EP 24714523A EP 4695354 A1 EP4695354 A1 EP 4695354A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- stream
- liquified
- combined
- conduits
- storage container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/08—Production of synthetic natural gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/12—Liquefied petroleum gas
Definitions
- the present specification generally relates to the field of blending of hydrocarbons, and more specifically, to processes to blend two or more streams of liquefied hydrocarbons.
- Blending of an LNG product which comprises mainly methane with another component, such as light hydrocarbons, such as ethane, propane, or butane, to increase the LNG heating value to meet market demands is known.
- another component such as light hydrocarbons, such as ethane, propane, or butane
- US20140338393 discloses a method for producing a blended mixture of liquefied natural gases to meet the particular requirements of an operator at a production facility, application site or a fueling station by blending together a lean liquefied natural gas and a rich liquefied natural gas.
- W02005093017 discloses compositions comprising mixtures of natural gas and synthetic light hydrocarbons, such as C2 to C5 paraffins, olefins and mixtures thereof, obtained via a hydrocarbon synthesis reactions, which are suitable for use as fuel compositions, and particularly to blends of such synthetic light hydrocarbons and a natural gas derived from LNG produced in an LNG process.
- US8381544 discloses altering the heating value of a liquefied natural gas by adding higher heating value components by using the LNG to cool the higher heating value component stream prior to combining the higher heating value components with the LNG.
- US 11416012 discloses in-line mixing of hydrocarbon liquids from a plurality of containers into a single pipeline, where the hydrocarbon liquids are generally those that exist in a liquid state at atmospheric conditions, such as hydrocarbons that exists as a viscous liquid in underground geological formations and at the surface, gasoline, crude oils, pyrolysis oil, etc. As such, this patent reference does not address the challenges of blending liquefied hydrocarbons.
- the facility comprises a first storage container for storing a first liquified hydrocarbon, optionally the first liquified hydrocarbon is liquefied natural gas, a blended storage container for storing a blended liquified product, and a network of conduits.
- the network of conduits comprises a first blending point located downstream of the first storage container and upstream of the blended-product storage container, a first conduits segment to provide fluid communication between the first storage container and the first blending point, a second conduits segment to provide fluid communication between a source of a second liquified hydrocarbon and the first blending point, optionally the second liquified hydrocarbon is selected from a group consisting of liquified ethane, liquified butane, liquified propane, and any combination thereof; and combined conduits to provide fluid communication between the first blending point and the blended-product storage container.
- the combined conduits comprise a final valve immediately upstream of an inlet of the blended-product storage container.
- the method comprises: (a) pumping a first liquified hydrocarbon stream from the first storage container to the first blending point via the first conduits segment; (b) pumping a second liquified hydrocarbon stream from the source of the second liquified hydrocarbon to the first blending point via the second conduits segment; (c) combining the first and second liquified hydrocarbon streams at the first blending point (108) in a volumetric ratio in a range from 1 :500, preferably from 1 : 100, and up to 500: 1 to provide a combined stream; and (d) providing at least a portion, including all, of the combined stream from the first blending point (108) to the blended-product storage container via the combined conduits, and (e) while the combined stream is between a segment of the combined conduits between the first blending point and the first final valve, providing the combined stream with an operating pressure above (preferably at least 0.1 bar above, more preferably at least 0.5 bar above, most preferably at least 1.2 bar above) a saturation pressure of
- the combined conduits further comprise a first subsequent blending point downstream of the first blending point and upstream of an inlet of the blended product storage container.
- the method can further comprise: (f) providing a second stream of the first liquified hydrocarbon from a source of the first liquefied hydrocarbon to the first subsequent blending point, optionally, such source being the first storage container; (g) combining the combined stream and the second stream of the first liquefied hydrocarbon at the first subsequent blending point in a volumetric ratio in a range from 25: 1, preferably 50: 1, and up to 500: 1, wherein the first stream of the first liquefied hydrocarbon and the stream of the second liquified hydrocarbon ethane stream are combined in a volumetric ratio in a range from 1 :500, preferably 1 : 100, and up to 50: 1 at the first blending point.
- the combined conduits further comprise a second subsequent blending point located downstream of the first subsequent blending point, and optionally, it is located either upstream or downstream of the final valve, and upstream of an inlet of the blended-product storage container.
- the method can further comprise: (f) providing a third stream of the first liquified hydrocarbon from a source of the first liquified hydrocarbon, optionally, such source (302) being different from the first storage container, to the second subsequent blending point; and (g) combining the combined stream and the third stream of the first liquified hydrocarbon at the second subsequent blending point in a volumetric ratio in a range from 25:1, preferably 50:1, and up to 150: 1, wherein the first liquefied hydrocarbon stream and the second liquefied hydrocarbon stream are combined in a volumetric ratio in a range from 1 :500, preferably 1 : 100, and up to 50: 1 at the first blending point and wherein the combined stream and the second stream of the first liquified hydrocarbon are combined in a volumetric ratio in a range from 100: 1, preferably 150: 1, and up to 500: 1 at the first subsequent blending point.
- the combined conduits further comprise a subsequent blending point located downstream of the final valve and upstream of the blended- product storage container.
