EP4403605A1 - Pa10t molding composite material, and preparation method therefor and application thereof - Google Patents

Pa10t molding composite material, and preparation method therefor and application thereof Download PDF

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Publication number
EP4403605A1
EP4403605A1 EP22869310.7A EP22869310A EP4403605A1 EP 4403605 A1 EP4403605 A1 EP 4403605A1 EP 22869310 A EP22869310 A EP 22869310A EP 4403605 A1 EP4403605 A1 EP 4403605A1
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EP
European Patent Office
Prior art keywords
pa10t
composite material
molding composite
toner
light source
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP22869310.7A
Other languages
German (de)
French (fr)
Other versions
EP4403605A4 (en
Inventor
Huixin YANG
Xianbo Huang
Jiehong MAI
Sujun JIANG
Zhiqiang Jiang
Kun YAN
Jianwei Li
Xianjun XU
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kingfa Science and Technology Co Ltd
Zhuhai Vanteque Speciality Engineering Plastics Co Ltd
Original Assignee
Kingfa Science and Technology Co Ltd
Zhuhai Vanteque Speciality Engineering Plastics Co Ltd
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Filing date
Publication date
Application filed by Kingfa Science and Technology Co Ltd, Zhuhai Vanteque Speciality Engineering Plastics Co Ltd filed Critical Kingfa Science and Technology Co Ltd
Publication of EP4403605A1 publication Critical patent/EP4403605A1/en
Publication of EP4403605A4 publication Critical patent/EP4403605A4/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06Polyamides derived from polyamines and polycarboxylic acids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/002Methods
    • B29B7/005Methods for mixing in batches
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/30Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/34Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
    • B29B7/38Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
    • B29B7/46Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
    • B29B7/48Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • B29B9/02Making granules by dividing preformed material
    • B29B9/06Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • B29B9/12Making granules characterised by structure or composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/203Solid polymers with solid and/or liquid additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F9/00Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements
    • G09F9/30Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements
    • G09F9/33Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements being semiconductor devices, e.g. diodes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2077/00Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/12Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of short lengths, e.g. chopped filaments, staple fibres or bristles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2507/00Use of elements other than metals as filler
    • B29K2507/04Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2509/00Use of inorganic materials not provided for in groups B29K2503/00 - B29K2507/00, as filler
    • B29K2509/02Ceramics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0012Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular thermal properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0018Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
    • B29K2995/002Coloured
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0018Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
    • B29K2995/003Reflective
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037Other properties
    • B29K2995/0039Amorphous
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037Other properties
    • B29K2995/0088Molecular weight
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037Other properties
    • B29K2995/0094Geometrical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2011/00Optical elements, e.g. lenses, prisms
    • B29L2011/0083Reflectors
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C08G69/265Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from at least two different diamines or at least two different dicarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2377/06Polyamides derived from polyamines and polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K2003/343Peroxyhydrates, peroxyacids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/004Additives being defined by their length
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/01Manufacture or treatment
    • H10H20/036Manufacture or treatment of packages
    • H10H20/0363Manufacture or treatment of packages of optical field-shaping means
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80Constructional details
    • H10H20/85Packages
    • H10H20/855Optical field-shaping means, e.g. lenses

Definitions

  • the objective of the present invention is to overcome the technical shortcomings, and to provide a polyamide molding composite material; the present invention has a high contrast and a high gray scale and thus, can satisfy requirements for a packaging process and long-term reliability.
  • a PA10T molding composite material includes the following components in parts by weight: PA10T resin 40-70 parts; wollastonite 30-60 parts; and toner 0.4-5 parts; in a resin matrix of the PA10T molding composite material, the wollastonite has an average diameter of 4-20 ⁇ m and an average length of 10-250 ⁇ m; a crystallization peak width at half maximum ⁇ T 1/2 of the PA10T molding composite material is measured to be 3-10°C by differential scanning calorimetry at a cooling rate of 20°C/min after being heated up to 345°C; and where the PA10T molding composite material has a whiteness of less than 26 and a 460 nm light source reflectivity of less than 6.5%.
  • a crystallization peak width at half maximum ⁇ T 1/2 of the PA10T molding composite material is measured to be 4.5-7°C by differential scanning calorimetry at a cooling rate of 20°C/min after being heated up to 345°C.
  • the PA10T resin in the present invention may be a commercially available product, and also may be synthesized by the following method.
  • the PA10T used in the examples and comparative examples of the present invention is a homemade sample; raw materials such as monomers and end-capping reagents are commercially available products.
