EP4610383A1 - Ferritic stainless steel with improved workability and ridging resistance and manufacturing method thereof - Google Patents

Ferritic stainless steel with improved workability and ridging resistance and manufacturing method thereof

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Publication number
EP4610383A1
EP4610383A1 EP23907406.5A EP23907406A EP4610383A1 EP 4610383 A1 EP4610383 A1 EP 4610383A1 EP 23907406 A EP23907406 A EP 23907406A EP 4610383 A1 EP4610383 A1 EP 4610383A1
Authority
EP
European Patent Office
Prior art keywords
stainless steel
ridging
ferritic stainless
cold
expression
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP23907406.5A
Other languages
German (de)
French (fr)
Other versions
EP4610383A4 (en
Inventor
Kayoung CHOI
Sangseok KIM
Donghoon Kim
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Posco Holdings Inc
Original Assignee
Posco Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Posco Co Ltd filed Critical Posco Co Ltd
Publication of EP4610383A1 publication Critical patent/EP4610383A1/en
Publication of EP4610383A4 publication Critical patent/EP4610383A4/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/002Heat treatment of ferrous alloys containing Cr
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0236Cold rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0273Final recrystallisation annealing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/004Very low carbon steels, i.e. having a carbon content of less than 0,01%
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/28Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite

Definitions

  • the present invention relates to a ferritic stainless steel with improved workability and ridging resistance and a method of manufacturing method thereof.
  • Ferritic stainless steels are steels that have excellent corrosion resistance while containing a lower amount of expensive alloying elements, offering superior cost competitiveness than austenitic stainless steels. Ferritic stainless steels are used in construction materials, transportation equipment, home appliances, and kitchen appliances.
  • Ferritic stainless steel cold-rolled products have ridge defects appearing as stripe-like patterns during forming processes such as deep drawing. Such ridging defects not only degrade the appearance of the product, but also increase the manufacturing costs because severe ridging defects require an additional polishing process after forming.
  • the present invention aims to provide a ferritic stainless steel with improved workability and ridging characteristics achieved by optimizing the steel composition and the manufacturing process to control the grain size of the final cold-rolled annealed material such that workability is enhanced, and a method of manufacturing the same.
  • a ferritic stainless steel with improved workability and ridging resistance includes, in percent by weight (wt%), 0.0005 to 0.02% of carbon (C); 0.01 to 0.2% of nitrogen (N); 0.01 to 1.0% of silicon (Si); 0.01 to 1.0% of manganese (Mn); 0.001 to 0.05% of phosphorus (P); 13.0 to 20.0% of chromium (Cr); 0.05 to 0.2% of titanium (Ti); and the balance being iron (Fe) and inevitable impurities, and satisfying Expression (1) below, and satisfying a grain size in a range of 20 to 25 ⁇ m: 2 * Ti / N ⁇ 2.3
  • the ferritic stainless steel with improved workability and ridging resistance according to an embodiment may have a ridging height of 10 ⁇ m or less measured after 15% tension.
  • the ferritic stainless steel with improved workability and ridging resistance according to an embodiment may have an elongation of 32% or more.
  • a method of manufacturing a ferritic stainless steel with improved workability and ridging resistance includes: preparing a slab comprising, in percent by weight (wt%), 0.0005 to 0.02% of carbon (C), 0.01 to 0.2% of nitrogen (N), 0.01 to 1.0% of silicon (Si), 0.01 to 1.0% of manganese (Mn), 0.001 to 0.05% of phosphorus (P), 13.0 to 20.0% of chromium (Cr), 0.05 to 0.2% of titanium (Ti), and the balance being iron (Fe) and inevitable impurities, and satisfying Expression (1) below; reheating the slab; hot-rolling the reheated slab, followed by hot-rolled annealing; and cold-rolling the hot-rolled steel sheet, followed by cold-rolled annealing at 800 to 850°C, 2 * Ti / N ⁇ 2.3
  • the reheating may be performed at 1,000 to 1,300°C.
  • the stainless steel may have a grain size satisfying a range of 20 to 25 ⁇ m.
  • the stainless steel may have a ridging height of 10 ⁇ m or less measured after 15% tension.
  • the stainless steel may have an elongation of 32% or more.
  • the present invention can provide a ferritic stainless steel with improved workability and ridging characteristics and a method of manufacturing the same by optimizing the steel composition and the manufacturing process to control the grain size of the final cold-rolled annealed material such that the workability of a cold-rolled product is enhanced.
  • a ferritic stainless steel with improved workability and ridging resistance may include, in percent by weight (wt%), 0.0005 to 0.02% of carbon (C); 0.01 to 0.2% of nitrogen (N); 0.01 to 1.0% of silicon (Si); 0.01 to 1.0% of manganese (Mn); 0.001 to 0.05% of phosphorus (P); 13.0 to 20.0% of chromium (Cr); 0.05 to 0.2% of titanium (Ti); and the balance being iron (Fe) and inevitable impurities, and satisfy Expression (1) below, and satisfy a grain size in a range of 20 to 25 ⁇ m: 2 * Ti / N ⁇ 2.3
  • a ferritic stainless steel with improved workability and ridging resistance may include, in percent by weight (wt%), 0.0005 to 0.02% of carbon (C); 0.01 to 0.2% of nitrogen (N); 0.01 to 1.0% of silicon (Si); 0.01 to 1.0% of manganese (Mn); 0.001 to 0.05% of phosphorus (P); 13.0 to 20.0% of chromium (Cr); 0.05 to 0.2% of titanium (Ti); and the balance being iron (Fe) and inevitable impurities.
