EP4256100A1 - Improved plasma resistant coatings for electrostatic chucks - Google Patents
Improved plasma resistant coatings for electrostatic chucksInfo
- Publication number
- EP4256100A1 EP4256100A1 EP21824529.8A EP21824529A EP4256100A1 EP 4256100 A1 EP4256100 A1 EP 4256100A1 EP 21824529 A EP21824529 A EP 21824529A EP 4256100 A1 EP4256100 A1 EP 4256100A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- coating
- layer
- ceramic
- metallic
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 188
- 239000011248 coating agent Substances 0.000 claims abstract description 171
- 229910052751 metal Inorganic materials 0.000 claims abstract description 41
- 239000002184 metal Substances 0.000 claims abstract description 41
- 239000000758 substrate Substances 0.000 claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 claims abstract description 25
- 238000005524 ceramic coating Methods 0.000 claims abstract description 17
- 239000004065 semiconductor Substances 0.000 claims abstract description 15
- 238000001020 plasma etching Methods 0.000 claims abstract description 13
- 229910001092 metal group alloy Inorganic materials 0.000 claims abstract description 11
- 239000010409 thin film Substances 0.000 claims abstract description 11
- 239000011247 coating layer Substances 0.000 claims abstract description 10
- 238000009501 film coating Methods 0.000 claims abstract description 6
- 239000010410 layer Substances 0.000 claims description 95
- 239000000919 ceramic Substances 0.000 claims description 64
- 238000000034 method Methods 0.000 claims description 46
- 229910052782 aluminium Inorganic materials 0.000 claims description 21
- 239000011148 porous material Substances 0.000 claims description 21
- 150000004767 nitrides Chemical class 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 8
- 229910000765 intermetallic Inorganic materials 0.000 claims description 6
- 230000000873 masking effect Effects 0.000 claims description 6
- 150000001247 metal acetylides Chemical class 0.000 claims description 6
- -1 oxynitrides Chemical class 0.000 claims description 6
- 229910052684 Cerium Inorganic materials 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 5
- 229910052746 lanthanum Inorganic materials 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 5
- 229910052727 yttrium Inorganic materials 0.000 claims description 5
- 150000002222 fluorine compounds Chemical class 0.000 claims description 4
- 229910052735 hafnium Inorganic materials 0.000 claims description 4
- 238000010849 ion bombardment Methods 0.000 claims description 4
- 150000004760 silicates Chemical class 0.000 claims description 4
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- 230000007423 decrease Effects 0.000 claims description 3
- 238000005498 polishing Methods 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 238000001771 vacuum deposition Methods 0.000 claims description 3
- 230000003213 activating effect Effects 0.000 claims description 2
- 230000003247 decreasing effect Effects 0.000 claims description 2
- 238000001755 magnetron sputter deposition Methods 0.000 claims description 2
- 239000007800 oxidant agent Substances 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 22
- 239000010408 film Substances 0.000 description 22
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 16
- 239000000463 material Substances 0.000 description 12
- 239000000126 substance Substances 0.000 description 11
- 239000000243 solution Substances 0.000 description 10
- 230000007704 transition Effects 0.000 description 10
- 238000000151 deposition Methods 0.000 description 9
- 239000011229 interlayer Substances 0.000 description 9
- 230000008021 deposition Effects 0.000 description 8
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 7
- 239000002346 layers by function Substances 0.000 description 6
- 238000005530 etching Methods 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- JNDMLEXHDPKVFC-UHFFFAOYSA-N aluminum;oxygen(2-);yttrium(3+) Chemical compound [O-2].[O-2].[O-2].[Al+3].[Y+3] JNDMLEXHDPKVFC-UHFFFAOYSA-N 0.000 description 3
- 230000033228 biological regulation Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000005240 physical vapour deposition Methods 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910019901 yttrium aluminum garnet Inorganic materials 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 238000005422 blasting Methods 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 238000009419 refurbishment Methods 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 229910052691 Erbium Inorganic materials 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000002679 ablation Methods 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000007743 anodising Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 229910002106 crystalline ceramic Inorganic materials 0.000 description 1
- 239000011222 crystalline ceramic Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000005546 reactive sputtering Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000005477 sputtering target Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000000427 thin-film deposition Methods 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/02—Pretreatment of the material to be coated
- C23C14/024—Deposition of sublayers, e.g. to promote adhesion of the coating
- C23C14/025—Metallic sublayers
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/4401—Means for minimising impurities, e.g. dust, moisture or residual gas, in the reaction chamber
- C23C16/4404—Coatings or surface treatment on the inside of the reaction chamber or on parts thereof
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/02—Pretreatment of the material to be coated
- C23C14/021—Cleaning or etching treatments
- C23C14/022—Cleaning or etching treatments by means of bombardment with energetic particles or radiation
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/50—Substrate holders
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/02—Pretreatment of the material to be coated
- C23C16/0272—Deposition of sub-layers, e.g. to promote the adhesion of the main coating
- C23C16/0281—Deposition of sub-layers, e.g. to promote the adhesion of the main coating of metallic sub-layers
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/4401—Means for minimising impurities, e.g. dust, moisture or residual gas, in the reaction chamber
- C23C16/4405—Cleaning of reactor or parts inside the reactor by using reactive gases
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32431—Constructional details of the reactor
- H01J37/32697—Electrostatic control
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32431—Constructional details of the reactor
- H01J37/32715—Workpiece holder
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/6831—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using electrostatic chucks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/687—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches
- H01L21/68714—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support
- H01L21/68757—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support characterised by a coating or a hardness or a material
Definitions
- the present invention relates to a method for producing a device to be used within a plasma etching chamber for the manufacturing of semiconductor components as well as to a device to be used within a plasma etching chamber for the manufacturing of semiconductor components, preferably produced by such a method.
