EP4365319A1 - Bande d'acier électrique à grains orientés et son procédé de fabrication - Google Patents
Bande d'acier électrique à grains orientés et son procédé de fabrication Download PDFInfo
- Publication number
- EP4365319A1 EP4365319A1 EP23207333.8A EP23207333A EP4365319A1 EP 4365319 A1 EP4365319 A1 EP 4365319A1 EP 23207333 A EP23207333 A EP 23207333A EP 4365319 A1 EP4365319 A1 EP 4365319A1
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- EP
- European Patent Office
- Prior art keywords
- grain
- oriented electrical
- electrical steel
- cold
- steel sheet
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- 229910001224 Grain-oriented electrical steel Inorganic materials 0.000 title claims abstract description 96
- 238000000034 method Methods 0.000 title claims abstract description 42
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 22
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 79
- 239000010959 steel Substances 0.000 claims abstract description 79
- 239000010410 layer Substances 0.000 claims abstract description 75
- 229910052839 forsterite Inorganic materials 0.000 claims abstract description 60
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims abstract description 60
- 239000012792 core layer Substances 0.000 claims abstract description 49
- 229920005989 resin Polymers 0.000 claims abstract description 45
- 239000011347 resin Substances 0.000 claims abstract description 45
- 239000010960 cold rolled steel Substances 0.000 claims abstract description 40
- 238000005452 bending Methods 0.000 claims abstract description 26
- 229910052742 iron Inorganic materials 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 13
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 12
- 238000005275 alloying Methods 0.000 claims abstract description 9
- 230000010287 polarization Effects 0.000 claims abstract description 7
- 230000005284 excitation Effects 0.000 claims abstract description 4
- 238000000137 annealing Methods 0.000 claims description 79
- 238000005096 rolling process Methods 0.000 claims description 38
- 239000004593 Epoxy Substances 0.000 claims description 26
- 238000000576 coating method Methods 0.000 claims description 20
- 238000005097 cold rolling Methods 0.000 claims description 18
- 238000001953 recrystallisation Methods 0.000 claims description 18
- 239000011248 coating agent Substances 0.000 claims description 17
- 238000005121 nitriding Methods 0.000 claims description 17
- 229910052757 nitrogen Inorganic materials 0.000 claims description 15
- 229910052782 aluminium Inorganic materials 0.000 claims description 12
- 238000011282 treatment Methods 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 230000004907 flux Effects 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 229910052796 boron Inorganic materials 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 229910052718 tin Inorganic materials 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 36
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 17
- 239000000203 mixture Substances 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 12
- 238000003475 lamination Methods 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- 239000011651 chromium Substances 0.000 description 9
- 238000005261 decarburization Methods 0.000 description 9
- 239000003822 epoxy resin Substances 0.000 description 9
- 229920000647 polyepoxide Polymers 0.000 description 9
- 229910000976 Electrical steel Inorganic materials 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- 239000000377 silicon dioxide Substances 0.000 description 8
- 238000002791 soaking Methods 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 7
- 238000009413 insulation Methods 0.000 description 7
- 235000012245 magnesium oxide Nutrition 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- 239000013067 intermediate product Substances 0.000 description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 238000010030 laminating Methods 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- 229910000851 Alloy steel Inorganic materials 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 238000005098 hot rolling Methods 0.000 description 4
- 230000005764 inhibitory process Effects 0.000 description 4
- 238000001000 micrograph Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000001878 scanning electron micrograph Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000001845 chromium compounds Chemical class 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
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- 238000005554 pickling Methods 0.000 description 3
- 230000008092 positive effect Effects 0.000 description 3
- 238000003303 reheating Methods 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000161 steel melt Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 2
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
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- 239000002612 dispersion medium Substances 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 2
- 239000004137 magnesium phosphate Substances 0.000 description 2
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 2
- 229960002261 magnesium phosphate Drugs 0.000 description 2
- 235000010994 magnesium phosphates Nutrition 0.000 description 2
- 239000000696 magnetic material Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000004626 scanning electron microscopy Methods 0.000 description 2
- 239000011669 selenium Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- GNFTZDOKVXKIBK-UHFFFAOYSA-N 3-(2-methoxyethoxy)benzohydrazide Chemical compound COCCOC1=CC=CC(C(=O)NN)=C1 GNFTZDOKVXKIBK-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- -1 BF3 amine Chemical class 0.000 description 1
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000035508 accumulation Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
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- 238000011049 filling Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 238000013532 laser treatment Methods 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical class [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 230000005381 magnetic domain Effects 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000002436 steel type Substances 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 238000009849 vacuum degassing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/004—Very low carbon steels, i.e. having a carbon content of less than 0,01%
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1216—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the working step(s) being of interest
- C21D8/1233—Cold rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1244—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest
- C21D8/1272—Final recrystallisation annealing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1277—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties involving a particular surface treatment
- C21D8/1283—Application of a separating or insulating coating
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/008—Ferrous alloys, e.g. steel alloys containing tin
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/20—Ferrous alloys, e.g. steel alloys containing chromium with copper
Definitions
- the present invention relates to a grain-oriented electrical steel strip, to a method for producing a grain-oriented electrical steel strip, to a laminated stack of at least two grain-oriented electrical steel strips of the invention and to the use of such a grain-oriented electrical steel strip or laminated stack thereof as material for the production of parts for electric motors, for electric transformers or for other electric devices and.