  • the range of the number average molecular weight of the PA10T is not particularly defined in the present invention; the number average molecular weight of the PA10T resin is 1,500-26,000, which may achieve the objectives of the present invention.
  • the number average molecular weight is tested by a conventional method, specifically as follows: the number average molecular weight (Mn) of the PA10T resin sample is determined by gel permeation chromatography (GPC).
  • GPC gel permeation chromatography
  • the molecular weight of the resin is determined at a column temperature of 40°C using hexafluoroisopropanol as a mobile phase. Data is processed using the cirrus software of a chromatographic work station to obtain the number average molecular weight distribution Mn.
  • the toner is at least one or a mixture of more toners selected from the group consisting of a carbon black toner, a black toner, and an amorphous carbon toner. It is available to use color mixing via using black as the major color and adding a small amount of other colors of toners, such as, purple, blue, and red.
  • the toner is selected from an amorphous carbon toner.
  • the PA10T molding composite material of the present invention is for use in preparing an LED display light source reflection support.
  • the present invention has the following beneficial effects:
  • the 460 nm light source reflectivity is mainly correlated to the surface roughness (when the surface roughness of an object becomes larger within a certain range, the ray of light emitted from a light source will generate diffuse reflection on the surface of the object, and finally, the energy of the ray of light received on a receiving end is less) and whiteness of materials (the lower the whiteness is, the lower the reflectivity is).
  • the LED display light source reflection support mainly affects the gray scale and contrast of the LED display via whiteness and reflectivity of the light source reflection support.
  • the PA10T molding composite material of the present invention is to control the whiteness to be less than 26, and control the reflectivity of a 460 nm light source to be less than 6.5% (to improve the gray scale and contrast) through the following three aspects. Moreover, the PA10T molding composite material of the present invention has the advantages of low blue ray of the LED screen packaged with long-term packaging stability (tightness).
  • the excellent tightness is achieved by adjusting the crystallization peak width at half maximum of the PA10T molding composite material, the specification of the wollastonite, and surface roughness.
  • Raw materials used in the examples and comparative examples are as follows: Monomers used in the polymerization of the following polyamides are commercially available products, polymerized pure.
  • Example 1-6 when the crystallization peak width at half maximum is controlled within the preferable range by increasing the amount of the wollastonite added, the tightness grade improves, whiteness and reflectivity are low.
  • Table 2 components (parts by weight) of the PA10T molding composite materials and test results in Examples 7-10 Example 7 Example 8 Example 9 Example 10 PA10T-A 60 60 60 60 Wollastonite A 45 45 45 45 Toner A 1 1.5 2 1 Toner D 0.5 Crystallization peak width at half maximum ⁇ T 1/2 , °C 6.3 6.3 6.3 6.3 Tightness grade B B B B Whiteness 22.62 21.57 21.10 22.34 Reflectivity, % 3.24 2.88 2.64 3.04
  • Example 4 As can be seen from Examples 4/7/8/9/10, whiteness and reflectivity are reduced by adjusting the amount of the toner used.
  • Table 3 components (parts by weight) of the PA10T molding composite materials and test results in Examples 11-15 Example 11 Example 12 Example 13 Example 14 Example 15 PA10T-A 60 60 60 60 60 Wollastonite A 45 45 Wollastonite B 45 Wollastonite C 45 Wollastonite D 45 Toner A 0.5 0.5 0.5 Toner B 0.5 Toner C 0.5 Crystallization peak width at half maximum ⁇ T 1/2 , °C 6.5 6.9 7.4 6.3 6.3 Tightness grade A A B B B Whiteness 24.18 23.94 24.64 24.70 25.53 Reflectivity, % 3.77 3.50 4.26 4.31 5.24
  • the wollastonite has an average diameter of 6-13 ⁇ m and an average length of 80-120 ⁇ m; the toner is preferably an amorphous carbon toner.
  • Table 4 components (parts by weight) of the PA10T molding composite materials and test results in Examples 16-21 Example 16 Example 17 Example 18 Example 19 Example 20 Example 21 PA10T-B 60 PA10T-C 60 PA10T-D 60 PA10T-E 60 PA10T-F 60 PA10T-G 60 Wollastonite A 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 Toner A 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Crystallization peak width at half maximum ⁇ T 1/2 , °C 3.9 4.3 5.1 6.9 8.2 8.5 Tightness grade C C B B C C Whiteness 23.64 24.
