EP4367073A1 - A chemical solution for cutting glass - Google Patents
A chemical solution for cutting glassInfo
- Publication number
- EP4367073A1 EP4367073A1 EP22837182.9A EP22837182A EP4367073A1 EP 4367073 A1 EP4367073 A1 EP 4367073A1 EP 22837182 A EP22837182 A EP 22837182A EP 4367073 A1 EP4367073 A1 EP 4367073A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- glass
- cutting
- alcohol
- chemical solution
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/06—Joining glass to glass by processes other than fusing
- C03C27/10—Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B33/00—Severing cooled glass
- C03B33/02—Cutting or splitting sheet glass or ribbons; Apparatus or machines therefor
- C03B33/023—Cutting or splitting sheet glass or ribbons; Apparatus or machines therefor the sheet or ribbon being in a horizontal position
- C03B33/033—Apparatus for opening score lines in glass sheets
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B33/00—Severing cooled glass
- C03B33/07—Cutting armoured, multi-layered, coated or laminated, glass products
- C03B33/074—Glass products comprising an outer layer or surface coating of non-glass material
Definitions
- the present disclosure relates, in general to glass cutting, and more specifically to a chemical solution for cutting glass and a method for chemically cutting glass.
- glass in sheet form is usually produced on a continuous basis.
- the principal glass cutting devices are of the type which scribe a small score across the glass sheet to be cut, the score being scribed by a material which is harder than glass, such as diamond. The score weakens the glass sheet and when bending pressure is applied to the glass along the score, the glass breaks along the score to produce a glass article of the desired size. All of the principal glass cutting methods employ the scribing technique, and the scribing tool used is always formed of a material harder than glass.
- This conventional glass cutting method is no trouble when the glass to be cut is a plain glass substrate that has no pre-applied coating(s) on one or both of its surface.
- a coating not limiting to paint or lacquer or other functional coatings such as a lamination layer for laminating glass or protective coating for providing safety from glass shattering is applied on the glass surface
- the conventional glass cutting method becomes inefficient. This is particularly true for a glass bearing a lamination or a polymer-based coating layer. This is because, while the conventional cutting method seamlessly cuts the glass side of a coated glass sheet, it does little to cut through the coated side of the glass sheet i.e., the surface of the glass bearing these coating layers.
- CNC cutting tools are used for cutting glass sheets bearing above mentioned coating layers wherein the glass is cut not from the glass side but from the coating side of the glass sheet.
- the glass side has always been a preference for cutting glass from the glass side as opposed to the coating side as the former provides more control over handling of the cutting tool.
- the present disclosure relates to a simple 2-component solution that can used for cutting mirror, lacquered glass, functionally-coated glass and laminated glass.
- the chemical solution proposed by the present disclosure for cutting glass comprises 20 to 80% of a hydrocarbon-based cutting medium and 80 to 20% of an alcohol-based carrying medium.
- the proposed chemical solution requires no external heat or pressure to cut the glass substrates.
- a method for cutting glass using the chemical solution is also disclosed.
- a chemical solution for cutting glass comprises a hydrocarbon-based cutting medium selected from n-hexane, heptane, acetone, xylene, methyl cyclohexane, toluene or isooctane; and an alcohol-based carrying medium selected from diacetyl-alcohol, isopropyl alcohol, ethyl alcohol, methyl alcohol, butyl alcohol or glycerol.
- the hydrocarbon -based cutting medium constitutes about 20 to 80% of the chemical solution while the alcohol-based carrying medium constitutes about 80 to 20% of the chemical solution.
- a method for chemically cutting glass comprises the steps of: cleaning the surface of a glass, scoring the glass using a glass scoring tool, separating the glass surface along the scoring line to create a V-shaped wedge, applying the chemical cutting solution of the present disclosure in the V-shaped wedge and snapping apart the two pieces of the scored glass along the scoring line.
- the chemical cutting solution dissolves the underlying paint, lacquer, coating or interlayer of the glass to separate the two pieces of scored glass.