- the present invention relates to a grain-oriented electrical steel strip with improved adhesion of a forsterite layer, formed thereon and excellent electromagnetic properties.
- sheet or “strip” are used in the present text synonymously to indicate a flat steel product which is obtained by a rolling process and which length and width is much greater than its thickness.
- sheet or “strip” are used in the present text synonymously to indicate a flat steel product which is obtained by a rolling process and which length and width is much greater than its thickness.
- Grain-oriented electrical steel is a soft magnetic material, which typically exhibits high silicon contents.
- GOES has a high permeability to the magnetic field and can be magnetized and demagnetized easily.
- An exemplary production route includes the following manufacturing steps:
- the casting and the high temperature slab reheating is performed at temperatures of up to 1400 °C.
- Such high temperature casting and reheating results in a well-developed inhibition system which comprises particles of AlN, MnS and other compounds in the iron matrix even before the cold process. The presence of said particles promotes an abnormal grain growth in the steel structure, which has a positive effect on the magnetic properties of the GOES sheet.
- the primary recrystallization (PRX) occurring during the decarburization annealing prepares and controls the secondary grain growth.
- PRX The primary recrystallization
- this process step is unstable due to the large number of metallurgical phenomena that compete with each other during the decarburization annealing. These phenomena are in particular carbon removal, formation of the oxide layer, primary grain growth.
- decarburization annealing is essential to obtain efficient nitriding, a high-quality insulating forsterite film, and a sufficient number of Goss nuclei in the matrix.
- a dense oxide layer which occurs during the beginning of decarburization annealing, can promote surface quality but can also act as a barrier to decarburization and nitriding.
- the steel strip runs through a high temperature annealing cycle either in a batch annealing furnace or a rotary batch annealing furnace.
- secondary recrystallization SRX
- an abnormal grain growth takes place which leads to the Goss texture controlled by the inhibitors previously formed.
- disturbing elements such as sulphur or nitrogen are removed and a forsterite layer, also often called “glass film” is formed on the surface of the strip.
- This forsterite layer acts as an electric insulation coating layer and applies an additional tension on the surface of the strip, which contributes to the magnetic properties of the strip.
- a solution based on magnesium phosphate or aluminum phosphate or mixtures of both with various additives, such as chromium compounds and Si oxide, can be applied to the forsterite layer and baked at temperatures above 350 °C.
- the layer system thus formed on the electrical steel forms an insulating layer, which transfers additional tensile stresses to the steel material that have a favorable effect on the electromagnetic properties of the electrical steel or sheet.
- the interface between the forsterite layer and the steel substrate is usually the weak point of the laminated stack under load.
- stacks of the GOES sheets are usually laminated together via a backlack type resin or an epoxy-based resin as described in DE 10 2015 012172 A1 . Therefore, for the production of laminated stacks of grain-oriented electrical steel strips for use in electric motors the adherence properties of the forsterite layer to the base steel of the GOES are of primary importance.
- the high-temperature annealing step during which the forsterite layer is formed usually takes 6 - 7 days and requires considerable energy input. Only after this long annealing period has elapsed it becomes possible to determine with conventional production methods whether the forsterite layer has formed properly or whether it is only insufficiently adhering to the steel substrate. Interventions in the production process to eliminate a defective formation of the forsterite layer can therefore, only be carried out after a considerable delay. As production continues during this time, larger quantities of likewise defective electrical steel strip may be produced until the cause of the defect has been eliminated.
- anchorages such as non-metallic inclusions or interface roughness, between the forsterite layer and the iron-silicon-steel matrix improve the adhesion of the forsterite layer to the steel base material of the electrical steel strip.
- these anchorages have the drawback that they penetrate the magnetic active part of the grain-oriented electrical steel sheet and act as a pinning point for the Bloch wall movement and thereby deteriorate the overall magnetic properties, especially the polarization properties of the grain-oriented electrical steel sheet at a given external field.
- an improvement in adhesion of the forsterite layer to the base steel strip is usually accompanied by a deterioration of the magnetic properties of the grain-oriented electrical steel strip.
- the object of the present invention was to provide a grain-oriented electrical steel strip, in particular for use in electric motors, in electric transformers or in other electric devices, with improved adhesion of the forsterite layer to the base steel without negatively affecting its electromagnetic properties.
