EP4334053A1 - Procédé de production d'un matériau de carbure cémenté ayant une phase liante renforcée - Google Patents

Procédé de production d'un matériau de carbure cémenté ayant une phase liante renforcée

Info

Publication number
EP4334053A1
EP4334053A1 EP22725382.0A EP22725382A EP4334053A1 EP 4334053 A1 EP4334053 A1 EP 4334053A1 EP 22725382 A EP22725382 A EP 22725382A EP 4334053 A1 EP4334053 A1 EP 4334053A1
Authority
EP
European Patent Office
Prior art keywords
carbide material
binder
cemented carbide
phase
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP22725382.0A
Other languages
German (de)
English (en)
Inventor
Heiko Friederichs
Britta PHILIPP
David CHMELIK
Ulrich Krämer
Alexander Haller
Tobias Hilgert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Betek GmbH and Co KG
Original Assignee
Betek GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE102021120273.6A external-priority patent/DE102021120273A1/de
Application filed by Betek GmbH and Co KG filed Critical Betek GmbH and Co KG
Publication of EP4334053A1 publication Critical patent/EP4334053A1/fr
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
    • C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
    • C22C29/08—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/10—Sintering only
    • B22F3/1017—Multiple heating or additional steps
    • B22F3/1028—Controlled cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/10—Sintering only
    • B22F3/1035—Liquid phase sintering
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/04—Making non-ferrous alloys by powder metallurgy
    • C22C1/05—Mixtures of metal powder with non-metallic powder
    • C22C1/051—Making hard metals based on borides, carbides, nitrides, oxides or silicides; Preparation of the powder mixture used as the starting material therefor
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/10—Alloys containing non-metals
    • C22C1/1084—Alloys containing non-metals by mechanical alloying (blending, milling)
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
    • C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
    • C22C29/067—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds comprising a particular metallic binder
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/05—Metallic powder characterised by the size or surface area of the particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/05—Metallic powder characterised by the size or surface area of the particles
    • B22F1/054—Nanosized particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/24—After-treatment of workpieces or articles
    • B22F2003/248—Thermal after-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • B22F2005/001—Cutting tools, earth boring or grinding tool other than table ware
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00—Making metallic powder or suspensions thereof
    • B22F9/02—Making metallic powder or suspensions thereof using physical processes
    • B22F9/04—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
    • B22F2009/043—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling by ball milling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/12—Both compacting and sintering
    • B22F3/14—Both compacting and sintering simultaneously
    • B22F3/15—Hot isostatic pressing

Definitions

  • the invention relates to a sintered carbide material, in particular a hard metal, with 70-95% by weight of tungsten carbide in dispersed form and a binder phase, the binder phase having a metallic binder material, in particular Co.
  • EP 2 691 198 B1 describes such a sintered carbide material, namely a hard metal body, and a method for its production.
  • a powder is mixed comprising coarse-grain tungsten carbide, a superstoichiometric proportion of carbon and cobalt powder.
  • tungsten in powder form was added to the powder.
  • the tungsten powder and the cobalt powder had an average particle size of about 1 pm.
  • the coarse-grain tungsten carbide had an average particle size of 40.8 ⁇ m.
  • this powder was ground in a ball mill, and hexane and paraffin wax were added thereto. A green compact was pressed from this mixture and this green compact was then sintered. Subsequent to the sintering process, the obtained cemented carbide material was subjected to a heat treatment. It was heated to 600°C and held at this temperature for 10 hours.
  • the sintered carbide material was subjected to an analysis. It has been shown that the sintered carbide material has nanoparticles in the binder phase, with the nanoparticles having a size of less than 10 nm.
  • the nanoparticles were formed by the eta phase (Co 3 W 3 C) or (Co 6 W 6 C) or theta phase (Co 2 W 4 C).
  • the grain size of the nanoparticles was less than 10 nm.
  • the nanoparticles are accompanied by a strengthening of the binder phase.
  • the hardness of the sintered carbide material can thus be increased.
  • the disadvantage of these materials is the lack of thermal stability of the nanoparticles. As a result, they are only suitable to a limited extent for high-temperature applications or for applications in which a high temperature input occurs. Very high temperatures occur on the tool surface due to friction when working rock and milling asphalt and concrete.
  • the hard material tungsten carbide has a high hot hardness at these temperatures and is not very affected by it.
  • the strength of the metallic binder drops dramatically at these temperatures.
  • the reduced strength of the metallic binder leads to increased abrasive wear and/or extrusion of the binder phase as a result of the stresses caused by use. As a result, the tungsten carbide grains can no longer be held in the hard metal.
  • a sintered carbide material in particular hard metal, is therefore proposed which either has a reinforced binder phase and/or is prepared in order to form a reinforced binder phase.
  • the binder phase is strengthened via the intermetallic phase material.
  • intermetallic phase material is already present in the binder phase, it immediately reinforces it. If the sintered carbide material in the binder phase contains the dissolved elements Ni and Al, thermal treatment of the sintered carbide material forms intermetallic phase material, which then leads to a strengthening of the binder phase.
  • the thermal treatment of the sintered carbide material can take place in different ways that are suitable for forming the intermetallic phase material as intended.
