EP4480941A4 - Process for the preparation of methacrolein and/or methacrylic acid and process for the preparation of methacrylic acid esters - Google Patents

Process for the preparation of methacrolein and/or methacrylic acid and process for the preparation of methacrylic acid esters

Info

Publication number
EP4480941A4
EP4480941A4 EP23756395.2A EP23756395A EP4480941A4 EP 4480941 A4 EP4480941 A4 EP 4480941A4 EP 23756395 A EP23756395 A EP 23756395A EP 4480941 A4 EP4480941 A4 EP 4480941A4
Authority
EP
European Patent Office
Prior art keywords
preparation
methacrylic acid
methacrolein
acid esters
esters
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP23756395.2A
Other languages
German (de)
French (fr)
Other versions
EP4480941A1 (en
Inventor
Tatsuya Suzuki
Yuki Kato
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corp filed Critical Mitsubishi Chemical Corp
Publication of EP4480941A1 publication Critical patent/EP4480941A1/en
Publication of EP4480941A4 publication Critical patent/EP4480941A4/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/08—Alkenes with four carbon atoms
    • C07C11/09—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C47/22—Acryaldehyde; Methacryaldehyde
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP23756395.2A 2022-02-17 2023-02-15 Process for the preparation of methacrolein and/or methacrylic acid and process for the preparation of methacrylic acid esters Pending EP4480941A4 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2022022717 2022-02-17
PCT/JP2023/005198 WO2023157870A1 (en) 2022-02-17 2023-02-15 Method for producing methacrolein and/or methacrylic acid, and method for producing methacrylic acid ester

Publications (2)

Publication Number Publication Date
EP4480941A1 EP4480941A1 (en) 2024-12-25
EP4480941A4 true EP4480941A4 (en) 2025-08-27

Family

ID=87578323

Family Applications (1)

Application Number Title Priority Date Filing Date
EP23756395.2A Pending EP4480941A4 (en) 2022-02-17 2023-02-15 Process for the preparation of methacrolein and/or methacrylic acid and process for the preparation of methacrylic acid esters

Country Status (6)

Country Link
US (1) US20240400486A1 (en)
EP (1) EP4480941A4 (en)
JP (1) JPWO2023157870A1 (en)
KR (1) KR20240149955A (en)
CN (1) CN118742533A (en)
WO (1) WO2023157870A1 (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110301316A1 (en) * 2009-01-06 2011-12-08 Arkema France Method for manufacturing biomass-derived methyl methacrylate
US20170129844A1 (en) * 2014-07-02 2017-05-11 Mitsubishi Rayon Co., Ltd. Method for producing isobutylene, method for producing methacrylic acid, and method for producing methyl methacrylate
WO2021200795A1 (en) * 2020-03-31 2021-10-07 三菱ケミカル株式会社 Method for producing isobutylene, method for producing methacrylic acid, and method for producing methyl methacrylate

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5112605B2 (en) 1971-09-01 1976-04-21
JPS5324403B2 (en) 1973-06-11 1978-07-20
US4413147A (en) * 1982-04-14 1983-11-01 The Halcon Sd Group, Inc. Conversion of isobutane to methacrolein
BR112012016883A2 (en) * 2010-01-08 2018-06-05 Gevo Inc integrated methods of preparing renewable chemical produsot
JP2013121946A (en) 2011-11-07 2013-06-20 Mitsubishi Rayon Co Ltd Method and apparatus for producing methacrolein and methacrylic acid from isobutanol
JP6107139B2 (en) 2011-11-07 2017-04-05 三菱レイヨン株式会社 Method for producing methacrolein and methacrylic acid from isobutanol and apparatus for producing the same
JP2014019675A (en) * 2012-07-20 2014-02-03 Nippon Kayaku Co Ltd Process for producing unsaturated aldehyde and/or unsaturated carboxylic acid
EP3967398A4 (en) * 2020-01-10 2022-09-07 Nippon Kayaku Kabushiki Kaisha CATALYST, AND METHOD FOR MAKING A COMPOUND USING THE SAME, AND COMPOUND

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110301316A1 (en) * 2009-01-06 2011-12-08 Arkema France Method for manufacturing biomass-derived methyl methacrylate
US20170129844A1 (en) * 2014-07-02 2017-05-11 Mitsubishi Rayon Co., Ltd. Method for producing isobutylene, method for producing methacrylic acid, and method for producing methyl methacrylate
WO2021200795A1 (en) * 2020-03-31 2021-10-07 三菱ケミカル株式会社 Method for producing isobutylene, method for producing methacrylic acid, and method for producing methyl methacrylate

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2023157870A1 *

Also Published As

Publication number Publication date
WO2023157870A1 (en) 2023-08-24
EP4480941A1 (en) 2024-12-25
KR20240149955A (en) 2024-10-15
CN118742533A (en) 2024-10-01
JPWO2023157870A1 (en) 2023-08-24
US20240400486A1 (en) 2024-12-05

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