  • the content of carbon (C) may be 0.0005 to 0.02 wt%, preferably 0.01 to 0.02 wt%.
  • C is an element that greatly affects the improvement of the strength of a steel.
  • amount of carbon (C) is less than 0.0005 wt%, the refining cost for producing a high-purity product may increase.
  • carbon content exceeds 0.02 wt%, corrosion resistance and formability may be degraded.
  • the content of nitrogen (N) may be 0.01 to 0.2 wt%, preferably 0.04 to 0.2 wt%.
  • Nitrogen is an element that forms nitrides and is present as an interstitial form, and thus excessive amounts of N may degrade impact toughness and formability. Considering this, the upper limit of the nitrogen content is limited to 0.2 wt% or less. However, when the content of nitrogen (N) is too low, TiN crystallization may decrease, which may reduce the equiaxed crystallinity of the slab.
  • the content of silicon (Si) may be 0.01 to 1.0 wt%, preferably 0.05 to 0.60 wt%.
  • Si may be added to deoxidize molten steel during steelmaking, and is an effective element for stabilizing ferrite.
  • the amount of silicon (Si) is less than 0.01 wt%, the refining cost may increase.
  • the silicon content exceeds 1.0 wt%, the amount of impurities may increase and formability may be degraded.
  • the content of manganese (Mn) may be 0.01 to 1.0 wt%, preferably 0.20 to 0.95 wt%.
  • Mn is an element that is effective in improving corrosion resistance.
  • the amount of manganese (Mn) is less than 0.01 wt%, the refining cost may increase, and when the amount of manganese (Mn) exceeds 1.0 wt%, the amount of impurities increase and thus the formability may be degraded.
  • the content of phosphorus (P) may be 0.001 to 0.05 wt%, preferably 0.001 to 0.020 wt%.
  • the amount of phosphorus (P) is less than 0.001 wt%, the refining cost may increase. However, when the content of phosphorus exceeds 0.05 wt%, the amount of impurities increases and the formability may be degraded.
  • the content of chromium (Cr) may be 13.0 to 20.0 wt%, preferably 13.5 to 17.5 wt%.
  • Cr is an element that is effective in ensuring the corrosion resistance of steel.
  • the amount of chromium (Cr) is less than 13.0 wt%, the corrosion resistance degrades. However, when the content of chromium exceeds 20.0 wt%, the formability may be degraded.
  • the content of titanium (Ti) may be 0.05 to 0.2 wt%, preferably 0.05 to 0.17 wt%.
  • Ti is an element that may preferentially combine with interstitial elements such as C and N to form precipitates.
  • the amount of titanium (Ti) is less than 0.05 wt%, it may be difficult to form Ti-based inclusions during manufacturing.
  • the titanium content is excessive, the Ti component reacts with oxygen, causing surface defects such as discoloring to yellow.
  • the remainder of the ferritic stainless steel according to the present invention is iron (Fe).
  • Fe iron
  • unintended impurities from raw materials or the surrounding environment may inevitably be introduced during typical manufacturing process, and thus cannot be excluded. Since such impurities may be well known to those skilled in the typical manufacturing process, details thereof are not specifically described in this specification.
  • ferritic stainless steel according to an embodiment may satisfy Expression (1) below. 2 * Ti / N ⁇ 2.3
  • the present invention is provided to form TiN precipitates by adjusting the contents of Ti and N to obtain a fine cast structure.
  • the value of 2*[Ti]/[N] in Expression (1) calculated based on the alloy composition exceeds 2.3, the amount of N available to combine with Ti becomes insufficient, thereby preventing refinement of the cast structure.
  • the value of 2*[Ti]/[N] in Expression (1) may be specifically 0.5 to 2.3, more specifically 1.0 to 2.3, and more specifically 1.7 to 2.3.
  • the ferritic stainless steel according to an embodiment of the present invention may have a further improved effect of controlling the microstructure, thereby having better workability and ridge resistance.
  • the ferritic stainless steel according to an embodiment may have a measured ridging height of 10 ⁇ m or less measured after being tensioned by 15% in a direction perpendicular to the rolling direction.
  • the ferritic stainless steel according to an embodiment may have an elongation of 32% or more, and preferably, a cold-rolled annealed steel sheet having a thickness of about 0.4 to 0.6 mm may have an elongation of 32% or more. A higher elongation may contribute to an improved workability.
  • both the ridging characteristics and elongation need to be satisfied. Since the steel sheet need to have good elongation during forming, it is preferable to satisfy an elongation of 32% or more while the ridging height is limited to about 10 ⁇ m or less, preferably 8.5 ⁇ m or less, in order to minimize streaks after processing and achieve a desired gloss.
  • the ferritic stainless steel according to an embodiment may satisfy a grain size of 20 to 25 ⁇ m, preferably 20 to 23 ⁇ m.
  • a method of manufacturing a ferritic stainless steel with improved workability and ridging resistance includes: preparing a slab including, in percent by weight (wt%), 0.0005 to 0.02% of carbon (C), 0.01 to 0.2% of nitrogen (N), 0.01 to 1.0% of silicon (Si), 0.01 to 1.0% of manganese (Mn), 0.001 to 0.05% of phosphorus (P), 13.0 to 20.0% of chromium (Cr), 0.05 to 0.2% of titanium (Ti), and the balance being iron (Fe) and inevitable impurities, and satisfying Expression (1) below; reheating the slab; hot-rolling the reheated slab, followed by hot-rolled annealing; and cold-rolling the hot-rolled steel sheet, followed by cold-rolled annealing. 2 * Ti / N ⁇ 2.3
  • a series of processes including reheating, hot rolling, hot-rolled annealing, cold rolling, and cold-rolled annealing may be performed.