- the method can comprise: (f) providing another stream of the first liquified hydrocarbon from a source of the first liquefied hydrocarbon, optionally, such source (302) being different from the first storage container, to the subsequent blending point; (g) combining the combined stream and the other stream of the first liquified hydrocarbon at the subsequent blending point in a volumetric ratio in a range from 25: 1, preferably 50: 1, and up to 500: 1, and wherein the first stream of the first liquified hydrocarbon and the stream of the second liquified hydrocarbon are combined in a volumetric ratio in a range from 1 :500, preferably 1 : 100, and up to 50: 1 at the first blending point.
- the combined stream that is downstream of the final valve and downstream of any optionally subsequent blending point comprises a volumetric ratio of the first liquified hydrocarbon, preferably LNG, to the second liquified hydrocarbon, preferably liquified ethane, of at least 2: 1, preferably at least 3:1, more preferably 4: 1.
- the first liquified hydrocarbon is LNG and the second and/or third stream of the first liquefied hydrocarbon comprises an LNG rundown stream.
- the method can further comprise providing the network of conduits with an overall operating pressure of at least 2 barg.
- the method can further comprise reducing the operating pressure of the combined stream downstream of the final valve to less than the saturation pressure of the combined stream.
- the method can further comprise reducing the operating pressure of the combined stream downstream of final valve to the storage pressure of the blended-product storage container.
- step (a) is performed before step (b).
- step (a) can comprise circulating the first stream of the first liquified hydrocarbon from the first storage container through the first portion of conduits, the combined conduits, the blended-product storage container, and recirculation conduits back to the first storage container, wherein the recirculation conduits provide fluid communication between the blended-product storage container and the first storage container.
- the second liquified hydrocarbon is liquified ethane
- the source of liquified ethane is selected from the group consisting of onshore storage, and ethane transport vessel, and any combination thereof.
- the facility comprises an LNG liquefaction facility.
- the method can further comprise operating the LNG liquefaction facility in liquefaction mode after the blending of the two or more liquified hydrocarbon streams is completed.
- FIG. 1 depicts a diagram of an exemplary embodiment of a system for use in blending two or more liquified hydrocarbon streams according to aspects disclosed in the present disclosure.
- FIG. 2 depicts a diagram of an exemplary embodiment of another system for use in blending two or more liquified hydrocarbon streams according to aspects disclosed in the present disclosure.
- FIG. 3 depicts a diagram of an exemplary embodiment of yet another system for use in blending two or more liquified hydrocarbon streams according to aspects disclosed in the present disclosure.
- FIG. 4 depicts a diagram of an exemplary embodiment of yet another system for use in blending two or more liquified hydrocarbon streams according to aspects disclosed in the present disclosure.
- a general concern when blending an LNG product with lighter hydrocarbons is the potential formation of stratified liquid layers (or stratification) of different density, in a storage container.
- stratified liquid layers or stratification
- heat leaking into the blended-LNG product via the storage container walls will slowly warm the blend-LNG in contact with the container walls and bottom plate.
- This warmer blended LNG has a lower density, which increases its buoyancy, slowly leading the warmer blended LNG to ascend in the bulk LNG inventory.
- the warmer LNG releases the accumulated excess heat through vaporization, becoming cooler and denser, which in turn decreases its buoyancy, slowly leading the cooler blended LNG to descend in the bulk LNG inventory.
- the present disclosure often refers to LNG and ethane as the two streams of liquefied hydrocarbons that benefit from the blending methods described herein, it is understood that the principles provided by the present disclosure can be applied to blend other streams of liquefied hydrocarbons, such as (i) LNG and liquified propane, or (ii) LNG and a mixture of liquified ethane, liquified propane, liquified butane, and any combination thereof.
- hydrocarbon has its ordinary meaning, which includes molecules comprised of carbon and hydrogen in various combinations, and may be of fossil (e.g., natural gas) or biogenic origin (e.g., biomethane).
- fossil e.g., natural gas
- biogenic origin e.g., biomethane
- the term “liquified hydrocarbons” refers to hydrocarbons that occur as gases at atmospheric pressure and temperature, and due to a reduction of temperature and/or an increase of pressure, or a combination of both, will change state and become liquids at the new pressure and temperature conditions. In some cases (as it is the case of natural gas liquefaction) this phase change can also be coupled with a subsequent lowering of the operating pressure to meet downstream processes (e.g., atmospheric storage of LNG), further lowering the liquefied hydrocarbon stream temperature.
- downstream processes e.g., atmospheric storage of LNG
- hydrocarbons may be described as being light or heavy according to the number of carbon atoms and hydrogen atoms in a molecule.
- liquified hydrocarbons include alkanes (or paraffins) (such as methane - CH4, ethane — C2H6, propane — C3H8, butanes: normal butane and isobutane — C4H10, natural gasoline or pentanes plus — C5H12 and heavier); and alkenes (or olefins) (such as ethylene — C2H44, propylene — C3H6, normal butylene and isobutylene — C4H8.
- the present disclosure provides methods for conducting a blending operation of two streams of liquefied hydrocarbons to produce a liquefied natural gas with desired composition at an LNG facility that mitigate the risk of stratification as well as other benefits that are apparent to one of ordinary skill.
- the methods described herein can be suitably adapted for blending of lean LNG with liquified ethane to meet desired LNG and/or natural gas specifications (such as the Wobbe Index (WI), Lower Heating Value (LHV), Methane Number (MN), or the Incomplete Combustion Factor (ICF)) at various LNG facilities or sites using existing infrastructure of the respective site.