  • the crystallization peak width at half maximum of the PA10T is adjusted by adding the wollastonite and toner, thus affecting the tightness grade, whiteness and reflectivity of the molding composite material.
  • the crystallization peak width at half maximum in Examples 18/19 is within the preferable range, the tightness grade and reflectivity are better.

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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Theoretical Computer Science (AREA)
  • Optics & Photonics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Planar Illumination Modules (AREA)

Abstract

The present invention provides a PA10T molding composite material that can be used to produce LED display light source reflection supports. The width of the crystallization peak at half height ΔT1/2 is adjusted to 3°C-10°C, the whiteness is adjusted to be less than 26, and the 460 nm light source reflectivity is adjusted to be less than 6.5%, such that the PA10T molding compound has the advantages of low blue light, high contrast, and high grayscale, can satisfy requirements of a packaging process and long-term reliability, and can be used as a packaging product to manufacture high-contrast LED display light source reflection supports applicable in multiple scenarios.

Description

    TECHNICAL FIELD
  • The present invention relates to the technical field of high polymer materials, and in particular, to a PA10T molding composite material, a preparation method therefor and use thereof.
  • BACKGROUND
  • LED light source mainly consists of a semiconductor chip, an LED light source reflection support, gold wire, and a packaging adhesive. The LED light source reflection support is the "framework" of an LED light source, and also is a functional element. LED packaging process is to assemble other materials and components therein through die bonding, wire welding, and packaging adhesive solidification. The LED reflection support needs to reflect the light emitted from an LED chip through a certain angle to reduce light loss, and to enable the light to transmit through packaging materials such as an epoxy resin or a silica gel, thus forming LED illumination or a light source displayed. The LED reflection support material is a kind of core LED lighting material and directly concerns the performance and service life of the LED light source.
  • The several points need to be considered in the selection of the LED reflection support material at the present stage:
    • Firstly, in the whole packaging process, the LED reflection support needs to be exposed at 150-200°C for 6-10 h; meanwhile, the packaged lamp beads need to be treated with a surface mount technology (SMT) when prepared to a display; the LED support or lamp bead is required to be free of deformation and free of damage under a load during the packaging or SMT process. Moreover, there is a higher demand for the tightness of the LED support material.
    • Secondly, in recent years, the LED display light source has gradually developed into a small-pitch display having a dot pitch of P2.5 below such that research & development and manufacturing of the LED display are unremittingly experiencing a great challenge. The small-pitch display support is gradually developed into thin wall, multi-mold cavity, and small size, which is more demanding for the mobility of the LED reflection support material, formability of the excessive mold cavities, mechanical strength, and the like.
    • Thirdly, during use procedure, the LED luminaire or display is often affected by severe weather such as high temperature, typhoon, rainstorm, thunder and lightning under different environment. To ensure the luminaire or display safe and sound in severe weather, there is a higher demand for the dimensional stability of the materials used, and other performances.
    • Fourthly, in the field of LED display application, to ensure the display image clear and keen, the display brightness and contrast are very important indicators. Currently, the solution used on the market more is the LED support produced by the pure white LED reflection support material; the support surface needs to be silk-screen printed with black ink; the process is tedious, efficiency is affected and cost is high; however, the surfaces of its side and reflection cup are still white, which reduces the contrast and gray scale displayed by the LED display.
    • Fifth, in terms of light source: on one hand, the wavelength capable of being perceived by ordinary people's eyes ranges from 780 nm to 400 nm. Short-wave blue ray having a wavelength of 400-450 nm causes the most serious extent of harm to retina; the blue ray at such a wavelength will increase the amount of toxins in the macular region of eyes, thereby seriously threatening people's eyes health. On the other hand, the light source of the LED full-color display consists of red (R), green (G), and blue (B) three chips, of which the brightness of the blue ray chip is the lowest, i.e., the contrast is the highest. Therefore, the overall contrast of the LED display will be directly affected by the reflectivity of chip-based blue ray on the LED light source support. LED screen anti blue-ray has popularized to the LED screens of various mobile phones and TVs; ordinary means are to paint an anti-blue ray film on the surface of the screen, but the means has the shortcomings of weak film and high costs, respectively.
  • Those skilled in the art are mainly focused on the aforesaid first and second points in terms of the improvement of the LED reflection support material. Packaging stability of the polyamide molding composite material is concerned less. Moreover, the contrast and gray scale of the LED display support are not improved by improving the contrast and gray scale of the material per se.