- FIG. 1 illustrates a glass sheet 100, according to multiple embodiments of the present disclosure
- FIG. 2 illustrates scoring of a glass sheet 100 to form a V-shaped wedge, according to one embodiment of the present disclosure
- FIG. 3 illustrates chemical cutting of glass sheet 100, according to one embodiment of the present disclosure
- FIG. 4A depicts an exemplary dispenser D for the chemical cutting solution, according to one embodiment of the present disclosure.
- FIG. 4B depicts an exemplary dispenser D for the chemical cutting solution, according to another embodiment of the present disclosure.
- Embodiments disclosed herein are related to a chemical solution for cutting glass and a method for chemically cutting glass.
- FIG. 1 illustrates a glass sheet 100 which is meant to be cut with the chemical solution described in the present disclosure using the method that will be outlined below.
- the glass sheet 100 (and also all glass sheets in general) have a glass side A and a coating side B as indicated in the said figure.
- the coating C present on the coating side B is a lacquer.
- the glass sheet 100 is a laminated glass, then the said glass sheet may be adopted in such a way that it is obtained by adhering two glass substrates to each other with a lamination layer there between (not shown in figure).
- the coating side B is provided with a styrene-butadiene-based coating layers.
- the coating side B is provided with paint overlaid with additional layer or layers.
- the glass sheet 100 are manufactured around 10ft by 7ft or 8ft by 6ft, which then are cut into smaller shapes and sizes as is required for the retail market.
- the glass sheet 100 intended to be cut can be any of the type outlined above. In all embodiments of the present disclosure, the glass sheet 100 is intended to be cut on the glass side A.
- a scribe line on a surface of the sheet glass 100 similar to any conventional technique, can be formed with a diamond cutter or a sintered carbide wheel cutter. A scribe line is thus formed by scribing or scoring a line on the sheet glass 100 with a diamond cutter or a sintered carbide wheel cutter.
- a scribe line can be formed by means of a conventional CNC cutting method as that adopted by a CNC machine employed in a conventional technique.
- a scribe line can be formed on a surface of the sheet glass 100.
- the scoring action is performed on the glass side A.
- a planned cutting line is formed on one of the glass sub substrates of the laminated glass, a planned cutting line of the like is usually formed on the other sub-substrate usually directly below the planned cutting line on the first sub-substrate.
- a cut face of the laminated glass is tracked in the thickness direction.
- FIG. 2 illustrates a glass sheet 100 post a scoring operation, where the two parts of the scored glass sheet are gradually titled to create a V-shaped wedge W between the two parts of the glass sheet.
- the scoring action effectively separates the two parts of the glass, it does little to the underlying coating layer C in the glass sheet 100. This is because the scoring operation does not dissolve the underlying coating, which is often a polymeric coating that binds the glass sheet 100 together.
- the coating is a splinter-proof coating as that described in the PCT application PCT/IN2019/050652 owned by the Applicant of the present disclosure.
- the splinter-proof coating forms a protective under layer to the glass substrate and prevents scattering of glass pieces on breakage of the glass substrate.
- the splinter-proof coating is a transparent self- adhesive film, on to which glass pieces formed on breakage of the glass adheres to thereby preventing them from scattering.
- the present disclosure proposes a steady dispensing action of a chemical solution in the V-shaped wedge W formed between the two parts of the glass sheet 100.
- the chemical solution dissolves the underlying coating C binding the two parts of the glass sheet to separate the two pieces of the scored glass sheet 100.
- the chemical solution proposed by the present disclosure comprises of a hydrocarbon-based cutting medium that is effective in cutting/ dissolving the underlying coating of the glass sheet 100.
- the hydrocarbon -based cutting medium is mixed with an alcohol-based carrying medium that optimizes the performance of the hydrocarbon-based cutting medium.
- the carrying medium dilutes the cutting medium in such a way that the chemical solution does not penetrate through the coating C present in the glass sheet 100 post the cutting action.
- This property of the proposed chemical solution enhances efficiency of the cutting medium and ensures nil deterioration of the coating C. This is advantageous because, a deteriorated coating at the edges of the cutting line reduces the aesthetic quotient of the glass sheet and further decreases yield of cut glass during post-production.