- An electrostatic chuck (E-chuck) is often coated with a layer system comprising ceramic phase coatings (oxides, nitrides, borides, carbides, oxynitrides, ... ) which are commonly used for semiconductor device manufacturing.
- Ceramic phase coatings oxides, nitrides, borides, carbides, oxynitrides, ...
- Such E-chucks are used in semiconductor etch chambers and they need to be coated with coatings resistant to etching by ion bombardment and halogen gas in order to protect the E-chuck exposed to the etching plasma.
- the current state-of-the-art for constructing plasma resistant E-chucks is a method to fabricate a minimum contact area (MCA) mesa structure that for example a silicon wafer rests upon during processing. Fabrication of this mesa MCA structure utilizes a positive hard mask (it translates its pattern into ‘high’ points of the MCA structure) and a subtractive ablation process (often a blasting operation) in order to remove an adequate amount of material to leave the mesas in the desired height. This process has certain drawbacks with respect to particulate contamination, resulting in semiconductor die yield loss. Other drawbacks include the limited ability to refurbish and restore the E-chucks after some production usage.
- MCA minimum contact area
- the state-of-the-art refurbishment includes a grinding/polishing step that removes a certain amount of the base ceramic material and the re-creation of the MCA pattern that has been mentioned before. Due to the importance of the dielectric properties of the base ceramic, the change of the thickness can have a deleterious effect on the electrostatic performance of the E-chuck, limiting the number of times it can be refurbished due to performance degradation. However according to a new methodology MCA pattern is created with a reverse mask in an additive process via thin film deposition which obviates the aforementioned issues.
- Such thin film deposited coatings typically consist of oxides, oxynitrides and oxyfluorides, which are applied by various methods including PVD and spray technologies. Even though these coatings have a low etching rate, they get thinner with usage or in some cases mechanical wear and have to be replaced at some point. Replacement of the coating may also be required if damage occurs during handling (ex. by scratches). This is motivated by the costs of the typical components and in some cases by the need to maintain dielectric properties if the coating gets too thin (i.e. for the function of electrostatic chucks, E-chucks). There is therefore the need for etch-resistant coatings which are easy to refurbish.
- the US10497598B2 discloses an electrostatic chuck comprising a ceramic structural element, at least one electrode disposed on the ceramic structural element and a surface dielectric layer disposed over the at least one electrode.
- the surface dielectric layer comprises an insulating layer of amorphous alumina of a thickness of less than 5 microns disposed directly over the at least one electrode, and a stack of dielectric layers disposed over the insulator comprising at least one dielectric layer including aluminum oxynitride and at least one dielectric layer including at least one silicon oxide and silicon oxynitride.
- the LIS9761417B2 discloses a bilayer coating made of plasma-resistant layer of AION overlying directly onto the substrate to protect and having a thickness from about 1 micron to about 10 microns thick, and an outermost plasma-resistant layer of yttria coating that is also from about 1 micron to about 10 microns thick immediately overlying the AION layer.
- the plasma-resistant layer for protection is directly deposited onto the substrate being a component in a semiconductor manufacturing system and can be quartz, alumina, aluminum, steels, metals, or alloys. Both AION and yttria layer are deposited on the substrate to protect it from plasma exposure during semiconductor manufacturing by pulsed reactive physical vapor deposition.
- the US10020218B2 discloses an electrostatic chuck comprising a ceramic body made of AIN or AI2O3 comprising an embedded electrode; a first ceramic coating deposited directly onto a surface of the ceramic body, a second ceramic coating on the first ceramic coating which comprises a material from the group consisting of AI2O3, AIN, Y2O3, Y2AI5O12 (YAG) and AION and having a thickness of about 5-30 pm; and a plurality of elliptical mesas on the second ceramic coating having a diameter of about 0.5-2.0 mm and a thickness of about 2-20 microns.
- the US8206829B2 discloses a plasma resistant coating and methods of forming such coatings on a plasma chamber component such as electrostatic chuck, wherein the plasma resistant coating comprises a crystalline ceramic non-native to the substrate and formed in a manner to include at least one of an oxide, nitride, boride, carbide, or halide of Yttrium, iridium (Ir), rhodium (Rh), or lanthanoid, such as Erbium (Er) and a porosity below 1 %.
- a plasma resistant coating comprises a crystalline ceramic non-native to the substrate and formed in a manner to include at least one of an oxide, nitride, boride, carbide, or halide of Yttrium, iridium (Ir), rhodium (Rh), or lanthanoid, such as Erbium (Er) and a porosity below 1 %.
- the plasma resistant coating is deposited over at least a portion of the substrate via an intermediate layer disposed between the substrate and the plasma resistant coating, wherein the intermediate layer comprises an oxide, nitride, or carbide of an element other than that of the primary constituent in the plasma resistant coating.