  • the slab may be heated at a temperature of 1,000 to 1,300 °C in a hot rolling furnace, and then hot rolled to produce a hot rolled steel sheet.
  • the heating temperature When the heating temperature is low, it may be difficult to re-decompose coarse precipitates generated during slab manufacturing. Considering this, the heating temperature may be 1,000 °C or higher. However, when the heating temperature is excessively high, the internal grains may become overly coarse, and severe surface oxidation may occur, causing surface defects. Considering this, the upper limit of the heating temperature may be limited to 1,300°C.
  • the finish rolling may be performed at 700 to 900°C.
  • finish rolling temperature When the finish rolling temperature is less than 700°C, sticking bonds may occur on the sheet surface of the slab during hot rolling. However, when the finish rolling temperature exceeds 900°C, coarse ferrite grains may be formed, resulting in poor ridging resistance.
  • the hot-rolled steel sheet is subjected to hot-rolled annealing to recrystallize the cast structure.
  • the hot-rolled annealing may be performed at a temperature of 700 to 900°C.
  • the hot-rolled annealing temperature When the hot-rolled annealing temperature is low, the stress generated during hot rolling may not be sufficiently removed, resulting in poor workability. However, when the hot-rolled annealing temperature is excessively high, grain coarsening may occur, leading to lowered strength and degraded ridging resistance.
  • the hot-rolled steel sheet which has been subjected to the hot-rolled annealing, may be cold-rolled and then subjected to cold-rolled annealing to produce a cold-rolled steel sheet.
  • the cold-rolled annealing may be performed at a temperature of 800 to 850°C.
  • the grain size may be controlled to 20 to 25 ⁇ m.
  • the cold-rolled annealing temperature exceeds 850°C, the grain size becomes coarser, and structures having a ⁇ 001 ⁇ //ND crystal orientation, which reduce the ridging resistance, grows.
  • the growth of structures having a ⁇ 001 ⁇ //ND crystal orientation not only increases plastic anisotropy with respect to the matrix, thereby reducing the ridging resistance, but also degrades the surface roughness.
  • the cold-rolled annealing temperature is less than 800°C, recrystallization may not occur, leading to degradation in the elongation and the ridging resistance.
  • grain refinement in the casting structure may be realized, thereby ensuring ridging resistance and elongation of the ferritic stainless steel.
  • the stainless steel manufactured according to an embodiment may satisfy a grain size range of 20 to 25 ⁇ m. By satisfying the grain size range, a stainless steel with excellent workability with targeted workability and ridging resistance may be obtained.
  • the stainless steel manufactured according to an embodiment may have a measured ridging height of 10 ⁇ m or less after being tensioned by 15% in a direction perpendicular to the rolling direction. By satisfying the ridging height range, a stainless steel having a minimum stripe formation after processing and a desired gloss may be obtained.
  • the stainless steel manufactured according to an embodiment may have an elongation of 32% or more. By satisfying the elongation range, a stainless steel with excellent formability due to high elongation of steel material during forming may be obtained.
  • slabs were prepared in a vacuum induction melting furnace.
  • the prepared slabs were reheated in a heating furnace at 1,100 °C, hot-rolled to produce hot-rolled steel sheets, and then air-cooled.
  • the air-cooled, hot-rolled steel sheets were subjected to hot-rolled annealing at 850°C, and then cold-rolled to a thickness of 0.5 mm, and then subjected to cold-rolling annealing at a temperature shown in Table 2 below to produce cold-rolled steel sheet specimens.
  • [Ti] and [N] represent the content (wt%) of each element.
  • Table 2 below shows the average grain size in the cast structure, the ridging height measured after 15% tension, and the elongation of the steel having the alloy composition of Table 1, according to the cold-rolled annealing temperature.
  • FIG. 1 shows the correlation between the ridging height and the elongation of the steel having the alloy composition of Steel 3 according to the cold rolled annealing temperature.
  • the grain size was measured by photographing the cast structure with an optical microscopy (OM).
  • FIGS. 2A to 2E are photographs of the grain sizes of stainless steels having the alloy composition of Steel 3, which were treated at cold rolled annealing temperatures of 750°C, 800°C, 850°C, 900°C, and 950°C, respectively.
  • the ridging height was measured using a surface roughness tester after the specimen was tensioned by 15% in a direction perpendicular to the rolling direction of the specimen.
  • Steels 1, 2, 4, 7 and 8 have values of Expression (1) exceeding 2.3. Accordingly, even when the cold rolled annealing temperature falls within the range of 800 to 850°C, the content of N to be combined with Ti was low, and thus equiaxed grain refinement was not realized. Accordingly, it can be seen that the ridging resistance was also inferior.