- the cutting medium of the chemical solution were to be used alone, the cutting medium penetrates through the coating C present on the glass sheet 100 and deteriorates the coating C causing an undesirable effect. Therefore, to reduce this effect, a carrying medium is added to the cutting medium in an optimized quantity. The carrying medium does not affect the cutting process directly.
- the chemical solution for cutting glass comprises a hydrocarbon-based cutting medium selected from a group consisting of n-hexane, heptane, acetone, xylene, methyl cyclohexane, toluene or isooctane and an alcohol -based carrying medium selected from a group consisting of di acetyl -alcohol, isopropyl alcohol, ethyl alcohol, methyl alcohol, butyl alcohol or glycerol.
- the hydrocarbon-based cutting medium constitutes about 20 to 80% of the chemical solution and the alcohol-based carrying medium constitutes about 80 to 20% of the chemical solution.
- the optimized % ranges of the hydrocarbon-based cutting medium and the alcohol-based carrying medium dissolves the underlying coating C of the glass sheet 100 post a scoring action without any defects to the coating C.
- the hydrocarbon-based cutting medium is n-hexane or heptane.
- the alcohol-based carrying medium is diacetyl-alcohol or isopropyl alcohol.
- the chemical solution for cutting glass comprises at least n-hexane and diacetyl-alcohol.
- the chemical solution for cutting glass comprises at least heptane and isopropyl alcohol.
- the chemical solution for cutting glass comprises 20 to 80% (still more preferred 40% to 50%)n-hexane and 80 to 20% (still more preferred 50% to 60%) of di acetyl -alcohol (still more preferred 50% to 60%).
- the chemical solution for cutting glass comprises 20 to 80% (still more preferred 40% to 50%) heptane and 80 to 20% (still more preferred 50% to 60%) of isopropyl alcohol.
- the chemical solution is caused to flow into the V-shaped wedge W created post the scoring operation.
- this action deepens the depth of the scoring line enabling the chemical solution to come in contact with the underlying coating C holding the two parts of the scored glass sheet 100.
- any of the above mentioned technique can be optimized in order to obtain the best desired effect and so the present disclosure is in no manner limited by the dispending technique used for causing the flow of the chemical cutting solution into the V- shaped wedge formed along the scoring line. Therefore, any other means/ techniques for dispensing the chemical cutting solution of the present disclosure is well within the purview of the present disclosure.
- Automated dispensing techniques such as dispensing gun mimicking a stick glue dispenser or that of a tattoo gun or that of a spray gun are all considered as alternative embodiments through which the chemical cutting solution of the present disclosure can be caused to flow.
- a dispenser D for the chemical solution of the present disclosure is depicted in FIG. 4A and FIG. 4B.
- a dispenser D for the chemical solution of the present disclosure is designed to be made from high-density polyethylene (HDPE) or polypropylene (PP).
- a preferred capacity of such a dispenser D ranges between 150 - 250 ml and bears a precision hole made with a surgical suture needle.
- the precision hole has a diameter ranging between 0.3 mm and 0.6 mm.
- the dispenser D shown in FIG. 4B optionally further comprises a jig to ensure repeatability in dispenser opening action.
- a sealing lid can be added to the dispenser D to ensure zero leakage and lower evaporation of the chemical cutting solution therein.
- the cutting solution of the present disclosure is also effective in cutting laminated glasses comprises two sub-substrates of glasses bonded together by an adhesive interlayer.
- the adhesive interlayers of laminated glasses comprise polyvinyl butyral- (PVB) or ethylene vinyl acetate- (EVA) or ethylene propylene diene monomer- (EPDM) based interlayers.
- PVB polyvinyl butyral-
- EDA ethylene vinyl acetate-
- EPDM ethylene propylene diene monomer-
- the present disclosure further discloses a method for chemically cutting glass using the chemical solution described herein.
- the method comprises of steps (1) to (5).
- the glass sheet 100 illustrated in FIG. 1 of the type mirror, lacquered glass, coated glass or laminated glass is used for performing all or selected steps of the method.
- the method comprises the steps of: (1) cleaning the surface of a glass sheet intended to be cut. Typically glass sheets as small as 100 mm * 100 mm
- a clean cloth is used for cleaning the surface of the glass sheet to be cut.