  • This can in particular be a thermal heat treatment, in particular an external introduction of heat into the sintered carbide material.
  • the thermal heat treatment can be effected, for example, in that an active source generates heat or cold and that this heat or cold is introduced into or withdrawn from the material.
  • the intermetallic phase material can correspondingly be formed in a furnace into which the sintered carbide material was introduced. It is also conceivable that at least part of the surface of the sintered carbide material is acted upon by a heating device, for example a burner.
  • an excitation source is present, which introduces energy into the cemented carbide material in order to generate heat therein.
  • This can be an induction coil or a laser device, for example.
  • the heat is generated by passive heating, i.e. by using the sintered carbide material in a preferably intended operating state or in the course of a method step in which the sintered carbide material is processed, in particular installed.
  • heat is generated in the sintered carbide material by friction, as occurs, for example, during the intended use, in particular the intended use, in particular the use of tools, of the sintered carbide material. If it is a tool, it is moved relative to the object to be machined (e.g. in the case of a road milling bit, this road milling bit relative to a road surface), this creates frictional energy that leads to heat generation in the sintered carbide material.
  • the resulting heat can be used to achieve a self-reinforcing effect of the binder phase through the at least partial formation of intermetallic phase material in the sintered carbide material.
  • the sintered carbide material is passively heated in the course of a method step in which the sintered carbide material is applied to a carrier, for example a tool base body or carrier.
  • a carrier for example a tool base body or carrier.
  • the resulting heat can be used to form the intermetallic phase material.
  • a conceivable joining method is a welding method, for example a friction welding method
  • Electron beam welding method a soldering method, for example a hard soldering method, a furnace soldering method, an inductive soldering method, a diffusion soldering method, a plating method, for example explosive plating.
  • a soldering method for example a hard soldering method, a furnace soldering method, an inductive soldering method, a diffusion soldering method, a plating method, for example explosive plating.
  • the binder phase has the following chemical element composition: Ni > 25% by weight, Al > 4% by weight, remainder Co and dissolved binder components, for example W and/or C .
  • the intermetallic phase material forms a crystalline intercalation in the metallic binder.
  • This intermetallic phase material has a significantly higher strength, especially at higher temperatures, compared to the metallic binder material in which it is embedded. At the surface of the cemented carbide material exposed to wear attack, the intermetallic phase material reduces a Erosion or extrusion of the metallic binder material when this is used, for example in a tillage tool.
  • the movement of the tillage tool and the loosened soil material as well as the remaining soil material creates an abrasive and mechanical load on the sintered carbide material.
  • the tungsten carbide grains counteract this wear attack with sufficient wear resistance.
  • the problem here is the binding material, which has a significantly lower strength than tungsten carbide. Since, according to the invention, the intermetallic phase material is integrated in the binder phase or is formed therein, rapid erosion or extrusion of the metallic binder material is prevented.
  • the intermetallic phase material can also reinforce the internal structure of the cemented carbide material. If severe, sudden stresses occur, the crystals of the intermetallic phase material reduce or prevent the tungsten carbide particles from sliding off in the area of the binder phase connecting them, and thus excessive plastic deformation of the binder phase. In particular, the individual crystals of the intermetallic phase material support one another. This has a significant advantage, particularly at high tool application temperatures, since the strength of the Co in the binder phase is reduced at such temperatures, but the intermetallic phase material still reliably provides sufficient support for the binder material.
  • the wear resistance of the sintered carbide material can be achieved with the solution according to the invention.
  • the use of the sintered carbide material according to the invention in the form of a cutting tip of a pick for road milling machines results in up to 50% higher wear resistance! It has been shown that such a significant increase in wear resistance can be achieved both when milling asphalt and concrete road surfaces.
  • the working areas of tools for machining, loosening, conveying and processing vegetable or mineral materials or building materials can be designed, in particular in the field of agriculture or forestry or road, mining or tunnel construction.
  • intermetallic phase material is present in the sintered carbide material, it can be provided according to a variant of the invention that the proportion of metallic binder material in the sintered carbide material is 1-28% by weight, preferably 1-19% by weight. In addition to unavoidable impurities, the entire proportion or almost the entire proportion of this metallic binder material can be formed by Co. Such a choice of material leads to a particularly tough binder phase, which can be effectively reinforced by the existing or the forming intermetallic phase material.
  • the sum of the elements Ni and Al in the sintered carbide material is 1-28% by weight, preferably 1.5-19% by weight, at least in one area of the sintered carbide body.
  • These ranges take into account both Ni and Al from intermetallic phase material that may be present and dissolved Ni or Al in the binder phase. With such compositions, it is possible in particular to create sophisticated hard metal tools for tilling the soil.
  • the proportion of the binder phase in the sintered carbide material is 5-30% by weight, preferably 5-20% by weight.
  • the binder phase can be predominantly formed by the metallic binder material Co.
  • Al and Ni can be dissolved in the binder phase as metallic binder material.
  • other elements and unavoidable impurities can also be present in the binder phase.
  • the binder phase has other components, in particular dissolved W, C and/or Fe, in addition to Co, Ni, Al.
  • the crystallites of the intermetallic phase material may be such that X is in the form of W as well as Mo and/or Nb and/or Ti and/or Ta and/or Cr and/or V is present.