- the US9633884B2 discloses a plasma-resistant coating covering an electrostatic chuck assembly for a plasma processing chamber consisting of a mixture of Y2O3/AI2O3 or YF3/AI2O3 deposited by plasma-enhanced physical vapor deposition.
- the authors also disclose an undercoat layer provided in between the E-chuck to protect and the plasma-resistant coating which comprises at least one of Y2O3 and AI2O3 and formed using standard plasma spray.
- the US7732056B2 discloses a method of providing a plasma-resistant coating on a surface of an aluminum component which comprises anodizing the surface of the aluminum component to form an anodized aluminum oxide layer and a sputtered layer comprising aluminum oxide deposited directly onto the anodized aluminum oxide layer.
- the US20190067069A1 discloses an electrostatic chuck comprising an electrode in a ceramic base, and a surface layer wherein the surface layer comprises a plurality of protrusions, the protrusions comprising a composition whose morphology is columnar or granular.
- Materials forming the protrusions can be made entirely of physical deposited aluminum oxynitride (AION) or may be a coating of aluminum oxynitride overtop of an underlying ceramic like alumina.
- Other examples of materials that can be used for protrusions can include yttria (Y2O3), yttrium aluminum garnet (YAG), alumina (AI2O3), or aluminum oxynitride.
- US7077918 describes a method for stripping a coating off a ceramic or metallic work piece.
- a first chromous and aluminiferous coat is applied directly on the work piece.
- On this coat deposited is a functional layer made of nitride of AlCr known for its large pored structure. Stripping is then performed with a permanganate solution. The solution does not attack the nitride of AlCr but through its large pores the AlCr layer is attacked as expected.
- a permanganate solution does not attack the nitride of AlCr but through its large pores the AlCr layer is attacked as expected.
- ceramic layers with finer pores and better protection compared to plasma etching processes it is not expected to destroy a metallic layer located under the ceramic layer.
- a special coating architecture using a dedicated base or intermediate layer is proposed in order to solve the problem of the invention.
- the nature of this interlayer is chosen to allow for an efficient de-coating with the wet chemical method.
- wet chemical methods may involve i.e. alkaline or oxidative solutions. The solution dissolves or oxidizes the interlayer, resulting in a “lift-off” or removal of the etch-resistant layer.
- the intention of the present invention is thereby to solve the problem of inadequate adhesion and easy de-coating when refurbishing of homogeneous ceramic films to base materials.
- the use of a metallic thin film layer or layer system is proposed before the homogeneous ceramic layer is deposited.
- the method may comprise a step of micro- and/or nanostructuring the device, wherein the structures being introduced by micro- and/or nanostructuring preferably may be made in form of grating structures, in particular introduced into the body of the device.
- vacuum coating methods may be used for applying the first coating and/or the second coating and/or the intermediate coating, wherein preferably CVD- or PVD-techniques, in particular magnetron sputtering techniques may be used.
- a pure metal layer and/or a pure metal alloy may be applied to the surface of the body, wherein the metal layer and/or the metal alloy may comprise at least one of the following metals: Al, V, Ti, Hf, Y, Er, Sc, Ce, La.
- a pure ceramic layer may be applied to the surface of the body, wherein the ceramic layer preferably may comprise at least one of the following: oxides, nitrides, oxynitrides, silicates, fluorides, carbides, oxyfluorides, wherein the reactive gases to form the ceramics in particular may be fed slowly and ramped.
- the coatings including the pores of the device may be designed that plasma in a plasma etching process cannot enter the second coating, however the coatings may be designed, in particular that pores being large enough to allow a stripping agent to enter the coatings and allow to dissolve the first coating.
- the device may be inhomogeneously coated along its surface, wherein the layer thickness of the first and/or second coating and/or the intermediate coating may be thinner at some points than at other points at the surface.
- the coating (first and/or second coating and/or the intermediate coating) may be distributed inhomogeneously along its surface, wherein the coating (first and/or second coating and/or the intermediate coating) preferably being thicker on the upper side of the grid at the protrusions than the coating in the region of the bottom within the apertures.
- Fig. 2 Shows a cross section of an embodiment of the present invention and shows the layers made to create the film stack
- Fig. 3 Shows a scratch test on ALON monolayer coating directly coated onto the substrate.
- the substrate material is AI2O3, the coating thickness is ⁇ 21 pm.
- the test revealed the LC2 failure is detected at 34N load,
- reactive gasses such as O2, and/or N2, and/or Fluorine containing gasses
- reactive gasses such as O2, and/or N2, and/or Fluorine containing gasses
- Argon plasma etching of substrates was done for 7 min. duration using a DC filament discharge and pulsed DC substrate biasing.
- the operating cathode voltage of the sputtering target was then noted to be ⁇ 565V in the pure metallic mode.
- a closed loop control of reactive gasses O2 and N2 was then used to create the transition from pure Aluminum to Aluminum oxynitride using a control of reactive process by discharge voltage regulation device.
- the software control of this device allows the user to program a ramping function while utilizing a master/ slave control of the reactive gasses.
- the N2 channel is the master and the O2 is the slave.