- the invention solved this problem by means of a grain-oriented electrical steel sheet with at least the features specified in claim 1, a laminated stack thereof with at least the features specified in claim 8 and a process for producing the grain-oriented electrical steel sheet with at least the features specified in claim 11.
- a grain-oriented electrical steel sheet according to the invention has a peak magnetic polarization of ⁇ 1.3 T at an external field of 100 A/m and an excitation of 1000 Hz and comprises
- the grain-oriented electrical steel sheet according to the present invention comprises a cold-rolled steel core layer consisting at least of iron (“Fe”) and silicon (“Si”), wherein the Fe, as in common GOES materials, accounts for by far the largest share.
- Fe iron
- Si silicon
- Si 1 to 8% by weight Si can be present in the steel of the core layer of the grain-oriented electrical steel sheet according the invention.
- a silicon content of 1 to 5% by weight Si being especially effective for practical applications.
- Si-contents of 2 to 4% by weight, particularly 2.5 to 3.5% by weight, of the core layer have proven to be especially advantageous with regard to the magnetic properties of a grain-oriented steel sheet according to the invention.
- a Si content of at least 2% by weight has proven to be particularly beneficial to ensure a high permeability and thereby an improved iron loss of the grain-oriented steel sheet.
- the Si content is preferably 4% by weight or less.
- the core layer of the grain-oriented steel sheet according to the invention optionally may contain further alloying elements.
- Such further elements may include at least one element of the group "C, Mn, Cu, Cr, Sn, Al, N, Ti, S, Se, Mo and B", wherein the sum of the contents of these elements in the alloy of the core layers is preferably restricted to 3% by weight.
- the amount of C, if present in the grain-oriented electrical steel sheet may amount to 0.0001 to 0.01% C, particularly preferably 0.0001 to 0.005% C.
- a C content of more than 0.005% leads to a significant deterioration of the iron loss of the grain-oriented electrical steel sheet and should therefore be avoided.
- the amount of Cr if present in the grain-oriented electrical steel sheet, may amount to 0.001 to 3.0% Cr, particularly preferably 0.01 to 0.50% by weight Cr.
- Cr improves the magnetic properties of the grain-oriented steel sheet by stabilizing the mixed oxide and glass film formation.
- the amount of Cr should be at least 0.001% by weight. Particularly good results are achieved in case the Cr content is limited to 0.50% by weight.
- the amount of Cu, if present in the grain-oriented electrical steel sheet can be 0.001 to 3.0 % by weight, particularly 0.01 to 0.50% Cu.
- Cu decreases the degree of oxidation and stabilizes the secondary recrystallization during bell anneal.
- the content of Cu should be at least 0.001% by weight, whereas when the Cu content is higher than 3.0%by weight, the hot rollability is decreased due to the formation of hard particles.
- Sn can be optionally present as well in the grain-oriented electrical steel sheet according to the invention in contents of 0.01 to 0.5% by weight, particularly 0.02 to 0.30% by weight. Sn improves magnetic quality by stabilizing the formation of the oxide layers and the glass film. This effect is achieved by adding at least 0.01% by weight Sn to the steel composition. A Sn content above 0.5% by weight shows negative influences on the oxidation process and as a result a stable glass film (forsterite film) cannot be formed.
- the amount of Mn, if present in the grain-oriented electrical steel sheet can be 0.001 to 3.0% by weight, particularly 0.01 to 0.50% Mn.
- Mn increases the specific resistivity of the steel, which effectively decreases the iron loss. This can be achieved by addition of an amount of at least 0.001% by weight Mn. In case the amount of Mn exceeds 3.0% by weight the magnetic flux density of the steel is unfavorably reduced.
- the contents of Al, N, Ti, S, Se, Mo and B, which may also be optionally present in the core layer of the grain-oriented electrical steel sheet according to the invention are delimited such that the sum of the contents of these elements is less than 3% by weight, preferably less than 1% by weight.
- a steel alloy before hot rolling which is especially suited to serve as basis for the core layer of a grain-oriented steel sheet according to the invention preferably comprises, in % by weight, 0.01 to 0.10% C, 2 to 5% Si, 0.01 to 0.5% Mn, 0.01 to 0.5% Cr, 0.01 to 0.5% Cu, 0.01 to 0,3% Sn, optionally in sum less than 3%, preferably less than 1%, of one or more elements selected from Al, N, Ti, S, Se, Mo and B, the remainder being Fe and unavoidable impurities.
- the sum of the content of unavoidable impurities is preferably restricted to less than 0.5% by weight.
- the sum of the sulfur (S) and selenium (Se) contents of the core layer of a grain-oriented steel sheet according to the invention is preferably restricted to less than 0.010% by weight.