- WI Wobbe Index
- LHV Lower Heating Value
- MN Methane Number
- ICF Incomplete Combustion Factor
- FIGS. 1 - 4 depict various facilities that comprise an storage container 102 to store a first liquified hydrocarbon, preferably LNG, and a blended-product storage container 106 to store the blended product.
- the depicted facilities further comprise a network of conduits in fluid communication with both the storage container 102 and the blended-product storage container 106.
- Liquified natural gas (LNG) is natural gas (predominantly methane) that has been liquefied. LNG can be stored in container 102 and/or 106 at a temperature lower than -110 °C, depending on the application, and more typically lower than -145 °C, such as between -159 °C and -162 °C.
- Lean LNG has a relatively lower calorific value whereas “rich” LNG contains a greater proportion of heavier hydrocarbons which gives it a higher calorific value.
- Lean LNG can be further enriched, such as by methods described herein, to meet various market quality specifications, such as the Wobbe Index (WI), Lower Heating Value (LHV), Methane Number (MN), or the Incomplete Combustion Factor (ICF).
- WI Wobbe Index
- LHV Lower Heating Value
- MN Methane Number
- ICF Incomplete Combustion Factor
- the network of conduits comprises a first blending point, which may be referred to as an LNG-ethane blending point 108 in reference to a preferred embodiment, located between the jetty and the storage container (102).
- the network of conduits further comprises first conduits segment 110 (which may be referred to as LNG conduits 110 for a preferred embodiment where the first liquified hydrocarbon is LNG), and second conduits segment 112 (which may be referred to as ethane conduits 112 for a preferred embodiment where the second liquified hydrocarbon is ethane).
- First conduits segment 110 provides fluid communication between the first storage container 102 and first blending point 108.
- Second conduits segment 112 provides fluid communication between the storage container 114 for the second liquified hydrocarbon and the first blending point 108.
- Container 114 may be referred to as ethane source 114 as reference to a preferred embodiment in which the second liquified hydrocarbon is ethane.
- the first blending point 108 is a fluid conduit junction between the first conduits segment 110 and the second conduits segment 112.
- Blending point 108 is a fluid conduit junction known to one of ordinary skill.
- suitable examples of blending point 108 include a tee junction, Y-shape junction, a mixing tee, a wye pipe fitting, and any combination thereof.
- the second liquified hydrocarbon is ethane.
- Liquified ethane can be stored at a temperature lower than -30 °C, depending on the application, and more typically lower than -75°C, such as between -80 °C to -89 °C.
- FIG. 1 depicts the ethane source 114 as on onshore storage container, it is understood that ethane source 114 suitably can additionally or alternatively be storage on a vessel (liquified ethane carrier) as known by one of ordinary skill.
- the network of conduits further comprises combined conduits 116 to provide fluid communication between the first blending point 108 and the blended product storage container 106.
- Suitable storage for liquefied hydrocarbons like LNG, liquefied ethane, and others that are noted herein, are known to one of ordinary skill.
- suitable examples can include single containment systems that typically have an inner wall or primary container that holds the refrigerated liquid and can be self-supporting.
- the inner container can be surrounded by an outer wall, thereby forming an annular space, which can hold insulation.
- the single containment system can be further insulated, such as the base and roof, and external insulation.
- Another suitable example includes double containment systems which typically adds to the single containment system, a secondary wall that is capable of containing both liquid and vapor.
- LNG liquefied natural gas
- the pumping of the LNG stream can be done at least by pump equipment 120.
- a liquefied ethane stream is pumped through ethane conduits 112 from the ethane source 114 to the LNG-ethane blending point 108.
- liquid ethane or “ethane” refers to a liquefied hydrocarbon stream comprising at least 50 mol%, preferably at least 95 mol%, of ethane.
- liquified hydrocarbons other than LNG and liquified ethane can be blended using the methods described herein.
- the liquified hydrocarbon stream that is liquified propane comprises at least 50 mol%, preferably at least 95 mol% propane; if liquified butane, then the stream comprises at least 50 mol% butane, preferably at least 95 mol
- the liquified hydrocarbon stream does not consist essentially of the component of its namesake (for instance, the liquified ethane stream is not essentially all ethane)
- the remaining portion of that stream be selected from a group consisting of ethane, methane, propane, butane, and any combination thereof, as applicable.
- an example of a mixture of liquefied hydrocarbons as defined herein can be LPG, which stands for liquefied petroleum gas, which includes mixes that are mostly propane, mostly butane, or mostly a mixture of both propane and butane.
- the pumping of the second liquified hydrocarbon stream can be done at least by pump equipment 118.
- the first LNG stream and the ethane stream are combined at the LNG-ethane blending point 108 in a volumetric blending ratio of LNG to ethane in a range from 1 :500 and up to 500: 1, preferably 1 : 100 and up to 500:1, and more preferably 1 : 10 and up to 500 to 1, to provide a combined stream.
- the pump equipment may be part of the existing infrastructure and equipment of the facility, such as a liquefaction plant.
- the combined stream can be provided to the blended-product storage container 106 via at least combined conduits 116 from the first blending point 108.
- the flow rate of the LNG stream and the flow rate of ethane stream, by the respective pumps provide suitable force to move the combined stream to the blended product storage container 106, without needing additional pump equipment.
- the network of conduits can comprise a plurality of valves as known by one of ordinary skill to control the flow of various streams.