  • a ferritic stainless steel with improved workability and ridging characteristics by optimizing the steel composition and the manufacturing process to control the grain size of the final cold-rolled annealed material such that the workability of a cold-rolled product is improved, and a method of manufacturing the same can be provided, and thus the present invention is considered to have the industrial applicability.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Sheet Steel (AREA)

Abstract

The present invention pertains to a ferritic stainless steel with improved workability and ridging resistance, and a manufacturing method thereof. A ferritic stainless steel with improved workability and ridging resistance according to an embodiment of the present invention contains, in wt%, 0.0005-0.02% of carbon (C), 0.01-0.2% of nitrogen (N), 0.01-1.0% of silicon (Si), 0.01-1.0% of manganese (Mn), 0.001-0.05% of phosphorus (P), 13.0-20.0% of chromium (Cr), and 0.05-0.2% of titanium (Ti), with the remainder comprising iron (Fe) and inevitable impurities, satisfies expression (1), and may have a grain size of 20 to 25 µm. Expression (1): 2*[Ti]/[N] ≤ 2.3 In expression (1), [Ti] and [N] refer to the content (in wt%) of the respective elements.

Description

    [Technical Field]
  • The present invention relates to a ferritic stainless steel with improved workability and ridging resistance and a method of manufacturing method thereof.
  • [Background Art]
  • Ferritic stainless steels are steels that have excellent corrosion resistance while containing a lower amount of expensive alloying elements, offering superior cost competitiveness than austenitic stainless steels. Ferritic stainless steels are used in construction materials, transportation equipment, home appliances, and kitchen appliances.
  • Ferritic stainless steel cold-rolled products have ridge defects appearing as stripe-like patterns during forming processes such as deep drawing. Such ridging defects not only degrade the appearance of the product, but also increase the manufacturing costs because severe ridging defects require an additional polishing process after forming.
  • In order to address the ridging defects, various manufacturing methods such as hot rolling at extremely low temperatures, low-speed rolling, and additional cold rolling have been proposed. However, the manufacturing methods proposed in the conventional technology are difficult to apply in the field, and increase manufacturing costs, thereby reducing the productivity of products.
  • [Disclosure] [Technical Problem]
  • The present invention aims to provide a ferritic stainless steel with improved workability and ridging characteristics achieved by optimizing the steel composition and the manufacturing process to control the grain size of the final cold-rolled annealed material such that workability is enhanced, and a method of manufacturing the same.
  • The technical objectives of the present invention are not limited to the above, and other objectives that are not described above will be clearly understood by those skilled in the art from the above detailed description.
  • [Solution to Problem]
  • A ferritic stainless steel with improved workability and ridging resistance according to an aspect of the present invention includes, in percent by weight (wt%), 0.0005 to 0.02% of carbon (C); 0.01 to 0.2% of nitrogen (N); 0.01 to 1.0% of silicon (Si); 0.01 to 1.0% of manganese (Mn); 0.001 to 0.05% of phosphorus (P); 13.0 to 20.0% of chromium (Cr); 0.05 to 0.2% of titanium (Ti); and the balance being iron (Fe) and inevitable impurities, and satisfying Expression (1) below, and satisfying a grain size in a range of 20 to 25 µm:
    2 * Ti / N 2.3
  • In Expression (1), [Ti] and [N] represent the content (wt%) of each element.
  • The ferritic stainless steel with improved workability and ridging resistance according to an embodiment may have a ridging height of 10 µm or less measured after 15% tension.
  • The ferritic stainless steel with improved workability and ridging resistance according to an embodiment may have an elongation of 32% or more.
  • A method of manufacturing a ferritic stainless steel with improved workability and ridging resistance according to an aspect of the present invention includes: preparing a slab comprising, in percent by weight (wt%), 0.0005 to 0.02% of carbon (C), 0.01 to 0.2% of nitrogen (N), 0.01 to 1.0% of silicon (Si), 0.01 to 1.0% of manganese (Mn), 0.001 to 0.05% of phosphorus (P), 13.0 to 20.0% of chromium (Cr), 0.05 to 0.2% of titanium (Ti), and the balance being iron (Fe) and inevitable impurities, and satisfying Expression (1) below; reheating the slab; hot-rolling the reheated slab, followed by hot-rolled annealing; and cold-rolling the hot-rolled steel sheet, followed by cold-rolled annealing at 800 to 850°C, 2 * Ti / N 2.3
  • In Expression (1), [Ti] and [N] represent the content (wt%) of each element.
  • In the method of manufacturing a ferritic stainless steel with improved workability and ridging resistance according to an embodiment, the reheating may be performed at 1,000 to 1,300°C.
  • In the method of manufacturing a ferritic stainless steel with improved workability and ridging resistance according to an embodiment, the stainless steel may have a grain size satisfying a range of 20 to 25 µm.
  • In the method of manufacturing a ferritic stainless steel with improved workability and ridging resistance according to an embodiment, the stainless steel may have a ridging height of 10 µm or less measured after 15% tension.
  • In the method of manufacturing a ferritic stainless steel with improved workability and ridging resistance according to an embodiment, the stainless steel may have an elongation of 32% or more.
  • [Advantageous Effects]
  • The present invention can provide a ferritic stainless steel with improved workability and ridging characteristics and a method of manufacturing the same by optimizing the steel composition and the manufacturing process to control the grain size of the final cold-rolled annealed material such that the workability of a cold-rolled product is enhanced.
  • [Description of Drawings]
    • FIG. 1 is a graph showing a ridging height (a solid line) and an elongation (a dotted line) as a function of the annealing temperature in a manufacturing of a stainless steel according to an embodiment.
    • FIG. 2A is a photograph showing the grain size of a stainless steel manufactured at a cold-rolled annealing temperature of 750°C.
    • FIG. 2B is a photograph showing the grain size of a stainless steel manufactured at a cold-rolled annealing temperature of 800°C.