- the glass sheets are cut on the glass side A of the glass and hence the glass side A of the glass sheet is wiped clean using a clean cloth.
- step (2) the glass sheet is scored along a desired cutting line using a diamond tip cutting tool.
- the scoring line is typically about 0.05 mm in depth. Measurement of the desired cutting line is established using conventional means.
- the glass sheet to be cut is placed on a flat surface such as a working table (larger than the dimension of the sheet glass) such that the desired cutting line is aligned over a wooden block E or other suitable material placed on the flat surface as depicted FIG. 2 and FIG. 3.
- step (3) the two parts of the scored glass sheet is snapped to create a V-shaped wedge using the support of the wooden block E or other suitable material used.
- the weight of the two parts of the scored glass sheet is usually sufficient for the breaking to take place without the action of additional force; however, if the part to be cut is narrow, its weight will probably not be sufficient and additional force will have to be applied either manually or mechanically to create the snapping action creating the V-shaped wedge.
- the chemical solution prepared as per the teachings of the present disclosure is caused to flow into the V-shaped wedge.
- the chemical cutting solution of the present disclosure is envisioned to be kept prepared and stored in a suitable dispenser bottle as described earlier. Before use of the solution the dispenser bottle is required to be shaken well. According to a preferred embodiment of the present disclosure, the chemical solution is dispensed from the dispenser at a rate ranging between 0.5 to 2.5 ml per meter of the glass surface. Since such a small amount of chemical cutting solution is used, the vapors emitted by the alcohol-based carrying medium during the cutting operation are very negligible, which makes the cutting operation much less harmful than ever before.
- This step of causing the chemical cutting solution to flow into the V-shaped wedge of the scored glass sheet deepens the depth of a scoring line such that the solution comes in contact with the underlying coating of the glass sheet. Once the chemical cutting solution contacts the underlying coating a dissolution action takes place.
- the glass sheets intended to be cut using the method described in the present disclosure are mirror, lacquered glass, coated glass and laminated glass.
- the coated glass comprises styrene-butadiene-based coating layers and the laminated glass comprises polyvinyl butyral- (PVB) or ethylene vinyl acetate- (EVA) or ethylene propylene diene monomer- (EPDM) based interlayers.
- PVB polyvinyl butyral-
- EVA ethylene vinyl acetate-
- EPDM ethylene propylene diene monomer-
- the two parts of the glass sheet are separated.
- the result is a clean cut without splinters.
- the chemical cutting solution of the present disclosure cuts the glass sheets within a maximum of 60 seconds of application time. Any excess cutting solution that may be present on the surface of separated glass sheets are wiped away with a clean cloth to prevent any occurrence of corrosion during stacking of the cut pieces of the glass sheet. Any excess cutting solution that may be present at the cut edges of the separated glass sheets are also wiped clean.
- the described chemical cutting procedure of glass sheets advantageously require no external pressure or heat.
- the chemical cutting solution has a shelf life of a maximum of 2 years provided the dispenser used for storing the solution is leakage free and sealed with a lid that prevent evaporation of the solution.
- Solution A and Solution B were tested for quantity required for cutting, speed of cutting, and any damage to the glass sheet or underlying coating of the glass sheet.
- a splinter-proof coated glass of made according to the teaching of PCT application PCT/IN2019/050652 owned by the Applicant was tested for cutting efficiency using solution A.
- solution A was used in order to cut a glass sample of size 915 mm x 1220 mmx 5 mm from a glass sheet that measured 1830 mm x 2440 mm x 5 mm.
- Post marking of the dimension to be cut on the glass sheet a cutting scorer was used to score the glass sheet and create the V-shaped wedge, where a cleavage was formed with the coating remained intact.
- the Solution A was dispensed into the wedge and post 8 - 10 seconds of application, the glass sample was cut and separated from the glass sheet.
- the total cutting length was 2.14 m in length, for which 3-3.2 ml of solution A was used.
- a splinter-proof coated glass of made according to the teaching of PCT application PCT/IN2019/050652 owned by the Applicant was tested for cutting efficiency using solution B.
- solution B was used in order to cut a glass sample of size 1000 mm x 1000 mm x 5 mm from a glass sheet that measured 1830 mm x 2440 mm x 5 mm.