  • the composition of the dissolved components in the binder phase in the finished cemented carbide material can be selected in such a way that the intermetallic phase material can be formed by heat treatment or exposure in this way (see above).
  • the binder phase has two or more intermetallic phase materials or only a single intermetallic phase material and/or that the sintered carbide material is prepared in such a way that two or more intermetallic phase materials or only forms a single intermetallic phase material.
  • the binder phase has the following chemical element composition: Ni > 35% by weight, Al > 5% by weight, remainder Co and dissolved binder components, for example W and/or C, particularly preferably Ni > 40, Al > 6.5% by weight, remainder Co and dissolved binder components, for example W and/or C,
  • This information relates to the total content of the respective substances in the binder phase.
  • the information therefore takes into account the respective elements in dissolved form and also the respective elements as they are bound in the intermetallic phase material.
  • the ratio of the mass fractions Al to Ni is >0.10, preferably >0.12.
  • the ratio of the mass fractions Al to Ni is ⁇ 0.46, preferably ⁇ 0.18, particularly preferably ⁇ 0.16.
  • the above information which relates the ratio of the mass fractions Al to Ni, takes into account the total mass fraction, ie both the dissolved elements Al and Ni and Al and Ni in the intermetallic phase material (if present).
  • the mass fractions of Al and Ni can be verified using a standard ICP measurement.
  • a conceivable variant of the invention is such that the sintered carbide material has at least two volume areas, the relative proportion of intermetallic phase material, based on a volume unit, being greater in the first volume area than in the second volume area.
  • the properties, in particular the tool properties, of the sintered carbide material can be influenced in a targeted manner.
  • one Zone subject to high abrasive wear having the volume region with a higher relative proportion of intermetallic phase material.
  • a zone which, in contrast, has to meet special toughness requirements can have the volume range with a lower relative proportion of intermetallic phase material.
  • the second volume area which has a lower relative proportion of intermetallic phase material compared to the first volume area, that this second volume area can also have no intermetallic phase material.
  • a conceivable alternative of the invention is such that the first volume region, which has the high relative proportion of intermetallic phase material, is delimited by at least one region of the surface of the sintered carbide material. In this way, a high resistance to abrasion is created on the surface of the cemented carbide material there.
  • the second volume region is preferably not arranged adjacent to a surface of the cemented carbide material, but is located in the interior of the cemented carbide material. Here he ensured a high fracture resistance.
  • the second volume area which compared to the first volume area has a lower relative proportion of intermetallic phase material or no intermetallic phase material, is delimited by at least one area of the surface of the sintered carbide material and preferably the first volume area is not bounded by a surface of the cemented carbide material.
  • a tool can be created that adapts its cutting contour to the cutting task in an optimal manner while the tool is being used, in order to achieve an optimal service life.
  • a so-called re-sharpening effect can be realized as a result.
  • a conceivable variant of the invention is such that the binder phase, in particular the metallic binder material and/or the intermetallic phase material, Nb and/or Ti and/or Ta, and/or Mo and/or V and/or Cr, preferably one or more of these materials in the dissolved form in the The binder phase and/or is in the carbide form.
  • the binder phase in particular the metallic binder material and/or the intermetallic phase material, Nb and/or Ti and/or Ta, and/or Mo and/or V and/or Cr, preferably one or more of these materials in the dissolved form in the The binder phase and/or is in the carbide form.
  • one or more of the aforementioned components is/are integrated into the crystal lattice of at least part of the intermetallic phase material or can be integrated into the crystal lattice of the intermetallic phase material by the thermal treatment (heat treatment or exposure to heat).
  • the titanium atom (or another material from the aforementioned group) in the crystal lattice of the intermetallic phase material primarily occupies the lattice site of Al or W and, like W, increases the precipitation temperature for the intermetallic phase material.
  • the intermetallic phase material can be precipitated more effectively during the sintering process, since the precipitations start at higher temperatures and since the diffusion rate is significantly higher here.
  • this measure achieves high heat resistance, since, as mentioned, the solvus temperature of the sintered carbide material is increased. In other words, the temperature required to redissolve the intermetallic phase material in the cemented carbide material increases.
  • the proportion of Mo and/or Nb and/or Ti and/or Ta and/or Cr and/or V in the binder phase is ⁇ 15 at%.
  • the elements mentioned above basically form carbides.
  • the material composition is selected such that these elements, depending on the solubility product and their affinity for carbon, are dissolved in small amounts in the binder phase and they can thus be incorporated into the crystal lattice of the intermetallic phase material and/or in the metallic be dissolved binder phase. If a cemented carbide material is desired that has a high toughness of the binder phase, then the proportion of the carbide form should be kept small. The materials should then be present in a total proportion of 15 at%.
  • the powder mixture for the production of the sintered carbide material can be set stoichiometrically with regard to the carbon content, since the titanium (and/or Mo and/or Nb and/or Ti and/or Ta and/or Cr and/or V ) takes over the task of tungsten.
  • the proportion of carbon is set stoichiometrically or sub-stoichiometrically. With this measure, graphite precipitations in the sintered material are prevented or minimized due to the over-stoichiometric carbon content.
