EP4367065A1 - System zur behandlung von biokontaminiertem abwasser und verfahren zur dekontaminierung einer abwasserquelle - Google Patents

System zur behandlung von biokontaminiertem abwasser und verfahren zur dekontaminierung einer abwasserquelle

Info

Publication number
EP4367065A1
EP4367065A1 EP22838275.0A EP22838275A EP4367065A1 EP 4367065 A1 EP4367065 A1 EP 4367065A1 EP 22838275 A EP22838275 A EP 22838275A EP 4367065 A1 EP4367065 A1 EP 4367065A1
Authority
EP
European Patent Office
Prior art keywords
wastewater
water
outlet
flow
inlet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP22838275.0A
Other languages
English (en)
French (fr)
Inventor
John D. Riley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
VERNO HOLDINGS LLC
Original Assignee
VERNO HOLDINGS LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US17/369,097 external-priority patent/US11608278B2/en
Application filed by VERNO HOLDINGS LLC filed Critical VERNO HOLDINGS LLC
Publication of EP4367065A1 publication Critical patent/EP4367065A1/de
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/08Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in rotating vessels; Atomisation on rotating discs
    • B01D3/085Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in rotating vessels; Atomisation on rotating discs using a rotary evaporator
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/0011Heating features
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/0082Regulation; Control
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D25/00Filters formed by clamping together several filtering elements or parts of such elements
    • B01D25/28Leaching or washing filter cakes in the filter handling the filter cake for purposes other than regenerating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D25/00Filters formed by clamping together several filtering elements or parts of such elements
    • B01D25/30Feeding devices ; Discharge devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/08Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in rotating vessels; Atomisation on rotating discs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/10Vacuum distillation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D33/00Filters with filtering elements which move during the filtering operation
    • B01D33/15Filters with filtering elements which move during the filtering operation with rotary plane filtering surfaces
    • B01D33/21Filters with filtering elements which move during the filtering operation with rotary plane filtering surfaces with hollow filtering discs transversely mounted on a hollow rotary shaft
    • B01D33/23Construction of discs or component sectors thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0057Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes
    • B01D5/006Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes with evaporation or distillation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • C02F1/004Processes for the treatment of water whereby the filtration technique is of importance using large scale industrial sized filters
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/22Nature of the water, waste water, sewage or sludge to be treated from the processing of animals, e.g. poultry, fish, or parts thereof
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/002Construction details of the apparatus
    • C02F2201/005Valves
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/02Temperature
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/03Pressure
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/40Liquid flow rate
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/24Separation of coarse particles, e.g. by using sieves or screens
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination

Definitions

  • the present invention relates to a system for treating waste water from animal slaughterhouses and similar biological processing facilities. More particularly, the present invention relates to an improved method that utilizes a series of pumps, filters, and water vaporizers to decontaminate such biological waste water by removing entrained and dissolved solids, vaporizing water, and maximizing recovery of usable water from contaminated water via a horizontal water processing vessel.
  • Decontamination of water sources can come in many forms, including filtration, desalination, purification, disinfection, etc.
  • Filtration removes entrained and/or dissolved solids from a water source.
  • Desalinization also desalination or desalinisation refers to one of many processes for removing excess salt, minerals and other natural or unnatural contaminants from water.
  • Purification are disinfection are useful methods to eliminate biological and similar contaminants or toxins.
  • evaporation-condensation is a natural desalinization process performed by nature during the hydrologic cycle.
  • water evaporates into the atmosphere from sources such as lakes, oceans and streams. Evaporated water then contacts cooler air and forms dew or rain. The resultant water is generally free from impurities.
  • the hydrologic process can be replicated artificially using a series of evaporation-condensation processes. In basic operation, salt water is heated to evaporation.
  • Salt and other impurities dissolve out from the water and are left behind during the evaporation stage.
  • the evaporated water is later condensed, collected and stored as fresh water.
  • the evaporation-condensation system has been greatly improved, especially with the advent of more efficient technology facilitating the process. But, these systems still require significant energy input to evaporate the water.
  • An alternative evaporation-based desalinization method includes multi-stage flash distillation, as briefly described above.
  • Multi-stage flash distillation uses vacuum distillation. Vacuum distillation is a process of boiling water at less than atmospheric pressure by creating a vacuum within the evaporation chamber. Hence, vacuum distillation operates at a much lower temperature than MED or VC and therefore requires less energy to evaporate the water to separate the contaminants therefrom. This process is particularly desirable in view of rising energy costs.
  • Alternative desalinization methods may include membrane-based processes such as reverse osmosis (RO), electrodialisys reversal (EDR), nanofiltration (NF), forward osmosis (FO) and membrane distillation (MD).
  • RO reverse osmosis
  • EDR electrodialisys reversal
  • NF nanofiltration
  • F forward osmosis
  • MD membrane distillation
  • RO reverse osmosis
  • EDR electrodialisys reversal
  • NF nanofiltration
  • F forward osmosis
  • MD membrane distillation
  • Reverse osmosis uses semi-permeable membranes and pressure to separate salt and other impurities from water.
  • Reverse osmosis membranes are considered selective. That is, the membrane is highly permeable to water molecules while highly impermeable to salt and other contaminants dissolved therein.
  • the membranes themselves are stored in expensive and highly pressurized containers. The containers arrange the membranes to maximize surface area and salt water flow rate therethrough.
  • a high-pressure pump helps filter salt water through the membrane.
  • the pressure in the system varies according to the pump settings and osmotic pressure of the salt water. Osmotic pressure depends on the temperature of the solution and the concentration of salt dissolved therein.
  • centrifuges are typically more efficient, but are more difficult to implement. The centrifuge spins the solution at high rates to separate materials of varying densities within the solution.
  • suspended salts and other contaminants are subject to constant radial acceleration along the length of the membrane.
  • One common problem with reverse osmosis in general is the removal of suspended salt and clogging of the membrane over time.
  • the energy produced between high pressure and low pressure sections of the reverse osmosis membrane is harnessed and not completely wasted.
  • Recovered energy may be used to drive any of the system components, including the high-pressure pump or centrifuge. Turbines help reduce overall energy expenditures to perform desalinization.
  • reverse osmosis systems typically consume less energy than thermal distillation and is, therefore, more cost effective. While reverse osmosis works well with somewhat brackish water solutions, reverse osmosis may become overloaded and inefficient when used with heavily salted solutions, such as ocean salt water.
  • Other, less efficient desalinization methods may include ionic exchange, freezing, geothermal desalinization, solar humidification (HDH or MEH), methane hydrate crystallization, high-grade water recycling or RF induced hyperthermia. Regardless of the process, desalinization remains energy intensive. Future costs and economic feasibility continue to depend on both the price of desalinization technology and the costs of the energy needed to operate the system.
  • the system requires significantly less operational energy than reverse osmosis and similar filtration systems to efficiently and economically purify water.
  • One drawback of this design is that the rotating shaft is built into a vertical chamber. As a result, the rotating shaft sections are only solidly anchored to the base unit by a bearing and a bearing cap. At high rotational speeds (e.g. over Mach 1), vibrations cause excessive bearing shaft and seal failure.
  • Another drawback is that a series of chambers are bolted together in housing sections. The perforated plates are coupled to these sections by an O- ring seal. The housing and O-ring seals tend to wear over time due to salt penetration because the multiple chambers and housing sections are connected via a plurality of nuts and bolts. In particular, the assembly of the Wallace design is particularly laborious.
  • the present invention is directed to a system for decontaminating impaired fluids containing biological waste, such as waste water from an animal slaughterhouse.
  • the decontaminating processes eliminate biological waste and other toxins from the waste water through physical separation and desalination using filtration and vaporization processes applied to the waste water, including generating water vapor and steam.
  • the system for decontaminating a wastewater source begins with a waste water source fluidly connected to an inlet on a flow-through wastewater filter-strainer device producing a filtered wastewater flow.
  • the filtered wastewater flow is connected to a wastewater inlet on a decontaminating vaporizer unit, said vaporizer unit comprising a generally horizontal elongated vessel having a plurality of alternately spaced rotating trays and fixed baffles disposed vertically along the elongated vessel between a first end of the elongated vessel proximate to the wastewater inlet and a second end of the elongated vessel proximate to a contaminant outlet and a vapor outlet.
  • the contaminant outlet on the vaporizer unit is fluidly connected to a contaminant tank for storage and later processing.
  • the vapor outlet on the vaporizer unit is fluidly connected to a vapor processing unit.
  • the vapor processing unit may comprise a heat exchanger, a condenser, a turbine, or other similar industrial processing unit.