- the sulfur (“S”) content of the core layer of the grain-oriented steel sheet according to the invention is restricted to less than 50 ppm by weight, preferably to less than 30 ppm by weight.
- the steel alloy before hot rolling, according to the present invention may also further contain Al and N, which can be used for the control of the inhibition system.
- the amount of Al in the steel alloy can be 0.001 to 1.0% by weight, particularly 0.001 to 0.10% Al.
- N can be part of the steel alloy and be 0.001 to 0.80% by weight, particularly 0.001 to 0.10% N.
- the amount of N is reduced, so that the grain-oriented electrical steel can contain 0.0001 to 0.010% N, preferably 0.0001 to 0.005% N.
- the grain-oriented steel according to the present invention comprises at least one forsterite layer present above one or both outer surfaces of the cold-rolled steel core layer.
- a forsterite layer as used herein is a layer that comprises mainly forsterite and may further comprise oxides and mixed oxides of iron, aluminum, titanium, magnesium and/or silica.
- the forsterite layer may comprise at least 50%, preferably at least 75%, more preferably at least 90%, forsterite.
- the remainder of the forsterite layer may be comprised of iron oxides, silica oxides, aluminum oxides, titanium oxides, magnesium oxides and/ or mixed oxides of iron, aluminum, titanium, magnesium and/or silica.
- an insulating layer may further be present on the surface of the at least one forsterite layer present on at least one of the surfaces of the cold-rolled steel core layer.
- Such insulating layers are known to the skilled person and may be formed, e.g., from a solution based on magnesium phosphate or aluminum phosphate or a mixture thereof with various additives, such as chromium compounds and silicon dioxide.
- coatings mentioned above further coatings may be present on the insulating layers to enhance the properties of the grain-oriented electrical steel sheet, if appropriate. Examples for such coatings are disclosed in DE 10 2008 008 781 A , US 3,948,786 A and JP S53-28375 B2 .
- the cold rolled steel core layer of the grain-oriented steel according to the present invention has a thickness of 160 to 380 ⁇ m, wherein a thickness of the core layer of at least 180 to 300 ⁇ m turned out to be especially useful for practical applications in rotating machines.
- the thickness of the forsterite layer of a steel sheet according to the invention typically amounts to 0.5 to 3 ⁇ m, wherein in practice thicknesses of at least 1 to 2 ⁇ m are observed.
- a restriction of the forsterite layer to a maximum of 3 ⁇ m turned out to be especially advantageous with regard to the iron filling factor of the steel sheet according to the invention.
- the grain-oriented electrical steel sheet according to the present invention further may comprise at least one, preferably exactly one, insulating layer present on each forsterite layer.
- the sum of the thicknesses of the insulating layers is preferably at least 0.1 ⁇ m and less than 5 ⁇ m, more preferably 0.1 to 2.5 ⁇ m.
- the grain-oriented steel according to the present invention comprises anchorages protruding from the forsterite layer into the cold rolled steel core layer, wherein the anchorages have a depth of ⁇ 0.5 ⁇ m and the mean number of anchorages is 1 to 8 per 10 ⁇ m length in rolling direction on at least one of the surfaces of the cold-rolled steel core layer.
- An anchorage as used herein is a part of the forsterite layer that protrudes into the cold rolled steel base layer with a depth of ⁇ 0.5 ⁇ m.
- Such anchorages can be determined by scanning electron microscopy (SEM).
- SEM scanning electron microscopy
- the determination of the anchorages is carried out by using a SEM-micrograph of the grain-oriented electrical steel sheet and placing a horizontal line, in the area between the forsterite layer and the cold-rolled steel core layer.
- the EDX unit of the SEM it is possible to determine exactly the elemental composition along the horizontal line in the SEM-micrograph.
- the horizontal line is moved down in the micrograph towards the cold-rolled steel core layer and the point at which the amount of iron in the elemental composition of the horizontal line is 10% is defined as the end of the forsterite layer.
- This horizontal line is used as zero point from which the depth of the anchorages protruding into the cold-rolled steel base layer is determined. Thereby, parts of the forsterite layer protruding from this line into the cold-rolled steel core layer having a depth of less than 0.5 ⁇ m are seen as surface roughness.
- the grain-oriented electrical steel sheet according to the invention has a bending radius of 9 mm or less determined using a taper mandrel bending device and bending a specimen of the grain oriented electrical steel continuously 180° around a taper mandrel with a taper base of 30 mm and a taper tip of 5 mm, the bending radius being the radius at which visible cracks appear in the grain-oriented electrical steel sheet.
- the aforementioned method of determining the bending radius corresponds to DIN 6860:2006-06.
- a low bending radius can be equated to a good adhesion of the forsterite layer. In other words, the better the adhesion of the forsterite layer, the lower the bending angle determined according to the method described above.
