EP4502526A1 - Air conditioner - Google Patents
Air conditioner Download PDFInfo
- Publication number
- EP4502526A1 EP4502526A1 EP23780898.5A EP23780898A EP4502526A1 EP 4502526 A1 EP4502526 A1 EP 4502526A1 EP 23780898 A EP23780898 A EP 23780898A EP 4502526 A1 EP4502526 A1 EP 4502526A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- heat transfer
- fins
- fin
- transfer tube
- potential
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
- F28F21/08—Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
- F28F21/081—Heat exchange elements made from metals or metal alloys
- F28F21/084—Heat exchange elements made from metals or metal alloys from aluminium or aluminium alloys
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F1/00—Room units for air-conditioning, e.g. separate or self-contained units or units receiving primary air from a central station
- F24F1/0003—Room units for air-conditioning, e.g. separate or self-contained units or units receiving primary air from a central station characterised by a split arrangement, wherein parts of the air-conditioning system, e.g. evaporator and condenser, are in separately located units
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F13/00—Details common to, or for air-conditioning, air-humidification, ventilation or use of air currents for screening
- F24F13/30—Arrangement or mounting of heat-exchangers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/02—Tubular elements of cross-section which is non-circular
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F19/00—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
- F28F19/004—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using protective electric currents, voltages, cathodes, anodes, electric short-circuits
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F19/00—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
- F28F19/02—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings
- F28F19/06—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings of metal
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
- F28F21/08—Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
- F28F21/089—Coatings, claddings or bonding layers made from metals or metal alloys
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F1/00—Room units for air-conditioning, e.g. separate or self-contained units or units receiving primary air from a central station
- F24F1/0007—Indoor units, e.g. fan coil units
- F24F1/0059—Indoor units, e.g. fan coil units characterised by heat exchangers
- F24F1/0067—Indoor units, e.g. fan coil units characterised by heat exchangers by the shape of the heat exchangers or of parts thereof, e.g. of their fins
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D1/00—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
- F28D1/02—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid
- F28D1/04—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits
- F28D1/053—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits the conduits being straight
- F28D1/05316—Assemblies of conduits connected to common headers, e.g. core type radiators
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D1/00—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
- F28D1/02—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid
- F28D1/04—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits
- F28D1/053—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits the conduits being straight
- F28D1/0535—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits the conduits being straight the conduits having a non-circular cross-section
- F28D1/05366—Assemblies of conduits connected to common headers, e.g. core type radiators
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
- F28F1/12—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element
- F28F1/24—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending transversely
- F28F1/32—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending transversely the means having portions engaging further tubular elements
Definitions
- the present disclosure relates to an air conditioner.
- Patent Literature 1 WO 2017/141943 A
- a heat exchanger including a heat transfer tube through which a refrigerant flows and a fin fixed to the heat transfer tube is known.
- the heat exchanger of Patent Literature 1 includes an aluminum tube as a heat transfer tube and an aluminum fin as a fin, a natural potential on a surface of the aluminum tube is higher than a natural potential on a surface of the aluminum fin, and a potential difference between the two is from 30 mV to 200 mV.
- Patent Literature 1 cannot be used for an indoor unit in some cases.
- An air conditioner includes an outdoor unit and an indoor unit.
- the outdoor unit includes a first heat exchanger.
- the first heat exchanger includes a first heat transfer tube and a plurality of first fins.
- the first heat transfer tube is made of aluminum or an aluminum alloy.
- the plurality of first fins is made of aluminum or an aluminum alloy.
- the indoor unit includes a second heat exchanger.
- the second heat exchanger includes a second heat transfer tube and a plurality of second fins.
- the second heat transfer tube is made of s aluminum or an aluminum alloy.
- the plurality of second fins is made of aluminum or an aluminum alloy.
- a first sacrificial layer is provided on a surface of the first heat transfer tube.
- the first sacrificial layer is lower in potential than a base material of the first heat transfer tube and higher in potential than the first fins.
- the first fins contain zinc.
- a rate of zinc content of the first fin is higher than a rate of zinc content of the second fin.
- the first sacrificial layer which is lower in potential than the base material is provided in the first heat transfer tube made of aluminum or an aluminum alloy, corrosion of the base material can be suppressed. Since the first sacrificial layer is higher in potential than the first fins, corrosion of the first sacrificial layer for suppressing corrosion of the base material can be suppressed.
- the fins contain zinc in order to be lower in potential, the fins are cured, and thus workability of the fins is deteriorated. Therefore, in the air conditioner according to the first aspect, focusing on the fact that the first fins of the outdoor unit is not required to have workability as compared with the second fins of the indoor unit, the rate of zinc content of the first fin is set to be higher than the rate of zinc content of the second fin. As a result, workability of the second fin of the indoor unit can be secured, and thus the second heat exchanger including the second fins can be used for the indoor unit.
- An air conditioner according to a second aspect is the air conditioner according to the first aspect, in which a rate of zinc content of the first fin is 2% by mass or more.
- the rate of zinc content of the first fin of the outdoor unit by setting the rate of zinc content of the first fin of the outdoor unit to 2% by mass or more, it is possible to provide the first sacrificial layer having a potential that can suppress corrosion of the base material.
- An air conditioner according to a third aspect is the air conditioner according to the first or second aspect, in which the fin pitch of the second fins is larger than the fin pitch of the first fins.
- the second fin Since the second fin has a lower rate of zinc content than the first fin, the second fin are easily corroded. Therefore, in the air conditioner according to the third aspect, by making the fin pitch of the second fins larger than the fin pitch of the first fins, a surface area of the second fins in contact with the second heat transfer tubes can be reduced. As a result, corrosion of the second fins can be suppressed.
- An air conditioner according to a fourth aspect is the air conditioner according to the third aspect, in which a difference between the fin pitch of the first fins and the fin pitch of the second fins is 0.1 mm or more and 0.3 mm or less.
- the corrosion of the second fins can be further suppressed by setting the pitch difference to 0.1 mm or more and 0.3 mm or less.
- An air conditioner according to a fifth aspect is the air conditioner according to the first to fourth aspects, in which a potential of the first fins is lower than a potential of the second fins.
- the first heat exchanger of the outdoor unit is more susceptible to salt damage than the second heat exchanger of the indoor unit. Therefore, in the air conditioner according to the fifth aspect, by making the potential of the first fins lower than the potential of the second fins, the first fins are sacrificed in the first heat transfer tube, and therefore it is possible to further suppress corrosion of the first heat transfer tube.
- An air conditioner according to a sixth aspect is the air conditioner according to the first to fifth aspects, in which the second sacrificial layer that is lower in potential than a base material of the second heat transfer tube and lower in potential than the second fins is provided on the surface of the second heat transfer tube.
- the second heat exchanger of the indoor unit is less susceptible to salt damage than the first heat exchanger of the outdoor unit. Therefore, in the air conditioner according to the sixth aspect, even if the second sacrificial layer of the indoor unit is made lower in potential than the second fins, corrosion of the base material can be suppressed. In addition, it is possible to further suppress a decrease in workability of the second fins.
- An air conditioner according to a seventh aspect is the air conditioner according to the first to sixth aspects, in which the first heat transfer tube has a flat shape.
- the second heat transfer tube has a cylindrical shape.
- the fins attached to the cylindrical heat transfer tube are required to have workability as compared with the fins attached to the flat heat transfer tube. Therefore, in the air conditioner according to the seventh aspect, the second heat transfer tube of the indoor unit is required to have workability as compared with the first heat transfer tube of the outdoor unit. As a result, the air conditioner of the present disclosure is suitably used.
- An air conditioner includes an outdoor unit and an indoor unit.
- the outdoor unit includes a first heat exchanger.
- the first heat exchanger includes a first heat transfer tube and a plurality of first fins.
- the first heat transfer tube is made of aluminum or an aluminum alloy.
- the plurality of first fins is made of s aluminum or an aluminum alloy.
- the indoor unit includes a second heat exchanger.
- the second heat exchanger includes a second heat transfer tube and a plurality of second fins.
- the second heat transfer tube is made of aluminum or an aluminum alloy.
- the plurality of second fins is made of aluminum or an aluminum alloy.
- a first sacrificial layer is provided on a surface of the first heat transfer tube. The first sacrificial layer is lower in potential than a base material of the first heat transfer tube and higher in potential than the first fins. An elongation of the second fin is larger than an elongation of the first fin.