  • an inventive system for treating bio contaminated wastewater may include a bio-contaminated wastewater source fluidly connected to an inlet on a first wastewater filter-strainer device producing a filtered wastewater flow from an outlet.
  • the outlet on the filter-strainer device is fluidly connected to a wastewater inlet on a decontamination unit having a generally horizontal elongated vessel having a plurality of alternately spaced rotating trays and fixed baffles disposed vertically along the elongated vessel between a first end of the elongated vessel proximate to the wastewater inlet and a second end of the elongated vessel proximate to a contaminant outlet and a vapor outlet.
  • the decontamination unit has a rotating shaft disposed along the elongated vessel from the first end to the second end, the rotating shaft passing through the fixed baffles and fixedly attached to the rotating trays.
  • the decontamination unit separates the filtered wastewater flow into a contaminant flow to the contaminant outlet and a vapor flow to the vapor outlet.
  • the system further includes a second wastewater filter-strainer device disposed in parallel to the first wastewater filter-strainer device.
  • An inlet on the second wastewater filter-strainer device is fluidly connected to the bio contaminated wastewater source and an outlet is fluidly connected to the wastewater inlet on the decontamination unit.
  • the system may further include a switching valve having an inlet side and an outlet side, wherein the inlet side is fluidly connected to the bio-contaminated wastewater source and the outlet side is fluidly connected to the inlet of the first wastewater filter-strainer device and the inlet of the second wastewater filter-strainer device.
  • the switching valve is configured such that the outlet side selectively alternates the bio-contaminated wastewater flow between the first wastewater filter-strainer device and the second wastewater filter-strainer device.
  • the outlet of the first wastewater filter-strainer device and the outlet of the second wastewater filter-strainer device are preferably both fluidly connected to a fluid junction pipe containing a one-way check valve, wherein an outlet of the fluid junction pipe is fluidly connected to the wastewater inlet on the decontamination unit.
  • An electrical generator is preferably operatively connected to the rotating shaft on the decontamination unit.
  • the electrical generator is configured to provide electricity to electronic circuits and electronic controls in the system.
  • the electronic circuits may include sensors, temperature gauges, pressure gauges, vibration sensors, lubrication systems, flow rate sensors, and computers.
  • the electronic controls may include pumps, valves, and motors.
  • each of the plurality of trays has a plurality of scoops each having an inlet of a first diameter and an outlet of a second smaller diameter
  • each of the plurality of baffles has a plurality of apertures each having an inlet of a first diameter and an outlet of a second smaller diameter.
  • the decontamination unit further includes an internal sleeve disposed in the elongated vessel downstream of the plurality of trays and plurality of baffles, the internal sleeve forming an annular passageway to the first contaminate outlet.
  • a process for decontaminating a wastewater source includes screen filtering the wastewater source producing a filtered wastewater flow.
  • the filtered wastewater flow is directed into a decontamination unit, wherein the decontamination unit has a rotating shaft extending from a first end of an elongated vessel to the second end thereof, and a plurality of alternately spaced rotating trays and fixed baffles disposed vertically in the elongated vessel between the first end and the second end, the rotating shaft passing through the fixed baffles and fixedly attached to the rotating trays.
  • the filtered wastewater flow is processed through the decontamination unit, wherein the filtered wastewater flow is separated into a contaminant flow and a decontaminated vapor flow.
  • the contaminant flow is directed to a contaminant storage vessel for further processing.
  • the decontaminated vapor flow is directed to a vapor outlet for further processing.
  • Electricity can be generated using an electrical generator fixedly attached to a portion of the rotating shaft that protrudes from the elongated vessel.
  • the process may further include the step of recycling a portion of the contaminant flow through the decontamination unit. Preferably, at least 75% of the contaminant flow is recycled through the decontaminant unit.
  • the step of screen filtering the wastewater source may include multiple screen filter units.
  • a first screen filter unit and a second screen filter unit may be provided in parallel.
  • a switching valve may be connected to inlets on both the first screen filter unit and the second screen filter unit. Outlets on both the first screen filter unit and the second screen filter unit may be connected to a fluid junction, with the fluid junction connected to the decontamination unit.
  • the wastewater source is pumped through the switching valve and one of the first screen filter unit and the second screen filter unit.
  • the fluid junction preferably includes a one-way check valve that selectively permits the filtered wastewater flow from one of the first screen filter unit or the second screen filter unit into the decontamination unit.
  • the switching valve may be selectively set to direct the wastewater source to one of the first screen filter unit or the second screen filter unit.
  • the process further includes the step of cleaning one of the first screen filter unit or the second screen filter unit when the switching valve directs the wastewater source to the other of the first screen filter unit or the second screen filter unit.
  • the plurality of alternately spaced rotating trays and fixed baffles in the decontamination unit may further include a plurality of scoops on each of the plurality of rotating trays, each scoop having an inlet of a first diameter and an outlet of a second smaller diameter, as well as, a plurality of apertures on each of the plurality of fixed baffles, each aperture having an inlet of a first diameter and an outlet of a second smaller diameter.
  • an internal sleeve may be disposed in the elongated vessel downstream of the plurality of alternately spaced rotating trays and fixed baffles, the internal sleeve forming an annular passageway to the contaminate outlet.
  • FIGURE 1 is a top schematic, and partially sectioned, view of a system for decontaminating water and generating water vapor, in accordance with the present invention
  • FIGURE 2 is a side schematic, and partially sectioned, view of the system of FIG. 1 ;
  • FUGURE 2A is a view similar to FIGURE 2 illustrating an alternative arrangement where the system 10 is controlled by a direct drive motor that is directly coupled to one end of a shaft;
  • FIGURE B is a top view illustrating the water processing vessel having an upper portion thereof opened;
  • FIGURE 4 is an end view of the horizontal water processing vessel attached to a portable framework, in accordance with the present invention.
  • FIGURE 5 is a top view of a rotating tray having a plurality of scoops therein;
  • FIGURE 6 is a cross-sectional view of a portion of the tray and a scoop thereof;
  • FIGURE 7 is a top view of a baffle, used in accordance with the present invention.
  • FIGURE 8 is a side view of a tray having a water director placed in front thereof;
  • FIGURE 9 is a cross-sectional view of a portion of the baffle, illustrating a tapered aperture thereof;
  • FIGURE 10 is a schematic illustrating the electric motor coupled to the transmission and then coupled to the shaft of the water processing vessel, in accordance with the present invention
  • FIGURE 1 1 is a schematic illustration of the system of the present invention, similar to FIG. 1 , but illustrating the incorporation of a control box and various sensors, in accordance with the present invention;
  • FIGURE 12 is a top schematic view of the system of the present invention, incorporating a turbine and electric generator;
  • FIGURE 12A is a view similar to FIGURE 12 illustrating that the system may be controlled by direct drive motor that is directly coupled to one end of a shaft;
  • FIGURE 13 is an end view of the water processing vessel, illustrating a vapor outlet thereof;
  • FIGURE 14 is a side schematic view of the system of FIG. 12;
  • FIGURE 15 is a front schematic and partially sectioned view of an alternate embodiment of a system for decontaminating water and generating water vapor, in accordance with the present invention.
  • FIGURE 16 is a close-up of the trays and baffles of the system of FIG. 15 indicated by circle 16;
  • FIGURE 17 is a lower perspective view of the vessel with inlet and outlets depicted in the system of FIG. 15;
  • FIGURE 18 is a cross-section of the vessel of FIG. 17 taken along line 18-18 thereof;
  • FIGURE 19 is an illustration of the shaft with trays and baffles of the system of FIG. 15;
  • FIGURE 20 is an illustration of a tray of the system of FIG. 15;
  • FIGURE 21 is an illustration of a baffle of the system of FIG. 15;
  • FIGURE 22 is a side view of a tray indicated by line 22-22 in FIG. 20;
  • FIGURE 23 is an opposite side view of the tray indicated by line 23- 23 of FIG. 20;
  • FIGURE 24 is a side view of a baffle indicated by line 24-24 in FIG.
  • FIGURE 25 is a partial cross-sectional view of the shaft, tray and baffle as disposed in the vessel;
  • FIGURE 26 is a cross-sectional view of a tray taken along line 26-26 of FIG. 20;
  • FIGURE 27 is a cross-sectional view of a baffle taken along line 27- 27 of FIG. 21 ;
  • FIGURE 28 is a schematic diagram of a control screen for a system of the present invention.
  • FIGURE 29 is a schematic illustration of the processes occurring at various points throughout the water processing vessel of the present invention.