  • SUMMARY
  • The objective of the present invention is to overcome the technical shortcomings, and to provide a polyamide molding composite material; the present invention has a high contrast and a high gray scale and thus, can satisfy requirements for a packaging process and long-term reliability.
  • Another objective of the present invention is to provide use of the aforesaid polyamide molding composite material.
  • The present invention is achieved by the following technical solution:
    A PA10T molding composite material includes the following components in parts by weight:
    PA10T resin 40-70 parts;
    wollastonite 30-60 parts; and
    toner 0.4-5 parts;

    in a resin matrix of the PA10T molding composite material, the wollastonite has an average diameter of 4-20 µm and an average length of 10-250 µm;
    a crystallization peak width at half maximum ΔT1/2 of the PA10T molding composite material is measured to be 3-10°C by differential scanning calorimetry at a cooling rate of 20°C/min after being heated up to 345°C;
    and where the PA10T molding composite material has a whiteness of less than 26 and a 460 nm light source reflectivity of less than 6.5%.
  • Preferably, a crystallization peak width at half maximum ΔT1/2 of the PA10T molding composite material is measured to be 4.5-7°C by differential scanning calorimetry at a cooling rate of 20°C/min after being heated up to 345°C.
  • The PA10T resin in the present invention may be a commercially available product, and also may be synthesized by the following method. To achieve more precise experiment, the PA10T used in the examples and comparative examples of the present invention is a homemade sample; raw materials such as monomers and end-capping reagents are commercially available products.
    1. (1) Pre-polymerization: terephthalic acid, 1,10-diaminodecane, an end-capping reagent benzoic acid and deionized water are added to a stainless steel high-pressure reactor provided with mechanical stirring. The reactor is vacuumized and replaced with N2 for three times, heated up to 180°C at a heating rate of 5°C/min and stirred, 60 min later after constant temperature, heated up to 270°C at a heating rate of 2°C/min, slowly stirred and subjected to constant temperature for 4 h such that the pre-polymerization reaction is performed fully. After the constant temperature, the reactor was slowly heated up to 280°C, and water is drained off to get normal pressure. The drain valve is turned off after the pressure reduces to normal pressure, after the reaction, the rector is cooled to room temperature, and discharged.
    2. (2) Solid phase viscosification: the materials prepared during the pre-polymerization are added to a vacuum rotary blower with a rotational speed preset at 10 r/min and a vacuum degree preset at 30 Pa. The rotary blower is heated up to 265°C at a rate of 20°C/min, samples are then taken and tested to obtain a viscosity, and the discharging end point is determined according to the viscosity (or number average molecular weight).
  • The range of the number average molecular weight of the PA10T is not particularly defined in the present invention; the number average molecular weight of the PA10T resin is 1,500-26,000, which may achieve the objectives of the present invention. The number average molecular weight is tested by a conventional method, specifically as follows: the number average molecular weight (Mn) of the PA10T resin sample is determined by gel permeation chromatography (GPC). Agilent HPLC- 1260 high performance liquid chromatograph, preparation: Eppendorf column oven, Shodex KF-801, 802, 802.5 and 803 GPC columns, differential detector, and G7129A automatic sampler. The molecular weight of the resin is determined at a column temperature of 40°C using hexafluoroisopropanol as a mobile phase. Data is processed using the cirrus software of a chromatographic work station to obtain the number average molecular weight distribution Mn.
  • Preferably, in the resin matrix of the PA10T molding composite material, the wollastonite has an average diameter of 6-13 µm and an average length of 80-120 µm; Wollastonite is a kind of powder having a certain length-to-diameter ratio, its microstructure is fibrous, and its length and diameter almost keep the same during the shear melting process of a screw. Experiments show that two substances, PA10T and wollastonite (average diameter of 17 µm and average length of 180 µm) are blended by a shear melting process, and then the resin is dissolved out with a solvent; average diameter and average length of wollastonite are tested. It has been found that the diameter of wollastonite is kept the same and its average length changes about 0.5% during the shear process of the screw.
  • The toner is at least one or a mixture of more toners selected from the group consisting of a carbon black toner, a black toner, and an amorphous carbon toner. It is available to use color mixing via using black as the major color and adding a small amount of other colors of toners, such as, purple, blue, and red.
  • Preferably, the toner is selected from an amorphous carbon toner.
  • Preferably, the PA10T molding composite material has a 460 nm light source reflectivity of less than 5%, and more preferably, the P A10T molding composite material has a 460 nm light source reflectivity of less than 2.5-4%.