- the ratio of 0 to N was set to a ratio of 3.5:6.5.
- the reactive gasses are then ramped at this set ratio slowly over a period of 20 min. so that the cathode voltage decreases steadily from 565V (pure metal film) to a final set point of 400V (fully oxy-nitrided film).
- the O/N ratio is still fixed and minor adjustments in gas flow is achieved by the regulation device to maintain the 400V operating setpoint on the sputtering cathode for the duration of the deposition.
- the resulting coating was comprised of a pure Aluminum layer of ⁇ .8 microns thickness, a transitional gradient layer of ⁇ .8 micron thickness and a functional top layer of ⁇ 21 microns.
- the adhesion strength was compared between the two coatings using a 200p radius conical diamond tip scratch tester. 3 mm length scratches were done in 2N load increments until Lc2 adhesive failure was achieved (Fig. 3,4). Compared to a monolayer ALON coating deposited under the same conditions with no adhesion layers the adhesion values were improved substantially with the use of this interlayer structure.
- Fig. 5 shows an example of a coated periodical rectangular grating structure introduced into the body 101 of the device.
- the structured body 101 comprises a periodical rectangular grating structure (with a grating period of 500 nm and a fillfactor of 0.5).
- the body is coated with a metallic coating 103. Because auf shadowing effects the coating thickness on top of the grating is thicker as compared to the metallic coating in the area of the grooves.
- the openings of the gratings are narrowed due to the coating. This has the effect that the ceramic overcoat 105 (shown in Fig. 5 as crossed area) is not reaching the bottom of the grooves.
- Chemical removal of the coating is also easier in comparison to homogenous type ceramic films covered in the prior art. This is primarily due to the ability of the stripping chemical to attack the metallic adhesion layer through the coating thus causing coating detachment.
- Fig. 6 shows the sample with the AION film directly coated on the substrate before stripping and Fig. 7 shows the sample after stripping. As can be seen in Fig. 7, the circular ceramic film is attacked, however not completely removed.
- Fig. 8 shows the sample with the AION film coated on the metallic interlayer and Fig. 9 shows the sample after stripping. As can be seen, the circular ceramic film is completely removed. Very interestingly, no damages (pitting, cracks) were observed at the surface of the freshly uncoated AI2O3 substrate after stripping.
Abstract
Method for producing a device to be used within a plasma etching chamber for the manufacturing of semiconductor components, comprising providing a body forming the substrate of the device, applying a first coating on the surface of the body, wherein the first coating comprises a metal and/or a metal alloy thin film coating layer in order to form a metal coated body, applying a second coating on the metal coated body, wherein the second coating comprises a ceramic coating layer, wherein the second coating at least partially overlaps with the first coating.
Description
Improved plasma resistant coatings for electrostatic chucks
The present invention relates to a method for producing a device to be used within a plasma etching chamber for the manufacturing of semiconductor components as well as to a device to be used within a plasma etching chamber for the manufacturing of semiconductor components, preferably produced by such a method.
Devices like electrostatic chucks are commonly used in semiconductor technology. An electrostatic chuck (E-chuck) is often coated with a layer system comprising ceramic phase coatings (oxides, nitrides, borides, carbides, oxynitrides, ... ) which are commonly used for semiconductor device manufacturing. Such E-chucks are used in semiconductor etch chambers and they need to be coated with coatings resistant to etching by ion bombardment and halogen gas in order to protect the E-chuck exposed to the etching plasma.
State of the art
The current state-of-the-art for constructing plasma resistant E-chucks is a method to fabricate a minimum contact area (MCA) mesa structure that for example a silicon wafer rests upon during processing. Fabrication of this mesa MCA structure utilizes a positive hard mask (it translates its pattern into ‘high’ points of the MCA structure) and a subtractive ablation process (often a blasting operation) in order to remove an adequate amount of material to leave the mesas in the desired height. This process has certain drawbacks with respect to particulate contamination, resulting in semiconductor die yield loss. Other drawbacks include the limited ability to refurbish and restore the E-chucks after some production usage. The state-of-the-art refurbishment includes a grinding/polishing step that removes a certain amount of the base ceramic material and the re-creation of the MCA pattern that has been mentioned before. Due to the importance of the dielectric properties of the base ceramic, the change of the thickness can have a deleterious effect on the electrostatic performance of the E-chuck, limiting the number of times it can be refurbished due to performance degradation.
However according to a new methodology MCA pattern is created with a reverse mask in an additive process via thin film deposition which obviates the aforementioned issues.
Such thin film deposited coatings typically consist of oxides, oxynitrides and oxyfluorides, which are applied by various methods including PVD and spray technologies. Even though these coatings have a low etching rate, they get thinner with usage or in some cases mechanical wear and have to be replaced at some point. Replacement of the coating may also be required if damage occurs during handling (ex. by scratches). This is motivated by the costs of the typical components and in some cases by the need to maintain dielectric properties if the coating gets too thin (i.e. for the function of electrostatic chucks, E-chucks). There is therefore the need for etch-resistant coatings which are easy to refurbish.