  • FIGURE 30 is an illustration of an embodiment of the shaft with trays and baffles of the system of FIG. 1 5 with an increased diameter and an increase number of scoops and apertures on the trays and baffles;
  • FIGURE 31 is a side view of a tray excerpted from FIG. 30;
  • FIGURE 32 is a side view of a baffle excerpted from FIG. 30;
  • FIGURE 33 is a schematic illustration of an embodiment of the system of the present invention, including a salt water capture system and storage tank;
  • FIGURE 34 is a schematic illustration of the salt water capture system of the present invention.
  • FIGURE 35 is a schematic illustration of an embodiment of the system of the present invention, including an elevated condenser and holding tank with a hydro-electric generator;
  • FIGURE 35A is a schematic illustration of the condenser of FIG. 35;
  • FIGURE 36 is a schematic illustration of an embodiment of the system of the present invention, including a bring recirculating system and a brine drying system;
  • FIGURE 37 is a schematic illustration of an embodiment of the system of the present invention, including a control system with a graphical display;
  • FIGURE 38 is a schematic illustration of the control system with graphical display of the main screen
  • FIGURE 39 is a schematic illustration of the control system with graphical display of the graphs screen
  • FIGURE 40 is a schematic illustration of the control system with graphical display of the trends screen
  • FIGURE 41 is a flow chart illustration of wastewater purification system and process according to the present invention.
  • FIGURE 42 is a flow chart illustration of an alternate embodiment of a wastewater purification system and process according to the present invention.
  • FIGURE 43 is a flow chart illustration of a biological wastewater decontamination system and process according to the present invention.
  • FIGURE 44 is a flow chart illustration of an alternate embodiment of the biological wastewater decontamination system and process according to the present invention.
  • FIGURE 45 is a flow chart illustration of a further alternate embodiment of the biological wastewater decontamination system and process according to the present invention.
  • the present invention resides in a system and method for decontaminating water and generating water vapor.
  • the method and system of the present invention is particularly suitable for desalinization of salt water, such as ocean or other brackish waters, as well as river water or other liquids/slurries.
  • This preferred treatment will be used for exemplary purposes herein, although it will be understood by those skilled in the art that the system and method of the present invention could be used to decontaminate other water sources.
  • the present invention may be used to remove dissolved or suspended solids (decontamination), as well as heavy metals and other pollutants.
  • the system and method of the present invention can be used in association with relatively clean water to create water vapor, in the form of steam, which has a sufficient pressure and temperature so as to be passed through a turbine which is operably connected to an electric generator for the generation of electricity, or other steam heating applications.
  • water vapor in the form of steam
  • a turbine which is operably connected to an electric generator for the generation of electricity, or other steam heating applications.
  • the system - a vaporization- desalination unit - generally referred to by the reference number 10, includes a water processing vessel or chamber 12 defining an inner chamber 14, wherein salt and other dissolved solids and contaminants are removed from the water to produce essentially mineral-free, potable water.
  • the processing vessel 12 receives contaminated water from a feed tank 16 through an inlet valve 18 via a feed tank tube 20.
  • the inlet valve 18 enters the vessel 12 laterally through a side wall.
  • This inlet valve 18 can be alternately positioned as described below.
  • the source of water can be sea or ocean water, other brackish waters, or even water which is contaminated with other contaminants.
  • the present invention envisions supplying the contaminated water directly from the source, wherein the feed tank 16 may not necessarily be used.
  • the vessel 12 is comprised of a lower shell and an upper shell portion 12b such that the lower and upper shell portions 12a and 12b can be opened or removed relative to one another so as to access the contents within the inner chamber 14 of the vessel 12.
  • the vessel 12 may also be constructed as a single unit as opposed to lower and upper shell portions.
  • the water processing vessel 12 includes, within the inner chamber 14 a plurality of rotatable trays 22 spaced apart from one another and having a baffle 24 disposed between each pair of trays 22.
  • the rotatable trays 22 include a plurality of scoops 26 formed therethrough and the baffles 24 typically comprise plates having a plurality of apertures 28 formed therethrough.
  • the baffles 24 are fixed to the vessel 12 so as to be stationary.
  • the baffles 24 may comprise a lower portion disposed in the lower shell 12a of the vessel and an upper portion attached to and disposed in the upper shell 12b of the vessel 12 and designed to form a single baffle when the lower and upper shells 12a and 12b of the vessel 12 are in engagement with one another and closed.
  • each baffle 24 may comprise a single piece that is attached to either the lower shell 12a or the upper shell 12b in the earlier embodiment or at multiple points in the single unit embodiment. In either embodiment, the baffle 24 will remain generally stationary as the water and water vapor is passed therethrough.
  • a variable frequency drive 30 may regulate the speed at which electric motor 32 drives a transmission 34 and a corresponding shaft 36.
  • the shaft 36 is rotatably coupled to bearings or the like, typically non-friction bearings lubricated with synthetic oil, Schmitt couplers, or ceramic bearings 38 and 40 at generally opposite ends of the vessel 12.
  • the shaft 36 extends through the trays 22 and baffles 24 such that only the trays 22 are rotated by the shaft. That is, the trays 22 are coupled to the shaft 36.
  • Bearings, or a low-friction material, such as a layer or sleeve of Teflon is disposed between the rotating shaft 36 and the aperture plate baffle 24 to reduce friction therebetween, yet stabilize and support the spinning shaft 36. Teflon is not preferred as it could fray and contaminate the fluid.
  • the system 10 may be controlled by a direct drive motor 32a that is directly coupled to one end of the shaft 36.
  • the direct drive motor 32a allows for the use of high speed electric motors or gas turbine direct drive.
  • a direct drive motor 32a one can avoid the step down in power and force associated with the resistance inherent in transmission gearing.
  • a direct drive motor would only need to provide 60 HP and 90 ft-lb to achieve the same parameters at the rotor - no step down is experienced because the gearing in the transmission is eliminated.
  • the water processing vessel 12 is oriented generally horizontally. This is in contrast to the Wallace ‘026 device wherein the water processing chamber was oriented generally vertically, and the top of the rotating shaft was secured by a bearing and a bearing cap, which supported the chamber itself. As a result, the rotating shaft sections were only solidly anchored to the base of the unit. At high rotational operating speeds, vibrations within the system cause excessive bearing, shaft and seal failure. In contrast, horizontally mounting the water processing vessel 12 to a frame structure 42 distributes the rotational load along the length of the vessel 12 and reduces vibrations, such as harmonic vibrations, that could otherwise cause excessive bearing, shaft and seal failures. Moreover, mounting the vessel 12 to the frame structure 42 enhances the portability of the system 10, as will be more fully described herein. Supporting the very rapidly rotating shaft 36 through each baffle 24 further stabilizes the shaft and system and reduces vibrations and damage caused thereby.
  • the water and water vapor is then passed through the apertures 28 of the baffles 24 before being processed again through the next rotating tray 22 with scoops 26.
  • the configurations of the trays 22 and baffles 24 are designed to minimize or eliminate drag and friction in the rotation of the shaft 36 by providing sufficient clearance at the perimeter of the trays 22 and through the central opening 59 of the baffles 24. At the same time leakage around the perimeter of the trays 22 and through the central opening 59 of the baffles 24 is to be minimized so as to increase efficiency.
  • the system 10 maintains the temperature of the water vapor at temperatures equal to or less than that of steam, thus avoiding the latent heat of vaporization and the additional energy necessary to convert liquid water to steam. Because of this, the energy required to return the water vapor to liquid water is correspondingly lower.
  • the trays 22 are rotated by the shaft 36.
  • the shaft 36 is supported within the interior of the water processing vessel 12 by a plurality of bearings, as mentioned above.
  • the bearings are typically non friction bearings lubricated with synthetic oil, steel, or ceramic.
  • Prior art desalinization systems incorporate standard roller bearings which would fail under high rotational speeds and high temperatures. Thus, desalinization systems known in the prior art had high failure rates associated with standard roller bearings.
  • the lubricated non-friction bearings, sealed steel ball bearings, or ceramic bearings 38 and 40 are more durable than standard roller bearings and fail less often under high rotational speeds and temperatures.
  • the bearings 38, 40 may include internal lubrication tubes to allow for lubricant flow therethrough to minimize wear and tear from operation.
  • the bearings 38, 40 also include vibrational sensors (as described below) to monitor and minimize the amount of vibration occurring during operation.
  • the shaft 36 may be intermittently supported by the low friction materials, such as Teflon sleeves or bearings 50 disposed between the baffle plate 24 and the shaft 36. This further ensures even distribution of weight and forces on the shaft 36 and improves the operation and longevity of the system.
  • the low friction materials such as Teflon sleeves or bearings 50 disposed between the baffle plate 24 and the shaft 36. This further ensures even distribution of weight and forces on the shaft 36 and improves the operation and longevity of the system.