- the first sacrificial layer which is lower in potential than the base material is provided in the first heat transfer tube made of aluminum or an aluminum alloy, corrosion of the base material can be suppressed. Since the first sacrificial layer is higher in potential than the first fins, corrosion of the first sacrificial layer for suppressing corrosion of the base material can be suppressed.
- the air conditioner according to the eighth aspect focusing on the fact that the first fins of the outdoor unit are not required to have workability as compared with the second fins of the indoor unit, the elongation of the second fins is made larger than the elongation of the first fins. As a result, workability of the second fins of the indoor unit can be secured, and thus the second heat exchanger including the second fins can be used for the indoor unit.
- an air conditioner 1 includes an outdoor unit 2, an indoor unit 3, and a connection pipe 4.
- the outdoor unit 2 is installed outdoors.
- the indoor unit 3 is installed indoors.
- the indoor unit 3 is attached to an indoor wall surface or the like.
- the connection pipe 4 connects the outdoor unit 2 and the indoor unit 3.
- Such an air conditioner 1 can perform a cooling operation, a heating operation, and the like indoors.
- the outdoor unit 2 includes a first heat exchanger 200, a first fan 21, a first drain pan 22, and the like.
- the first fan 21 sucks outdoor air into the outdoor unit 2, supplies the outdoor air to the first heat exchanger 200, and then discharges the outdoor air to the outside of the outdoor unit 2.
- the first heat exchanger 200 exchanges heat between the outdoor air and a refrigerant.
- the first heat exchanger 200 is a heat exchanger that functions as a radiator for the refrigerant during the cooling operation, and functions as an evaporator for the refrigerant during the heating operation.
- the first drain pan 22 receives water.
- the indoor unit 3 includes a second heat exchanger 300, a second fan 31, a second drain pan 32, and the like.
- the second fan 31 sucks indoor air into the indoor unit 3, supplies the indoor air to the second heat exchanger 300, and then discharges the indoor air to the outside of the indoor unit 3.
- the second heat exchanger 300 exchanges heat between the refrigerant and the indoor air.
- the second heat exchanger 300 is a heat exchanger that functions as an evaporator for the refrigerant during the cooling operation, and functions as a radiator for the refrigerant during the heating operation.
- the second drain pan 32 receives water.
- the first heat exchanger 200 includes a plurality of first heat transfer tubes 210 and a plurality of first fins 220.
- the first heat transfer tubes 210 and the first fins 220 are made of aluminum or an aluminum alloy.
- the first heat exchanger 200 according to the present embodiment is of a microchannel heat exchanger.
- the first heat transfer tubes 210 each allow the refrigerant to flow therethrough. As illustrated in FIGS. 4 and 5 , the first heat transfer tube 210 has a flat shape. Here, the first heat transfer tube 210 is a flat porous tube. In the first heat transfer tube 210, a plurality of through holes through which the refrigerant heat-exchanged with the outdoor air in the first heat exchanger 200 passes is aligned in a predetermined direction. The plurality of through holes penetrates along a first direction.
- the first direction is a longitudinal direction.
- the first heat transfer tube 210 includes a first base material 211 and a first sacrificial layer 212.
- the first sacrificial layer 212 is provided on a surface of the first heat transfer tube 210.
- the first sacrificial layer 212 may be provided on the entire surface of the first heat transfer tube 210, or may be provided on a part of the surface of the first heat transfer tube 210 (not illustrated).
- the first sacrificial layer 212 may be formed on an entire exposed outer surface, or may be formed on a part of the exposed outer surface (not illustrated).
- the first sacrificial layer 212 is formed in a part in a thickness direction from the outer surface of the first heat transfer tube 210 toward an inner surface through which the refrigerant flows, and is not formed in an entire thickness. In other words, in the first heat transfer tube 210, the first sacrificial layer 212 is not formed on at least a part of the inner surface through which the refrigerant flows. In the present embodiment, the first sacrificial layer 212 is not formed on the entire inner surface of the first heat transfer tube 210.
- the first sacrificial layer 212 is lower in potential than the first base material 211 of the first heat transfer tube 210 and higher in potential than the first fin 220.
- the potential difference between the potential of the first sacrificial layer 212 and the potential of the first base material 211 is, for example, 132 mV.
- the potential difference between the potential of the first fin 220 and the potential of the first sacrificial layer 212 is, for example, 61 mV.
- the first sacrificial layer 212 contains a metal such as zinc (Zn) in order to lower the potential.
- the first sacrificial layer 212 according to the present embodiment is a zinc diffusion layer sprayed with zinc.
- the first sacrificial layer 212 on the outer surface side prevents a progress of corrosion of the first base material 211 on the inner surface side in the first heat transfer tube 210.
- the plurality of first heat transfer tubes 210 is aligned in an up-down direction. A lowermost end of the plurality of first heat transfer tubes 210 is located above a water level of the first drain pan 22 (see FIG. 2 ).
- the first fin 220 increases a heat transfer area between the first heat transfer tube 210 and the outdoor air to promote heat exchange between the refrigerant and the outdoor air.
- the first fin 220 is in contact with the first heat transfer tube 210.
- the first fin 220 is lower in potential than the first base material 211 of the first heat transfer tube 210 and lower in potential than the first sacrificial layer 212.
- the first base material 211, the first sacrificial layer 212, and the first fin 220 have higher potentials in that order.
- the potential difference between the potential of the first fin 220 and the potential of the first base material 211 is, for example, 193 mV.
- the first fin 220 contains a metal such as zinc in order to lower the potential.
- the metal is not limited, but the first fin 220 according to the present embodiment contains zinc.
- a rate of zinc content of the first fins 220 is preferably 2% by mass or more.
- An upper limit value of the rate of zinc content of the first fins 220 is not limited, but is, for example, 6% in terms of workability.
- the "rate of zinc content" described in the present specification is a value measured by, for example, an emission spectroscopic analysis method.
- the first fin 220 according to the present embodiment further contains magnesium (Mg) and copper (Cu).
- the plurality of first fins 220 is stacked in the first direction (see FIG. 4 ) in which the first heat transfer tubes 210 extend.
- the plurality of first fins 220 extends in the up-down direction so as to cross (be orthogonal to in FIG. 4 ) the first heat transfer tubes 210.
- the plurality of first fins 220 is disposed in parallel and at equal intervals. In other words, the plurality of first fins 220 is aligned in the first direction at a predetermined fin pitch P1.
- the first fin 220 is a flat plate-shaped member.
- the first fin 220 has a notch through which the first heat transfer tube 210 passes. The notches are aligned in the first direction. Note that the first fin 220 may have a collar.
- the first heat exchanger 200 of the outdoor unit 2 may further include a fillet that connects the first heat transfer tubes 210 and the first fins 220.
- the potential of the fillet is not limited, but in the present embodiment, the first base material 211, the first sacrificial layer 212, the fillet, and the first fin 220 have higher potentials in that order.
- the second heat exchanger 300 includes a plurality of second heat transfer tubes 310 and a plurality of second fins 320.
- the second heat transfer tubes 310 and the second fins 320 are made of aluminum or an aluminum alloy.
- the second heat exchanger 300 according to the present embodiment is a cross-fin-tube heat exchanger.
- the second heat transfer tubes 310 each allow the refrigerant to flow therethrough.
- the second heat transfer tube 310 has a cylindrical shape.
- the second heat transfer tube 310 is a round tube.
- the second heat transfer tube 310 is provided with a through hole through which the refrigerant that exchanges heat with the indoor air in the second heat exchanger 300 passes.
- the through hole of the second heat transfer tube 310 penetrates along a second direction.
- the second direction is a longitudinal direction.
- the second heat transfer tube 310 includes a second base material 311 and a second sacrificial layer 312.
- the second sacrificial layer 312 is provided on a surface of the second heat transfer tube 310.
- the second sacrificial layer 312 may be provided on the entire surface of the second heat transfer tube 310 (not illustrated), or may be provided on a part of the surface of the second heat transfer tube 310.
- the second sacrificial layer 312 may be formed on an entire exposed outer surface (not illustrated), or may be formed on a part of the exposed outer surface.
- the second sacrificial layer 312 is formed in a part in a thickness direction from the outer surface of the second heat transfer tube 310 toward an inner surface through which the refrigerant flows, and is not formed in an entire thickness. In other words, in the second heat transfer tube 310, the second sacrificial layer 312 is not formed on at least a part of the inner surface through which the refrigerant flows. In the present embodiment, the second sacrificial layer 312 is not formed on the entire inner surface of the second heat transfer tube 310.