  • The PA10T molding composite material further includes 0-3 parts of an antioxidant in part by weight; the antioxidant is selected from at least one of from group consisting of hindered phenol antioxidants, hindered amine antioxidants, phosphite ester antioxidants, mercaptan antioxidants, and thiodipropionate antioxidants.
  • The PA10T molding composite material of the present invention is for use in preparing an LED display light source reflection support.
  • A method for preparing the PA10T molding composite material of the present invention includes the following steps: adding components to a blender mixer for uniform mixing, extruding and pelleting the mixed components with a twin-screw extruder to obtain the PA10T molding composite material, where the screw temperature ranges within 280-330°C, and the revolving speed is 450 r/min.
  • The present invention has the following beneficial effects:
    The 460 nm light source reflectivity is mainly correlated to the surface roughness (when the surface roughness of an object becomes larger within a certain range, the ray of light emitted from a light source will generate diffuse reflection on the surface of the object, and finally, the energy of the ray of light received on a receiving end is less) and whiteness of materials (the lower the whiteness is, the lower the reflectivity is). The LED display light source reflection support mainly affects the gray scale and contrast of the LED display via whiteness and reflectivity of the light source reflection support. Based on the principle, the PA10T molding composite material of the present invention is to control the whiteness to be less than 26, and control the reflectivity of a 460 nm light source to be less than 6.5% (to improve the gray scale and contrast) through the following three aspects. Moreover, the PA10T molding composite material of the present invention has the advantages of low blue ray of the LED screen packaged with long-term packaging stability (tightness).
  • Firstly, compared with other inorganic fillers, wollastonite enables the surface roughness of the PA10T molding composite material workpiece to a reasonable range of reducing reflection of light, i.e., the reflectivity of a 460 nm light source is reduced. The preferable size distribution of the wollastonite in the resin matrix can further reduce the reflectivity of a 460 nm light source (to reduce the blue ray of the LED display).
  • Secondly, the color of materials is adjusted with a toner to obtain the black with good light absorption effect; preferably, the amorphous carbon toner can further reduce the whiteness and improve the light absorption, thereby reducing the reflectivity of a 460 nm light source.
  • Thirdly, through experimental findings, the crystallization peak width at half maximum of the PA10T molding composite material also will obviously affect the reflectivity of a 460 nm light source of the composite material; when the crystallization peak width at half maximum ΔT1/2 of the composite material is 3.5-10°C, the surface roughness of the prepared workpiece can meet the requirement of reducing the reflectivity of a 460 nm light source. In the technical solution of the present invention, the crystallization peak width at half maximum of the PA10T molding composite material is mainly adjusted by the amount and specification of the toner and wollastonite added, and the number average molecular weight of the PA10T.
  • Fourthly, on the other hand, the excellent tightness is achieved by adjusting the crystallization peak width at half maximum of the PA10T molding composite material, the specification of the wollastonite, and surface roughness.
  • The PA10T molding composite material of the present invention has no need for painting a light-absorbing paint or matting additionally, and thus reduces the cost of the LED display light source support.
  • DETAILED DESCRIPTION OF EMBODIMENTS
  • The present invention will be further described with reference to the detailed examples. The following examples will help those skilled in that art further understand the present invention, but are not construed as limiting the scope of the present invention in any form. It should be indicated that those skilled in the art could further make several deformations and improvements in the premise of not departing from the inventive concept. These all fall within the protection scope of the present invention.
  • Raw materials used in the examples and comparative examples are as follows:
    Monomers used in the polymerization of the following polyamides are commercially available products, polymerized pure.
    • PA10T-A: a number average molecular weight of 3,000 and a crystallization peak width at half maximum ΔT1/2 of 8.5°C, it is homemade referring to the method of the summary of the present invention;
    • PA10T-B: a number average molecular weight of 3400 and a crystallization peak width at half maximum ΔT1/2 of 5.6°C, it is homemade referring to the method of the summary of the present invention;
    • PA10T-C: a number average molecular weight of 5500 and a crystallization peak width at half maximum ΔT1/2 of 5.9°C, it is homemade referring to the method of the summary of the present invention;
    • PA10T-D: a number average molecular weight of 6500 and a crystallization peak width at half maximum ΔT1/2 of 6.5°C, it is homemade referring to the method of the summary of the present invention;
    • PA10T-E: a number average molecular weight of 10000 and a crystallization peak width at half maximum ΔT1/2 of 11.2°C, it is homemade referring to the method of the summary of the present invention;
    • PA10T-F: a number average molecular weight of 12000 and a crystallization peak width at half maximum ΔT1/2 of 12.4°C, it is homemade referring to the method of the summary of the present invention;
    • PA10T-G: a number average molecular weight of 25000 and a crystallization peak width at half maximum ΔT1/2 of 15.3°C, it is homemade referring to the method of the summary of the present invention.