- Post marking of the dimension to be cut on the glass sheet a cutting scorer was used to score the glass sheet and create the V-shaped wedge, where a cleavage was formed with the coating remained intact.
- Solution B was dispensed into the wedge and post 6 - 7 seconds of application, the glass sample was cut and separated from the glass sheet.
- the total cutting length was 2 m in length, for which 2.3 - 2.5 ml of solution B was used.
- the use of the proposed chemical solution of the present disclosure for cutting glass sheets including mirror, lacquered glass, coated glass or laminated glass has a number of advantages. While most of the prior art around this domain require additional treatment conditions while using a chemical solution to cut glass sheets, the present invention necessitates no further/ additional treatment step (such as heating or external pressure be it thermal or mechanical) post the cutting operation using the proposed chemical solution. This is advantageous particularly because the cutting of a glass sheet is performed at a low cost. Further this also means that productivity in glass cutting is improved. Furthermore, since the cutting of the glass sheet is achieved using a chemical treatment step, the glass sheet is not exposed to any physical damage thereby keeping the strength of the glass sheet intact post the cutting operation.
- additional treatment step such as heating or external pressure be it thermal or mechanical
- the terms “comprises,” “comprising,” “includes,” “including,” “has,” “having” or any other variation thereof, are intended to cover a non-exclusive inclusion.
- a method, article, or apparatus that comprises a list of features is not necessarily limited only to those features but may include other features not expressly listed or inherent to such method, article, or apparatus.
- “or” refers to an inclusive-or and not to an exclusive-or. For example, a condition A or B is satisfied by any one of the following: A is true (or present) and B is false (or not present), A is false (or not present) and B is true (or present), and both A and B are true (or present).
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IN202141030251 | 2021-07-06 | ||
| PCT/IN2022/050574 WO2023281526A1 (en) | 2021-07-06 | 2022-06-22 | A chemical solution for cutting glass |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP4367073A1 true EP4367073A1 (en) | 2024-05-15 |
| EP4367073A4 EP4367073A4 (en) | 2025-06-18 |
Family
ID=84800416
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP22837182.9A Pending EP4367073A4 (en) | 2021-07-06 | 2022-06-22 | CHEMICAL SOLUTION FOR CUTTING GLASS |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP4367073A4 (en) |
| MX (1) | MX2024000399A (en) |
| WO (1) | WO2023281526A1 (en) |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2386494A1 (en) * | 1977-04-04 | 1978-11-03 | Saint Gobain | Cutting glass laminate with middle plastics layer - by scoring and cutting glass sheets then heating, bending and dissolving plastic-along score line |
| US5385649A (en) * | 1994-05-18 | 1995-01-31 | Lloyd Berg | Separation of 1-hexene from hexane by azeotropic distillation |
| JP3795897B2 (en) * | 2003-03-24 | 2006-07-12 | 西山ステンレスケミカル株式会社 | Glass surface processing method |
| CN100577755C (en) * | 2008-12-10 | 2010-01-06 | 深圳市嘉卓成科技发展有限公司 | Two-component polyurethane coating and its production method and construction method |
| WO2021086709A1 (en) * | 2019-10-31 | 2021-05-06 | Corning Incorporated | Micro-perforated glass laminates with controlled hole shape, applications thereof, and methods of making micro-perforated glass laminates |
-
2022
- 2022-06-22 WO PCT/IN2022/050574 patent/WO2023281526A1/en not_active Ceased
- 2022-06-22 MX MX2024000399A patent/MX2024000399A/en unknown
- 2022-06-22 EP EP22837182.9A patent/EP4367073A4/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP4367073A4 (en) | 2025-06-18 |
| WO2023281526A1 (en) | 2023-01-12 |
| MX2024000399A (en) | 2024-01-29 |
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| RIC1 | Information provided on ipc code assigned before grant |
Ipc: C03C 17/28 20060101ALI20250509BHEP Ipc: C03C 27/10 20060101ALI20250509BHEP Ipc: C03B 33/033 20060101ALI20250509BHEP Ipc: C03B 33/02 20060101ALI20250509BHEP Ipc: C03B 33/07 20060101AFI20250509BHEP |