- the second sacrificial layer 312 is lower in potential than the second base material 311 of the second heat transfer tube 310 and lower in potential than the second fin 320.
- the second sacrificial layer 312 contains a metal such as zinc in order to lower the potential.
- the second sacrificial layer 312 according to the present embodiment is a zinc diffusion layer sprayed with zinc.
- the second sacrificial layer 312 on the outer surface side prevents a progress of corrosion of the second base material 311 on the inner surface side in the second heat transfer tube 310.
- the plurality of second heat transfer tubes 310 is aligned in an up-down direction. A lowermost end of each of the plurality of second heat transfer tubes 310 is located above a water level of the second drain pan 32 (see FIG. 3 ).
- the second fin 320 increases a heat transfer area between the second heat transfer tube 310 and the indoor air to promote heat exchange between the refrigerant and the indoor air.
- the second fin 320 is in contact with the second heat transfer tube 310.
- the second fin 320 is lower in potential than the second base material 311 of the second heat transfer tube 310 and higher in potential than the second sacrificial layer 312.
- the second base material 311, the second fin 320, and the second sacrificial layer 312 have higher potentials in that order.
- the second fin 320 contains a metal such as zinc in order to lower the potential.
- the second fin 320 may or is not required to contain zinc.
- the rate of zinc content of the second fins 320 is, for example, 0% by mass or more and 1% by mass or less.
- the plurality of second fins 320 is stacked in the second direction (see FIG. 6 ) in which the second heat transfer tubes 310 extend.
- the plurality of second fins 320 extends in the up-down direction so as to cross (be orthogonal to in FIG. 6 ) the second heat transfer tubes 310.
- the plurality of second fins 320 is disposed in parallel and at equal intervals. In other words, the plurality of second fins 320 is aligned in the second direction at a predetermined fin pitch P2.
- the plurality of second fins 320 each includes a fin body 321 and a second collar 322.
- the fin body 321 is a flat plate-shaped member.
- the second collar 322 allows the second heat transfer tube 310 to pass therethrough.
- the second collar 322 has a through hole through which the second heat transfer tube 310 passes.
- the second collar 322 includes a first upright portion 323, a flat portion 324, a second upright portion 325, and a flange 326.
- the first upright portion 323, the flat portion 324, the second upright portion 325, and the flange 326 are constituted by one member.
- the first upright portion 323, the flat portion 324, the second upright portion 325, and the flange 326 are constituted by nesting.
- the first upright portion 323 extends in the second direction from the fin body 321.
- the first upright portion 323 is orthogonal to the fin body 321.
- a coupling portion between the first upright portion 323 and the fin body 321 has a curved (R) shape.
- the flat portion 324 extends from the first upright portion 323 toward the second heat transfer tube 310.
- the flat portion 324 is orthogonal to the first upright portion 323.
- a coupling portion between flat portion 324 and first upright portion 323 has a curved shape.
- the second upright portion 325 extends from the flat portion 324 along the second heat transfer tube 310.
- the second upright portion 325 is in contact with the second heat transfer tube 310.
- the second upright portion 325 is orthogonal to the flat portion 324.
- a coupling portion between second upright portion 325 and flat portion 324 has a curved shape.
- the flange 326 extends outward from the second upright portion 325.
- the flange 326 is orthogonal to the second upright portion 325.
- the coupling portion between the flange 326 and the second upright portion 325 has a curved shape.
- One flat portion 324 is in contact with the flange 326 of another adjacent second fin 320.
- the flat portion 324 and the flange 326 extend in the same direction.
- the second fin 320 according to the present embodiment is required to have high workability.
- An elongation of the second fin 320 is larger than an elongation of the first fin 220.
- “elongation” of the present disclosure conforms to JIS H4000.
- a rate of zinc content of the first fins 220 is higher than a rate of zinc content of the second fins 320.
- the rate of zinc content of the first fins 220 is higher than the rate of zinc content of the second fins 320 by 1% by mass or more.
- the potential of the first fin 220 is lower than the potential of the second fin 320.
- the potential of the first fin 220 is lower than the potential of the second fin 320 by 10 mV or more.
- the potential is adjusted by, for example, a type, content by rate, content by amount, or the like of a metal that is lower in potential.
- the fin pitch P2 of the second fins 320 illustrated in FIG. 6 is larger than the fin pitch P1 of the first fins 220 illustrated in FIG. 4 .
- the fin pitch P1 is a distance between the adjacent first fins 220.
- the fin pitch P1 is a distance between opposing faces of the adjacent first fins 220.
- the fin pitch P2 is a distance between the adjacent second fins 320.
- the fin pitch P2 is a distance between opposing faces of the adjacent second fins 320.
- a difference between the fin pitch P1 of the first fins 220 and the fin pitch P2 of the second fins 320 is 0.1 mm or more and 0.3 mm or less.
- a pitch difference (fin pitch P2 - fin pitch P 1) is 0.1 mm or more and 0.3 mm or less.
- the fin pitch P1 of the first fins 220 is, for example, 1.2 mm or more and 1.4 mm or less.
- the fin pitch P2 of the second fins 320 is, for example, 1.3 mm or more and 1.5 mm or less.
- the air conditioner 1 includes the outdoor unit 2 and the indoor unit 3.
- the outdoor unit 2 includes the first heat exchanger 200.
- the first heat exchanger 200 includes the first heat transfer tube 210 and the plurality of first fins 220.
- the first heat transfer tubes 210 are made of aluminum or an aluminum alloy.
- the plurality of first fins 220 is made of aluminum or an aluminum alloy.
- the indoor unit 3 includes the second heat exchanger 300.
- the second heat exchanger 300 includes the second heat transfer tube 310 and the plurality of second fins 320.
- the second heat transfer tubes 310 are made of aluminum or an aluminum alloy.
- the plurality of second fins 320 is made of aluminum or an aluminum alloy.
- the first sacrificial layer 212 is provided on the surface of the first heat transfer tube 210.
- the first sacrificial layer 212 is lower in potential than the first base material 211 of the first heat transfer tube 210 and higher in potential than the first fin 220.
- the first fins 220 contain zinc.
- a rate of zinc content of the first fin 220 is higher than a rate of zinc content of the second fins 320.
- the first sacrificial layer 212 which is lower in potential than the first base material 211 is provided in the first heat transfer tube 210 made of aluminum or an aluminum alloy, corrosion of the first base material 211 can be suppressed. Since the first sacrificial layer 212 is higher in potential than the first fin 220, corrosion of the first sacrificial layer 212 for suppressing corrosion of the first base material 211 can be suppressed.
- the present inventor has focused on the fact that the second fin 320 of the indoor unit 3 has a high degree of processing difficulty for reasons such as compactness and bending. In other words, the present inventor has paid attention to the fact that the first fin 220 of the outdoor unit 2 is not required to have workability as compared with the second fin 320 of the indoor unit 3. Therefore, in the air conditioner 1 according to the present embodiment, the rate of zinc content of the first fin 220 is higher than the rate of zinc content of the second fin 320. As a result, workability of the second fin 320 of the indoor unit 3 can be secured, and thus the second heat exchanger 300 including the second fin 320 can be used for the indoor unit 3.
- the second fins 320 have less a rate of zinc content than the first fins 220, the second fins are easily corroded. Therefore, here, by making the fin pitch P2 of the second fins 320 larger than the fin pitch P1 of the first fins 220, the number of the second fins 320 can be reduced, and a surface area of the second fins 320 in contact with the second heat transfer tubes 310 can be reduced. As a result, corrosion of the second fins 320 can be suppressed.
- the second fin 320 of the indoor unit 3 is required to have high workability. Therefore, by reducing the number of second fins 320, it is possible to reduce a burden associated with processing.
- the first heat exchanger 200 of the outdoor unit 2 is more susceptible to salt damage than the second heat exchanger 300 of the indoor unit 3. Therefore, here, by making the potential of the first fins 220 lower than the potential of the second fins 320, the first fins 220 are sacrificed in the first heat transfer tube210, and therefore it is possible to further suppress corrosion of the first heat transfer tube 210.
- the second sacrificial layer 312 that is lower in potential than the second base material 311 of the second heat transfer tube 310 and lower in potential than the second fin 320 is provided on the surface of the second heat transfer tube 310.
- the second heat exchanger 300 of the indoor unit 3 is less susceptible to salt damage than the first heat exchanger 200 of the outdoor unit 2. Therefore, here, even if the second sacrificial layer 312 of the indoor unit 3 is made lower in potential than the second fins 320, corrosion of the second base material 311 can be suppressed. In addition, it is possible to further suppress a decrease in workability of the second fin 320.