- the grain-oriented electrical steel sheet according to the present invention can be manufactured by performing a method, which comprises at least the following working steps:
- the method of the invention may comprise further steps that are known to the skilled person and that are usually performed when producing grain-oriented electrical steel sheets.
- the invention is based here on the realization that the formation of an optimally adhering forsterite layer on the steel substrate of a grain-oriented electrical steel strip according to the invention can be ensured by fulfilling the condition (I) above during cold rolling of the hot strip and primary recrystallization annealing of the cold-rolled steel strip, which forms the cold-rolled electrical steel core layer of the grain-oriented electrical steel strip according to the invention and is subsequently coated with the forsterite layer.
- the invention makes use of the fact that on each outer surface of the steel core mixed oxides, in particular of at least iron, silica and/or aluminum, are formed during cold-rolling between consecutive rolling passes with or without intermediate annealing as a result of a chemical reaction of the alloying elements contained in the steel material of the core layer with the atmosphere.
- Step a) of the method comprises providing a hot rolled steel strip, which is made from a steel comprising Fe, Si and optionally further alloying elements.
- the steel may be alloyed in accordance with the explanations and provisions given above with regard to the cold-rolled steel core layer of the grain-oriented electrical steel sheet of the invention, which are equally applicable to the hot-rolled steel strip provided in the method of the invention.
- Step a) of the process according to the invention comprises a common steelmaking step to produce a steel melt, which afterwards is cast into an intermediate product such as slabs, thin slabs or cast strip.
- the intermediate product obtained in this way is hot rolled to a hot rolled strip, which is coiled to a coil and optionally undergoes a hot strip annealing and pickling if appropriate before further manufacturing.
- the hot rolled strip provided in step a) of the process according to the invention preferably has a thickness of 1.5 to 3.5 mm, more preferably 1.8 to 2.7 mm. Examples for known methods suited for the production of a hot rolled strip to be provided in working step a) can be found in DE 197 45 445 C1 and EP 1 752 549 B1 .
- step a) hot rolled steel strips having the above-mentioned composition and thickness are obtained. These hot rolled steel strips are preferably directly introduced into step b) of the process. Alternatively, the hot rolled steep strip may be annealed after step a) and before step b).
- the hot rolled strip is cold rolled in at least three passes with a temperature T CR during the third pass in a single-stage rolling or during the last pass prior to an intermediate annealing in a multi-stage rolling, to obtain a cold rolled strip.
- single stage rolling is cold-rolling in at least three passes, wherein no intermediate annealing takes place between individual passes.
- multi-stage rolling is cold rolling in at least three passes, wherein the hot-rolled strip is cold rolled to an intermediate thickness, an intermediate annealing takes place, and after the intermediate annealing the strip is further cold-rolled to the final thickness.
- Methods for cold rolling a grain-oriented steel strip are generally known to the skilled expert as well and, for example, described in WO 2007/014868 A1 and WO 99/19521 A1 .
- an intermediate annealing is performed in a temperature range of 700 to 1150 °C, preferably 800 to 1100 °C, under an atmosphere which dew point is set to 10 to 80 °C.
- Typical annealing times are 30s to 900 s. Installations with which such annealing can be performed are generally known and disclosed, for example, in WO 2007/014868 A1 and WO 99/19521 A1 .
- the temperature T CR as used herein is the temperature of the strip determined during the third pass of single stage rolling or during the last pass of multi-stage rolling prior to intermediate annealing, which is significantly higher than the temperature of the strip during the first pass of single stage rolling or of multi-stage rolling, e.g., at least 50°C, preferably at least 100°C, most preferably at least 150°C, higher.
- the temperature T CR is between 150 and 450°C, more preferably between 200 and 270°C.
- the thickness of the cold rolled strip is 0.05 to 0.5 mm, preferably a maximum thickness of 0.35 mm, preferably of ⁇ 0.27 mm at most or of 0.22 mm at most, are especially favorable. Apparatuses in which such cold rolling can be performed are generally known to the skilled expert and, for example, disclosed in WO 2007/014868 A1 and WO 99/19521 A1 .
- step c) of the process according to the invention primary recrystallization annealing of the cold rolled strip obtained in step b), optionally including a nitriding treatment, at an annealing temperature between 600 to 950 °C for the duration t A in a high dew-point atmosphere DP takes place.
- the primary recrystallization annealing is preferably carried out at temperatures in the range of 600 to 900 °C.
- the duration t A of the primary recrystallization annealing is preferably 30 to 300 s.
- a high dew point atmosphere as used herein is an atmosphere with a dew point between 40 and 80°C, preferably between 40 and 65°C.
- a dew point of more than 80°C cannot be set in industrial settings, while with a dew point below 40°C the resulting oxide layer becomes too dense and all surface-controlled chemical reactions, e.g. decarburization, nitriding, de-nitriding, can no longer take place as desired.