- LNG conduits 110 comprise valve 122 to control the flow of the first LNG stream flowing from storage container 102 to the LNG-ethane blending point 108.
- ethane conduits 112 comprise valve 124 to control the flow of the liquified ethane stream flowing from ethane source 114 to the LNG-ethane blending point 108.
- the network of conduits comprises a final valve 126.
- Final valve 126 is the last valve that the combined stream flows through before it is introduced to blended-product storage container 106. That is, final valve 126 is the valve immediately upstream of an inlet of blended-product storage container 106.
- combined conduits 116 have an operating pressure due at least to the force exerted by the flow of the combined stream through combined conduits 116, as well as any available flow control devices in the conduits, such as the final valve 126. While the combined stream is being provided to the blended-product storage container 106, the portion of the combined conduits 116 between the LNG-ethane blending point 108 and final valve 126 is provided with an operating pressure that is higher than the saturation pressure of the combined stream, preferably at least 0.1 bar, more preferably at least 0.5 bar, and most preferably at least 1.2 bar above the saturation pressure of the combined stream.
- An operating pressure of at least 1.2 bar higher than the saturation pressure of the combined stream is most preferred because it provides a most preferred buffer to accommodate fluctuations in pressure conditions along conduits 116, although embodiments with a lower operating pressure that is higher than the saturation pressure of the combined stream can still provide benefits described herein.
- the saturation pressure of the combined stream can change as it travels through conduits 116 to blended-product storage container 106, at least due to heat transfer from the environment and/or equipment. Generally, the saturation pressure of the combined stream increases as it travels through the combined conduits 116 toward container 106.
- Either the operating pressure of the combined conduits 116 between the LNG-ethane blending point 108 and final valve 126 is adjusted frequently, preferably in response to the monitoring, to accommodate the increase in saturation pressure and/or the saturation pressure of the combined stream can be reduced to ensure that the operating pressure remains higher than the saturation pressure of the combined stream as the saturation pressure changes.
- the methods described herein mitigates two phase flow formation in that portion of the combined conduits 116 (whether localized or sustained two phase flow formation).
- saturation pressure has its ordinary meaning and includes the definition of the pressure at which the fluid exists both as a vapor and liquid, and the rate of evaporation equals its rate of condensation for a given temperature.
- the saturation pressure of the combined stream is the pressure at which the combined stream exhibits both a vapor and liquid phase, which are in thermodynamic equilibrium at the temperature of the combined stream.
- the saturation pressure of the combined stream while in the combined conduits 116 between the LNG-ethane blending point 108 and final valve 126 can be suitably determined by one of ordinary skill, based on the temperature of the combined stream and blending ratio (both of which can be measured by sensors).
- the network of conduits can comprise suitable sensors known to one of ordinary skill to provide the relevant data to implement the methods as described herein. Examples of suitable sensors include hydrometers, gravitometers, densitometers, density measuring sensors, gravity measuring sensors, pressure transducers, temperature sensors, flow meters, mass flow meters, Coriolis meters, other measurement sensors to determine a density, gravity, or other variable as will be understood by those skilled in the art, or some combination thereof.
- the determination of the saturation pressure of the combined stream can be done manually, or autonomously using a computer or other similar process control systems such that subsequent corrective action (e.g., increase of the system operating pressure, increase of blending ratio, or other) may be implemented as desired.
- the methods described herein provide an operating pressure in the combined conduits 116 between the LNG-ethane blending point 108 and final valve 126 that is higher than the saturation pressure of the combined stream, preferably at least 0.1 bar, more preferably at least 0.5 bar, and most preferably at least 1.2 bar above the saturation pressure of the combined stream. Providing such operating pressure that is higher than the saturation pressure of the combined stream enables the combined stream to remain in the liquid phase while flowing through these segments of conduits, despite varying pressure conditions along such conduits segments.
- the operating pressure of the combined stream in the combined conduits, as well as other parts of the network of conduits, can be monitored as known by one of ordinary skills, such as by sensors.
- the monitoring can allow for continuous monitoring of the operating conditions of the combined stream to ensure that the operating pressure in combined conduits 116 stays above (preferably at least 0.1, 0.5, or 1.2 bar above) the saturation pressure of the combined stream.
- an operating pressure of the combined stream upstream of the final valve 126 that is higher than the saturation pressure of the combined stream can be provided by adjusting the opening percentage of the final valve 126 to provide the desired operating pressure upstream of valve 126.
- the opening percentage of the final valve 126 can be adjusted continuously as needed during the blending operation to provide the desired operating pressure at or above the saturation pressure of the combined stream as described herein.
- the operating pressure of the combined stream 116 can also be influenced by operating conditions of downstream systems, such as adjustments to the operating pressure of a storage container, such as 102 106 (possibly and 102)
- the saturation pressure of the combined stream can be reduced by adjusting the volumetric ratio of the first LNG stream and liquefied ethane at the LNG-ethane blending point 108, and/or along the combined conduits 116 by providing additional blending points.
- additional blending point(s) allows for more LNG to be added to the combined stream, which lowers the saturation pressure of the combined stream, thereby providing another option to ensure achieving of an operating pressure of the combined stream that is higher than the saturation pressure of the combined stream.
- conduits 116 further comprises subsequent blending point 208 located upstream of the final valve 126 and downstream of the LNG-ethane blending point 108.