- the first heat transfer tube 210 has a flat shape.
- the second heat transfer tube 310 has a cylindrical shape.
- the second fin 320 attached to the cylindrical second heat transfer tube 310 is required to have higher workability than the first fin 220 attached to the flat first heat transfer tube 210.
- the second heat transfer tube 310 of the indoor unit 3 is required to have higher workability than the first heat transfer tube 210 of the outdoor unit 2. Therefore, the air conditioner 1 according to the present embodiment can be suitably used for the air conditioner 1 including the first heat exchanger 200 having the first heat transfer tube 210 of a flat shape and the second heat exchanger 300 having the second heat transfer tube 310 of a cylindrical shape.
- the air conditioner 1 includes the outdoor unit 2 and the indoor unit 3.
- the outdoor unit 2 includes the first heat exchanger 200.
- the first heat exchanger 200 includes the first heat transfer tube 210 and the plurality of first fins 220.
- the first heat transfer tubes 210 is made of aluminum or an aluminum alloy.
- the plurality of first fins 220 is made of aluminum or an aluminum alloy.
- the indoor unit 3 includes the second heat exchanger 300.
- the second heat exchanger 300 includes the second heat transfer tube 310 and the plurality of second fins 320.
- the second heat transfer tubes 310 is made of aluminum or an aluminum alloy.
- the plurality of second fins 320 is made of aluminum or an aluminum alloy.
- the first sacrificial layer 212 is provided on the surface of the first heat transfer tube 210.
- the first sacrificial layer 212 is lower in potential than the first base material 211 of the first heat transfer tube 210 and higher in potential than the first fin 220.
- An elongation of the second fin 320 is larger than an elongation of the first fin 220.
- the first sacrificial layer 212 which is lower in potential than the first base material 211 is provided in the first heat transfer tube 210 made of aluminum or an aluminum alloy, corrosion of the first base material 211 can be suppressed. Since the first sacrificial layer 212 is higher in potential than the first fin 220, corrosion of the first sacrificial layer 212 for suppressing corrosion of the first base material 211 can be suppressed.
- the air conditioner 1 focusing on the fact that the first fin 220 of the outdoor unit 2 is not required to have workability as compared with the second fin 320 of the indoor unit 3, the elongation of the second fin 320 is made larger than the elongation of the first fin 220. As a result, workability of the second fin 320 of the indoor unit 3 can be secured, and thus the second heat exchanger 300 including the second fin 320 can be used for the indoor unit 3.
- the first sacrificial layer 212 of the first heat transfer tube 210 and the second sacrificial layer 312 of the second heat transfer tube 310 have been described by taking a diffusion layer sprayed with zinc as an example, but the present disclosure is not limited thereto.
- a clad material is used as the base material and the sacrificial layer.
- the first heat transfer tube 210 is formed by using a clad material in which a metal to be the first base material 211 and a metal to be the first sacrificial layer 212 are bonded together.
- the second heat transfer tube 310 is formed by using a clad material in which a metal to be the second base material 311 and a metal to be the second sacrificial layer 312 are bonded together.
- the second base material 311, the second fin 320, and the second sacrificial layer 312 are higher in potential in that order, but the present disclosure is not limited thereto.
- the second base material 311, the second sacrificial layer 312, and the second fin 320 are higher in potential in that order in the second heat exchanger 300 of the indoor unit 3.
- the second heat transfer tube 310 of the indoor unit 3 includes the second sacrificial layer 312, but in this modification, the second sacrificial layer 312 is omitted.
- the second heat transfer tubes 310 are higher in potential than the second fins 320, corrosion of the second heat transfer tubes 310 can be still suppressed.
- the first heat exchanger 200 is a microchannel heat exchanger
- the second heat exchanger 300 is a cross-fin-tube heat exchanger, but the present invention is not limited thereto.
- the first heat exchanger 200 may be a cross-fin-tube heat exchanger
- the second heat exchanger 300 may be a microchannel heat exchanger.
- the first heat transfer tubes 210 and the second heat transfer tubes 310 can be made common.
- Patent Literature 1 WO 2017/141943 A
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Abstract
Description
- The present disclosure relates to an air conditioner.
- Conventionally, as disclosed in Patent Literature 1 (
WO 2017/141943 A ), a heat exchanger including a heat transfer tube through which a refrigerant flows and a fin fixed to the heat transfer tube is known. The heat exchanger ofPatent Literature 1 includes an aluminum tube as a heat transfer tube and an aluminum fin as a fin, a natural potential on a surface of the aluminum tube is higher than a natural potential on a surface of the aluminum fin, and a potential difference between the two is from 30 mV to 200 mV. - However, the present inventor has found a problem that the heat exchanger of
Patent Literature 1 cannot be used for an indoor unit in some cases. - An air conditioner according to a first aspect includes an outdoor unit and an indoor unit. The outdoor unit includes a first heat exchanger. The first heat exchanger includes a first heat transfer tube and a plurality of first fins. The first heat transfer tube is made of aluminum or an aluminum alloy. The plurality of first fins is made of aluminum or an aluminum alloy. The indoor unit includes a second heat exchanger. The second heat exchanger includes a second heat transfer tube and a plurality of second fins. The second heat transfer tube is made of s aluminum or an aluminum alloy. The plurality of second fins is made of aluminum or an aluminum alloy. A first sacrificial layer is provided on a surface of the first heat transfer tube. The first sacrificial layer is lower in potential than a base material of the first heat transfer tube and higher in potential than the first fins. The first fins contain zinc. A rate of zinc content of the first fin is higher than a rate of zinc content of the second fin.
- In the air conditioner according to the first aspect, since the first sacrificial layer which is lower in potential than the base material is provided in the first heat transfer tube made of aluminum or an aluminum alloy, corrosion of the base material can be suppressed. Since the first sacrificial layer is higher in potential than the first fins, corrosion of the first sacrificial layer for suppressing corrosion of the base material can be suppressed.
- However, when the fins contain zinc in order to be lower in potential, the fins are cured, and thus workability of the fins is deteriorated. Therefore, in the air conditioner according to the first aspect, focusing on the fact that the first fins of the outdoor unit is not required to have workability as compared with the second fins of the indoor unit, the rate of zinc content of the first fin is set to be higher than the rate of zinc content of the second fin. As a result, workability of the second fin of the indoor unit can be secured, and thus the second heat exchanger including the second fins can be used for the indoor unit.
- An air conditioner according to a second aspect is the air conditioner according to the first aspect, in which a rate of zinc content of the first fin is 2% by mass or more.
- In the air conditioner according to the second aspect, by setting the rate of zinc content of the first fin of the outdoor unit to 2% by mass or more, it is possible to provide the first sacrificial layer having a potential that can suppress corrosion of the base material.
- An air conditioner according to a third aspect is the air conditioner according to the first or second aspect, in which the fin pitch of the second fins is larger than the fin pitch of the first fins.
- Since the second fin has a lower rate of zinc content than the first fin, the second fin are easily corroded. Therefore, in the air conditioner according to the third aspect, by making the fin pitch of the second fins larger than the fin pitch of the first fins, a surface area of the second fins in contact with the second heat transfer tubes can be reduced. As a result, corrosion of the second fins can be suppressed.
- An air conditioner according to a fourth aspect is the air conditioner according to the third aspect, in which a difference between the fin pitch of the first fins and the fin pitch of the second fins is 0.1 mm or more and 0.3 mm or less.
- In the air conditioner according to the fourth aspect, the corrosion of the second fins can be further suppressed by setting the pitch difference to 0.1 mm or more and 0.3 mm or less.
- An air conditioner according to a fifth aspect is the air conditioner according to the first to fourth aspects, in which a potential of the first fins is lower than a potential of the second fins.
- The first heat exchanger of the outdoor unit is more susceptible to salt damage than the second heat exchanger of the indoor unit. Therefore, in the air conditioner according to the fifth aspect, by making the potential of the first fins lower than the potential of the second fins, the first fins are sacrificed in the first heat transfer tube, and therefore it is possible to further suppress corrosion of the first heat transfer tube.
- An air conditioner according to a sixth aspect is the air conditioner according to the first to fifth aspects, in which the second sacrificial layer that is lower in potential than a base material of the second heat transfer tube and lower in potential than the second fins is provided on the surface of the second heat transfer tube.