- the atmosphere may comprise 5 to 95 Vol.-% Hz, the reminder being nitrogen or any inert gas or a mix gas.
- the annealing can be carried out under an atmosphere, which comprises N 2 or N-comprising compounds, for example NH 3 .
- Annealing and nitriding can be conducted in two separate steps one after the other with the annealing being performed at first.
- annealing and nitriding can be performed simultaneously.
- nitriding degree is calculated as the difference between the nitrogen content of the steel strip before the second recrystallization annealing (working step e)) minus the nitrogen content before the primary recrystallization annealing (working step c)).
- the nitrogen content can be determined by usual means, such as the 736 analyzer offered by Leco Corporation, St. Joseph, USA.
- step d) of the method according to the invention the cold-rolled steel strip obtained in step c) is coated with an annealing separator comprising MgO and optionally oxides and mixed oxides of iron, aluminum, titanium, magnesium and/or silica.
- the annealing separator comprising MgO and optionally oxides and mixed oxides of iron, aluminum, titanium, magnesium and/or silica applied to the cold-rolled steel strip to produce the forsterite layer during annealing in step e) in a manner known per se can consist of at least 70% by weight MgO, optionally up to 25% by weight of oxides and mixed oxides of iron, aluminum, titanium, magnesium and/or silica and can further contain up to 5% by weight additives, based on the total dry weight of the annealing separator.
- additives may be, for example, elements like Ca, B and Sr, ammonium chloride or antimony chloride, and other salts like magnesium sulfate or sodium chloride, the addition of which controls the density of the subsequent forsterite layer and the gas exchange between the annealing atmosphere during high-temperature annealing and the metal.
- step e) of the process according to the invention the cold rolled strip obtained in step c) and coated with the annealing separator in step d) undergoes a high temperature annealing treatment during which the forsterite layer is formed and secondary recrystallization occurs.
- This high temperature annealing treatment can also be carried out in a manner known per se.
- the cold-rolled steel strip obtained after step c) and coated with the annealing separator in step d) can be wound into a coil and kept in a bell furnace for 10 - 200 hours at a temperature of 730 - 1325°C under an atmosphere consisting of at least 50% H 2 .
- the strip or sheet that is obtained after step d) can be rapidly heated to a soaking temperature of 1150°C or above, wherein soaking temperatures of at least 1200°C are particularly advantageous.
- the heating and soaking is preferably carried out under a protective gas atmosphere, which, for example, comprises Hz.
- a protective gas atmosphere which, for example, comprises Hz.
- the heating to and soaking at the respective soaking temperature is performed under an atmosphere which comprises 5 to 95 Vol.-% Hz, the reminder being nitrogen or any inert gas or a mix gas, the local dew point of the atmosphere being at least 10 °C.
- the soaking time, during which the high temperature soaking is carried out in this way can be determined in a common manner, which is well known to the expert. By the soaking performed in this way atoms of elements are removed, which would deteriorate the properties of the grain-oriented electrical steel sheet. These elements are in particular N and S.
- the steel strip After the high temperature annealing the steel strip is cooled down in a common manner, e.g. by natural cooling, down to room temperature.
- step e) of the process according to the invention the secondary recrystallization takes place which ensures that the grain-oriented steel sheet processed in this way is prepared to reliably develop the optimized properties of a grain-oriented steel sheet according to the invention as outlined above.
- the steel strip is cleaned, and optionally pickled.
- Methods with which the steel strip is pickled are known to the skilled expert.
- the steel strip can be treated with an aqueous acidic solution. Suitable acids are for example phosphoric acid, sulfuric acid and/or hydrochloric acid.
- an insulating layer is applied on at least one side of the GOES.
- the method for applying the insulating layer is known to the artisan and can be found in e.g. EP 2 902 509 B1 and EP2 954 095 A1 .
- An insulation coating applied to a grain oriented electrical steel product has a positive effect on minimization of the hysteresis losses.
- the insulation coating can transfer tensile stresses to the base material, which not only improves the magnetic loss values of the grain oriented electrical steel product but also reduces the magnetostriction, thereby having in turn a positive effect on the noise behavior of the finished transformer.
- Formation of the insulation coating involves applying an aqueous solution of metallic phosphate containing colloidal silica and optional chromium compounds onto the surface of the steel sheet and baking the same at temperatures in the range of 800 °C to 950 °C for 10 to 600 s.
- the phosphate coating is usually applied on top of the forsterite layer. However, it is also possible to apply the insulation directly onto the steel surface with no forsterite layer in between.
- a domain refinement transverse to the rolling direction is performed.
- the method for domain refinement by laser or electron beam treatment is known to the artisan and can be found in e.g. EP 2 675 927 A1 .