- the network of conduits further comprises another conduits segment 216 (which may be referred to as second LNG conduits 216 for a preferred embodiment) to provide fluid communication between storage container 102 (or a second suitable source of LNG, which is not depicted in FIG. 2) and subsequent blending point 208.
- second LNG conduits 216 can provide fluid communication between the subsequent blending point 208 and container 102 via a connection with LNG conduits 110 or it can connect directly to container 102.
- a second stream of the first liquified hydrocarbon can be provided to subsequent blending point 208 from storage container 102 (or a second source of LNG) via second LNG conduits 216.
- second LNG conduits 216 can further comprise valve 222 to control the flow of the second LNG stream through the second LNG conduits 216.
- valve 222 can be closed when blending at subsequent blending point 208 is not desired and opened when blending of additional LNG to the combined stream is desired. The opening of valve 222 can be adjusted to achieve a desired blending ratio at subsequent blending point 208.
- the combined stream and the second LNG stream are combined in a ratio in a range from 25: 1, preferably 50: 1, and up to 500: 1 at the subsequent blending point 208 and the first LNG stream and ethane stream are combined in a ratio in a range preferably from 1 : 100 and up to 50: 1 at the LNG-ethane blending point 108. Because an additional blending point is provided, the ratio of LNG and ethane at the LNG-ethane blending point 108 can be less than if there is only a single blending point (i.e., 108).
- the ratio of LNG to ethane at the LNG-ethane blending point is in a range from 1 :500 and up to 500: 1 versus a multi-blending-points scenario as depicted in FIG. 2, the ratio is in a range from 1 :500, preferably from 1 : 100, and up to 50: 1 of LNG to ethane at the LNG-ethane blending point 108 and from 25: 1, preferably from 50: 1, and up to 500: 1 of combined stream to second LNG stream at the subsequent blending point 208.
- the provided blending ratio ranges, for a multiblending-points scenario can be extended or changed, to suit asset and/ or process specific requirements, as understood by one of ordinary skill.
- first blending points may have a blending ratio of 1 : 1
- second blending point may have a blending ratio of 47 : 1.
- combined conduits 116 further comprises subsequent blending point 308 located downstream of the final valve 126 and upstream of the blended-product storage container 106.
- subsequent blending point 308 can be located upstream of the final valve 126, depending on the particular arrangement of the existing infrastructure of the plant at which the blending operation is carried out. As can be seen in FIG.
- the network of conduits further comprises a third LNG conduits 316 to provide fluid communication between a source of the first liquified hydrocarbon, such as LNG (which source can be different from container 102, optionally second source 302 of the first liquified hydrocarbon) and subsequent blending point 308.
- a source of the first liquified hydrocarbon such as LNG (which source can be different from container 102, optionally second source 302 of the first liquified hydrocarbon) and subsequent blending point 308.
- first liquified hydrocarbon from source 302 can be provided to subsequent blending point 208 via second LNG conduits 216.
- another LNG stream can be provided to subsequent blending point 308 from the LNG source 302 via third LNG conduits 316.
- third LNG conduits 316 can further comprise a valve to control the flow of the LNG stream therethrough.
- the combined stream and the LNG stream from LNG source 302 are combined in a ratio in a range from 25: 1, preferably from 50: 1, and up to 500:1 at the subsequent blending point 208 and the first LNG stream and ethane stream are combined in a ratio in a range preferably from 25: 1, preferably 50: 1, and up to 500: 1 at the LNG-ethane blending point 108.
- the first LNG stream and ethane stream are combined in a ratio in a range preferably from 25: 1, preferably 50: 1, and up to 500: 1 at the LNG-ethane blending point 108.
- the blending ratio of LNG to ethane at the LNG-ethane blending point 108 is in a range from 1 :500, preferably from 1 : 100, and up to 50: 1, and at the subsequent blending point 308, the ratio of the combined stream to the LNG stream from second LNG source 302 is in a range from 25: 1, preferably from 50: 1, and up to 500: 1.
- LNG source 302 can be an LNG storage container similar to container 102 and/or the LNG rundown from the liquefaction plant, which comprises of the liquefied natural gas primary, or alternate, production stream, exiting the liquefaction system.
- both additional blend points can be present along with the LNG-ethane blend point 108.
- combined conduits 116 comprises both subsequent blending point 208 and subsequent blending point 308 as described in FIGS. 2 and 3, respectively.
- the blending ratio of (i) LNG to ethane at the LNG-ethane blending point 108 is in a range from 1 : 500, preferably from 1 : 100, and up to 50: 1
- (ii) the combined stream to the second LNG stream at the subsequent blending point 208 is in a range from 25: 1, preferably from 50:1, and up to 150: 1
- (iii) the combined stream to the LNG stream from second LNG source 302 at the subsequent blending point 308 is in a range from 100: 1, preferably from 150: 1, and up to 500:1.
- the network of conduits can comprise more than three blending points depicted in the figures (such as 108, 208, and 308) to achieve the desired operating pressure that is higher than the saturation pressure of the combined stream.
- the provided blending ratio ranges, for a multi -blending-points scenario can be extended or changed, to suit asset and/ or process specific requirements, as understood by one of ordinary skill.
- the first blending point (such as 108) may have a blending ratio of the first liquified hydrocarbon stream to the second liquified hydrocarbon stream of 1 : 1, while subsequent blending points (such as 208 and/or 308) may have a blending ratio of 47: 1 of the combined stream to the first liquified hydrocarbon stream.