  • the inventors have recognized that such inclusions have an adverse effect on the breaking strength of the sintered carbide material.
  • the proportion of carbon in the sintered carbide material is in the range between:
  • the advantageous effects described above are particularly pronounced in the case of coarse-grain flart metal.
  • the dispersed tungsten carbide in the sintered carbide material is in grain form with an average particle diameter, measured according to DIN ISO 4499 Part 2, in the range between 1 and 15 m ⁇ p, preferably in the range between 1.3 and 10 gm, particularly preferably in the range between 2.5 and 6 gm.
  • the intermetallic phase (M,Y) 3 (AI,X) present or resulting from heat treatment or exposure has a crystal structure L1 2 (space group 221) according to ICSD (Inorganic Crystal Structure Database), then results A microstructure develops in the binder phase in which the crystals of the intermetallic phase can effectively support each other in the metallic binder material when the sintered carbide body is subjected to heavy loads.
  • the intermetallic phase material that is present or that results from heat treatment or heat treatment has a maximum size of 1500 nm, preferably a maximum size of 1000 nm.
  • the sintered carbide material is free or as free as possible of eta phase and/or Al 2 O 3 .
  • the inventors have recognized that the maximum proportion of the eta phase or the maximum proportion of Al 2 O 3 should be a maximum of 0.6% by volume based on the total sintered carbide material. If both substances are present in the sintered carbide material, it is advantageous if the sum of eta phase material and Al 2 O 3 is at most 0.6% by volume.
  • the particle size of Al 2 0 3 and/or the eta phase material is advantageously a maximum of 5 times the mean WC grain size, the mean WC grain size and the particle size of Al 2 0 3 and/or the eta phase material being calculated using the line intersection method DIN ISO 4499, Part 2 can be determined.
  • the toughness of the sintered carbide material can be negatively influenced by the eta phase or Al 2 O3. With higher eta phase proportions, the sintered carbide material is only conditionally suitable for use in demanding tillage tools. The same also applies to Al 2 O3.
  • a tool in particular a comminuting, soil-working tool, preferably for a road milling machine, a recycler, a stabilizer, an agricultural or forestry soil-working machine, with a base body that has a working area, with at least a working element consisting of a sintered carbide material according to one of Claims 1 to 17, preferably with a material connection, in particular a soldered connection, in particular a hard-soldered connection, is held.
  • the cemented carbide material preferably forms a cutting body with a cutting tip or a cutting edge or a cutting edge or a working edge in the working area. It is also conceivable that the sintered carbide material is an armored coating.
  • the working element is in the form of a cutting element, preferably with at least one cutting edge and/or at least one cutting tip, or in the form of a wear protection element, in particular a protective plate, a protective strip, a protective pin, a Protective projection or a protective bolt is formed.
  • the tool is a cutting tool, a milling tool, in particular a road milling or mining tool, a ploughshare, a cultivator point, a drilling tool, in particular an earth auger, a crushing tool, for example a crushing tool or a crushing bar, a mulching tool, a wood chipping tool or a shredding tool, a fractionating tool, e.g. a screen.
  • a further particularly preferred application of the invention is such that the milling chisel has a chisel head and a chisel shank directly or indirectly connected thereto, and that the working element is held on the chisel head.
  • the working element is formed from the sintered carbide material according to the invention, with this working element forming a carrier for a super-hard cutting tip, which consists of PCD material, for example.
  • the cemented carbide material may be a hard metal with a reinforced binder phase. This reinforcement can take place through the precipitation of intermetallic phase material during cooling in the sintering process and/or it is such that the intermetallic phase material is formed in a thermal process subsequent to the sintering process, in which the cemented carbide material is brought to a temperature that allows precipitation of the intermetallic phase material in the cemented carbide material.
  • a nominal composition of 70-95% by weight of WC, 1-28% by weight of metallic binder and 1-28% by weight of intermetallic phase can be selected when the raw materials are weighed.
  • the metallic binder can contain the elements Co and optionally Fe and/or other components.
  • the intermetallic phase is Ni 3 AI when weighed.
  • the object of the invention is also achieved with a method for creating a sintered carbide material, with a preliminary sintered carbide material, in particular a hard metal, being created in a first method step, which contains 70-95% by weight, preferably 80-95 % by weight, tungsten carbide in dispersed form, and a binder phase, the binder phase comprising metallic binder material, the metallic binder material comprising Co, the binder phase contains the dissolved elements Ni and Al, with the binder phase having the following chemical element composition:
  • the thermal treatment can include at least one heating step or at least one cooling step.
  • M,Y intermetallic phase material
  • AI,X intermetallic phase material
  • the intermetallic phase material has a maximum size of 1500 nm, preferably a maximum size of 1000 nm (measured according to the line intersection method at a micrograph).
  • the coercive field strength HcM of at least one region, preferably a region in which intermetallic phase material is present, of the sintered carbide material produced using the method according to the invention is:
  • the coercive field strength is usually used to indirectly determine the average grain size of the WC for a given binder content.
  • the intermetallic phase material brings about a significant increase in the coercive field strength.
  • the coercive field strength can thus be evaluated indirectly as a measure of the strengthening of the binder phase as a result of the embedded intermetallic phase material.