  • FIG. 6 is a cross-sectional view of the tray 22 and the scoop 26 formed therein.
  • the scoops 26 are tapered such that a diameter of an inlet 52 thereof is greater than the diameter of an outlet 54 thereof.
  • the tapered scoop 26 is essentially a Venturi tube that has the vertical opening or inlet 52 substantially perpendicular to the horizontal surface of the rotating tray base 22. Liquid and vapor accelerates through the tapered scoop 26 because the tapered scoop has a larger volume at the entrance 52 thereof and a smaller volume at the exit or outlet 54 thereof. The change in volume from the inlet to the outlet of the tapered scoop 26 causes an increase in velocity due to the Venturi effect.
  • the tapered scoop 26 may be attached to the rotating tray 22 by any means known in the art.
  • the angle of the scoop 26 illustrated as approximately forty-five degrees in FIG. 6, can be varied from tray to tray 22. That is, by increasing the angle of the spinning scoop, such as by twenty-five degrees to thirty-one degrees to thirty- six degrees on the subsequent tray, to forty degrees, forty-five degrees on a next tray, etc. the increase in angle of the scoop 26 of the spinning tray 22 accommodates increases in pressure of the water vapor which builds up as the water vapor passes through the vessel 12. The increase in angle can also be used to further agitate and create water vapor, and increase the pressure of the water vapor, which may be used in a steam turbine, as will be more fully described herein.
  • a baffle 24, in the form of an apertured plate, is shown in FIG. 7.
  • the baffle 24 is formed as a first plate member 56 and a second plate member 58 which are connected by connectors 60 to the inner wall of the vessel 12.
  • the connectors 60 can comprise bolts, dowels, rods, or any other connecting means which is adequate.
  • the baffle 24 can be formed as a single unit connected to either the upper or the lower vessel shell 12a and 12b.
  • the plate members 56 and 58 inter-engage with one another when the vessel 12 is closed so as to effectively form a single baffle 24.
  • FIG. 9 is a cross-sectional view of one such aperture 28.
  • the aperture preferably includes an inlet 62 having a diameter which is greater than an outlet 64 thereof, such that the aperture 28 is tapered which will increase the pressure and velocity of the water and water vapor which passes therethrough, further increasing the temperature and creating additional vapor from the water.
  • apertures 28 may be formed in the entire baffle plate, as represented by the series of dashed lines. The particular number and size of the apertures 28 may vary depending upon the operating conditions of the system 10.
  • the shaft 36 is illustrated extending through the rotating tray 22.
  • a cone-shaped water director 66 is positioned in front of the tray 22.
  • the director 66 may have a forty-five degree angle to deflect the remaining water and vapor passing through the central opening 59 of the baffle 24 from the shaft 36 and towards the periphery or outer edge of the tray 22 for improved vaporization and higher percentage recovery of potable water.
  • the vessel 12 may be formed into two shells or sections 12a and 12b. This enables rapid inspection and replacement of vessel components, as necessary.
  • the wall of the inner chamber 14 and any other components are treated with Melonite, or other friction reducing and corrosion resistant substance.
  • these components can be comprised of materials which are corrosion resistant and have a low friction coefficient, such as polished stainless steel or the like.
  • the lower and upper sections 12a and 12b of the vessel 12 are preferably interconnected such that when closed they are substantially air and water tight. Moreover, the closed vessel 12 needs to be able to withstand high temperatures and pressures due to the water vaporization therein during operation of the system 10.
  • a transmission 34 interconnects the electric motor 32 and the drive shaft 36.
  • the motor 32 may be a combustion engine (gasoline, diesel, natural gas, etc.), electric motor, gas turbine, or other known means for providing drive.
  • the speed of the transmission 34 is set by the variable frequency drive 30.
  • the illustrations in FIGS. 1 , 2 and 10 are only schematic and not representative of the relative sizes of the variable frequency drive 30, the motor 32m and the transmission 34.
  • the variable frequency drive 30 is primarily regulated by a computerized controller 68, as will be more fully described herein.
  • the shaft 36 may be belt or gear driven. As described below, the motor 32 may also be directly connected to the shaft 36.
  • the shaft 70 of the motor is connected to an intermediate shaft 72 by a belt 74.
  • the intermediate shaft 72 is connected to the shaft by another belt 76.
  • the high-speed industrial belt and pulley system shown in FIG. 10 drives the shaft 36 inside the water processing vessel 12.
  • a plurality of belts 74 and 76 and a set of intermediate shafts 72 increase the rotational output speed at the shaft 36 by a multiple of the rotational input speed applied by the electric motor 32 on the electric motor driveshaft 70.
  • the ratio of rotational input speed to rotational output speed can be changed by changing the relative rotational velocities of the belts 74 and 76 and corresponding intermediate shafts 72.
  • the present invention is able to avoid the vibrational and reliability problems that plague other prior art desalinization systems.
  • the water vapor is directed through a water vapor outlet 48 of the vessel 12.
  • the water vapor travels through a recovery tube 78 to a vapor recovery container or tank 80.
  • the water vapor then condenses and coalesces into liquid water within the vapor recovery tank 80.
  • a plurality of spaced apart members 82 such as in the form of louvers, are positioned in the flow pathway of the water vapor such that the water vapor can coalesce and condense on the louvers and become liquid water.
  • the liquid water is then moved to a potable water storage tank 84 or a pasteurizing and holding tank 86. If the water and water vapor in the vessel 12 is heated to the necessary temperature for pasteurization, so as to kill harmful microorganisms, zebra mussel larvae, and other harmful organisms, the liquid water may be held in holding tank 86.
  • FIG. 15 illustrates the overall system 10 including the alternate single piece construction of the vessel 12.
  • the vessel 12 has a construction similar to the previously described embodiment, including elements such as the inner chamber 14, the inlet valve 18, the trays 22 having scoops 26, the baffles 24 having apertures 28, the brine outlet 46, and the vapor outlet 48.
  • the inlet valve 18 comprises multiple inlets, preferably at least two, to the vessel 12. These inlets 18 are disposed on the end of the vessel around the shaft 36 so as to more evenly distribute the fluid across the inner chamber 14.
  • the inlets 18 preferably enter the vessel 12 in-line with the shaft 36 so as to avoid a steep, especially a right angle, of entry into the inner chamber 14 relative to the direction of movement through the vessel 12.
  • the contaminant outlet 46 is preferably oversized so as to not restrict the flow of concentrated fluid out of the system 10. The recirculating feature described below can address any excessive allowance of liquid that may be permitted to exit the system 10 through the oversized contaminant outlet 46.
  • a shaft 36 supported by ceramic bearings 38, 40 passes through the center of the trays 22 and baffles 24.
  • the trays 22 are affixed to the shaft 36 and extend outward toward the wall of the inner chamber 14 as described above.
  • the baffles 24 preferably comprise a single piece extending from the walls of the inner chamber 14 toward the shaft 36 with a central opening 59 forming a gap between the baffles 24 and the shaft 36 as described above.
  • the baffles 24 are preferably fixed to the walls of the inner chamber by screws or dowels 60 also as described above.
  • the vessel 12 includes six trays 22 and five baffles 24 alternatingly dispersed through the inner chamber 14.
  • the inner chamber 14 includes an internal sleeve 45 disposed proximate to the brine outlet 46.
  • the internal sleeve 45 has an annular shape with a diameter slightly less than the diameter of the inner chamber 14.
  • the internal sleeve 45 extends from a point downstream of the last tray 22 to another point immediately downstream of the brine outlet 46.
  • An annular passageway 47 is created between the internal sleeve 45 and the outer wall of the inner chamber 14.
  • the internal sleeve 45 is about six inches long and the annular passageway 47 is about 1 -1 1 ⁇ 2 inches wide.
  • This annular passageway or channel 47 captures the brine or contaminate material that is spun out from the rotating trays 22 to the outer wall of the chamber 14 as described above. This annular passageway 47 facilitates movement of the brine or contaminate material to the outlet 46 and minimizes the chances of contamination of the vapor discharge or buildup of material within the chamber 14.
  • FIGURE 16 illustrates a close-up of the trays 22 and baffles 24.
  • the baffles 24 extend from the wall of the vessel 12 through the chamber 14 and end proximate to the shaft 36.
  • a cone 66 is preferably disposed on each tray 22 so as to deflect any fluid flowing along the shaft as described above (FIG. 8).
  • FIG. 17 illustrates an external view of the vessel 12 indicating the inlets 18, the outlets 46, 48 and the shaft 36. Ordinarily, the ends of the vessel 12 would be enclosed and sealed against leaks. They are depicted open here for clarification and ease of illustration.