- various blending scenarios (such as single or multi blending point) and blending ratio within the provided ranges can be selected to achieve the volumetric blending ratio of LNG to ethane of at least 2: 1, preferably at least 3:1, more preferably at least 4:1, in the combined stream that is downstream of final valve 126 (for a scenario involving a single blending point and/or multi-blending points with the subsequent blending point 208) or downstream of subsequent blending point 308 (for the scenarios that include blending point 308).
- the first LNG stream is pumped to the LNG-ethane blending point 108 at a volumetric flow rate and pressure, which may be adjusted throughout the blending operation to meet the relevant process requirements.
- the flow rate and pressure of the first LNG stream pumped to blending point 108 may be adjusted, it is preferred to minimize the rate of change in the operation of the first LNG stream to a reasonable and/or practical extent.
- the volumetric flow rate and pressure of the liquified ethane stream in ethane conduits 112 may be suitably adjusted, as known to one of ordinary skill, to meet the desired blending ratio at the LNG-ethane blending point 108, in a range from 1 :500, preferably from 1 : 100 to 500: 1 of LNG to liquefied ethane, for a single blending point, or the various ranges of blending ratios at other blending points in scenarios that include multi -blending points as described herein.
- Embodiments described in the present disclosure provide options for implementation, such as a selection between a single-point blending operation or a multi-point process, to allow for consideration of various factors in optimizing the blending operation as desired. For instance, at a facility with hydraulic limitations in a conduits segment that is upstream of the first blending point 108 (such as at least a portion of conduits 110 leading to the first blending point having a reduced inner diameter, such as one that is 12 inches or smaller or one that is smaller than the diameter of conduits 116 and/or conduits 112).
- a multi-point blending operation may be more suitable for such a scenario because such limitations can limit a single-point blending operation, such as in terms of flow rate and blending ratio possibilities (including a reduction of the amount of the second liquified hydrocarbon that can be blended) and higher operational costs.
- a multi-point blending operation allows for improve control and flexibility of the overall operation.
- combined conduits 116 continue through final valve 126 to provide the combined stream (which can be from single or multi blending point(s)) to blended- product storage container 106, which is downstream of final valve 126.
- Portion 116A of the combined conduits 116 is between the final valve 126 and blended-product storage container (106), particularly its inlet.
- the operating pressure of the combined conduits 116, including portionl l6A downstream of final stream 126 can be also influenced by manipulating the operating pressure of a blended-product storage container 106 that is in fluid communication with a vapor management system (not shown in the provided figures).
- the operating pressure of such container 106 can be increased or decreased by implementing a change on the boil off gas (BOG) management pressure setpoint of the container 106.
- BOG boil off gas
- the operating pressure of container 106 can be adjusted (increasing or decreasing) to influence the operating pressure of combined conduits 116, upstream and downstream of final valve 126, to mitigate or minimize two phase flow formation downstream of valve 126 and the inlet of container 106, as well as, to contribute to an increase in the operation pressure of 116 and 116A.
- the storage pressure of the blended-product storage container 106 provides another potential factor for consideration.
- the operating pressure of the combined stream downstream of final valve 126 can be reduced below the saturation pressure of the combined stream, through a reduction of the storage container 106 Boil Off Gas (BOG) management system pressure setpoint.
- the operating pressure of the combined stream downstream of final valve 126 can be indirectly (via the manipulation of the storage container 106 operating pressure) reduced to fall within the operational parameters of this portion of the combined conduits 116 and the storage pressure of the blended-product storage container 106.
- the pressure can be reduced by adjusting final valve 126, or through the manipulation of the storage container 106 BOG management system pressure setpoint, as known by one of ordinary skill.
- the blending operation can be further improved, such as a reduction in the amount of time to complete the blending operation, by providing a receiving storage container (a storage container to which the combined stream is being provided, such as container 102) with an operating pressure that is higher than the saturation pressure of the combined stream.
- a receiving storage container a storage container to which the combined stream is being provided, such as container 102
- the higher operating pressure is subject to limitations imposed by the safety operating parameters of the respective storage container.
- the operating pressure of the container receiving the combined stream is at least 5% higher, more preferably at least 50%, and most preferably at least 100% higher than the saturation pressure of the combined stream.
- a suitable way to provide such container with the operating pressure higher than the saturation pressure of the combined stream is to adjust the BOG pressure setpoint as known to one of ordinary skill.
- the option to provide a receiving storage container with a higher operating pressure than the saturation pressure of the combined stream is subject to limitations imposed by safety operating parameters of the respective storage container, is not typical in standard operational practice (primarily storage of liquified hydrocarbon for transport) for these storage containers, and it can be exercised as desired. If employed, the higher operating pressure is temporarily provided to the respective storage container during part or all of the duration of the blending operation, or even maintained after the blending operation, as desired.
- the operating pressure relatively low, preferably as low as possible within the relevant technical and contractual constraints, to maintain the temperature of the product in the storage container correspondingly low, thereby optimizing the volumetric capacity of the storage container and reducing BOG formation.
- the lower operating pressure is further desirable because it can help minimize changes in LNG quality over time. It is understood that the standard practice of keeping a low operating pressure for the receiving storage container is also available as an option for selection during part or all of the blending operation. Implementing a desired operating pressure for a particular receiving container is achieved primarily by managing the BOG of the respective container, which is typically done through the associated BOG management system.