  • the higher the coercivity the larger the total interface between metallic binder material, intermetallic phase material and WC.
  • a high number of precipitated intermetallic phase material leads to a good support of the individual crystals of the intermetallic phase material against each other in the binder phase, especially at high temperatures (especially at high tool application temperatures).
  • Coercive field strengths of at least one area of the sintered carbide material HCM [kA/m]>(1.5+0.04*B)+(12.5-0.5*B)/D+4 [kA/m] can primarily be used are, for the wear protection applications mentioned above, for example for wear armor.
  • Coercive field strengths of at least one area of the sintered carbide material preferably HCM [kA/m] > (1.5 + 0.04*B) + (12.5-0.5*B)/D + 6 [kA/m] can primarily be used for the above mentioned demanding
  • Coercive field strengths of at least one area of the sintered carbide material preferably HCM [kA/m] > (1.5 + 0.04*B) + (12.5-0.5*B)/D + 10 [kA/m] can primarily be used for the high-performance tools mentioned above.
  • the coercive field strength of at least one area of the sintered carbide material is 20% higher than the coercive field strength of a hard metal body that has the same composition and WC grain size as the sintered carbide material, with the binder phase alone is formed of metallic Co binder; however, this has no intermetallic phase material.
  • a cemented carbide body having the same composition is therefore a cemented carbide body with 70-95% by weight of tungsten carbide in dispersed form and a binder phase, the binder phase having metallic binder material without intermetallic phase material, the proportion of metallic binder material in the sintered carbide material is 5-30% by weight and the binder material otherwise has the same or approximately the same composition as the binder material of the sintered carbide material according to the invention.
  • the coercivity indirectly gives an indication of the proportion of intermetallic phase material in the binder phase.
  • the degree of reinforcement of the binder phase is indirectly indicated with the coercive field strength.
  • the sintered carbide material can be designed in such a way that the hot compressive strength of the sintered carbide material produced using the method according to the invention is >1650 [MPa] at a temperature of 800° C. and a strain rate of 0.001 [1/s] and/ or that the hot compressive strength of the cemented carbide material at a temperature of 800 °C and a strain rate of 0.01 [1/s] > 1600 [MPa] (measurement for a cylindrical specimen with a diameter of 8 mm and a height of 12 mm).
  • Such a sintered carbide material can be used, in particular, to manufacture cutting tips for road milling tools in which the proportion of metallic binder material in the binder phase is 5-7% by weight and the proportion of WC is in the range of 93-95% by weight, with preference being given to here WC is present in coarse grain form with an average particle size in the range between 2-5 pm.
  • a cemented carbide material with intermetallic phase material in the binder phase can be manufactured via a powder metallurgical process routine.
  • the latter is divided into the process steps of producing a compressible powder mixture, shaping and finally sintering to form compact and dense sintered carbide bodies.
  • WC powders of different grain sizes can be used as starting materials for the production of the powder mixture, in particular coarse-grain WC with a particle size FSSS > 25 pm.
  • Starting powders for the binder phase are extra-fine cobalt powder (FSSS 1.3 pm) and nickel-aluminum powder, for example Ni-13Al powder with an aluminum content of approx. 13.3% by weight.
  • the particle size of the Ni-Al powder is FSSS ⁇ 70 pm, preferably less than FSSS 45 pm.
  • W metal powder (FSSS ⁇ 2pm) and lamp black are used to set and adjust a specific carbon content.
  • alloying elements such as Ti, Ta, Mo, Nb, V, Cr, their carbide powder or their W-containing mixed carbides with particle sizes ⁇ 3 pm are used.
  • the powder mixture is produced according to the state of the art by wet grinding, preferably in a ball mill fitted with hard metal balls. Ethanol and hexane are used as grinding media. Other possible grinding media would be acetone or aqueous media with suitable inhibitors.
  • the Ni-Al powder is intensively mixed with milling liquid and coarse-grain tungsten carbide with an average particle size FSSS>20 gm, preferably between 30 and 60 gm. If necessary, pressing aids, small amounts of alloying components and cobalt powder can also be added here.
  • the grinding parameters (duration, ratio of grinding balls to material to be ground, grinding medium) and the ratio of WC to Ni-Al powder are based on the WC grain size to be set in the sintered carbide material.
  • pre-grinding VM If the alloy adjustment and the addition of the pressing aid have not already been carried out in the first grinding step (pre-grinding VM), this can also be done in the second step.
  • the slip obtained during wet grinding is dried according to the state of the art and converted into a powder ready for pressing. This is preferably done by the process of spray drying.
  • Shaping is preferably done directly, by axial pressing on mechanical, hydraulic or electromechanical presses.
  • Sintering takes place between 1350 and 1550 °C in a vacuum, preferably in industrial sinter-HIP furnaces, in which, following liquid-phase sintering, an overpressure is created by means of an inert gas inlet, with any residual porosity being able to be eliminated.
  • FIGS. 2 and 3 Two different sintered carbide materials according to the invention, in the form of flart metals, are illustrated in FIGS. 2 and 3 on the basis of such scanning electron microscope images.
  • the binder phase of such a flart metal can be clearly seen, in which the intermetallic phase material (lighter phase) 10 and the metallic binder material 30 (dark) can be seen.