    • FIG. 2C is a photograph showing the grain size of a stainless steel manufactured at a cold-rolled annealing temperature of 850°C.
    • FIG. 2D is a photograph showing the grain size of a stainless steel manufactured at a cold-rolled annealing temperature of 900°C.
    • FIG. 2E is a photograph showing the grain size of a stainless steel manufactured at a cold-rolled annealing temperature of 950°C.
    [Best Mode of the Invention]
  • A ferritic stainless steel with improved workability and ridging resistance according to an embodiment may include, in percent by weight (wt%), 0.0005 to 0.02% of carbon (C); 0.01 to 0.2% of nitrogen (N); 0.01 to 1.0% of silicon (Si); 0.01 to 1.0% of manganese (Mn); 0.001 to 0.05% of phosphorus (P); 13.0 to 20.0% of chromium (Cr); 0.05 to 0.2% of titanium (Ti); and the balance being iron (Fe) and inevitable impurities, and satisfy Expression (1) below, and satisfy a grain size in a range of 20 to 25 µm:
    2 * Ti / N 2.3
  • In Expression (1), [Ti] and [N] represent the content (wt%) of each element.
  • [Modes of the Invention]
  • Hereinafter, embodiments of the present disclosure will be described in detail with reference to the accompanying drawings. The embodiments of the present disclosure may, however, be embodied in many different forms and should not be construed as being limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the concept of the invention to those skilled in the art.
  • Also, the terms used herein are merely used to describe particular embodiments. An expression used in the singular encompasses the expression of the plural, unless otherwise indicated. Throughout the specification, the terms such as "including" or "having" are intended to indicate the existence of features, operations, functions, components, or combinations thereof disclosed in the specification, and are not intended to preclude the possibility that one or more other features, operations, functions, components, or combinations thereof may exist or may be added.
  • Meanwhile, unless otherwise defined, all terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this disclosure belongs. Thus, these terms should not be interpreted in an idealized or overly formal sense unless expressly so defined herein. As used herein, the singular forms are intended to include the plural forms as well, unless the context clearly indicates otherwise.
  • The terms "about", "substantially", etc. used throughout the specification means that when a natural manufacturing and a substance allowable error are suggested, such an allowable error corresponds the value or is similar to the value, and such values are intended for the sake of clear understanding of the present invention or to prevent an unconscious infringer from illegally using the disclosure of the present invention.
  • A ferritic stainless steel with improved workability and ridging resistance according to an aspect of the present invention, may include, in percent by weight (wt%), 0.0005 to 0.02% of carbon (C); 0.01 to 0.2% of nitrogen (N); 0.01 to 1.0% of silicon (Si); 0.01 to 1.0% of manganese (Mn); 0.001 to 0.05% of phosphorus (P); 13.0 to 20.0% of chromium (Cr); 0.05 to 0.2% of titanium (Ti); and the balance being iron (Fe) and inevitable impurities.
  • Hereinafter, the reason for limiting the composition range of each alloy element is described in more detail below. Unless otherwise specified, the units thereof are expressed in weight percent (wt%).
  • The content of carbon (C) may be 0.0005 to 0.02 wt%, preferably 0.01 to 0.02 wt%.
  • C is an element that greatly affects the improvement of the strength of a steel. When the amount of carbon (C) is less than 0.0005 wt%, the refining cost for producing a high-purity product may increase. However, when the carbon content exceeds 0.02 wt%, corrosion resistance and formability may be degraded.
  • The content of nitrogen (N) may be 0.01 to 0.2 wt%, preferably 0.04 to 0.2 wt%.
  • Nitrogen is an element that forms nitrides and is present as an interstitial form, and thus excessive amounts of N may degrade impact toughness and formability. Considering this, the upper limit of the nitrogen content is limited to 0.2 wt% or less. However, when the content of nitrogen (N) is too low, TiN crystallization may decrease, which may reduce the equiaxed crystallinity of the slab.
  • The content of silicon (Si) may be 0.01 to 1.0 wt%, preferably 0.05 to 0.60 wt%.
  • Si may be added to deoxidize molten steel during steelmaking, and is an effective element for stabilizing ferrite. When the amount of silicon (Si) is less than 0.01 wt%, the refining cost may increase. However, when the silicon content exceeds 1.0 wt%, the amount of impurities may increase and formability may be degraded.
  • The content of manganese (Mn) may be 0.01 to 1.0 wt%, preferably 0.20 to 0.95 wt%.
  • Mn is an element that is effective in improving corrosion resistance. When the amount of manganese (Mn) is less than 0.01 wt%, the refining cost may increase, and when the amount of manganese (Mn) exceeds 1.0 wt%, the amount of impurities increase and thus the formability may be degraded.
  • The content of phosphorus (P) may be 0.001 to 0.05 wt%, preferably 0.001 to 0.020 wt%.
  • When the amount of phosphorus (P) is less than 0.001 wt%, the refining cost may increase. However, when the content of phosphorus exceeds 0.05 wt%, the amount of impurities increases and the formability may be degraded.
  • The content of chromium (Cr) may be 13.0 to 20.0 wt%, preferably 13.5 to 17.5 wt%.
  • Cr is an element that is effective in ensuring the corrosion resistance of steel. When the amount of chromium (Cr) is less than 13.0 wt%, the corrosion resistance degrades. However, when the content of chromium exceeds 20.0 wt%, the formability may be degraded.
  • The content of titanium (Ti) may be 0.05 to 0.2 wt%, preferably 0.05 to 0.17 wt%.