  • FIG. 18 illustrates a cross-section of the vessel 12 shown in FIG. 17, further illustrating the internal components, including the trays 22, baffles 24, internal sleeve 45 and annular passageway 47.
  • FIG. 19 illustrates the shaft 36 with trays 22 and baffles 24 apart from the vessel 12.
  • FIGS. 30, 31 , and 32 illustrate an alternate embodiment of the trays 22 and baffles 24 along the shaft 36.
  • the trays 22 and baffles 24 are of an increased diameter with an increased number of rows - preferably 3 to 4 rows - and a corresponding increase in the number of scoops and apertures therein. These increases allow for a larger volume of fluid to be processed per unit of time.
  • the vessel 12 will have a corresponding increase in its diameter to accommodate the larger trays 22 and baffles 24. This increased diameter creates a situation where the outermost edges of the rotating trays 22 have a significantly greater rotational velocity compared to the trays 22 of smaller diameter.
  • FIGURES 20 and 21 illustrate the tray 22 and baffle 24, respectively.
  • FIGS. 22, 23 and 26 illustrate various views and cross-sections of the tray 22 in FIG. 20.
  • FIGS. 24 and 27 similarly illustrate various views and cross-sections of the baffle 24 in FIG. 21 .
  • the tray 22 includes scoops 26 which pass through the body of the tray 22.
  • the scoops 26 include a scoop inlet 52 and a scoop outlet 54 configured as described above.
  • the scoop inlet 52 is preferably oriented such that the opening faces into the direction of rotation about the shaft. This maximizes the amount of fluid that enters the scoop inlet 52 and passes through the plurality of scoops.
  • the angle of the scoops 26 on successive trays 22 may be adjusted as described above.
  • the baffle 24 also includes a plurality of apertures 28 configured and profiled (FIG. 9) as described above. FIG.
  • the shaft 36 and a pairing of a tray 22 with a baffle 24 illustrates the shaft 36 and a pairing of a tray 22 with a baffle 24.
  • the arrows indicate the direction of rotation of the shaft and accordingly the tray 22 in this particular figure.
  • the scoops 26 with the scoop inlet 52 are illustrated as facing in the direction of the rotation, i.e., out of the page, in the top half of the figure. In the bottom half of the figure, the scoop 26 with scoop inlet 52 is also illustrated as being oriented in the direction of rotation, i.e., into the page, as the tray 22 rotates with the shaft 36.
  • the direction of rotation may be either clockwise or counter-clockwise. The direction of rotation can be changed without departing from the spirit and scope of the invention.
  • the scoop inlet 52 has a larger diameter than the scoop outlet 54 so as to increase the flow rate and decrease the fluid pressure.
  • the temperature of the water vapor is heated to between one hundred degrees Fahrenheit and less than two hundred twelve degrees Fahrenheit. Even more preferably, the water vapor is heated to between one hundred forty degrees Fahrenheit and one hundred seventy degrees Fahrenheit for pasteurization purposes. However, the water vapor temperature is kept to a minimum and almost always less than two hundred twelve degrees Fahrenheit such that the water does not boil and become steam, which is more difficult to condense and coalesce from water vapor to liquid water.
  • Increased RPMs result in increased temperatures and pressures. The RPMs can be adjusted to achieve the desired temperatures.
  • the contaminated water referred to as brine in desalinization processes
  • the contaminated water is collected at outlet 46 and moved to a brine disposal tank 88.
  • polymers or other chemistry 90 may be added to the brine to recover trace elements, etc.
  • the salt from the brine may be processed and used for various purposes, including generating table salt, agricultural brine and/or fertilizer.
  • the treated contaminated water is reprocessed by recycling the contaminants and remaining water through the system again. This may be done multiple times such that the amount of potable water extracted from the contaminated water increases, up to as much as ninety-nine percent. This may be done by directing the contaminants and waste water from the outlet 46 to a first brine, or contaminant, reprocessing tank 92. The remaining waste water, in the form of brine or other contaminants, is then reintroduced through inlet 18 of the vessel 12 and reprocessed and recirculated through the vessel 12, as described above. Additional potable water will be extracted in the form of water vapor for condensing and collection in the vapor recovery tank 80.
  • the remaining contaminants and wastewater are then directed to a second brine or contaminant reprocessing tank 94.
  • the concentration of contaminants or brine will be much higher in the reprocessing tank 92.
  • this contaminated water is then passed through the inlet 18 and circulated and processed through the system 10, as described above.
  • Extracted potable water vapor is removed at outlet 48 and turned into liquid water in the vapor recovery tank 80, as described above.
  • the resulting contaminants and wastewater can then be placed into yet another reprocessing tank, or into the brine disposal tank 88. It is anticipated that an initial pass-through of seawater will yield, for example, eighty percent to ninety percent potable water.
  • the first reprocessing will yield an additional amount of potable water, such that the total extracted potable water is between ninety percent and ninety-five percent. Passing the brine and remaining water through the system again can yield up to ninety-nine percent recovery of potable water, by recycling the brine at little to no increase in unit cost. Moreover, this reduces the volume of the brine or contaminants, which can facilitate trace element recovery and/or reduce the disposal costs thereof.
  • a computer system is integrated into the system 10 of the present invention which regulates the variable frequency drive BO based on measurements taken from a plurality of sensors that continually read temperature, pressure, flow rate, rotational rates of components and remaining capacity of a variety of tanks connected to the water processing vessel 12. Typically, these readings are taken in real-time.
  • temperature and/or pressure sensors 96 may be employed to measure the temperature of the water or water vapor within or exiting the vessel 12, as well as the pressure thereof as needed.
  • the control box 68 will cause the variable frequency drive BO to maintain the rotational speed of shaft 36, decrease the rotational speed of the shaft 36, or increase the rotational speed of the shaft 36 to either maintain the temperature and pressure, reduce the temperature and pressure, or increase the pressure and temperature, respectively, of the water and water vapor. This may be done, for example, to ensure that the water vapor temperature is at the necessary pasteurization temperature so as to kill all harmful microorganisms and other organisms therein.
  • a sensor may be used to detect the rotational speed (RPMS) of the shaft 36 and/or trays 22 to ensure that the system is operating correctly and that the system is generating the necessary water vapor at a desired temperature and/or pressure.
  • the computerized controller may also adjust the amount of water input through inlet 18 (GPMS) so that the proper amount of water is input as to the amount of water vapor and wastewater which is removed so that the system 10 operates efficiently.
  • the control box 68 may adjust the flow rate of water into the vessel 12, or even adjust the water input.
  • FIGURE 28 illustrates schematically a computer display 112 or similar configuration.
  • This computer display schematically illustrates the vessel 12 with the various inlets and outlets 18, 46, 48, as well as the shaft 36 and the plurality of trays 22.
  • the shaft 36 has multiple vibration and temperature sensors 114 disposed along its length.
  • the bearings 38, 40 also include vibration and temperature sensors 114.
  • the vibration and temperature sensors 114 are configured to detect horizontal and vertical vibrations at each point, as well as the temperature of the shaft 36 generated by the friction of rotation.
  • the bearings 38, 40 include oil supply 116a and return 1 16b lines to provide lubrication thereof.
  • the inlets 18 and brine outlet 46 include flow meters 118 to detect the corresponding flow rates.
  • Temperature and pressure sensors 96 are disposed throughout the vessel 12. The temperature and pressure sensors 96 are also disposed throughout the vessel 12 to take measurements at various predetermined points.
  • the contaminated water may come from a feed tank 16, or can be from any other number of tanks, including reprocessing tanks 92 and 94. It is also contemplated that the collected water storage tank could be fluidly coupled to the inlet 18 so as to ensure that the water is purified to a certain level or for other purposes, such as when generating steam which requires a higher purity of water than the contaminated water may provide. As such, one or more sensors 98 may track the data within the tanks to determine water or wastewater/brine levels, concentrations, or flow rates into the tanks or out of the tanks.
  • the controller 68 may be used to switch the input and output of the tanks, such as when the brine is being reprocessed from a first brine reprocessing tank 92 to the second brine reprocessing tank 94, and eventually to the brine disposal tank 88, as described above.
  • first brine reprocessing tank reaches a predetermined level
  • fluid flow from the feed tank 16 is shut off, and instead fluid is provided from the first brine reprocessing tank 92 into the vessel 12.
  • the treated contaminants and remaining wastewater are then directed into the second brine reprocessing tank 94, until it reaches a predetermined level.
  • the water is directed from the second brine reprocessing tank 94 through the system and water processing vessel 12 to, for example, the brine disposal tank 88.