- The second heat exchanger of the indoor unit is less susceptible to salt damage than the first heat exchanger of the outdoor unit. Therefore, in the air conditioner according to the sixth aspect, even if the second sacrificial layer of the indoor unit is made lower in potential than the second fins, corrosion of the base material can be suppressed. In addition, it is possible to further suppress a decrease in workability of the second fins.
- An air conditioner according to a seventh aspect is the air conditioner according to the first to sixth aspects, in which the first heat transfer tube has a flat shape. The second heat transfer tube has a cylindrical shape.
- The fins attached to the cylindrical heat transfer tube are required to have workability as compared with the fins attached to the flat heat transfer tube. Therefore, in the air conditioner according to the seventh aspect, the second heat transfer tube of the indoor unit is required to have workability as compared with the first heat transfer tube of the outdoor unit. As a result, the air conditioner of the present disclosure is suitably used.
- An air conditioner according to an eight aspect includes an outdoor unit and an indoor unit. The outdoor unit includes a first heat exchanger. The first heat exchanger includes a first heat transfer tube and a plurality of first fins. The first heat transfer tube is made of aluminum or an aluminum alloy. The plurality of first fins is made of s aluminum or an aluminum alloy. The indoor unit includes a second heat exchanger. The second heat exchanger includes a second heat transfer tube and a plurality of second fins. The second heat transfer tube is made of aluminum or an aluminum alloy. The plurality of second fins is made of aluminum or an aluminum alloy. A first sacrificial layer is provided on a surface of the first heat transfer tube. The first sacrificial layer is lower in potential than a base material of the first heat transfer tube and higher in potential than the first fins. An elongation of the second fin is larger than an elongation of the first fin.
- In the air conditioner according to the eighth aspect, since the first sacrificial layer which is lower in potential than the base material is provided in the first heat transfer tube made of aluminum or an aluminum alloy, corrosion of the base material can be suppressed. Since the first sacrificial layer is higher in potential than the first fins, corrosion of the first sacrificial layer for suppressing corrosion of the base material can be suppressed.
- However, when the fins are lower in potential, the fins are cured, and thus workability of the fins is deteriorated. Therefore, in the air conditioner according to the eighth aspect, focusing on the fact that the first fins of the outdoor unit are not required to have workability as compared with the second fins of the indoor unit, the elongation of the second fins is made larger than the elongation of the first fins. As a result, workability of the second fins of the indoor unit can be secured, and thus the second heat exchanger including the second fins can be used for the indoor unit.
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FIG. 1 is an external view of an air conditioner according to an embodiment of the present disclosure. -
FIG. 2 is a schematic diagram of an outdoor unit. -
FIG. 3 is a schematic diagram of an indoor unit. -
FIG. 4 is a perspective view of a first heat exchanger. -
FIG. 5 is a sectional view of a first heat transfer tube. -
FIG. 6 is a perspective view of a second heat exchanger. -
FIG. 7 is a sectional view of a second heat transfer tube. -
FIG. 8 is a sectional view of a second fin. -
FIG. 9 is a plan view of a second fin. - An air conditioner according to an embodiment of the present disclosure will be described with reference to the drawings. In the following description, expressions indicating directions such as "up", "down", and the like are appropriately used, and these expressions indicate directions in a state of normal use, and the present disclosure is not limited thereto.
- As illustrated in
FIG. 1 , anair conditioner 1 according to an embodiment of the present disclosure includes anoutdoor unit 2, anindoor unit 3, and aconnection pipe 4. Theoutdoor unit 2 is installed outdoors. Theindoor unit 3 is installed indoors. Here, theindoor unit 3 is attached to an indoor wall surface or the like. Theconnection pipe 4 connects theoutdoor unit 2 and theindoor unit 3. Such anair conditioner 1 can perform a cooling operation, a heating operation, and the like indoors. - As illustrated in
FIG. 2 , theoutdoor unit 2 includes afirst heat exchanger 200, afirst fan 21, afirst drain pan 22, and the like. Thefirst fan 21 sucks outdoor air into theoutdoor unit 2, supplies the outdoor air to thefirst heat exchanger 200, and then discharges the outdoor air to the outside of theoutdoor unit 2. Thefirst heat exchanger 200 exchanges heat between the outdoor air and a refrigerant. Thefirst heat exchanger 200 is a heat exchanger that functions as a radiator for the refrigerant during the cooling operation, and functions as an evaporator for the refrigerant during the heating operation. Thefirst drain pan 22 receives water. - As illustrated in
FIG. 3 , theindoor unit 3 includes asecond heat exchanger 300, asecond fan 31, asecond drain pan 32, and the like. Thesecond fan 31 sucks indoor air into theindoor unit 3, supplies the indoor air to thesecond heat exchanger 300, and then discharges the indoor air to the outside of theindoor unit 3. Thesecond heat exchanger 300 exchanges heat between the refrigerant and the indoor air. Thesecond heat exchanger 300 is a heat exchanger that functions as an evaporator for the refrigerant during the cooling operation, and functions as a radiator for the refrigerant during the heating operation. Thesecond drain pan 32 receives water. - As illustrated in
FIG. 4 , thefirst heat exchanger 200 includes a plurality of firstheat transfer tubes 210 and a plurality offirst fins 220. The firstheat transfer tubes 210 and thefirst fins 220 are made of aluminum or an aluminum alloy. Thefirst heat exchanger 200 according to the present embodiment is of a microchannel heat exchanger. - The first
heat transfer tubes 210 each allow the refrigerant to flow therethrough. As illustrated inFIGS. 4 and5 , the firstheat transfer tube 210 has a flat shape. Here, the firstheat transfer tube 210 is a flat porous tube. In the firstheat transfer tube 210, a plurality of through holes through which the refrigerant heat-exchanged with the outdoor air in thefirst heat exchanger 200 passes is aligned in a predetermined direction. The plurality of through holes penetrates along a first direction. Here, the first direction is a longitudinal direction. - As illustrated in
FIG. 5 , the firstheat transfer tube 210 includes afirst base material 211 and a firstsacrificial layer 212. The firstsacrificial layer 212 is provided on a surface of the firstheat transfer tube 210. The firstsacrificial layer 212 may be provided on the entire surface of the firstheat transfer tube 210, or may be provided on a part of the surface of the first heat transfer tube 210 (not illustrated). In other words, the firstsacrificial layer 212 may be formed on an entire exposed outer surface, or may be formed on a part of the exposed outer surface (not illustrated). The firstsacrificial layer 212 is formed in a part in a thickness direction from the outer surface of the firstheat transfer tube 210 toward an inner surface through which the refrigerant flows, and is not formed in an entire thickness. In other words, in the firstheat transfer tube 210, the firstsacrificial layer 212 is not formed on at least a part of the inner surface through which the refrigerant flows. In the present embodiment, the firstsacrificial layer 212 is not formed on the entire inner surface of the firstheat transfer tube 210. - The first
sacrificial layer 212 is lower in potential than thefirst base material 211 of the firstheat transfer tube 210 and higher in potential than thefirst fin 220. The potential difference between the potential of the firstsacrificial layer 212 and the potential of thefirst base material 211 is, for example, 132 mV. The potential difference between the potential of thefirst fin 220 and the potential of the firstsacrificial layer 212 is, for example, 61 mV. The firstsacrificial layer 212 contains a metal such as zinc (Zn) in order to lower the potential. The firstsacrificial layer 212 according to the present embodiment is a zinc diffusion layer sprayed with zinc. The firstsacrificial layer 212 on the outer surface side prevents a progress of corrosion of thefirst base material 211 on the inner surface side in the firstheat transfer tube 210. - As illustrated in
FIG. 4 , the plurality of firstheat transfer tubes 210 is aligned in an up-down direction. A lowermost end of the plurality of firstheat transfer tubes 210 is located above a water level of the first drain pan 22 (seeFIG. 2 ). - The
first fin 220 increases a heat transfer area between the firstheat transfer tube 210 and the outdoor air to promote heat exchange between the refrigerant and the outdoor air. Thefirst fin 220 is in contact with the firstheat transfer tube 210. - The
first fin 220 is lower in potential than thefirst base material 211 of the firstheat transfer tube 210 and lower in potential than the firstsacrificial layer 212. In other words, thefirst base material 211, the firstsacrificial layer 212, and thefirst fin 220 have higher potentials in that order. The potential difference between the potential of thefirst fin 220 and the potential of thefirst base material 211 is, for example, 193 mV. - The
first fin 220 contains a metal such as zinc in order to lower the potential. The metal is not limited, but thefirst fin 220 according to the present embodiment contains zinc. A rate of zinc content of thefirst fins 220 is preferably 2% by mass or more. An upper limit value of the rate of zinc content of thefirst fins 220 is not limited, but is, for example, 6% in terms of workability. - Here, the "rate of zinc content" described in the present specification is a value measured by, for example, an emission spectroscopic analysis method.