- the flashing of the combined stream when it enters the respective storage container is reduced or even potentially eliminated, thereby minimizing or even eliminating the rate of boil off gas formation associated with the blending operation.
- a minimal or zero BOG formation rate during blending operation relaxes the constraints on the boil off gas management, which decreases the operational time.
- the operating pressure of the respective container may be reduced to return it to the standard operating pressure, or optionally maintained as per the relevant technical and contractual constraints impose to the vessel and its cargo.
- the BOG can be managed using standard operating procedures after blending operation, thereby allowing the blending operation to proceed without any time delays associated with the BOG management.
- the methods of the present disclosure address certain negative impacts of in-tank blending two different liquified hydrocarbons, such as stratification, by promoting the inline blending of two different liquified hydrocarbons in a conduit under an operating pressure that is higher than the saturation pressure of the combined stream. Because the saturation pressure of the combined stream can vary throughout its journey from the blending point 108 to its destination, such as back to container 102, reference to the “saturation pressure of the combined stream” is generally in the context of a particular segment of conduits.
- Adjusting the blending ratios and/or providing additional blending points as described herein are some suitable ways of manipulating the operating pressure of a relevant segment of conduits and/or influencing the saturation pressure of the combined stream in the relevant segment to achieve the desired level of operating pressure that is higher than the saturation pressure of the combined stream to ensure it stays in liquid state.
- the methods described herein further provide an option to minimize the BOG management requirements during the blending operation, thereby decreasing operational time of the blending operation, by providing the respective receiving storage container with an operating pressure that is higher than the saturation pressure of the combined stream to minimize flashing of the combined stream as it enters the respective storage container.
- the methods herein can be employed to conduct a blending operation of two streams of liquefied hydrocarbons, such as LNG and liquefied ethane, particularly at existing facility using the infrastructure already being used in standard operations, such as liquefaction and storage and loading. For instance, if it is desired to produce “rich” LNG at a particular LNG liquefaction facility, such as an export terminal or facility, the methods describe herein can be used to add liquefied ethane (or another lighter hydrocarbon or mixture of light hydrocarbons) to the LNG from the facility using existing infrastructure, such as pump equipment, conduits, and valves, etc. When the blending operation is desired, certain operating parameters of the facility can be changed to implement the methods described herein.
- the LNG facility is operated under its standard parameters to generate LNG.
- the product in storage container 102 is typically lean LNG that can be further enriched with another liquified hydrocarbon.
- another liquified hydrocarbon such as ethane
- the methods described herein can be employed with minimal changes to the existing infrastructure and ease of transition between blending mode and normal plant operation mode, such as liquefaction.
- the lean LNG from storage container 102 is preferably circulated in a similar manner as that of normal operation, including from the LNG from container 102 to the first blending point 108 and through combined conduits 116, into blended-product storage container 106, and back out either back to storage container 102 via recirculation conduits 126 and/or to another storage container (not shown) via line 132.
- Additional benefits of recirculating the LNG (i) prior to the addition of the second liquified hydrocarbon (such as liquified ethane) and (ii) during blending operation includes keeping the various conduits cold to minimize formation of vapor, particularly at blending point 108, and to facilitate mixing.
- the circulation of the lean LNG as described can be suitably facilitated by various pump equipment as known by one of ordinary skill, such as pumps 118, 120, and 130.
- the liquified ethane stream can be pumped from the ethane source 114 according to aspects described in the present disclosure to begin the blending operation.
- the combined stream can be provided to the blended-product storage container 106 according to aspects described herein, such as being provided to container 106 via conduits 116 at an operating pressure higher than the saturation pressure of the combined stream.
- the operating parameters of the blending operation as described herein impacts the operating pressure of the network of conduits as compared to standard operating parameters.
- the network of conduits is provided with an operating pressure of at least 2 bar g (bar gauge) to accommodate the impacts from the blending operation while meeting operational parameters. Suitable methods to provide the network of conduits with such operating pressure are known to one of ordinary skill.
- blended product in container 106 can be stored as inventory and/or routed elsewhere, depicted as line 132.
- the methods described herein can be carried out continuously over a period of time until the blended product in container 106 has desired specifications, such as a certain heating value.
- the properties of the blended product in container 106 can be monitored pursuant to standard operation of the facility to determine whether desired specifications have been achieved.
- the blended product from blended-product storage container 106 is recirculated back to the storage container 102 via conduits 128.
- the first LNG stream that is pumped to LNG-ethane blending point 108 comprises an increasing amount of ethane over time, which amount can be accounted for by adjusting the blending ratio at LNG-ethane blending point 108.
- LNG facilities typically include equipment to continuously monitor the properties of the LNG flowing through the network of conduits, including sensors (e.g., flow). The continuous monitor allows for continuous adjustment of flow of the respective streams, preferably the liquified ethane stream, to achieve desired blending ratios.
- the flow of the combined stream in the part of the combined conduits 116 upstream of final valve 126 is preferably carried out under turbulent flow regime.
- the methods provided herein which include in-line mixing of the first LNG stream and the liquified ethane stream, particularly under turbulent flow regime, can maximize mixing of the LNG and liquefied ethane in the combined stream, thereby enabling the combined stream to exhibit a homogenous composition and characteristics (e.g., density), such that it can be provided to the blended-product storage container 106 in homogenous condition, which mitigates the risk for fluid stratification.