  • Ti is an element that may preferentially combine with interstitial elements such as C and N to form precipitates. When the amount of titanium (Ti) is less than 0.05 wt%, it may be difficult to form Ti-based inclusions during manufacturing. When the titanium content is excessive, the Ti component reacts with oxygen, causing surface defects such as discoloring to yellow.
  • The remainder of the ferritic stainless steel according to the present invention is iron (Fe). However, unintended impurities from raw materials or the surrounding environment may inevitably be introduced during typical manufacturing process, and thus cannot be excluded. Since such impurities may be well known to those skilled in the typical manufacturing process, details thereof are not specifically described in this specification.
  • In addition, the ferritic stainless steel according to an embodiment may satisfy Expression (1) below. 2 * Ti / N 2.3
  • In Expression (1), [Ti] and [N] represent the content (wt%) of each element.
  • In order to improve the ridging resistance of stainless steel, the present invention is provided to form TiN precipitates by adjusting the contents of Ti and N to obtain a fine cast structure. When the value of 2*[Ti]/[N] in Expression (1) calculated based on the alloy composition exceeds 2.3, the amount of N available to combine with Ti becomes insufficient, thereby preventing refinement of the cast structure.
  • The value of 2*[Ti]/[N] in Expression (1) may be specifically 0.5 to 2.3, more specifically 1.0 to 2.3, and more specifically 1.7 to 2.3. Within the range, the ferritic stainless steel according to an embodiment of the present invention may have a further improved effect of controlling the microstructure, thereby having better workability and ridge resistance.
  • The ferritic stainless steel according to an embodiment may have a measured ridging height of 10 µm or less measured after being tensioned by 15% in a direction perpendicular to the rolling direction. In addition, the ferritic stainless steel according to an embodiment may have an elongation of 32% or more, and preferably, a cold-rolled annealed steel sheet having a thickness of about 0.4 to 0.6 mm may have an elongation of 32% or more. A higher elongation may contribute to an improved workability.
  • In order to have the workability of cold-rolled stainless steel products used for home appliances, both the ridging characteristics and elongation need to be satisfied. Since the steel sheet need to have good elongation during forming, it is preferable to satisfy an elongation of 32% or more while the ridging height is limited to about 10 µm or less, preferably 8.5 µm or less, in order to minimize streaks after processing and achieve a desired gloss.
  • The ferritic stainless steel according to an embodiment may satisfy a grain size of 20 to 25 µm, preferably 20 to 23 µm.
  • When the average grain size of the stainless steel is limited to 20 to 25 µm, a desired elongation and a desired ridging height may be satisfied simultaneously due to the refinement of the casting structure.
  • Next, a method of manufacturing a ferritic stainless steel with improved ridging resistance according to another aspect of the present invention will be described.
  • A method of manufacturing a ferritic stainless steel with improved workability and ridging resistance according to an aspect of the present invention includes: preparing a slab including, in percent by weight (wt%), 0.0005 to 0.02% of carbon (C), 0.01 to 0.2% of nitrogen (N), 0.01 to 1.0% of silicon (Si), 0.01 to 1.0% of manganese (Mn), 0.001 to 0.05% of phosphorus (P), 13.0 to 20.0% of chromium (Cr), 0.05 to 0.2% of titanium (Ti), and the balance being iron (Fe) and inevitable impurities, and satisfying Expression (1) below; reheating the slab; hot-rolling the reheated slab, followed by hot-rolled annealing; and cold-rolling the hot-rolled steel sheet, followed by cold-rolled annealing. 2 * Ti / N 2.3
  • In Expression (1), [Ti] and [N] represent the content (wt%) of each element.
  • The reasons for numerically limiting the component range of each alloy composition and the value of Expression (1) are as described above, and the following provides details of manufacturing operations.
  • First, after manufacturing a slab satisfying the above alloy composition, a series of processes including reheating, hot rolling, hot-rolled annealing, cold rolling, and cold-rolled annealing may be performed.
  • First, the slab may be heated at a temperature of 1,000 to 1,300 °C in a hot rolling furnace, and then hot rolled to produce a hot rolled steel sheet.
  • When the heating temperature is low, it may be difficult to re-decompose coarse precipitates generated during slab manufacturing. Considering this, the heating temperature may be 1,000 °C or higher. However, when the heating temperature is excessively high, the internal grains may become overly coarse, and severe surface oxidation may occur, causing surface defects. Considering this, the upper limit of the heating temperature may be limited to 1,300°C.
  • In the hot rolling, the finish rolling may be performed at 700 to 900°C.
  • When the finish rolling temperature is less than 700°C, sticking bonds may occur on the sheet surface of the slab during hot rolling. However, when the finish rolling temperature exceeds 900°C, coarse ferrite grains may be formed, resulting in poor ridging resistance.
  • The hot-rolled steel sheet is subjected to hot-rolled annealing to recrystallize the cast structure. In this case, the hot-rolled annealing may be performed at a temperature of 700 to 900°C.
  • When the hot-rolled annealing temperature is low, the stress generated during hot rolling may not be sufficiently removed, resulting in poor workability. However, when the hot-rolled annealing temperature is excessively high, grain coarsening may occur, leading to lowered strength and degraded ridging resistance.
  • The hot-rolled steel sheet, which has been subjected to the hot-rolled annealing, may be cold-rolled and then subjected to cold-rolled annealing to produce a cold-rolled steel sheet. In this case, the cold-rolled annealing may be performed at a temperature of 800 to 850°C.