- linear deformations, which are arranged with a spacing, are formed into the surface of the flat steel product by means of a laser beam emitted by a laser beam source, thereby decreasing the length of the domains and reducing the losses of the grain-oriented electrical steel sheet.
- the grain-oriented electrical steel is presenting a cold-rolled steel core layer and at least one forsterite layer being present on at least one of the outer surfaces of the cold-rolled steel core layer and anchorages protruding from the forsterite layer into the cold rolled steel core layer, wherein the anchorages have a depth of ⁇ 0.5 ⁇ m and the mean number of anchorages is 1 to 8 per 10 ⁇ m length in rolling direction on at least one of the surfaces of the cold-rolled steel core layer.
- Such a grain-oriented electrical steel sheet has a peak magnetic polarization of ⁇ 1.3 T at an external field of 100 A/m and an excitation of 1000 Hz.
- the magnetic polarization is determined according to IEC 60404-3.
- the grain-oriented electrical steel sheets can be prepared in any format, like steel strips that are provided as coils, or cut steel pieces that are provided by cutting these steel pieces from the steel strips. Methods to provide coils or cut steel pieces are known to the skilled expert.
- the grain-oriented electrical steel sheet according to the present invention shows improved adhesion of the forsterite layer and at the same time excellent magnetic properties in comparison to grain-oriented electrical steel sheets according to the prior art.
- the grain-oriented electrical steel sheet according to the invention is in particular useful for the manufacture of parts for electric transformers, for electric motors or for other electric devices.
- a preferred use of the grain-oriented electrical steel sheet of the present invention is as material for the manufacture of stator and/or rotor core for axial flux motors.
- stator or rotor core stacks of the grain-oriented electrical steel sheet are typically formed by laminating the GOES sheets together with a resin, for example, an epoxy-based resin, e.g., as described in paragraph [0008] of DE 10 2015 012172 A1 , or a backlack type resin.
- a resin for example, an epoxy-based resin, e.g., as described in paragraph [0008] of DE 10 2015 012172 A1 , or a backlack type resin.
- a preferred epoxy-based resin comprises 60 parts by weight of an epoxy resin, 0.5 to 15 parts by weight of a latent curing agent and 1 to 15 parts by weight of a latent accelerator, based on the total dry weight of the epoxy-based resin.
- the components in this preferred epoxy-based resin are present as solids in the indicated parts by weight based on the total dry weight of the epoxy-based resin.
- This dry coating mixture is dispersed and/or dissolved in a suitable medium before being applied to the GOES sheets.
- the dry coating mixture comprising the specified components is preferably provided as a dispersion of the above-mentioned composition in a dispersion medium.
- the dispersion medium is water.
- the epoxy resin present in the epoxy-based resin may comprise one or more epoxy resins having more than one epoxy group.
- Preferably at least one epoxy resin in the epoxy-based resin has a softening point of greater than 50°C.
- the epoxy resin in the epoxy-based resin can be selected from aliphatic, cycloaliphatic and/or aromatic epoxy resins.
- the epoxy-based resin comprises 1 to 10 parts by weight of the latent curing agent, particularly preferably 2 to 5 parts by weight of the latent curing agent, based on the total dry weight of the epoxy-based resin.
- the latent curing agent preferably undergoes curing reactions with the epoxy resin of the epoxy-based resin at temperatures in the range from 80°C to 200°C.
- latent curing agent refers to a substance which serves to cure the epoxy resin, but which must be activated for curing, in particular by supplying chemical and/or thermal energy.
- the latent curing agent is added to the epoxy-based resin for example, as a solid in powder form.
- the latent curing agent contains a dicyandiamide, an imidazole, a BF 3 amine complex or a combination thereof.
- the epoxy-based resin comprises 1 to 10 parts by weight of a latent accelerator, preferably 1 to 5 parts by weight of a latent accelerator, more preferably 1 to 4 parts by weight of a latent accelerator, based on the total dry weight of the epoxy-based resin.
- latent accelerator refers to a substance that accelerates the curing of the epoxy resin by the latent curing agent.
- attribute latent also refers, in the context of the accelerator, to the fact that the accelerator must also be activated beforehand by chemical and/or thermal energy in order to perform its function.
- the latent accelerator is added to the epoxy-based resin, for example, as a solid in powder form.
- the latent accelerator contains a urea derivative and/or imidazole.
- the epoxy-based resin may further contain other components, such as anticorrosion additives, insulation additives, colorants and/or fillers.
- the epoxy-based resin is applied to the GOES sheet on one side or on both sides. If an epoxy-based resin is applied on both sides of the GOES sheet, the thickness of the coating can be the same, but different thicknesses can also be provided.
