EP4448473C0 - Integrierte anlage und verfahren zur herstellung von methanol aus kohlendioxid und wasserstoff - Google Patents

Integrierte anlage und verfahren zur herstellung von methanol aus kohlendioxid und wasserstoff

Info

Publication number
EP4448473C0
EP4448473C0 EP22830198.2A EP22830198A EP4448473C0 EP 4448473 C0 EP4448473 C0 EP 4448473C0 EP 22830198 A EP22830198 A EP 22830198A EP 4448473 C0 EP4448473 C0 EP 4448473C0
Authority
EP
European Patent Office
Prior art keywords
methanol
hydrogen
production
carbon dioxide
integrated plant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP22830198.2A
Other languages
English (en)
French (fr)
Other versions
EP4448473B1 (de
EP4448473A1 (de
Inventor
Susanne Britzius
Maximilian Vicari
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of EP4448473A1 publication Critical patent/EP4448473A1/de
Application granted granted Critical
Publication of EP4448473C0 publication Critical patent/EP4448473C0/de
Publication of EP4448473B1 publication Critical patent/EP4448473B1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0285—Heating or cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/007—Energy recuperation; Heat pumps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B01D3/143—Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0278—Feeding reactive fluids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00256—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles in a heat exchanger for the heat exchange medium separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00389—Controlling the temperature using electric heating or cooling elements
    • B01J2208/00415—Controlling the temperature using electric heating or cooling elements electric resistance heaters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00132—Controlling the temperature using electric heating or cooling elements
    • B01J2219/00135—Electric resistance heaters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP22830198.2A 2021-12-14 2022-12-05 Integrierte anlage und verfahren zur herstellung von methanol aus kohlendioxid und wasserstoff Active EP4448473B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP21214263.2A EP4197993A1 (de) 2021-12-14 2021-12-14 Integrierte anlage und verfahren zur herstellung von methanol aus kohlendioxid und wasserstoff
PCT/EP2022/084345 WO2023110479A1 (en) 2021-12-14 2022-12-05 Integrated plant and process for the production of methanol from carbon dioxide and hydrogen

Publications (3)

Publication Number Publication Date
EP4448473A1 EP4448473A1 (de) 2024-10-23
EP4448473C0 true EP4448473C0 (de) 2025-11-12
EP4448473B1 EP4448473B1 (de) 2025-11-12

Family

ID=78851024

Family Applications (2)

Application Number Title Priority Date Filing Date
EP21214263.2A Withdrawn EP4197993A1 (de) 2021-12-14 2021-12-14 Integrierte anlage und verfahren zur herstellung von methanol aus kohlendioxid und wasserstoff
EP22830198.2A Active EP4448473B1 (de) 2021-12-14 2022-12-05 Integrierte anlage und verfahren zur herstellung von methanol aus kohlendioxid und wasserstoff

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP21214263.2A Withdrawn EP4197993A1 (de) 2021-12-14 2021-12-14 Integrierte anlage und verfahren zur herstellung von methanol aus kohlendioxid und wasserstoff

Country Status (4)

Country Link
US (1) US20250041816A1 (de)
EP (2) EP4197993A1 (de)
CN (1) CN118382607A (de)
WO (1) WO2023110479A1 (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024223472A1 (en) * 2023-04-27 2024-10-31 Topsoe A/S A method for storing hydrogen in a reactor or a synthesis loop
WO2025087918A1 (en) * 2023-10-26 2025-05-01 Casale Sa A system for methanol synthesis
GB202400240D0 (en) * 2024-01-08 2024-02-21 Johnson Matthey Davy Technologies Ltd Process for synthesising methanol

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2751307B1 (de) * 2011-08-29 2015-09-09 Karl-Hermann Busse Energieversorgungsanlage, insbesondere für den bereich der haustechnik
EP2617478A1 (de) * 2012-01-23 2013-07-24 Methanol Casale SA Verfahren und Vorrichtung zur Destillation von Methanol mit Wärmerückgewinnung
GB2545474A (en) 2015-12-17 2017-06-21 Avocet Infinite Plc Integrated system and method for producing methanol product
WO2020150247A1 (en) * 2019-01-15 2020-07-23 Sabic Global Technologies, B.V. Use of renewable energy in methanol synthesis
EP3730473A1 (de) * 2019-04-24 2020-10-28 SABIC Global Technologies B.V. Verwendung von erneuerbarer energie in der methanolsynthese
EP4093723A1 (de) 2020-01-22 2022-11-30 Basf Se Verfahren zum herstellen von methanol aus kohlendioxid und wasserstoff mit quantitativer kohlendioxidnutzung

Also Published As

Publication number Publication date
EP4197993A1 (de) 2023-06-21
CN118382607A (zh) 2024-07-23
EP4448473B1 (de) 2025-11-12
WO2023110479A1 (en) 2023-06-22
US20250041816A1 (en) 2025-02-06
EP4448473A1 (de) 2024-10-23

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