  • the WC grains 20 are connected to one another via the binder phase.
  • the crystals of the intermetallic phase material (M,Y) 3 (AI,X) have a crystal structure L1 2 (space group 221) according to ICSD (Inorganic Crystal Structure Database).
  • Such cemented carbide material can be bonded to a steel body to form a working element of a tool, e.g. a crusher, tillage tool, preferably for a road milling machine, a recycler, a stabilizer, an agricultural or forestry tillage machine.
  • a working element e.g. a crusher, tillage tool, preferably for a road milling machine, a recycler, a stabilizer, an agricultural or forestry tillage machine.
  • this working element is then arranged in the working area of the tool.
  • the connection to the base body is made with a soldered connection, in particular a hard-soldered connection. Heat is introduced into the tool to create the soldered connection.
  • the tool is then quenched, e.g. in a water-oil emulsion.
  • the intermetallic phase material is at least partially dissolved again, so that components of the intermetallic phase material are present as dissolved components in the sintered carbide material after quench hardening.
  • a precursor cemented carbide material is formed in this way.
  • This precursor sintered carbide material is then subjected to a thermal treatment, as has already been described several times above. It can be the case that heat is introduced into the sintered carbide material via the thermal treatment, the temperature should be below the solvus temperature and preferably above 400 degrees Celsius.
  • the treatment duration ie the time within which the thermal treatment takes place, is in the range between 0.25 and 24 hours.
  • intermetallic phase material forms again, at least in some areas in the sintered carbide material, in order to strengthen the binder phase.
  • the thermal treatment can be an active process in which heat is introduced into the sintered carbide material in a targeted manner by means of a heat source. It is preferably the case that the heat treatment takes place passively, with the precursor cemented carbide material coming into contact with the workpiece to be machined, for example a road surface of a road, for example during use of the tool. This contact introduces heat into the precursor cemented carbide material to bring it to a temperature at which the intermetallic phase material forms. In this way, the tool is automatically strengthened according to the invention, with the sintered carbide material according to the invention being formed in the area subject to wear.
  • a sintered carbide material designed in the manner described above is manufactured in a sintering process in which intermetallic phases are formed.
  • This product can then be brought to a temperature, preferably above the solvus temperature, at which the intermetallic phase material at least partially dissolves again. Thereafter, this material is quenched to form the precursor cemented carbide material. Then, the precursor cemented carbide material becomes one Subjected to heat treatment to form the cemented carbide material of the present invention.
  • the (M,Y) 3 (AI,X) content in the binder phase is >40% and the carbon balance is adjusted to be stoichiometric or substoichiometric.
  • the amount of alloy that can be used depends on the respective solubility product of the metal carbides. Even if these seem negligible in terms of their magnitude, there are surprisingly clear effects that cannot be attributed to a grain-refining effect.
  • the proportion of intermetallic phase material in the binder can be reduced and even be below 40%. Furthermore, in the presence of Ti or Ta, for example, the carbon balance no longer has to be substoichiometric, because these elements take over the role of tungsten as a stabilizer.
  • Physical parameters are determined on the sintered carbide material samples according to the invention, which help to characterize the material and its properties.
  • Both measured variables are also determined for the characterization of the sintered carbide material according to the invention on a Koerzimat® 1.097 from Förster.
  • Another parameter for characterizing the material is the density, which is determined by weighing according to the Archimedean principle.
  • the hardness of the material is determined according to the standard applicable to hard metals on metallographically prepared polished samples.
  • the Vickers HV10 hardness test with a test load of 10 kp is preferably used (ISO 3878).
  • the porosity of the sintered material (standard DIN-ISO 4499-4) and aluminum oxide particles are also determined and assessed using a light microscope on polished samples.
  • comparison images for A and B porosity can be used, with A08 and B08 approximately corresponding to a volume percentage of 0.6% by volume.
  • this is etched with Murakami solution in accordance with the standard (DIN-ISO 4499-4).
  • the average WC grain size is determined according to DIN ISO 4499-2.
  • REM scanning electron microscope
  • the proportions of the intermetallic phase in the binder and the maximum size of the separated particles are also determined using SEM images, but using an in-lense BSE detector. For this purpose, recordings are made at several points on the sample and the evaluation is carried out at a representative one Section by means of image processing and determination of the areas by tonal value delimitation.
  • Example 2 Example 3
  • Example 4 6-50 Ti 8.5-40 15-50 6-50 C-S 6-50
  • Example 5 Example 6
  • Example 8 Example 9
  • FIG. 5 shows a vertical section through a chisel tip
  • FIG. 6 shows the chisel tip according to FIG. 5 along the line of cut marked VI-VI in FIG. 5 and
  • FIGS. 7 to 12 show the chisel tip 50 according to FIGS. 5 to 6 in vertical section, but with a different structural composition.
  • Chisel tips 50 in the form of a cemented carbide material 40 are shown in FIGS. These chisel tips 50 are advantageously used on a cutting tool, in particular a cutting chisel, a pick, a road milling chisel, a mining chisel or the like.
  • the chisel tip 50 is designed and prepared to be connected, preferably soldered, to a steel body.
  • the steel body usually has a head to which a shank, preferably a round shank, is integrally formed. Away from the shank, the head has a receptacle for the chisel tip 50 .