  • Brine water in the first reprocessing tank 92 may be approximately twenty percent of the contaminated water, including most of the total dissolved solids.
  • the residual brine which is finally directed to the brine disposal tank 88 may only comprise one percent of the contaminated water initially introduced into the decontamination system 10 via the feed tank 16.
  • the temperature and pressure sensors, RPM and flow meters can be used to control the desired water output including water vapor temperature controls that result in pasteurized water.
  • FIG. 12 illustrates a steam turbine 100 integrated into the system 10.
  • the steam turbine 100 may also be used with the vessel depicted in FIGS. 15-27. Water vapor in the form of steam could be generated in the water processing vessel 12 to drive a high pressure, low temperature steam turbine by feeding the vapor outlet 48 into an inlet on the turbine 100.
  • the turbine 100 is in turn coupled to an electric generator 102, for cost- effective and economical generation of electricity. As shown in FIG.
  • the steam turbine 100 may be eliminated with the shaft 36 of the vessel 12 extended to turn the generator 102 directly or indirectly.
  • the later stages of the trays and baffles inside the vessel 12 act as a steam turbine due to the presence of the water vapor which aids the rotation of the shaft.
  • FIG. 13 and 14 illustrate an embodiment wherein a steam outlet 104 is formed at an end of the vessel 12 and the steam turbine 100 is directly connected thereto such that the pressurized steam passes through the turbine 100 so as to rotate the blades 106 and shaft 108 thereof so as to generate electricity via the electric generator coupled thereto.
  • a water vapor outlet 1 10 conveys the water vapor to a vapor recovery container 80 or the like.
  • the recovery tank 80 may need to include additional piping, condensers, refrigeration, etc. so as to cool the steam or high temperature water vapor so as to condense it into liquid water.
  • the present invention by means of the sensors and controller 68 can generate water vapor of a lower temperature and/or pressure for potable water production, which water vapor is directed through outlet 48 directly into a vapor recovery container, and the system sped up to create high temperature water vapor or steam for passage through the steam turbine 100 to generate electricity as needed.
  • the system 10 may be used to generate potable water when very little electricity is needed.
  • the system 10 can be adjusted to generate steam and electricity.
  • variable frequency drive BO As described above, many of the components of the present invention, including the variable frequency drive BO, electric motor B2, transmission 34, and water processing vessel 12 and the components therein can be attached to a framework 42 which is portable.
  • the entire system 10 of the present invention can be designed to fit into a forty foot long ISO container.
  • This container can be insulated with a refrigeration (HVAC) unit for controlled operating environment and shipping and storage.
  • HVAC refrigeration
  • the various tanks, including the feed tank, vapor recovery tank, portable water storage tank, and contaminant/brine reprocessing or disposal tanks can either be fit into the transportable container, or transported separately and connected to the inlet and outlet ports as needed.
  • the entire system 10 of the present invention can be easily transported in an ISO container, or the like, via ship, semi-tractor trailer, or the like.
  • the system 10 of the present invention can be taken to where needed to address natural disasters, military operations, etc., even at remote locations.
  • Such an arrangement results in a high level of mobility and rapid deployment and startup of the system 10 of the present invention.
  • FIGURE 29 schematically illustrates the processes occurring at various points, i.e., sub-chambers, throughout the vessel 12.
  • the inner chamber 14 of the vessel 12 is effectively divided into a series of sub-chambers as illustrated.
  • the vessel 12 contains five sub-chambers that perform the functions of an axial flow pump, an axial flow compressor, a centrifugal flow compressor, an unlighted gas turbine and/or a hydraulic/water turbine.
  • the system 10 has the capability to vaporize the water through a mechanical process, thereby enabling efficient and effective desalination, decontamination and vaporization of a variety of impaired fluids.
  • the fluid Before entering the vessel 12, the fluid may be subject to a pretreatment step 120 wherein the fluid is passed through filters and various other processes to separate contaminants that are more easily removed or that may damage or degrade the integrity of the system 10.
  • the fluid Upon passing through the inlets 18, the fluid enters an intake chamber 122 which has an effect on the fluid similar to an axial flow pump once the system 10 reaches its operating rotation speed.
  • An external initiating pump (not shown) may be shut off such that the system 10 draws the contaminated water through the inlet, i.e., the intake chamber functions as an axial flow pump, without the continued operation of the initiating pump.
  • a significant reduction in intake chamber pressure causes vacuum distillation or vaporization to occur at temperatures below 212° F.
  • the fluid encounters the first tray 22 where it enters the first processing chamber 124.
  • This first processing chamber acts as both a centrifugal flow compressor and as an axial flow compressor through the combined action of the rotating tray 22 and the adjacent baffle 24.
  • a high percentage of the intake water is vaporized through cavitation upon impact with the high speed rotating tray 22 in the first processing chamber 124.
  • a centrifugal flow compression process occurs within the first processing chamber 124 and each subsequent processing chamber. The centrifugal flow compression process casts the non-vaporized dissolved solids and at least some of the liquid water to the outer wall of the processing chamber 124. This action separates the dissolved solids and most of the remaining liquid from the vapor.
  • An axial flow compression process also occurs within the first processing chamber 124 and each subsequent chamber.
  • This axial flow compression process compresses the vapor and liquid which also increases the pressure and temperature within the processing chamber.
  • the second processing chamber 126 and the third processing chamber 128 both function similarly by compounding the action of the centrifugal flow compressor and axial flow compressor features of the first processing chamber 124.
  • the fluid After exiting the fifth processing chamber 132 the fluid has been separated to a high degree such that nearly all of the contaminants in the form of brine pass through the annular passageway 47 to the outlet 46 and the purified vapor passes through the central portion of the inner chamber 14 to the vapor outlet 48.
  • the turbine operations of the fourth and fifth processing chambers 130, 132 allow for continued operation of the system 10 with a reduced energy input (by as much as 25%) as compared to a startup phase once an equilibrium in the operation is reached.
  • the system After the fifth processing chamber 132, the system includes a discharge chamber.
  • the discharge chamber 134 which is larger than any of the preceding processing chambers, contains the two discharge outlets 46, 48.
  • the large increase in volume results in a dramatic reduction in pressure and a physical separation of the dissolved solids and the remaining water from the vapor.
  • the dimensions of the vessel 12 are preferably configured such that the combined processing chambers, 124-132 occupy about one-half of the total length.
  • the discharge chamber 134 occupies about one-third of the total length.
  • the remainder of the length of the vessel, about one-sixth of the total length, is occupied by the intake chamber 122.
  • the processing chambers 124-132 are divided into approximately three-fifths compressor functionality and two-fifths turbine functionality. Once the fluid exits the last processing chamber 132, it has achieved about eighty percent vaporization as it enters the discharge chamber 134 and is directed to the respective outlets 46, 48.
  • FIGS. 33 and 34 illustrate an embodiment of the system 10 that includes a system to capture water from a body of water 150.
  • the body of water 150 is preferably a sea or ocean containing salt water, but could be any body of water.
  • the capture system 152 includes a capture vessel 154 that is disposed in the body of water 150 such that an open top or sides 156 of the vessel 154 are at least partially above a median water level for the body of water 150.
  • the system 10 may function with an open top 156 on the vessel 154 as shown in FIG. 33, but the vessel preferably has open sides 156 facing the seaward and landward sides of the vessel 154 to take advantage of both the incoming and receding waves/tide.
  • the water level of the body of water 150 must vary sufficiently to allow a portion of the body of water to enter the open sides 156 but not completely submerge the vessel 154. Ideally, this would occur with the rise and fall of a tide in a sea or ocean, as well as waves that may occur in such a body of water.
  • the distance that the open sides 156 of the vessel 154 extend above the median water level depends upon the variability in the water level for a particular body of water 150.
  • the open sides 156 are preferably covered by a filter screen 158 to reduce the occurrence of living organisms and other large objects in the body of water 150 from entering the vessel 154.
  • the open sides 156 preferably also include pivoting louvers 157 disposed over the screens 158 that can be opened or closed so as to control the amount of water and/or sand entering the vessel 154.
  • a capture funnel 160 Inside the vessel 154 is a capture funnel 160 or similar structure configured to direct most of the water that enters the vessel 154 into a feed pipe 162.
  • the capture funnel 160 is preferably positioned below the median water level for the body of water.
  • the vessel 154 and capture funnel 160 are illustrated as generally square shaped, they may be configured in other forms. It has been found that the square shape, with a corner thereof oriented into the a wave or tide that is preferably present in the body of water 150 facilitates the rise of the wave or tide over the vessel 154 such that water enters the open sides 156.
  • the vessel 154 may also be configured whereby the open sides 156 angled other than vertical on a side that faces the incoming waves or tides so as to facilitate entry of water thought the open side 156.