    • Wollastonite A: an average diameter of 4 µm and an average length of 60 µm;
    • Wollastonite B: an average diameter of 6 µm and an average length of 120 µm;
    • Wollastonite C: an average diameter of 13 µm and an average length of 80 µm; and
    • Wollastonite D: an average diameter of 17 µm and an average length of 180 µm.
  • The wollastonite used in the present invention is purchased commercially and screened to obtain the required ranges of the average diameter and average length.
    • Talc powder: AH-1250, Guangxi Longsheng Huamei Talc Development Co., Ltd.
    • Toner A: amorphous carbon toner N774, Tianjin Tianyang Qiushi Chemical Technology Co. LTD.
    • Toner B: carbon black M570, CABOT Chemical;
    • Toner C: Black UN2014, CABOT Chemical;
    • Toner D: Mazcol Blue 153K, Shenzhen Dingtai Chemical Co., LTD.
    • Antioxidant: Irganox 1 098, hindered phenol antioxidants.
  • Methods for preparing the polyamide molding composite materials in examples and comparative examples: PA10T, wollastonite, toner and antioxidants were added to a blender mixer and mixed well, extruded and pelleted with a twin-screw extruder to obtain the PA10T molding composite material, where the screw temperature ranged within 280-330°C, and the revolving speed was 450 r/min.
  • Test method:
    1. (1) Tightness: representation of the tightness of the support plastic and hardware by red ink testing on the PA10T molding composite material sample: a LED display light source support material and an electroplating hardware strip were soaked with red ink in an injection in-molded LED reflector cup; pins were soaked with red ink and placed to observe whether red ink permeates into the reflector cup.
      If red ink does not permeate into the reflector cup within 5 min, the tightness grade was determined as level A;
      • if red ink does not permeate into the reflector cup within 3 min, but permeates within 5 min, the tightness grade was determined as level B;
      • if red ink does not permeate into the reflector cup within 1 min, but permeates within 3 min, the tightness grade was determined as level C;
      • if red ink permeates into the reflector cup within 1 min, the tightness grade was determined as level D; and
      • if the tightness grade was level D, the tightness between plastic and hardware was proved to be poor, which may lead to the risk of lamp bead failure. On the contrary, if the tightness grade was level A, B, or C, the packaged lamp bead has excellent gas tightness and good reliability.
    2. (2) Whiteness: representation of the contrast of materials via its whiteness index: the PA10T molding composite material was injection molded to prepare a test piece having a length of 60 mm, a width of 60 mm, and a thickness of 1 mm. A Color Eye 7000A color difference meter was used to measure values L, a and b to calculate the whiteness: W H = 100 100 L 2 + a 2 + b 2 1 / 2 .
      Figure imgb0001
    3. (3) Reflectivity: the PA10T molding composite material was injection molded to prepare a test piece having a length of 60 mm, a width of 60 mm, and a thickness of 1 mm. A Color Eye 7000A color difference meter was used to measure the reflectivity of the test piece to a 460 nm-wavelength light.
    4. (4) Crystallization peak width at half maximum ΔT1/2 of the PA10T molding composite material: the PA10T molding composite material was heated up to 345°C from 30°C at a rate of 20°C/min under nitrogen conditions, 2 min later after constant temperature, cooled at a cooling rate of 20°C/min; the temperature of the crystallization peak emerging at this time was set as a crystallization temperature Tc (°C), and the temperature at an half of the peak width measured was set as a crystallization peak width at half maximum ΔT 1/2.