Mechanical removal of the coating by methods like grit blasting or lapping are not practical in some cases or have the drawback of damaging the components each time they are applied. This is especially the case for patterned surfaces like the mesa structures on E-chucks as mentioned above. Therefore, selectively removing the coating in a conformal manner by a chemical or electro-chemical method would be greatly advantageous. However, these methods are unfortunately not very efficient for etch-resistant coatings, which are by design inert towards most chemicals. This challenge is even greater if the etch-resistant coating is applied onto a substrate of a similar chemical nature (i.e.. AI2O3/AION coating on the AI2O3/AION surface of an E-chuck).
The US10497598B2 discloses an electrostatic chuck comprising a ceramic structural element, at least one electrode disposed on the ceramic structural element and a surface dielectric layer disposed over the at least one electrode. The surface dielectric layer comprises an insulating layer of amorphous alumina of a thickness of less than 5 microns disposed directly over the at least one electrode, and a stack of dielectric layers disposed over the insulator comprising at least one dielectric layer including aluminum oxynitride and at least one dielectric layer including at least one silicon oxide and silicon oxynitride.
The LIS9761417B2 discloses a bilayer coating made of plasma-resistant layer of AION overlying directly onto the substrate to protect and having a thickness from about 1 micron to about 10 microns thick, and an outermost plasma-resistant layer of yttria coating that is also from about 1 micron to about 10 microns thick immediately overlying the AION layer. The plasma-resistant layer for protection is directly deposited onto the substrate being a component in a semiconductor manufacturing system and can be quartz, alumina, aluminum, steels, metals, or alloys. Both AION and yttria layer are deposited on the substrate to protect it from plasma exposure during semiconductor manufacturing by pulsed reactive physical vapor deposition.
The US10020218B2 discloses an electrostatic chuck comprising a ceramic body made of AIN or AI2O3 comprising an embedded electrode; a first ceramic coating deposited directly onto a surface of the ceramic body, a second ceramic coating on the first ceramic coating which comprises a material from the group consisting of AI2O3, AIN, Y2O3, Y2AI5O12 (YAG) and AION and having a thickness of about 5-30 pm; and a plurality of elliptical mesas on the second ceramic coating having a diameter of about 0.5-2.0 mm and a thickness of about 2-20 microns.
The US8206829B2 discloses a plasma resistant coating and methods of forming such coatings on a plasma chamber component such as electrostatic chuck, wherein the plasma resistant coating comprises a crystalline ceramic non-native to the substrate and formed in a manner to include at least one of an oxide, nitride, boride, carbide, or halide of Yttrium, iridium (Ir), rhodium (Rh), or lanthanoid, such as Erbium (Er) and a porosity below 1 %. The plasma resistant coating is deposited over at least a portion of the substrate via an intermediate layer disposed between the substrate and the plasma resistant coating, wherein the intermediate layer comprises an oxide, nitride, or carbide of an element other than that of the primary constituent in the plasma resistant coating.
The US9633884B2 discloses a plasma-resistant coating covering an electrostatic chuck assembly for a plasma processing chamber consisting of a mixture of Y2O3/AI2O3 or YF3/AI2O3 deposited by plasma-enhanced physical vapor deposition.
The authors also disclose an undercoat layer provided in between the E-chuck to protect and the plasma-resistant coating which comprises at least one of Y2O3 and AI2O3 and formed using standard plasma spray.
The US7732056B2 discloses a method of providing a plasma-resistant coating on a surface of an aluminum component which comprises anodizing the surface of the aluminum component to form an anodized aluminum oxide layer and a sputtered layer comprising aluminum oxide deposited directly onto the anodized aluminum oxide layer.
The US20190067069A1 discloses an electrostatic chuck comprising an electrode in a ceramic base, and a surface layer wherein the surface layer comprises a plurality of protrusions, the protrusions comprising a composition whose morphology is columnar or granular. Materials forming the protrusions can be made entirely of physical deposited aluminum oxynitride (AION) or may be a coating of aluminum oxynitride overtop of an underlying ceramic like alumina. Other examples of materials that can be used for protrusions can include yttria (Y2O3), yttrium aluminum garnet (YAG), alumina (AI2O3), or aluminum oxynitride.
All the above-mentioned patents disclose a solution based on the direct deposition of a functional ceramic thin film onto the surface of the base ceramic. The reliability and performance of the E-chucks are therefore intrinsically linked on the resilience of the ceramic layer to adhere well on a base ceramic component. However, it is well-known that ceramic coatings are easily prone to cracking during mechanical solicitations due to their brittle mechanical behavior. The weak and unstable coating integrity can result in a premature coating failures and even catastrophic film delamination, hampering the lifetime time and performance of the E-chucks.
US7077918 describes a method for stripping a coating off a ceramic or metallic work piece. In order to facilitate the stripping at least a first chromous and aluminiferous coat is applied directly on the work piece. On this coat deposited is a functional layer made of nitride of AlCr known for its large pored structure. Stripping is then performed with a permanganate solution. The solution does not attack the nitride of AlCr but through its large pores the AlCr layer is attacked as expected. However, by the use of ceramic
layers with finer pores and better protection compared to plasma etching processes it is not expected to destroy a metallic layer located under the ceramic layer.
Objective of the present invention
It is an object of the present invention to alleviate or to overcome one or more difficulties related to the prior art. In particular, it is an object of the present invention to provide a method for producing a device as well as a device, which has a high surface resistance in plasma etching processes, can be easily and quickly surface renewed as required and offers great flexibility with regard to the selection of coating materials.