- In-line blending operations can introduce partial vaporization with two-phase flow formation due to the difference in specific enthalpy of the lean LNG and liquid ethane streams, which can lead to the undesirable risk of excessive piping vibrations that lead to stress and fatigue of the pipes.
- the methods described herein address the potential two- phase flow formation by maintaining the operating pressure in the combined stream to be above the combined stream saturation pressure.
- a computer program can be used to control and/or implement some, including all, aspects of the methods described herein.
- This computer program may be referred to as a controller.
- the computer program can be used to control the pump discharge pressure and flow, the system operating pressure via the manipulation of the flow control valve opening percentage, among others.
- a suitable computer program includes one that is executed by a data processor.
- reference to a computer program is intended to be equivalent to a reference to a program element and/or a computer readable medium containing instructions for controlling a computer system to coordinate the performance of the above described method.
- the computer program may be implemented as computer readable instruction code by use of any suitable programming language, such as, for example, JAVA, C++, and may be stored on a computer-readable medium (removable disk, volatile or nonvolatile memory, embedded memory/processor, etc.).
- the instruction code is operable to program a computer or any other programmable device to carry out the intended functions.
- the computer program may be available from a network, such as the World Wide Web, from which it may be downloaded.
- the various aspects described herein may be realized by means of a computer program respectively software; however, they may also be realized by means of one or more specific electronic circuits respectively hardware.
- the invention may also be realized in a hybrid form, i.e. in a combination of software modules and hardware modules. Additionally or alternatively, any or all aspects of the methods described herein can be performed manually by one or more human operator with relevant operational knowledge of the facility.
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Abstract
Description
Claims
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP23167285 | 2023-04-11 | ||
| EP23167284 | 2023-04-11 | ||
| EP23167286 | 2023-04-11 | ||
| PCT/EP2024/058868 WO2024213429A1 (en) | 2023-04-11 | 2024-04-02 | Processes for blending two or more streams of liquified hydrocarbons |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP4695354A1 true EP4695354A1 (en) | 2026-02-18 |
Family
ID=90473340
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP24714203.7A Pending EP4695352A1 (en) | 2023-04-11 | 2024-04-02 | Processes for blending two or more streams of liquified hydrocarbons |
| EP24714204.5A Pending EP4695353A1 (en) | 2023-04-11 | 2024-04-02 | Processes for blending two or more streams of liquified hydrocarbons |
| EP24714523.8A Pending EP4695354A1 (en) | 2023-04-11 | 2024-04-02 | Processes for blending two or more streams of liquified hydrocarbons |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP24714203.7A Pending EP4695352A1 (en) | 2023-04-11 | 2024-04-02 | Processes for blending two or more streams of liquified hydrocarbons |
| EP24714204.5A Pending EP4695353A1 (en) | 2023-04-11 | 2024-04-02 | Processes for blending two or more streams of liquified hydrocarbons |
Country Status (11)
| Country | Link |
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| EP (3) | EP4695352A1 (en) |
| JP (2) | JP2026512108A (en) |
| KR (2) | KR20250171305A (en) |
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| AR (3) | AR132361A1 (en) |
| AU (2) | AU2024252710A1 (en) |
| MX (2) | MX2025012026A (en) |
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| TW (2) | TW202509199A (en) |
| UY (3) | UY40709A (en) |
| WO (3) | WO2024213429A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MY123311A (en) * | 1999-01-15 | 2006-05-31 | Exxon Production Research Co | Process for producing a pressurized methane-rich liquid from a methane-rich gas |
| US20050204625A1 (en) | 2004-03-22 | 2005-09-22 | Briscoe Michael D | Fuel compositions comprising natural gas and synthetic hydrocarbons and methods for preparation of same |
| US8381544B2 (en) | 2008-07-18 | 2013-02-26 | Kellogg Brown & Root Llc | Method for liquefaction of natural gas |
| US20140338393A1 (en) | 2013-05-13 | 2014-11-20 | Rustam H. Sethna | Methods for blending liquefied natural gas |
| JP5833070B2 (en) * | 2013-09-10 | 2015-12-16 | 中国電力株式会社 | Heterogeneous LNG receiving apparatus and heterogeneous LNG receiving method |
| JP2016147997A (en) * | 2015-02-13 | 2016-08-18 | 大阪瓦斯株式会社 | Heat amount control system for liquefied gas shipping facility |
| CA3103416C (en) | 2019-12-30 | 2022-01-25 | Marathon Petroleum Company Lp | Methods and systems for inline mixing of hydrocarbon liquids |
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2024
- 2024-04-02 WO PCT/EP2024/058868 patent/WO2024213429A1/en not_active Ceased
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| UY40710A (en) | 2024-11-15 |
| KR20250171304A (en) | 2025-12-08 |
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| EP4695352A1 (en) | 2026-02-18 |
| WO2024213432A1 (en) | 2024-10-17 |
| AU2024256055A1 (en) | 2025-10-09 |
| EP4695353A1 (en) | 2026-02-18 |
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| CN121002156A (en) | 2025-11-21 |
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| MX2025012081A (en) | 2025-11-03 |
| TW202509199A (en) | 2025-03-01 |
| UY40708A (en) | 2024-11-15 |
| AR132360A1 (en) | 2025-06-18 |
| AU2024252710A1 (en) | 2025-10-09 |
| JP2026512108A (en) | 2026-04-14 |
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