- The
first fin 220 according to the present embodiment further contains magnesium (Mg) and copper (Cu). - The plurality of
first fins 220 is stacked in the first direction (seeFIG. 4 ) in which the firstheat transfer tubes 210 extend. Here, the plurality offirst fins 220 extends in the up-down direction so as to cross (be orthogonal to inFIG. 4 ) the firstheat transfer tubes 210. In the present embodiment, the plurality offirst fins 220 is disposed in parallel and at equal intervals. In other words, the plurality offirst fins 220 is aligned in the first direction at a predetermined fin pitch P1. - The
first fin 220 is a flat plate-shaped member. Thefirst fin 220 has a notch through which the firstheat transfer tube 210 passes. The notches are aligned in the first direction. Note that thefirst fin 220 may have a collar. - The
first heat exchanger 200 of theoutdoor unit 2 may further include a fillet that connects the firstheat transfer tubes 210 and thefirst fins 220. The potential of the fillet is not limited, but in the present embodiment, thefirst base material 211, the firstsacrificial layer 212, the fillet, and thefirst fin 220 have higher potentials in that order. - As illustrated in
FIG. 6 , thesecond heat exchanger 300 includes a plurality of secondheat transfer tubes 310 and a plurality ofsecond fins 320. The secondheat transfer tubes 310 and thesecond fins 320 are made of aluminum or an aluminum alloy. Thesecond heat exchanger 300 according to the present embodiment is a cross-fin-tube heat exchanger. - The second
heat transfer tubes 310 each allow the refrigerant to flow therethrough. The secondheat transfer tube 310 has a cylindrical shape. Here, the secondheat transfer tube 310 is a round tube. The secondheat transfer tube 310 is provided with a through hole through which the refrigerant that exchanges heat with the indoor air in thesecond heat exchanger 300 passes. The through hole of the secondheat transfer tube 310 penetrates along a second direction. Here, the second direction is a longitudinal direction. - As illustrated in
FIG. 7 , the secondheat transfer tube 310 includes asecond base material 311 and a secondsacrificial layer 312. The secondsacrificial layer 312 is provided on a surface of the secondheat transfer tube 310. The secondsacrificial layer 312 may be provided on the entire surface of the second heat transfer tube 310 (not illustrated), or may be provided on a part of the surface of the secondheat transfer tube 310. In other words, the secondsacrificial layer 312 may be formed on an entire exposed outer surface (not illustrated), or may be formed on a part of the exposed outer surface. The secondsacrificial layer 312 is formed in a part in a thickness direction from the outer surface of the secondheat transfer tube 310 toward an inner surface through which the refrigerant flows, and is not formed in an entire thickness. In other words, in the secondheat transfer tube 310, the secondsacrificial layer 312 is not formed on at least a part of the inner surface through which the refrigerant flows. In the present embodiment, the secondsacrificial layer 312 is not formed on the entire inner surface of the secondheat transfer tube 310. - The second
sacrificial layer 312 is lower in potential than thesecond base material 311 of the secondheat transfer tube 310 and lower in potential than thesecond fin 320. The secondsacrificial layer 312 contains a metal such as zinc in order to lower the potential. The secondsacrificial layer 312 according to the present embodiment is a zinc diffusion layer sprayed with zinc. The secondsacrificial layer 312 on the outer surface side prevents a progress of corrosion of thesecond base material 311 on the inner surface side in the secondheat transfer tube 310. - As illustrated in
FIG. 6 , the plurality of secondheat transfer tubes 310 is aligned in an up-down direction. A lowermost end of each of the plurality of secondheat transfer tubes 310 is located above a water level of the second drain pan 32 (seeFIG. 3 ). - The
second fin 320 increases a heat transfer area between the secondheat transfer tube 310 and the indoor air to promote heat exchange between the refrigerant and the indoor air. Thesecond fin 320 is in contact with the secondheat transfer tube 310. - The
second fin 320 is lower in potential than thesecond base material 311 of the secondheat transfer tube 310 and higher in potential than the secondsacrificial layer 312. In other words, thesecond base material 311, thesecond fin 320, and the secondsacrificial layer 312 have higher potentials in that order. - The
second fin 320 contains a metal such as zinc in order to lower the potential. Thesecond fin 320 may or is not required to contain zinc. Specifically, the rate of zinc content of thesecond fins 320 is, for example, 0% by mass or more and 1% by mass or less. - The plurality of
second fins 320 is stacked in the second direction (seeFIG. 6 ) in which the secondheat transfer tubes 310 extend. Here, the plurality ofsecond fins 320 extends in the up-down direction so as to cross (be orthogonal to inFIG. 6 ) the secondheat transfer tubes 310. In the present embodiment, the plurality ofsecond fins 320 is disposed in parallel and at equal intervals. In other words, the plurality ofsecond fins 320 is aligned in the second direction at a predetermined fin pitch P2. - As illustrated in
FIGS. 8 and9 , the plurality ofsecond fins 320 each includes afin body 321 and asecond collar 322. Thefin body 321 is a flat plate-shaped member. Thesecond collar 322 allows the secondheat transfer tube 310 to pass therethrough. Specifically, thesecond collar 322 has a through hole through which the secondheat transfer tube 310 passes. - The
second collar 322 includes a firstupright portion 323, aflat portion 324, a secondupright portion 325, and aflange 326. The firstupright portion 323, theflat portion 324, thesecond upright portion 325, and theflange 326 are constituted by one member. Here, the firstupright portion 323, theflat portion 324, thesecond upright portion 325, and theflange 326 are constituted by nesting. - The first
upright portion 323 extends in the second direction from thefin body 321. Here, the firstupright portion 323 is orthogonal to thefin body 321. A coupling portion between the firstupright portion 323 and thefin body 321 has a curved (R) shape. - The
flat portion 324 extends from the firstupright portion 323 toward the secondheat transfer tube 310. Here, theflat portion 324 is orthogonal to the firstupright portion 323. A coupling portion betweenflat portion 324 and firstupright portion 323 has a curved shape. - The
second upright portion 325 extends from theflat portion 324 along the secondheat transfer tube 310. Thesecond upright portion 325 is in contact with the secondheat transfer tube 310. Here, thesecond upright portion 325 is orthogonal to theflat portion 324. A coupling portion between secondupright portion 325 andflat portion 324 has a curved shape. - The
flange 326 extends outward from thesecond upright portion 325. Here, theflange 326 is orthogonal to thesecond upright portion 325. The coupling portion between theflange 326 and thesecond upright portion 325 has a curved shape. - One
flat portion 324 is in contact with theflange 326 of another adjacentsecond fin 320. Theflat portion 324 and theflange 326 extend in the same direction. - In this manner, the
second fin 320 according to the present embodiment is required to have high workability. - Next, a relationship between the
first fin 220 of thefirst heat exchanger 200 and thesecond fin 320 of thesecond heat exchanger 300 will be described. - An elongation of the
second fin 320 is larger than an elongation of thefirst fin 220. Here, "elongation" of the present disclosure conforms to JIS H4000. - A rate of zinc content of the
first fins 220 is higher than a rate of zinc content of thesecond fins 320. For example, the rate of zinc content of thefirst fins 220 is higher than the rate of zinc content of thesecond fins 320 by 1% by mass or more. - The potential of the
first fin 220 is lower than the potential of thesecond fin 320. For example, the potential of thefirst fin 220 is lower than the potential of thesecond fin 320 by 10 mV or more. The potential is adjusted by, for example, a type, content by rate, content by amount, or the like of a metal that is lower in potential. - The fin pitch P2 of the
second fins 320 illustrated inFIG. 6 is larger than the fin pitch P1 of thefirst fins 220 illustrated inFIG. 4 . Here, the fin pitch P1 is a distance between the adjacentfirst fins 220. Specifically, the fin pitch P1 is a distance between opposing faces of the adjacentfirst fins 220. Similarly, the fin pitch P2 is a distance between the adjacentsecond fins 320. Specifically, the fin pitch P2 is a distance between opposing faces of the adjacentsecond fins 320. - A difference between the fin pitch P1 of the
first fins 220 and the fin pitch P2 of thesecond fins 320 is 0.1 mm or more and 0.3 mm or less. In other words, a pitch difference (fin pitch P2 - fin pitch P 1) is 0.1 mm or more and 0.3 mm or less. - The fin pitch P1 of the
first fins 220 is, for example, 1.2 mm or more and 1.4 mm or less. The fin pitch P2 of thesecond fins 320 is, for example, 1.3 mm or more and 1.5 mm or less. - (3-1) The
air conditioner 1 according to the present embodiment includes theoutdoor unit 2 and theindoor unit 3. Theoutdoor unit 2 includes thefirst heat exchanger 200. Thefirst heat exchanger 200 includes the firstheat transfer tube 210 and the plurality offirst fins 220. The firstheat transfer tubes 210 are made of aluminum or an aluminum alloy. The plurality offirst fins 220 is made of aluminum or an aluminum alloy. Theindoor unit 3 includes thesecond heat exchanger 300. Thesecond heat exchanger 300 includes the secondheat transfer tube 310 and the plurality ofsecond fins 320. The secondheat transfer tubes 310 are made of aluminum or an aluminum alloy. The plurality ofsecond fins 320 is made of aluminum or an aluminum alloy. The firstsacrificial layer 212 is provided on the surface of the firstheat transfer tube 210. The firstsacrificial layer 212 is lower in potential than thefirst base material 211 of the firstheat transfer tube 210 and higher in potential than thefirst fin 220. Thefirst fins 220 contain zinc. A rate of zinc content of thefirst fin 220 is higher than a rate of zinc content of thesecond fins 320. - In the