Description of the present invention
In order to overcome these problems, a method for producing a device to be used within a plasma etching chamber for the manufacturing of semiconductor components has been invented.
Thus, in a first aspect of the present invention disclosed is a method for producing a device to be used within a plasma etching chamber for the manufacturing of semiconductor components comprising:
- providing a body forming the substrate of the device,
- applying a first coating on the surface of the body, wherein the first coating comprises a metal and/or a metal alloy thin film coating layer in order to form a metal coated body,
- applying a second coating on the metal coated body, wherein the second coating comprises a ceramic coating layer, wherein the second coating at least partially overlaps with the first coating.
Hereby, the device may preferably be designed as an electrostatic chuck. Moreover, the first and/or second coating may be applied at least partially on the surface of the body of the device. The term that the second coating at least partially overlaps with the first coating may preferably be understood in that the second coating may be at least partially applied over the first coating which includes a direct connection as well as an indirect connection between the first and the second coating.
In another example of the first aspect, the method may comprise manufacturing the body, wherein the manufacturing may comprise uncoating the body, preferably by polishing and cleaning the surface of the body, wherein in particular plasma methods and/or ion bombardment may be used for cleaning and/or activating the surface. Alternatively or cumulatively, the manufacturing may comprise treating the body with an alkaline or oxidizing substance to dissolve existing coatings from the surface of the body.
In another example of the first aspect, an intermediate coating comprising metallic and ceramic components may be applied between the first coating and the second coating, wherein the intermediate coating may be applied preferably by using a controlled feed of reactive gases forming the ceramic components while continuously decreasing the addition of metallic components in order to create a gradient of the metallic component within the intermediate coating starting with a higher amount of the metallic compound at the interface to the first coating and finishing with a lower amount of the metallic compound at the interface to the second coating, wherein in particular the feed of the reactive gases forming the ceramic components and/or the addition of the metallic compound may be variated at least partially stepwise and/or at least partially continuously. In other words the atomic composition may change with depth from at least almost metallic near the interface to the first layer to at least almost ceramic near the interface to the second coating, wherein such change may be at least partially stepwise and/or at least being partially continuous, thereby forming a gradient.
Thus, in this invention, a special coating architecture using a dedicated base or intermediate layer is proposed in order to solve the problem of the invention. The nature of this interlayer is chosen to allow for an efficient de-coating with the wet chemical method. Examples of wet chemical methods may involve i.e. alkaline or oxidative solutions. The solution dissolves or oxidizes the interlayer, resulting in a “lift-off” or removal of the etch-resistant layer.
The interlayer also has the function of promoting adhesion of the etch-resistant layer to the surface of the component.
Thus, disclosed here is also a method for increasing the adhesion strength of vacuum deposited ceramic coatings to different substrate materials for E-chucks. These materials may include aluminium, stainless steel and various types of ceramics like AI2O3, quartz, AI2O3/AION and ALN. According to the present invention this may be done by depositing a thin, pure metallic layer followed by a gradual transition going from pure metal phase to a ceramic phase coating. The top functional layer through the improved adhesion is able to provide a more robust surface for aggressive applications then weaker bonded homogeneous films that do not have such an interlayer structure.
The intention of the present invention is thereby to solve the problem of inadequate adhesion and easy de-coating when refurbishing of homogeneous ceramic films to base materials. In order to improve the adhesion strength and facilitate the de-coating of the functional etch-resistant coating, the use of a metallic thin film layer or layer system is proposed before the homogeneous ceramic layer is deposited.
According to a preferred embodiment a gradual transition from a metallic based coating to a ceramic based coating may be realized. Depending on the method of deposition, process stability and repeatability are improved as well through this gradual transition from a metal to a ceramic based coating. Instead of abrupt changes in the process conditions a slow transition may be employed to make the coating more structurally robust and repeatable.
As turned out surprisingly even with the quite dense ceramic layers as used for E- chucks the intermediate metal layer facilitates the stripping method. One possible explanation could be that the ceramic layer may comprise pores which are however small enough that the plasma cannot enter, however are big enough that the stripping solution enters and attacks the underlying metal based coating.
Based on this explanation and according to a preferred embodiment of the present invention the body forming the device to be used in an etching chamber may be micro- and or nanostructured in order to even further improve the access of the stripping agent to the metallic coating on the body of the device. This may be done by structuring the uncoated body. The upper layers of the thin film coatings will then only to a certain extend or to a certain amount be in contact with lower areas of the structure.
On the other side, if a solvent agent may easily enter into the grooves of the body, thereby dissolving effectively the metal coating and as a consequence a lift off effect happens and the ceramic layer is removed as well.
Based on this, in a further example of the first aspect the method may comprise a step of micro- and/or nanostructuring the device, wherein the structures being introduced by micro- and/or nanostructuring preferably may be made in form of grating structures, in particular introduced into the body of the device.
As just explained (and not limited to the example as given above), the ease of coating removal for component level refurbishment is made easier by the employment of this adhesion layer structure. Chemical stripping methods can be used to remove the ceramic coatings rather easily due to the chemical attack of the metal-based layer. This works simply by undercutting of the ceramic film which results in film detachment from the substrate surface. In the case of homogeneous ceramic coatings with no metal layers, there is no such layer for the chemicals to attack. Stripping of these types of coatings is therefore much more difficult.