    Table 1: components (parts by weight) of the PA10T molding composite materials and test results in Examples 1-6
    Example 1 Example 2 Example 3 Example 4 Example 5 Example 6
    PA10T-A 60 60 60 60 60 60
    Wollastonite A 30 35 40 45 50 60
    Toner A 0.5 0.5 0.5 0.5 0.5 0.5
    Crystallization peak width at half maximum ΔT1/2, °C 7.6 7.1 6.5 6.3 6.0 5.6
    Tightness grade B B B B A A
    Whiteness 25.88 25.61 25.17 24.35 23.80 24.22
    Reflectivity, % 6.05 5.64 4.30 4.07 3.81 4.18
  • As can be seen from Examples 1-6, when the crystallization peak width at half maximum is controlled within the preferable range by increasing the amount of the wollastonite added, the tightness grade improves, whiteness and reflectivity are low. Table 2: components (parts by weight) of the PA10T molding composite materials and test results in Examples 7-10
    Example 7 Example 8 Example 9 Example 10
    PA10T-A 60 60 60 60
    Wollastonite A 45 45 45 45
    Toner A 1 1.5 2 1
    Toner D 0.5
    Crystallization peak width at half maximum ΔT1/2, °C 6.3 6.3 6.3 6.3
    Tightness grade B B B B
    Whiteness 22.62 21.57 21.10 22.34
    Reflectivity, % 3.24 2.88 2.64 3.04
  • As can be seen from Examples 4/7/8/9/10, whiteness and reflectivity are reduced by adjusting the amount of the toner used. Table 3: components (parts by weight) of the PA10T molding composite materials and test results in Examples 11-15
    Example 11 Example 12 Example 13 Example 14 Example 15
    PA10T-A 60 60 60 60 60
    Wollastonite A 45 45
    Wollastonite B 45
    Wollastonite C 45
    Wollastonite D 45
    Toner A 0.5 0.5 0.5
    Toner B 0.5
    Toner C 0.5
    Crystallization peak width at half maximum ΔT1/2, °C 6.5 6.9 7.4 6.3 6.3
    Tightness grade A A B B B
    Whiteness 24.18 23.94 24.64 24.70 25.53
    Reflectivity, % 3.77 3.50 4.26 4.31 5.24
  • As can be seen from Examples 4/11-15, preferably, the wollastonite has an average diameter of 6-13 µm and an average length of 80-120 µm; the toner is preferably an amorphous carbon toner. Table 4: components (parts by weight) of the PA10T molding composite materials and test results in Examples 16-21
    Example 16 Example 17 Example 18 Example 19 Example 20 Example 21
    PA10T-B 60
    PA10T-C 60
    PA10T-D 60
    PA10T-E 60
    PA10T-F 60
    PA10T-G 60
    Wollastonite A 45 45 45 45 45 45
    Toner A 0.5 0.5 0.5 0.5 0.5 0.5
    Crystallization peak width at half maximum ΔT1/2, °C 3.9 4.3 5.1 6.9 8.2 8.5
    Tightness grade C C B B C C
    Whiteness 23.64 24.30 23.55 24.15 24.81 24.53
    Reflectivity, % 4.80 5.00 4.37 4.18 4.67 4.66
    Table 5: components (parts by weight) of the PA10T molding composite materials and test results in Examples 22-24
    Example 22 Example 23 Example 24 Example 25 Example 26
    PA10T-B 60 40 70
    PA10T-G 60 60
    Wollastonite A 35 55 35 60
    Wollastonite B 55
    Toner A 1.5 0.5 1 0.8 5
    Antioxidant 0.5
    Crystallization peak width at half maximum ΔT1/2, °C 4.5 7.0 6.9 4.1 4.2
    Tightness grade B B A B B
    Whiteness 22.04 24.28 23.27 21.65 20.12
    Reflectivity, % 3.01 3.96 3.46 2.88 2.25
  • As can be seen from Examples 4/16-24, the crystallization peak width at half maximum of the PA10T is adjusted by adding the wollastonite and toner, thus affecting the tightness grade, whiteness and reflectivity of the molding composite material. Specifically, as can be seen from Examples 16-21, when the crystallization peak width at half maximum in Examples 18/19 is within the preferable range, the tightness grade and reflectivity are better. Table 6: components (parts by weight) of the PA10T molding composite materials and test results in Comparative Examples
    Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 Comparative Example 7
    PA10T-A 60 60 60 60
    PA10T-B 60
    PA10T-G 60 60
    Wollastonite A 70 20 70 25 30 30
    Talc powder 45
    Toner A 0.5 0.5 0.5 0.5 0.5 0.2 6
    Crystallization peak width at half maximum ΔT1/2, °C 2.9 10.4 8.3 6.5 7.1 7.6 7.2
    Tightness grade D D D D C B D
    Whiteness 25.77 28.70 27.84 27.40 26.91 28.35 22.30
    Reflectivity, % 7.20 7.88 7.35 12.33 6.80 7.21 6.8
  • As can be seen from Comparative Example 1, too high content of wollastonite will lead to a too low crystallization peak width at half maximum; the tightness grade is not only poor, but also the surface structure of the PA10T molding composite material workpiece is damaged, thus leading to poor reflectivity.