air conditioner 1 according to the present embodiment, since the firstsacrificial layer 212 which is lower in potential than thefirst base material 211 is provided in the firstheat transfer tube 210 made of aluminum or an aluminum alloy, corrosion of thefirst base material 211 can be suppressed. Since the firstsacrificial layer 212 is higher in potential than thefirst fin 220, corrosion of the firstsacrificial layer 212 for suppressing corrosion of thefirst base material 211 can be suppressed. - However, when the
first fin 220 and thesecond fin 320 contain zinc in order to be lower in potential, thefirst fin 220 and thesecond fin 320 are cured, and thus their workability is deteriorated. The present inventor has focused on the fact that thesecond fin 320 of theindoor unit 3 has a high degree of processing difficulty for reasons such as compactness and bending. In other words, the present inventor has paid attention to the fact that thefirst fin 220 of theoutdoor unit 2 is not required to have workability as compared with thesecond fin 320 of theindoor unit 3. Therefore, in theair conditioner 1 according to the present embodiment, the rate of zinc content of thefirst fin 220 is higher than the rate of zinc content of thesecond fin 320. As a result, workability of thesecond fin 320 of theindoor unit 3 can be secured, and thus thesecond heat exchanger 300 including thesecond fin 320 can be used for theindoor unit 3. - (3-2) In the
air conditioner 1 according to the present embodiment, thefirst fins 220 have a rate of zinc content of 2% by mass or more. As a result, it is possible to provide the firstsacrificial layer 212 having a potential that can suppress corrosion of thefirst base material 211. - (3-3) In the
air conditioner 1 according to the present embodiment, the fin pitch P2 of thesecond fins 320 is larger than the fin pitch P1 of thefirst fins 220. - Since the
second fins 320 have less a rate of zinc content than thefirst fins 220, the second fins are easily corroded. Therefore, here, by making the fin pitch P2 of thesecond fins 320 larger than the fin pitch P1 of thefirst fins 220, the number of thesecond fins 320 can be reduced, and a surface area of thesecond fins 320 in contact with the secondheat transfer tubes 310 can be reduced. As a result, corrosion of thesecond fins 320 can be suppressed. - As described above, the
second fin 320 of theindoor unit 3 is required to have high workability. Therefore, by reducing the number ofsecond fins 320, it is possible to reduce a burden associated with processing. - Furthermore, by reducing the fin pitch P1 of the
first fins 220 of thefirst heat exchanger 200 of theoutdoor unit 2, it is possible to secure a large number offirst fins 220. It is therefore possible to suppress a decrease in performance of theair conditioner 1 as a whole. - In addition, in the
outdoor unit 2 that is more susceptible to salt damage, it is possible to increase an area of thefirst fin 220 to be a sacrifice of the firstheat transfer tube 210. As a result, corrosion of the firstheat transfer tube 210 can be further suppressed. - (3-4) In the
air conditioner 1 according to the present embodiment, a difference (P2 - P1) between the fin pitch P1 of thefirst fins 220 and the fin pitch P2 of thesecond fins 320 is 0.1 mm or more and 0.3 mm or less. As a result, corrosion of thesecond fin 320 can be further suppressed. - (3-5) In the
air conditioner 1 according to the present embodiment, the potential of thefirst fins 220 is lower than the potential of thesecond fins 320. - The
first heat exchanger 200 of theoutdoor unit 2 is more susceptible to salt damage than thesecond heat exchanger 300 of theindoor unit 3. Therefore, here, by making the potential of thefirst fins 220 lower than the potential of thesecond fins 320, thefirst fins 220 are sacrificed in the first heat transfer tube210, and therefore it is possible to further suppress corrosion of the firstheat transfer tube 210. - (3-6) In the
air conditioner 1 according to the present embodiment, the secondsacrificial layer 312 that is lower in potential than thesecond base material 311 of the secondheat transfer tube 310 and lower in potential than thesecond fin 320 is provided on the surface of the secondheat transfer tube 310. - The
second heat exchanger 300 of theindoor unit 3 is less susceptible to salt damage than thefirst heat exchanger 200 of theoutdoor unit 2. Therefore, here, even if the secondsacrificial layer 312 of theindoor unit 3 is made lower in potential than thesecond fins 320, corrosion of thesecond base material 311 can be suppressed. In addition, it is possible to further suppress a decrease in workability of thesecond fin 320. - (3-7) In the
air conditioner 1 according to the present embodiment, the firstheat transfer tube 210 has a flat shape. The secondheat transfer tube 310 has a cylindrical shape. - The
second fin 320 attached to the cylindrical secondheat transfer tube 310 is required to have higher workability than thefirst fin 220 attached to the flat firstheat transfer tube 210. In this manner, the secondheat transfer tube 310 of theindoor unit 3 is required to have higher workability than the firstheat transfer tube 210 of theoutdoor unit 2. Therefore, theair conditioner 1 according to the present embodiment can be suitably used for theair conditioner 1 including thefirst heat exchanger 200 having the firstheat transfer tube 210 of a flat shape and thesecond heat exchanger 300 having the secondheat transfer tube 310 of a cylindrical shape. - (3-8) The
air conditioner 1 according to the present embodiment includes theoutdoor unit 2 and theindoor unit 3. Theoutdoor unit 2 includes thefirst heat exchanger 200. Thefirst heat exchanger 200 includes the firstheat transfer tube 210 and the plurality offirst fins 220. The firstheat transfer tubes 210 is made of aluminum or an aluminum alloy. The plurality offirst fins 220 is made of aluminum or an aluminum alloy. Theindoor unit 3 includes thesecond heat exchanger 300. Thesecond heat exchanger 300 includes the secondheat transfer tube 310 and the plurality ofsecond fins 320. The secondheat transfer tubes 310 is made of aluminum or an aluminum alloy. The plurality ofsecond fins 320 is made of aluminum or an aluminum alloy. The firstsacrificial layer 212 is provided on the surface of the firstheat transfer tube 210. The firstsacrificial layer 212 is lower in potential than thefirst base material 211 of the firstheat transfer tube 210 and higher in potential than thefirst fin 220. An elongation of thesecond fin 320 is larger than an elongation of thefirst fin 220. - In the
air conditioner 1 according to the present embodiment, since the firstsacrificial layer 212 which is lower in potential than thefirst base material 211 is provided in the firstheat transfer tube 210 made of aluminum or an aluminum alloy, corrosion of thefirst base material 211 can be suppressed. Since the firstsacrificial layer 212 is higher in potential than thefirst fin 220, corrosion of the firstsacrificial layer 212 for suppressing corrosion of thefirst base material 211 can be suppressed. - However, when the
first fin 220 and thesecond fin 320 are lower in potential, thefirst fin 220 and thesecond fin 320 are cured, and thus their workability is deteriorated. Therefore, in theair conditioner 1 according to the present embodiment, focusing on the fact that thefirst fin 220 of theoutdoor unit 2 is not required to have workability as compared with thesecond fin 320 of theindoor unit 3, the elongation of thesecond fin 320 is made larger than the elongation of thefirst fin 220. As a result, workability of thesecond fin 320 of theindoor unit 3 can be secured, and thus thesecond heat exchanger 300 including thesecond fin 320 can be used for theindoor unit 3. - In the above- described embodiment, the first
sacrificial layer 212 of the firstheat transfer tube 210 and the secondsacrificial layer 312 of the secondheat transfer tube 310 have been described by taking a diffusion layer sprayed with zinc as an example, but the present disclosure is not limited thereto. In this modification, a clad material is used as the base material and the sacrificial layer. - Specifically, the first
heat transfer tube 210 is formed by using a clad material in which a metal to be thefirst base material 211 and a metal to be the firstsacrificial layer 212 are bonded together. The secondheat transfer tube 310 is formed by using a clad material in which a metal to be thesecond base material 311 and a metal to be the secondsacrificial layer 312 are bonded together. - In the above-described embodiment, in the
second heat exchanger 300 of theindoor unit 3, thesecond base material 311, thesecond fin 320, and the secondsacrificial layer 312 are higher in potential in that order, but the present disclosure is not limited thereto. In this modification, thesecond base material 311, the secondsacrificial layer 312, and thesecond fin 320 are higher in potential in that order in thesecond heat exchanger 300 of theindoor unit 3. - In the above-embodiment and
1 and 2, the secondModifications heat transfer tube 310 of theindoor unit 3 includes the secondsacrificial layer 312, but in this modification, the secondsacrificial layer 312 is omitted. In this case, since the secondheat transfer tubes 310 are higher in potential than thesecond fins 320, corrosion of the secondheat transfer tubes 310 can be still suppressed. - In the above-embodiment, the
first heat exchanger 200 is a microchannel heat exchanger, and thesecond heat exchanger 300 is a cross-fin-tube heat exchanger, but the present invention is not limited thereto. Thefirst heat exchanger 200 may be a cross-fin-tube heat exchanger, and thesecond heat exchanger 300 may be a microchannel heat exchanger. When both thefirst heat exchanger 200 and thesecond heat exchanger 300 are microchannel heat exchangers or cross-fin type heat exchangers, the firstheat transfer tubes 210 and the secondheat transfer tubes 310 can be made common. - The embodiments of the present disclosure have been described above. It will be understood that various changes to modes and details can be made without departing from the gist and scope of the present disclosure recited in the claims.