  • the chisel tip 50 can be fastened in or on this receptacle.
  • the chisel tip 50 is made in one piece and has a base part 51 .
  • the chisel point 50 can be connected to the steel body with the base part 51 .
  • the base part 51 preferably has a connecting surface 51.1.
  • the soldering material of a hard-soldered connection can be arranged between the connecting surface 51.1 and the steel body.
  • the indentation can preferably be such that it transitions via a convex rounding from the connecting surface 51.1 into a recessed section which is advantageously designed as a concave trough.
  • the material requirement for the chisel tip 50 can be reduced with the indentation 52 .
  • the depression 52 forms a reservoir for excess solder material in the area of the connecting surface 51.1.
  • the base part 51 has a preferably circumferential edge 51.3, which can be designed as a convex shape at least in some areas.
  • the edge 51.3 can be designed as a transition between the base part 51 and a transition section 53.
  • the transition section 53 has a first area which is designed as a concave area 53.1.
  • a truncated cone-shaped geometry or a combination consisting of a concave area 53.1 and a truncated cone-shaped geometry, at least in some areas, can also be provided.
  • the chisel point 50 is tapered in the direction of the base part 51 towards a tip 54 of the chisel point 50 in the area.
  • the transition section 53 can furthermore also have a cylindrical area 53.2, which adjoins the first area opposite the base part 51.
  • the transition at least in areas of the chisel tip 50, between the first area and the cylindrical area is continuous, preferably continuously differentiable in the direction of the central longitudinal axis of the chisel tip, so that discontinuities are avoided, as shown in Figure 5 .
  • the chisel tip 50 can preferably have indentations 53.3 in the region of the transition section 53. These are used to reduce material and to optimize the removal of soil material that is removed during tool use.
  • the chisel tip 50 has a tip 54 which adjoins the transition section 53, preferably the cylindrical area 53.2.
  • the connecting section 54.1 can be designed as a convex curvature.
  • the connecting section 54.1 is followed by a tapering section 54.2, which merges into an end section 54.3.
  • the end section 54.3 is preferably in the form of a convex curvature, particularly preferably in the form of a spherical cap.
  • FIG. 6 shows the chisel tip 50 in section and in a plan view.
  • the indentations 53.3 are arranged evenly distributed over the circumference of the chisel tip 50 and can be clearly seen.
  • the chisel tip 50 has at least one 1st volume area 70 and at least one 2nd volume area 60 .
  • the sintered carbide material 40 has tungsten carbide grains (WC grains) 20, which are connected to one another via metallic binder material 30 of a binder phase. It can be provided that in the 2nd Volume region 60 no intermetallic phase material 10 or intermetallic phase material 10 preferably in a concentration of less than 30% by weight / volume unit, preferably less than 25% by weight / volume unit, particularly preferably less than 15% by weight / volume unit.
  • the sintered carbide material 40 has tungsten carbide grains (WC grains) 20 which are connected to one another via metallic binder material 30 of a binder phase.
  • Intermetallic phase material 10 is located in the 1st volume region 70, preferably in a concentration >30% by weight/volume unit, preferably in the range between 30-70% by weight/volume unit, particularly preferably in the range between 35-60% by weight/volume unit. more preferably in the range between 40-50% by weight/volume.
  • the binder phase has the following chemical element composition: Ni > 25% by weight, Al > 4% by weight, remainder Co and dissolved binder components, for example W and/or C.
  • the relative proportion Y of intermetallic phase material, based on a unit volume, in the first volume region 70 is greater than in the second volume region 60.
  • first volume region 70 and the second volume region 60 may be bounded by at least a portion of the surface of the cemented carbide material 40 .
  • the first volume region 70 which has the relatively higher proportion of intermetallic phase material 10, forms part of the surface of the chisel tip 50, in particular at the tip 54 at the tapering section 54.2 and/or at the end section 54.3.
  • the 1st volume region 70 extends up to the base part 51 .
  • the Area of the base part 51 are formed by the second volume area 60.
  • the 2nd volume region 60 with the relatively lower content of intermetallic phase material 10 or without intermetallic phase material 10 is preferably arranged in the area of the transition section 53 .
  • FIG. 6 illustrates, it can also be the case that both the 1st volume area 70 and the 2nd volume area 60 adjoin the surface of the chisel tip 50 in the area of the transition section 53 .
  • FIGS. 5 and 6 has the following technical advantages:
  • forms of wear can be set in a targeted manner with the volume areas 60, 70, which, for example, support resharpening of the chisel tip.
  • FIGS. 7 to 12 show further embodiment variants of a chisel tip 50.
  • the chisel tip 50 is constructed essentially identically to the chisel tip 50 according to Figures 5 and 6. In this respect, to avoid repetition, reference is made to the above explanations and only the differences are discussed.
  • the chisel tips 50 according to FIGS. 7 to 12 differ in particular in the arrangement and design of the 1st and 2nd volume areas 70, 60.
  • the first volume area 70 is arranged in the area of the tip 54 and preferably partially in the cylindrical area 53.2 of the transition section 53. However, it is also conceivable that the 1st volume area 70 is only arranged in the area of the tip 54 . The first volume area 70 effectively protects against abrasive wear in the area of the tip 54 .