  • As can be seen from Comparative Example 2, too low content of wollastonite may not enable the crystallization peak width at half maximum to be reduced within 10°C; therefore, the tightness grade is not only poor, but also the reflectivity is high.
  • As can be seen from Comparative Example 3, the PA10T molding composite material added with too much wollastonite may not achieve the purposes of excellent tightness grade and low reflectivity even though the crystallization peak width at half maximum ranges from 3°C to 10°C. This is because too much wollastonite damages the surface structure of the composite material; moreover, as wollastonite is a kind of white powder, too much amount may increase the whiteness on the contrary.
  • As can be seen from Comparative Example 4, wollastonite may not be replaced by talc powder.
  • As can be seen from Comparative Example 5, if the content of wollastonite is too low, it fails to achieve the purposes of excellent tightness grade and low reflectivity even though the crystallization peak width at half maximum ranges from 3°C to 10°C.
  • As can be seen from Comparative Example 6, too low content of the toner may lead to a too high whiteness and a high reflectivity.
  • As can be seen from Comparative Example 7, too much toner added may lead to the enrichment of too much toner onto the surface, thereby affecting the tightness and reflectivity.

Claims (10)

  1. A PA10T molding composite material, characterized by comprising the following components in parts by weight: PA10T resin 40-70 parts; wollastonite 30-60 parts; and toner 0.4-5 parts;
    in a resin matrix of the PA10T molding composite material, the wollastonite has an average diameter of 4 µm to 20 µm and an average length of 10 µm to 250 µm;
    a crystallization peak width at half maximum ΔT1/2 of the PA10T molding composite material is measured to be 3°C to 10°C by differential scanning calorimetry at a cooling rate of 20°C/min after being heated up to 345°C;
    and wherein the PA10T molding composite material has a whiteness of less than 26 and a 460 nm light source reflectivity of less than 6.5%.
  2. The PA10T molding composite material according to claim 1, characterized in that, the crystallization peak width at half maximum ΔT1/2 of the PA10T molding composite material is measured to be 4.5°C to 7°C by differential scanning calorimetry at a cooling rate of 20°C/min after being heated up to 345°C.
  3. The PA10T molding composite material according to claim 1, characterized in that, the PA10T resin has a number average molecular weight of 1,500 to 26,000.
  4. The PA10T molding composite material according to claim 1, characterized in that, in the resin matrix of the PA10T molding composite material, the wollastonite has an average diameter of 6 µm to 13 µm and an average length of 80 µm to 120 µm.
  5. The PA10T molding composite material according to claim 1, characterized in that, the toner is at least one or a mixture of more toners selected from the group consisting of a carbon black toner, a black toner, and an amorphous carbon toner.
  6. The PA10T molding composite material according to claim 5, characterized in that, the toner is selected from an amorphous carbon toner.
  7. The PA10T molding composite material according to claim 1, characterized in that, preferably, the PA10T molding composite material has a 460 nm light source reflectivity of less than 5%, and more preferably, the PA10T molding composite material has a 460 nm light source reflectivity of less than 2.5% to 4%.
  8. The PA10T molding composite material according to claim 1, characterized in that, the PA10T molding composite material further comprises 0-3 parts of an antioxidant in part by weight.
  9. A method for preparing the PA10T molding composite material according to any one of claims 1-8, characterized by comprising the following steps: adding components to a blender mixer for uniform mixing; extruding and pelleting the mixed components with a twin-screw extruder to obtain the PA10T molding composite material, wherein a screw temperature ranges within 280°C to 330°C, and a revolving speed ranges within 400 r/min to 500 r/min.
  10. A use of the PA10T molding composite material according to any one of claims 1-8, in preparing an LED display light source reflection support.
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CN112358610A (en) * 2020-05-28 2021-02-12 金发科技股份有限公司 Polyamide and polyamide molding composition composed of same
CN112745672B (en) * 2020-12-16 2022-06-14 金发科技股份有限公司 Polyamide molding composition and preparation method and application thereof
CN112724667B (en) * 2020-12-16 2022-06-14 金发科技股份有限公司 Polyamide molding composition and preparation method and application thereof

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