-
- 1: air conditioner
- 2: outdoor unit
- 3: indoor unit
- 200: first heat exchanger
- 210: first heat transfer tube
- 211: first base material (base material)
- 212: first sacrificial layer
- 220: first fin
- 300: second heat exchanger
- 310: second heat transfer tube
- 311: second base material (base material)
- 312: second sacrificial layer
- 320: second fin
- P1, P2: fin pitch
- Patent Literature 1:
WO 2017/141943 A
Claims (8)
- An air conditioner (1) comprising:an outdoor unit (2) including a first heat exchanger (200) havinga first heat transfer tube (210) made of aluminum or an aluminum alloy, anda plurality of first fins (220) made of aluminum or an aluminum alloy; andan indoor unit (3) including a second heat exchanger (300) havinga second heat transfer tube (310) made of aluminum or an aluminum alloy, anda plurality of second fins (320) made of aluminum or an aluminum alloy, whereina first sacrificial layer (212) that is lower in potential than a base material (211) of the first heat transfer tube and higher in potential than the first fins is provided on a surface of the first heat transfer tube,the first fins contain zinc, anda rate of zinc content of the first fin is higher than a rate of zinc content of the second fin.
- The air conditioner according to claim 1, wherein the rate of zinc content of the first fin is 2% by mass or more.
- The air conditioner according to claim 1 or 2, wherein a fin pitch (P2) of the second fins is larger than a fin pitch (P1) of the first fins.
- The air conditioner according to claim 3, wherein a difference between the fin pitch of the first fins and the fin pitch of the second fins is 0.1 mm or more and 0.3 mm or less.
- The air conditioner according to any one of claims 1 to 4, wherein a potential of the first fin is lower than a potential of the second fin.
- The air conditioner according to any one of claims 1 to 5, wherein a second sacrificial layer (312) that is lower in potential than a base material (311) of the second heat transfer tube and lower in potential than the second fins is provided on a surface of the second heat transfer tube.
- The air conditioner according to any one of claims 1 to 6, whereinthe first heat transfer tube has a flat shape, andthe second heat transfer tube has a cylindrical shape.
- An air conditioner (1) comprising:an outdoor unit (2) including a first heat exchanger (200) havinga first heat transfer tube (210) made of aluminum or an aluminum alloy, anda plurality of first fins (220) made of aluminum or an aluminum alloy; andan indoor unit (3) including a second heat exchanger (300) havinga second heat transfer tube (310) made of aluminum or an aluminum alloy, anda plurality of second fins (320) made of aluminum or an aluminum alloy, whereina first sacrificial layer (212) that is lower in potential than a base material (211) of the first heat transfer tube and higher in potential than the first fin is provided on a surface of the first heat transfer tube, andan elongation of the second fin is larger than an elongation of the first fin.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2022060706A JP7401803B2 (en) | 2022-03-31 | 2022-03-31 | air conditioner |
| PCT/JP2023/013217 WO2023190890A1 (en) | 2022-03-31 | 2023-03-30 | Air conditioner |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP4502526A1 true EP4502526A1 (en) | 2025-02-05 |
| EP4502526A4 EP4502526A4 (en) | 2025-11-05 |
Family
ID=88202832
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP23780898.5A Pending EP4502526A4 (en) | 2022-03-31 | 2023-03-30 | Air conditioner |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20250020415A1 (en) |
| EP (1) | EP4502526A4 (en) |
| JP (1) | JP7401803B2 (en) |
| CN (1) | CN119137439B (en) |
| WO (1) | WO2023190890A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4718012A2 (en) * | 2023-03-31 | 2026-04-01 | Daikin Industries, Ltd. | Air conditioner |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61143592A (en) * | 1984-12-17 | 1986-07-01 | Shozo Shibano | Production of gold-colored hard corrosion-resistant alumite alloy |
| JPH11211377A (en) * | 1998-01-26 | 1999-08-06 | Kobe Steel Ltd | Aluminum for heat-exchanger or aluminum alloy fin materials, and manufacture thereof |
| JP2009257744A (en) * | 2008-03-25 | 2009-11-05 | Daikin Ind Ltd | Refrigerating device |
| JP5614829B2 (en) * | 2009-06-24 | 2014-10-29 | 株式会社Uacj | Aluminum alloy heat exchanger |
| US10422593B2 (en) * | 2012-04-12 | 2019-09-24 | Carrier Corporation | Sacrificial aluminum fins for failure mode protection of an aluminum heat exchanger |
| JP2014095524A (en) * | 2012-11-12 | 2014-05-22 | Hitachi Appliances Inc | Air conditioner |
| JP6641721B2 (en) | 2015-04-27 | 2020-02-05 | ダイキン工業株式会社 | Heat exchangers and air conditioners |
| CN108351183B (en) | 2016-02-15 | 2020-09-22 | 株式会社Uacj | heat exchanger |
| JP7561483B2 (en) | 2018-06-12 | 2024-10-04 | ダイキン工業株式会社 | Indoor heat exchanger and air conditioning device |
| JP2020051731A (en) | 2018-09-28 | 2020-04-02 | 三菱アルミニウム株式会社 | Hydrophilic fin and heat exchanger |
| WO2021234954A1 (en) * | 2020-05-22 | 2021-11-25 | 三菱電機株式会社 | Heat exchanger, outdoor unit, and refrigeration cycle device |
-
2022
- 2022-03-31 JP JP2022060706A patent/JP7401803B2/en active Active
-
2023
- 2023-03-30 WO PCT/JP2023/013217 patent/WO2023190890A1/en not_active Ceased
- 2023-03-30 EP EP23780898.5A patent/EP4502526A4/en active Pending
- 2023-03-30 CN CN202380031193.4A patent/CN119137439B/en active Active
-
2024
- 2024-09-27 US US18/899,338 patent/US20250020415A1/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CN119137439B (en) | 2025-10-14 |
| EP4502526A4 (en) | 2025-11-05 |
| JP2023151215A (en) | 2023-10-16 |
| CN119137439A (en) | 2024-12-13 |
| JP7401803B2 (en) | 2023-12-20 |
| US20250020415A1 (en) | 2025-01-16 |
| WO2023190890A1 (en) | 2023-10-05 |
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