  • By satisfying the cold-rolled annealing temperature, the grain size may be controlled to 20 to 25 µm. When the cold-rolled annealing temperature exceeds 850°C, the grain size becomes coarser, and structures having a {001}//ND crystal orientation, which reduce the ridging resistance, grows. The growth of structures having a {001 }//ND crystal orientation not only increases plastic anisotropy with respect to the matrix, thereby reducing the ridging resistance, but also degrades the surface roughness. However, when the cold-rolled annealing temperature is less than 800°C, recrystallization may not occur, leading to degradation in the elongation and the ridging resistance.
  • As described above, by optimizing the alloy composition and the composition relationship as well as the reheating, hot-rolled annealing, and cold-rolled annealing processes, grain refinement in the casting structure may be realized, thereby ensuring ridging resistance and elongation of the ferritic stainless steel.
  • The stainless steel manufactured according to an embodiment may satisfy a grain size range of 20 to 25 µm. By satisfying the grain size range, a stainless steel with excellent workability with targeted workability and ridging resistance may be obtained.
  • The stainless steel manufactured according to an embodiment may have a measured ridging height of 10 µm or less after being tensioned by 15% in a direction perpendicular to the rolling direction. By satisfying the ridging height range, a stainless steel having a minimum stripe formation after processing and a desired gloss may be obtained.
  • The stainless steel manufactured according to an embodiment may have an elongation of 32% or more. By satisfying the elongation range, a stainless steel with excellent formability due to high elongation of steel material during forming may be obtained.
  • Hereinafter, the present invention will be described in more detail through examples. However, the following examples are intended to further illustrate the present invention, and the scope of the present invention is not limited by the following examples.
  • [Examples]
  • For the various alloy composition ranges shown in Table 1 below, slabs were prepared in a vacuum induction melting furnace. The prepared slabs were reheated in a heating furnace at 1,100 °C, hot-rolled to produce hot-rolled steel sheets, and then air-cooled. The air-cooled, hot-rolled steel sheets were subjected to hot-rolled annealing at 850°C, and then cold-rolled to a thickness of 0.5 mm, and then subjected to cold-rolling annealing at a temperature shown in Table 2 below to produce cold-rolled steel sheet specimens.
  • In addition, Expression (1) below is calculated and the values of Expression (1) are show in Table 1 below. 2 * Ti / N
  • In Expression (1), [Ti] and [N] represent the content (wt%) of each element. [Table 1]
    Alloy composition (wt %)
    Class. C Si Mn P Cr Ti N Expr.(1) Remarks
    Steel 1 0.020 0.11 0.50 0.001 14.0 0.20 0.062 6.45 Comparative Example
    Steel 2 0.010 0.20 0.28 0.001 16.8 0.19 0.066 5.76
    Steel 3 0.020 0.24 0.81 0.006 16.2 0.17 0.196 1.73 Inventive Example
    Steel 4 0.015 0.15 0.88 0.007 15.8 0.30 0.080 7.50 Comparative Example
    Steel 5 0.020 0.20 0.64 0.001 14.9 0.14 0.146 1.92 Inventive Example
    Steel 6 0.018 0.28 0.70 0.003 16.5 0.16 0.150 2.13
    Steel 7 0.008 0.09 0.94 0.008 13.9 0.18 0.149 2.42 Comparative Example
    Steel 8 0.014 0.17 0.73 0.010 17.2 0.18 0.138 2.61
    Steel 9 0.020 0.55 0.90 0.015 16.0 0.05 0.045 2.23 Inventive Example
  • Table 2 below shows the average grain size in the cast structure, the ridging height measured after 15% tension, and the elongation of the steel having the alloy composition of Table 1, according to the cold-rolled annealing temperature. In addition, FIG. 1 shows the correlation between the ridging height and the elongation of the steel having the alloy composition of Steel 3 according to the cold rolled annealing temperature. The grain size was measured by photographing the cast structure with an optical microscopy (OM). FIGS. 2A to 2E are photographs of the grain sizes of stainless steels having the alloy composition of Steel 3, which were treated at cold rolled annealing temperatures of 750°C, 800°C, 850°C, 900°C, and 950°C, respectively. The ridging height was measured using a surface roughness tester after the specimen was tensioned by 15% in a direction perpendicular to the rolling direction of the specimen.