  • the open sides 156 are preferably disposed with most of their surface area above the median water level so that there is less likelihood of sand or other sediment being in the higher portion of the wave or tide when it reaches the open side 156.
  • the feed pipe 162 preferably passes to the shore and into a storage vessel 164.
  • the system 10 may include multiple storage vessels 164 to accommodate and store a sufficient quantity of captured seawater.
  • the feed pipe 162 may be underground as it passes to shore, but realizing that any changes in elevation to an above ground facility would require appropriate piping and pumps.
  • the storage vessel 164 may be located near the body of water 150 or located some distance from the body of water 150 depending upon the need of the user.
  • a pump 166 attached to an outlet 168 on the vessel 164 directs the stored water through an inlet pipe 170 to the inlet 18 on the processing system 10.
  • the inlet pipe 170 preferably includes a filtration system 172 to remove and large sediment or particles that may have made it through the storage vessel 164 and pump 166.
  • the system 10 can then be used to desalinate the water as described elsewhere.
  • FIGURE 35 illustrates another embodiment of the inventive system 10, wherein the system 10 is used to generate electricity from the water vapor produced from the vapor outlet 48 as described elsewhere.
  • the system 10 further includes a condenser 174 disposed a first distance 176 above the vessel 12.
  • a vapor pipe 178 directs the water vapor from the vapor outlet 48 to the condenser 174. Since the water vapor is lighter than air and rises under its own power, no mechanical means are necessary to raise the water vapor through the first distance 176 to the condenser 174.
  • the vapor pipe 178 has a generally vertical section 178a that extends at least the first distance 176, if not slightly more than the first distance 176.
  • a generally horizontal section 178b of the vapor pipe 178 extends from the end of this vertical section 178a to an inlet 180 on the condenser 174.
  • This generally horizontal section 178b may have a slight decline from the end of the vertical section 178a to the inlet 180 on the condenser 174. This allows for the possibility that any incidental condensing that occurs in the vapor pipe 178 runs down the slope of the generally horizontal section 178b into the condenser 174.
  • the vapor pipe 178 and all sections thereof is preferably insulated to prevent the premature loss of heat and minimize the occurrence of condensation during the rise to the condenser.
  • FIG. 35A illustrate the condenser 174 in a particular generally diamond-shape
  • the condenser 174 may be constructed in other shapes as known by those skilled in the art of processing vapor or steam.
  • the purpose of the condenser is to fully condense vapor that is produced by the system 10.
  • The preferably includes sufficient structures inside as are known to those skilled in the art to facilitate condensation of the vapor.
  • the holding tank 184 is preferably disposed a second distance 186 above a hydro-electric generator 188.
  • the condensed processed fluid is released from an outlet 190 on the holding tank 184.
  • the condensed processed fluid falls under the force of gravity across the second distance 186 into the hydro-electric generator 188.
  • the hydro-electric generator 188 converts the kinetic energy of the falling condensed processed fluid into electrical energy for storage or immediate use.
  • the electrical energy may be stored in a rechargeable chemical battery, a capacitor, or similar known means of electrical storage 192.
  • the condensed processes fluid that falls into the hydroelectric generator 188 is released through a generator outlet 189 to be used for subsequent processing (not shown), as would typically be done with such treated water.
  • first distance 176 and the second distance 186 are depicted in FIG. 35 as apparently “stacking” one on top of the other, that is not a requirement of these distances.
  • the only requirement on either of these distances is that the second distance 186 be sufficiently above the hydro-electric generator 188 so as to allow for the efficient conversion of kinetic energy of the falling processed fluid into electrical energy.
  • this second distance 186 is at least ten feet, but may be twenty feet or more, depending upon the quantity of condensed processed fluid and the capabilities of the hydro-electric generator.
  • the first distance 176 needs to be of sufficient distance to place the condenser 174 and holding tank 184 above the second distance 186.
  • the first distance 176 depends upon the sizes of the condenser 174, the holding tank 184, and the second distance 186.
  • FIG. 36 illustrates another embodiment of the inventive system 10, wherein the brine outlet 46 and vapor outlet 48 are both used for further processing.
  • a brine reprocessing tank 194 receives the brine from the brine outlet 46 through a reprocessing inlet 196.
  • the brine reprocessing tank 194 also includes a reprocessing outlet 198 and a recirculating outlet 200.
  • a first portion of the brine in the brine reprocessing tank 194 is passed to the recirculating outlet 200 where it is directed by a recirculating pipe 202 back to the inlet 18 of the system 10 for re-processing. In this way, the brine is reprocessed to recover additional water vapor from the processing fluid.
  • a second portion of the brine in the brine reprocessing tank 194 is passed to the reprocessing outlet 198 for storage in a brine holding tank 204.
  • This reprocessing outlet 198 may include a valve 206 for restricting or completely closing off the flow of the second portion of the brine to the brine holding tank 204.
  • the brine holding tank 204 is connected to a brine drying system 208 which includes a heat exchanger 210 with circulating heat pipes 212.
  • the circulating heat pipes 212 pass back and forth as is typical of heat exchangers 210. Being part of the inventive system 10, the heat exchanger 210 receives its heat source from the water vapor from the vapor outlet 48.
  • a vapor diverting pipe 214 extracts a portion of the water vapor from vapor out 48 and communicates to the circulating heat pipes 212 of the heat exchanger 210.
  • the stored brine from the brine holding tank 204 passes over the heat exchanger 210 and any residual water is dried from the heat of the water vapor.
  • the dried brine is then transported to a dried brine holding tank 216 for subsequent use or processing.
  • Such dried brine could be used to produce salt or other compounds found in salt water.
  • any useful contaminants, i.e., metals, elements, or other valuable compounds, found in the water processed in the inventive system 10 may be recovered from the dried brine for resale or other subsequent processing.
  • the system 10 may be controlled by a control system 218 that measures various operating parameters of the system 10.
  • the control system 218 includes a graphical display 220 that is touch screen sensitive.
  • the graphical display 220 can be used to adjust the power, torque, and rpms of the motor and shaft, as well as the flow rate of fluid entering the system 10.
  • This graphical display 220 is similar to the graphical display depicted in FIG. 28.
  • the graphical display 220 includes a schematic graphical depiction of the system 10 corresponding to various components thereof.
  • the control system 218 and graphical display 220 described herein is an updated from the version of FIG. 28.
  • the graphical display 220 includes indicator lights 238 around its border that indicate power, CPU activity, and operating modes, corresponding to the fluid being processed in the system 10, i.e., (1) brackish water, (2) sea water, (3) produced water, and (4) pasteurizing water.
  • the updated graphical display provides measurement data captured by a plurality of operating sensors 222 connected to the system 10, as well as an internal clock to measure operating time and determine a rate for any of the data measured by the operating sensors 222.
  • the operating sensors 222 include temperature and pressure sensors 224 associated with each of a plurality of processing stages 226 within the system 10.
  • the processing stages may include an inlet stage 226a, an outlet stage 226b, and tray/baffle stages 226c associated with each operating pair of a tray 22 followed by a baffle 24.
  • the operating sensors 222 also include rotational sensors 228 associated with the shaft 36 and the motor 32, 32a.
  • the rotational sensors 228 are configured to measure revolutions per minute, torque, horsepower, runtime, and total revolutions.
  • the operating sensors 222 may also include bearing sensors 230 associated with the bearings 38, 40 on either end of the shaft 36.
  • the bearing sensors 230 are configured to measure temperature and flow rate of a lubricant passing through the bearings 38, 40, as well as vibration of the shaft 36.
  • the operating sensors 222 may also include flow sensors 232 associated with the fluid inlet 18 and contaminant outlet 46.
  • the flow sensors 232 are configured to measure an opened or closed state of a valve on the fluid inlet 18, flow rate in the fluid inlet 18 and concentrate outlet 46, and total fluid flow in the fluid inlet 18 and concentrate outlet 46.
  • the graphical display 220 has several display modes.
  • the main screen is shown in FIG. 38 and displays the values measured by the operational sensors 222 in the schematic illustration of the system 10.
  • a graphs screen shown in FIG. 39 displays the values measured by the temperature and pressure sensors 224 in a bar graph format 234 configured to represent the orientation of the plurality of operational stages 226.
  • the graphs screen also displays numerical measurement values for the rotational sensors 228, the bearing sensors 230, and the flow sensors 232.
  • a trends screen shown in FIG. 40, displays a line graph 236 of the values measured by the temperature and pressure sensors 224 against time. On this line graph, each operational stage 226 associated with one of the temperature and pressure sensors 224 is depicted as a separate line.