  • FIG. 8 illustrates that the 1st volume region 70 can be arranged completely or partially within the chisel tip 50 .
  • the first volume area 70 can be designed in such a way that it preferably extends in the direction of the central longitudinal axis of the chisel tip 50 over the entire area of the transition section 53 .
  • the first volume region 70 is distinguished by a particularly high shearing strength as a result of the presence of intermetallic phase material 10 .
  • the transition area 53 that is in danger of breaking is effectively reinforced with the first volume area 70 .
  • the second volume area 60 can be arranged completely or partially within the chisel tip 50 .
  • the 1st volume area 70 then preferably completely surrounds the 2nd volume area 60 .
  • the first volume area completely or almost completely forms the surface of the chisel tip 50 in order to protect it particularly effectively from abrasion and to prevent the chisel tip 50 from breaking in the area of the transition section 53 .
  • FIG. 10 illustrates that, in a further development of the variant according to FIG preferably completely forms the surface of the tip 54 and the transition section.
  • the 1st volume region 70 is brought up to the base part 51 or also led into the base part 51, as FIG. 10 illustrates.
  • Figure 11 shows that the first volume area 70 can also extend within the chisel tip 50 in such a way that it forms a continuous volume area, from the end section 543 of the tip 54 to the base part 51.
  • FIG. 12 illustrates that, conversely to the exemplary embodiment according to FIGS. 5 and 6, provision can also be made for the 1st and the 2nd volume region 70, 60 to be swapped with one another.
  • a method is used according to the invention, in which first a precursor cemented carbide material, in particular a flart metal, is created in a first method step, the 70-95 wt. %, preferably with 80-95% by weight, tungsten carbide in dispersed form, and a binder phase.
  • the binder phase has at least Co as the metallic binder material and the dissolved elements Ni and Al.
  • the binder phase has the following chemical element composition:
  • the precursor cemented carbide material is subjected to a heat treatment as explained above in order to form the cemented carbide material 40 which has at least in the 1st volume region 70 intermetallic phase material 10 in the binder phase.
  • the precursor cemented carbide material can be kept in a temperature range between 400° C. and the solvus temperature for a period in the range between 0.25 to hours during the heat treatment.
  • the individual Volume areas 60, 70 can, for example, be heated in a targeted manner by means of a laser or an induction coil.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Powder Metallurgy (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Drilling Tools (AREA)
  • Ceramic Products (AREA)

Abstract

L'invention concerne un matériau de carbure cémenté, en particulier un métal dur, comprenant de 70 à 95 % en poids, de préférence de 80 à 95 % en poids, de carbure de tungstène sous forme dispersée, ainsi qu'une phase liante, la phase liante comprenant un matériau liant métallique, le matériau de liant métallique comprenant du Co, la phase liante comprenant un matériau de phase intermétallique et/ou les éléments dissous Ni et Al, ledit matériau de phase intermétallique, si présent, étant formé selon la formule structurale (M,Y)3 (Al, X), dans laquelle M = Ni, Y = Co et/ou un autre constituant, et X = tungstène et/ou un autre constituant, ladite phase liante ayant la composition en éléments chimiques suivante : Ni > 25 % en poids, Al > 4 % en poids, le reste étant du Co et des constituants de liant dissous, par exemple du W et/ou du C. Un tel matériau de carbure cémenté est caractérisé par une résistance élevée à l'usure ainsi que par une résistance élevée à la rupture.
EP22725382.0A 2021-05-03 2022-04-21 Procédé de production d'un matériau de carbure cémenté ayant une phase liante renforcée Pending EP4334053A1 (fr)

Applications Claiming Priority (3)

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DE102021111370 2021-05-03
DE102021120273.6A DE102021120273A1 (de) 2021-05-03 2021-08-04 Verfahren zur Herstellung eines Sinterkarbid-Materials mit verstärkter Binderphase
PCT/EP2022/060610 WO2022233589A1 (fr) 2021-05-03 2022-04-21 Procédé de production d'un matériau de carbure cémenté ayant une phase liante renforcée

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EP (1) EP4334053A1 (fr)
JP (1) JP2024518385A (fr)
AU (1) AU2022270294A1 (fr)
CA (1) CA3217196A1 (fr)
TW (1) TW202309307A (fr)
WO (1) WO2022233589A1 (fr)

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DE3264742D1 (en) * 1981-04-06 1985-08-22 Mitsubishi Metal Corp Tungsten carbide-base hard alloy for hot-working apparatus members
GB201105150D0 (en) 2011-03-28 2011-05-11 Element Six Holding Gmbh Cemented carbide material and tools comprising same
CN106756393A (zh) * 2016-12-30 2017-05-31 永平县建达鑫鑫合金铸造有限公司 一种高强度超耐磨钢
CN108118230B (zh) * 2017-12-22 2020-04-10 株洲硬质合金集团有限公司 一种硬质合金及其制备方法
CN110106424A (zh) * 2019-06-13 2019-08-09 河源市全诚硬质合金有限公司 一种硬质合金棒材及其制造方法

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WO2022233589A1 (fr) 2022-11-10
TW202309307A (zh) 2023-03-01

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