  • The elongation was calculated by dividing the amount of extension by the initial length during uniaxial tension of a cold-rolled stainless steel product at a time of fracture. [Table 2]
    Compositi on Cold-Rolled Annealing Temperature (°C) Grain Size (µm) Ridging Height (µm) Elongation (%) Remarks
    Steel 1 800 28.4 16.8 29.0 Comparative Example
    820 33.3 22.3 29.5
    850 41.9 29.2 32.6
    Steel 2 800 30.6 15.3 30.3 Comparative Example
    820 38.4 18.2 32.6
    850 45.5 18.9 33.5
    Steel 3 750 Unrecrystallized 12.5 16.9 Comparative Example
    800 20.8 8.4 32.0 Inventive Example
    820 21.3 8.2 32.2
    850 22.1 7.9 32.6
    880 28.5 10.1 33.4 Comparative Example
    900 31.2 10.3 34.2
    920 40.4 12.3 34.3
    950 44.8 12.8 34.5
    960 49.2 13.9 35.0
    Steel 4 800 31.2 18.2 28.6 Comparative Example
    820 39.8 19.6 33.1
    850 48.7 20.3 34.0
    Steel 5 800 20.9 8.6 32.3 Inventive Example
    820 21.5 8.9 33.5
    850 23.4 9.3 33.9
    Steel 6 800 21.3 9.0 32.0 Inventive Example
    820 21.9 9.2 32.5
    850 22.5 9.6 33.0
    Steel 7 800 29.0 19.2 30.0 Comparative Example
    820 31.5 19.5 30.9
    850 36.0 22.8 32.4
    Steel 8 800 32.6 18.4 31.1 Comparative
    820 38.8 19.9 31.3 Example
    850 44.1 22.6 32.5
    Steel 9 800 22.6 9.2 32.3 Inventive Example
    820 23.9 9.5 32.5
    850 24.0 9.7 33.0
  • Referring to Tables 1 and 2 above, Steels 3, 5, 6, and 9 satisfied the alloy composition, component range, and Expression (1) proposed in the present invention, and furthermore, when the cold rolled annealing temperature was satisfied, the grain size in the cast structure was refined to 20 to 25 µm (see FIGS. 2B and 2C), and the ridging height was 10 µm or less while the elongation was 32% or more. That is, it can be seen that the invention examples satisfying all of the alloy composition, component range, Expression (1), and cold rolled annealing temperature have excellent workability and ridging resistance. However, in the case of the comparative examples that do not satisfy the cold rolled annealing temperature even while satisfying the alloy composition, component range, and Expression (1) proposed in the present invention, one or more of the properties among the grain size, ridging height, or elongation were not satisfied.
  • Specifically, referring to FIGS. 1 and 2A, when the cold rolled annealing temperature was less than 800°C, recrystallization did not occur, resulting in a ridging height exceeding 10 µm and a significant decrease in elongation.
  • On the other hand, referring to FIGS. 1, 2D and 2E, when the cold rolled annealing temperature exceeded 850°C, the elongation was improved, but the grains in the cast structure coarsened, resulting in a ridging height exceeding 10 µm. That is, it can be seen that as the cold rolled annealing temperature increases, elongation is improved, but the cast structure coarsens, leading to an increase in ridging height.
  • In addition, Steels 1, 2, 4, 7 and 8 have values of Expression (1) exceeding 2.3. Accordingly, even when the cold rolled annealing temperature falls within the range of 800 to 850°C, the content of N to be combined with Ti was low, and thus equiaxed grain refinement was not realized. Accordingly, it can be seen that the ridging resistance was also inferior.
  • While exemplary embodiments of the present disclosure have been described above with reference to the accompanying drawings, it will be understood by those of ordinary skill in the art that various modifications and changes can be made without departing from the spirit and scope of the present disclosure as defined by the appended claims.
  • [Industrial applicability]
  • According to the present invention, a ferritic stainless steel with improved workability and ridging characteristics by optimizing the steel composition and the manufacturing process to control the grain size of the final cold-rolled annealed material such that the workability of a cold-rolled product is improved, and a method of manufacturing the same can be provided, and thus the present invention is considered to have the industrial applicability.

Claims (8)

  1. A ferritic stainless steel with improved workability and ridging resistance, comprising, in percent by weight (wt%), 0.0005 to 0.02% of carbon (C); 0.01 to 0.2% of nitrogen (N); 0.01 to 1.0% of silicon (Si); 0.01 to 1.0% of manganese (Mn); 0.001 to 0.05% of phosphorus (P); 13.0 to 20.0% of chromium (Cr); 0.05 to 0.2% of titanium (Ti); and the balance being iron (Fe) and inevitable impurities, and satisfying Expression (1) below, and satisfying a grain size in a range of 20 to 25 µm: 2 * Ti / N 2.3 In Expression (1), [Ti] and [N] represent the content (wt%) of each element.
  2. The ferritic stainless steel with improved workability and ridging resistance of claim 1, having a ridging height of 10 µm or less measured after 15% tension.
  3. The ferritic stainless steel with improved workability and ridging resistance of claim 1, having an elongation of 32% or more.
  4. A method of manufacturing a ferritic stainless steel with improved workability and ridging resistance, the method comprising
    preparing a slab comprising, in percent by weight (wt%), 0.0005 to 0.02% of carbon (C), 0.01 to 0.2% of nitrogen (N), 0.01 to 1.0% of silicon (Si), 0.01 to 1.0% of manganese (Mn), 0.001 to 0.05% of phosphorus (P), 13.0 to 20.0% of chromium (Cr), 0.05 to 0.2% of titanium (Ti), and the balance being iron (Fe) and inevitable impurities, and satisfying Expression (1) below;
    reheating the slab;
    hot-rolling the reheated slab, followed by hot-rolled annealing; and
    cold-rolling the hot-rolled steel sheet, followed by cold-rolled annealing at 800 to 850°C, 2 * Ti / N 2.3
    In Expression (1), [Ti] and [N] represent the content (wt%) of each element.
  5. The method of claim 4, wherein the reheating is performed at 1,000 to 1,300°C.
  6. The method of claim 4, wherein the stainless steel has a grain size satisfying a range of 20 to 25 µm.
  7. The method of claim 4, wherein the stainless steel has a ridging height of 10 µm or less measured after 15% tension.
  8. The method of claim 4, wherein the stainless steel has an elongation of 32% or more.
EP23907406.5A 2022-12-20 2023-11-08 FERRITIC STAINLESS STEEL WITH IMPROVED MACHINESABILITY AND ROUGHING RESISTANCE AND MANUFACTURING METHOD FOR IT Pending EP4610383A4 (en)

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