  • the line graphs may show present operational conditions or may be reviewed to show historical operational temperature and pressure data.
  • the trends screen may also display data measured by the other sensors, including at least revolutions per minute of the rotor from the rotational sensors 228.
  • the display screen 220 also has functionality to capture an image of the graphical display, as well as, to regulate whether data logging is on or off.
  • FIGS. 41 and 42 illustrate schematic flowcharts of preferred systems and methods for purifying a waste water source.
  • the system 250 of the first preferred embodiment, shown in FIG. 41 begins with a waste water source 252.
  • the waste water source 252 can be any contaminated water source that typically needs to cleaned or purified, i.e., sewage, domestic wastewater, effluent, run-off, industrial waste, etc.
  • the flow from the waste water source 252 is first passed through a macro filter-strainer 254 that is designed to remove large objects, i.e., rocks, branches, etc., from the flow. The goal is to remove solid objects that might be too large to pass through the remainder of the system 250.
  • the separation tank 256 relies on weight or density differences to allow for the waste water flow to separate into different regions, i.e., a heavy fraction region 256a at the bottom, an intermediate fraction region 256b in the middle, and a light fraction region 256c at the top.
  • the heavy fraction is typically sludge or similar solid or semi-solid contaminants.
  • the light fraction is typically oil or similar lighter contaminants.
  • the waste water flow removed from an intermediate fraction outlet 258 in the intermediate region 256b is passed on for further processing.
  • the tank 256 also includes a heavy fraction outlet 258a and a light fraction outlet 258c, whereby both fractions may be removed when needed.
  • the intermediate fraction outlet 258 is preferably disposed in the intermediate fraction region 256b, but close to the heavy fraction region 256a to maximize the accessibility of the intermediate fraction.
  • the waste water flow from intermediate outlet 258 enters vaporizer- desalination unit 10 constructed as described above and is processed in the same manner as described above.
  • the contaminant outlet flow 46 is directed to contaminant flow tank 260 for storage or subsequent processing.
  • the vapor outlet flow 48 having been purified, is directed elsewhere for subsequent processing, where it is condensed for use in clean water systems, including but not limited to potable or irrigation water.
  • the contaminant outlet flow 46 may be recycled - in whole or in part - via recycle line 46a back through the vaporizer-desalination unit 10 for further purification. Rather than recycling, the contaminant outlet flow 46 may be processed through a second vaporizer- desalination unit 10 set-up in series with the first unit.
  • FIG. 42 A second embodiment of the water purification system 262 is shown in FIG. 42.
  • the second system 262 is the same as the first system 250 up through the separation tank 256 and the vaporization-desalination unit 10.
  • the contaminant outlet flow 46 is directed into a contaminant flow tank 264.
  • the contaminant flow tank 264 includes heat exchanger pipes 266 that are connected to the vapor outlet flow 48.
  • the heat from the vapor outlet flow 48 dries the contaminant outlet flow 46.
  • the dried contaminant outlet flow 268 is then sent to further processing for contaminant mineral recovery 270.
  • the vapor outlet flow 48 has been cooled and is sent to a decontaminated water recovery tank 272.
  • FIGS 43-45 illustrate embodiments of a variation on the purification and/or decontamination system and process of the present invention.
  • FIG 43 generally illustrates system 280 for the decontamination of a waste water stream containing biological waste as might be found in a slaughterhouse or similar business.
  • the system 280 generally includes a wastewater source 282 that feeds into an inlet 284a on a macro-filter/strainer 284. Similar to those described above, the macro-filter/strainer 284 is configured to remove larger contaminant materials that are generally easier to remove. In the context of decontamination of slaughterhouse wastewater, the macro-filter/strainer 284 might remove chunks of tissue or other biological solids.
  • An outlet 286 from the macro-filter/strainer 284 leads into a decontamination unit 10, which is constructed as the vaporizer-desalination unit 10 described above.
  • the decontamination unit 10 is designed to vaporize the liquid portion of the wastewater source 282 by passing it through the series of alternating rotating trays 22 and stationary baffles 24.
  • the vaporized portion of the wastewater source 282 exits the decontamination unit 10 through the vapor outlet 48.
  • the non-vaporized and remaining solid portions of the wastewater source 282 exits the decontamination unit 10 through the contaminant outlet 46 into the contaminant outflow 260.
  • the vapor outlet 48 and the contaminant outflow 260 may be further processed in any of the ways described above in connection with the other embodiments.
  • the shaft 36 of the decontamination unit 10 extends from one end of the vessel 12 a length sufficient to allow for functional connection to an electrical generator 288.
  • the rotation of the shaft 36 is converted into electricity by the generator 288 and, as shown in FIG. 45, can be used to power electronic circuits 294 in the system 280.
  • Such circuits 294 might include sensors, temperature gauges, pressure gauges, vibration sensors, lubrication systems, flow rate sensors, computers, etc.
  • the electricity from the generator 288 can be used to power electronic controls 296 in the system 280.
  • Such controls 296 might include pumps, valves, motors, etc.
  • This electrical generator 288 provides particular benefit to operate the electronic circuits 294 and controls 296 without significant external electrical input.
  • the decontamination unit 10 might be started by initially rotating the shaft 36 by a starter motor 32, which may be gasoline or electric.
  • the starter motor 32 is designed to only be used at the beginning to impart initial rotation to the shaft 36.
  • the shaft 36 acquires a measure of self-rotation through the force of the wastewater stream flowing through the unit 10. This self-rotation of the shaft 36 provides a source of electricity that can be used as described.
  • FIG 44 shows an alternate embodiment of the system 280 in FIG 43, in particular, the introduction of a first macro-filter/strainer 284 and a second macro-filter/strainer 285 installed in parallel.
  • the waste water source 282 can be run through one of the macro-filter/strainers 284, 285 while the other is being cleaned allowing for virtually uninterrupted operation of the system 280.
  • the wastewater source 282 is introduced into the inlet 290a of a switching valve 290 having two outlets 290b, 290c, which separately direct the wastewater source 282 from the inlet 290a to one or the other - but not both - of the outlets 290b, 290c.
  • the outlet 290b is connected directly to the inlet 284a on the first macro-filter/strainer 284.
  • the outlet 290c is connected directly to the inlet 285a on the second macro-filter/strainer 285.
  • the outlets 284b, 285b from the filter/strainers 284, 285 are both fluidly connected to a fluid junction 292 that includes a one-way check valve 292a.
  • the outlets 284b, 285b connect to separate inlets on the check valve 292a.
  • the check valve 292a provides for the outlet flows 284b, 285b from the filter/strainers 284, 285 to flow into the fluid junction 292 without back flowing into the other filter/strainers 284, 285.
  • the outlet 286 from the fluid junction 292 is effectively the outlet 286 from the filter/strainers 284, 285 that is introduced into the inlet of the decontamination unit 10.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)
  • Biological Treatment Of Waste Water (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)
EP22838275.0A 2021-07-07 2022-07-01 System zur behandlung von biokontaminiertem abwasser und verfahren zur dekontaminierung einer abwasserquelle Pending EP4367065A1 (de)

Applications Claiming Priority (2)

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US17/369,097 US11608278B2 (en) 2009-06-22 2021-07-07 System for treating bio-contaminated wastewater and process for decontaminating a wastewater source
PCT/US2022/035948 WO2023283127A1 (en) 2021-07-07 2022-07-01 System for treating bio-contaminated wastewater and process for decontaminating a wastewater source

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EP (1) EP4367065A1 (de)
KR (1) KR20240032936A (de)
CN (1) CN117980272A (de)
AU (1) AU2022309211A1 (de)
CA (1) CA3223700A1 (de)
CL (1) CL2024000015A1 (de)
CO (1) CO2024001281A2 (de)
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US8562791B2 (en) * 2008-06-23 2013-10-22 Verno Holdings, Llc System for decontaminating water and generating water vapor
US11319218B2 (en) * 2009-06-22 2022-05-03 Verno Holdings, Llc System for decontaminating water and generating water vapor
BR112014032485B1 (pt) * 2012-06-28 2021-05-11 Verno Holdings , Llc sistema para processar um fluido
CN104132034B (zh) * 2014-07-22 2016-09-21 山西凌志达煤业有限公司 带反冲洗双过滤器的等分布角液压缸式马达
CN108947000B (zh) * 2018-06-15 2021-08-13 浙江名博建设有限公司 一种节能减排的城镇污水处理系统
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KR20240032936A (ko) 2024-03-12
CN117980272A (zh) 2024-05-03
CL2024000015A1 (es) 2024-08-02
WO2023283127A1 (en) 2023-01-12
MX2024000374A (es) 2024-01-26

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