One specific area where this improved stripping may be applied is the removal of deposited ceramic coatings from hard shadow masking. For example, if this masking is being used to deposit features onto electrostatic chucks the masking will need to be cleaned periodically. This routine stripping of the mask is needed to prevent possible flaking from thick coating build up which can lead to particles in the coating. If the masking is of a ceramic material like AI2O3 the use of the metallic layer makes the stripping of the masks more efficient and repeatable.
In order to ensure an exact and targeted layer build-up, vacuum coating methods may be used for applying the first coating and/or the second coating and/or the intermediate coating, wherein preferably CVD- or PVD-techniques, in particular magnetron sputtering techniques may be used.
With respect to the layer build-up, as the first coating a pure metal layer and/or a pure metal alloy may be applied to the surface of the body, wherein the metal layer and/or
the metal alloy may comprise at least one of the following metals: Al, V, Ti, Hf, Y, Er, Sc, Ce, La.
Furthermore, with respect to the layer build-up as the second coating a pure ceramic layer may be applied to the surface of the body, wherein the ceramic layer preferably may comprise at least one of the following: oxides, nitrides, oxynitrides, silicates, fluorides, carbides, oxyfluorides, wherein the reactive gases to form the ceramics in particular may be fed slowly and ramped.
In a second aspect of the present invention disclosed is a device to be used within a plasma etching chamber for the manufacturing of semiconductor components, preferably produced by a method according to one of the previous claims, comprising a body forming the substrate of the device, a first coating applied on the surface of the body, wherein the first coating comprises a metal and/or metal alloy thin film coating layer, a second coating on the metal coated body, wherein the second coating comprises a ceramic coating layer, wherein the second coating at least partially overlaps with the first coating. The body forming the substrate of the device may include aluminium, stainless steel and/or various types of ceramics like AI2O3, quartz, AI2O3/AION or ALN.
In another example of the second aspect, the device may further include an intermediate coating located between the first and the second coating, wherein the intermediate coating comprises metallic and ceramic components, which may be preferably inhomogeneously distributed within the layer.
With respect to the intermediate coating, the metallic portion within the intermediate coating may continuously decrease starting from the interface between the intermediate coating and the first coating to the interface between the intermediate coating and the second coating and wherein at the same time the ceramic portion within the layer may continuously increase starting from the interface between the intermediate coating and the first coating to the interface between the intermediate coating and the second coating, wherein the ratio of the metallic component and the ceramic component to each other preferably may change at least partially stepwise and/or at least continuously.
In order to guarantee a high surface resistance in plasma etching processes combined with the ability to be easily and quickly surface renewed, the second coating and if given the intermediate coating may comprise pores, wherein the pores preferably may have a different pore diameter at a pore inlet and a pore outlet, wherein the diameter of the pores at the pore inlet adjacent to the second coating may be in particular smaller than at the pore outlet adjacent to the first coating.
In particular the coatings including the pores of the device may be designed that plasma in a plasma etching process cannot enter the second coating, however the coatings may be designed, in particular that pores being large enough to allow a stripping agent to enter the coatings and allow to dissolve the first coating.
In a further example of the second aspect the device may comprise micro- and/or nanostructured parts, wherein the micro- and/or nanostructured parts preferably may be in form of grid structures, in particular introduced into the body of the device.
With respect to the micro- and/or nanostructured parts, the grid structures may comprise protrusions and apertures disposed between two neighbouring protrusions, wherein the apertures preferably may comprise a constriction disposed between two neighbouring protrusions adjacent to the second coating, wherein the diameter of the apertures in particular may increase continuously from the constriction to the bottom of the grid within the apertures.
Hereby, the ceramic top layer preferably may not extend to the bottom of the grid within the apertures, wherein the bottom of the grid may only be coated with a metallic coating.
With respect to the layer build-up the first coating may be a pure metal and/or metal alloy thin film, preferably comprising at least one of the following metals: Al, V, Ti, Hf Y, Er, Sc, Ce, La.
With respect to the layer build-up the second coating may be a pure ceramic layer, preferably comprising at least one of the following: oxides, nitrides, oxynitrides, silicates, fluorides, carbides, oxyfluorides.
Hereby, the micro- and/or nanostructured parts may be designed in the form of a periodic grid structure, wherein the distances between two adjacent protrusions may preferably be at least 200 nm in width, in particular at least 400 nm in width. According to a particularly preferred embodiment the distances between two adjacent protrusions may also be more than 500 nm in width.
In another example of the second aspect, the device may be inhomogeneously coated along its surface, wherein the layer thickness of the first and/or second coating and/or the intermediate coating may be thinner at some points than at other points at the surface.
Preferably in an embodiment of the device with a grid structure, the coating (first and/or second coating and/or the intermediate coating) may be distributed inhomogeneously along its surface, wherein the coating (first and/or second coating and/or the intermediate coating) preferably being thicker on the upper side of the grid at the protrusions than the coating in the region of the bottom within the apertures.
According to a preferred embodiment the device may be an electrostatic chuck or a hard shadow masking device.