- the preferred thickness of the epoxy-based resin i.e. the thickness of the coating on one side of the GOES sheet in the case of a single-sided application of the epoxy-based resin or the total thickness of the epoxy-based resin coating on both sides of the GOES sheet in the case of a double-sided epoxy-based resin coating, is between 1 ⁇ m and 20 ⁇ m, preferably between 2 ⁇ m and 10 ⁇ m. A total thickness of the epoxy-based resin coating between 4 and 8 ⁇ m is particularly preferred.
- the lamination of the GOES sheets temperatures below 230°C are usually used.
- the optimal duration of the lamination depends on the lamination temperature used and on the thickness of the stack to be laminated and is typically adapted depending on the stack geometry and the type of heating used.
- the exact conditions for the manufacturing of the resin coating depend on the resin type used and can be found in the respective data sheets of the resin manufacturer.
- the optimal duration for the lamination increases with decreasing lamination temperature and/or increasing laminated stack thickness.
- lamination of a thin stack of GOES at a lamination temperature of 200°C using a lamination time of 2 minutes may be sufficient, while for laminating a thicker stack of GOES a lower temperature of 180°C for a duration of 1 hour or at 140°C for a duration of 2 hours may be preferable.
- the temperatures mentioned for the lamination are not the furnace temperatures but the core temperatures of the stack and the holding time is the time that elapses between reaching the core temperature and removal from the furnace.
- the lamination is usually carried out using a pressure between 150 to 300 N/cm 3 .
- Another aspect of the present invention is a laminated stack of grain-oriented electrical steel sheets, wherein the stack comprises at least two grain-oriented electrical steel sheets according to the invention laminated together with a resin.
- a laminated stack of grain-oriented electrical steel sheets comprises at least 2 or at least 3 grain-oriented electrical steel sheets according to the invention laminated together with a resin.
- the resin for laminating the grain-oriented electrical steel sheets together is not particularly limited. Any resin known to the skilled person for this purpose can be used.
- the resin for laminating the grain-oriented electrical steel sheets together is selected from a backlack type resin,an epoxy-based resin, e.g., as described in paragraph [0008] of DE 10 2015 012172 A1 or as described in detail above. These resin types are known to the skilled person and are described, e.g., in DE 10 2015 012172 A1 .
- Laminated stacks according to the invention preferably have a peel strength of ⁇ 13 N/cm determined according to ISO 11339-2010-06. Such peel strength has been found to be particularly beneficial for the practical application of these laminated stacks as a material for the production of stator or rotor core in axial flux motors.
- the laminated stacks show good adhesion and magnetic properties.
- the weak point lies no longer between the forsterite layer and the grain-oriented steel sheet but is transferred to the resin, which is favorable as such stacks fulfill all demands of the targeted applications.
- FIG. 1 shows a schematic representation of a SEM micrograph of an embodiment of a grain-oriented electrical steel sheet according to the present invention.
- the grain-oriented electrical steel sheet 1 comprises a cold-rolled steel sheet core layer 2 and a forsterite layer 3 as well as an insulating layer 7.
- Anchorages 4 protrude from the forsterite layer 3 into the cold-rolled steel sheet core layer 2.
- the anchorages have a depth of ⁇ 0.5 ⁇ m starting from a horizontal line 5 in the micrograph, wherein the elemental composition of the horizontal line determined by EDX comprises an amount of iron that is 10% by weight.
- the micrograph represents a two-dimensional section of the grain-oriented electrical steel sheet some of the anchorages 4 are visible as inclusions 6 in the cold-rolled steel sheet core. However, in the three-dimensional grain-oriented electrical steel sheet these inclusions 6 are in fact connected to the forsterite layer 3, i.e. the connection to the forsterite layer lies outside the two-dimensional plane of the micrograph.
- the bending radius of these samples was determined using a taper mandrel bending device and bending a specimen of the grain oriented electrical steel continuously 180° around a taper mandrel with a taper base of 30 mm and a taper tip of 5 mm, the bending radius being the radius at which visible cracks appear in the grain-oriented electrical steel sheet.
- Laminated stacks of these grain-oriented electrical steel sheets were produced by coating specimen of GOES with a Backlack like type resin and additional laminating of two specimen to produce a small stack for testing.
- the peel strength of these laminated stacks was determined according to ISO 11339- 2016-06.
- Table 1 Figures in % by weight, balance: Fe and impurities Steel C Si Mn Cr Cu Sn A 0,0007 3,03 0,113 0,061 0,195 0,102 B 0,0009 3,43 0,026 0,012 0,089 0,076 C 0,0010 3,21 0,051 0,121 0,149 0,018 D 0,0014 3,19 0,203 0,039 0,056 0,099 Table 2 No. Steel type T CR DP t A (3.4 ⁇ T CR -(1.2xDP-5.8 ⁇ t A ))/500 Peel strength Bending radius J 100 at 1000 Hz Condition (I) met? Invention ?
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