The invention can be used with electrostatic chucks; however, the concepts of the invention are intended to have a wider applicability both within the semiconductor processing industry and within other industries as well.
The utilization of a metallic adhesion promoting layer followed by a transition layer to a homogeneous ceramic layer was found to produce the best adhesion results. This layer structure also improves the ease of chemical stripping of the coating as needed.
The invention will now be described in more details based on examples and with the help of figures.
Description of the figures
Fig. 1 : Shows a cross section of the current state of the art solution
(1 ) Substrate
(2) Ceramic based monolayer,
Fig. 2: Shows a cross section of an embodiment of the present invention and shows the layers made to create the film stack
(1 ) Substrate
(2) Pure metal layer
(3) Transition layer (pure metal to ceramic)
(4) Ceramic based layer,
Fig. 3: Shows a scratch test on ALON monolayer coating directly coated onto the substrate. The substrate material is AI2O3, the coating thickness is ~21 pm. As the test revealed the LC2 failure is detected at 34N load,
Fig. 4: Shows a scratch test on a coating with a pure Aluminium adhesion layer and transition to the ALON functional layer according to one embodiment of the present invention. The substrate material is AI2O3 the coating thickness is ~23pm. As the test revealed the LC2 failure is detected at 50N load,
Fig. 5: Shows an example of a coated periodical rectangular grating structure introduced into the body of the device,
Fig. 6: Shows a sample with an AION film directly coated on an AI2O3 substrate before stripping,
Fig. 7: Shows the sample with the AION film according to Fig. 6 after stripping,
Fig. 8: Shows a sample with an AION film coated on a metallic interlayer which is directly coated on the substrate before stripping,
Fig. 9: Shows the sample with the AION film coated on the metallic interlayer according to Fig. 8 after stripping.
Detailed description of the inventive solution
In order to create an improved adhesion layer structure for the ceramic coatings, a vacuum deposition source is used to deposit a pure metal layer onto a clean substrate surface of an E-chuck. The coatings may include but are not limited to oxides, nitrides, borides, carbides, oxyfluorides as well as classes of materials such as Al, V Ti Zr, Hf Y, Er, Sc, Ce, La as well as AION. The substrate surface can be cleaned or activated by plasma cleaning or ion bombardment prior to the deposition of the metal. After a certain thickness of the pure metal layer is deposited, reactive gasses (such as O2, and/or N2, and/or Fluorine containing gasses) are introduced slowly and ramped over a period of minutes until a fully stoichiometric ceramic coating is realized. At this point the deposition is left to continue for some time during which the functional layer is deposited.
A more detailed example is given below.
Example
In the case of this example, an ALON (Aluminum Oxynitride) coating was deposited using magnetron reactive sputtering. A metal-based adhesion layer and transition were created before the functional ALON was deposited. The following steps were taken to create this film:
1. The polished (4pm Ra) Aluminum Oxide surface of an E-chuck was solvent cleaned and the E-chuck loaded onto a 2-axis of rotation planetary system inside a stainless-steel deposition system.
2. The chamber was evacuated to the low 10E-05 mbar range.
3. Argon plasma etching of substrates was done for 7 min. duration using a DC filament discharge and pulsed DC substrate biasing.
4. The operating pressure was then adjusted to 4.5E’3 mbar with turbo pump speed regulation along with the Argon flow regulated to 180 seem.
5. Pulsed DC power was then delivered to a balanced 08” circular planar Aluminum target (99% purity) starting at a 50% power setting and then ramping to 6 kW in
one minute.
6. Sputtering at 6kW was continued for a 10 min. duration in order to create the pure Aluminum adhesion layer.
7. The operating cathode voltage of the sputtering target was then noted to be ~565V in the pure metallic mode.
8. A closed loop control of reactive gasses O2 and N2 was then used to create the transition from pure Aluminum to Aluminum oxynitride using a control of reactive process by discharge voltage regulation device. The software control of this device allows the user to program a ramping function while utilizing a master/ slave control of the reactive gasses. In this case the N2 channel is the master and the O2 is the slave. The ratio of 0 to N was set to a ratio of 3.5:6.5. The reactive gasses are then ramped at this set ratio slowly over a period of 20 min. so that the cathode voltage decreases steadily from 565V (pure metal film) to a final set point of 400V (fully oxy-nitrided film). At this point the O/N ratio is still fixed and minor adjustments in gas flow is achieved by the regulation device to maintain the 400V operating setpoint on the sputtering cathode for the duration of the deposition.
9. The conditions are then held at constant until the desired thickness is reached for the functional top layer of the coating.
The resulting coating was comprised of a pure Aluminum layer of ~.8 microns thickness, a transitional gradient layer of ~.8 micron thickness and a functional top layer of ~21 microns. The adhesion strength was compared between the two coatings using a 200p radius conical diamond tip scratch tester. 3 mm length scratches were done in 2N load increments until Lc2 adhesive failure was achieved (Fig. 3,4). Compared to a monolayer ALON coating deposited under the same conditions with no adhesion layers the adhesion values were improved substantially with the use of this interlayer structure.
The pure metallic layer improves the bonding of the upper layers to the substrate material. The transition from metal to the ceramic layer provides good bonding between the metal layer and the upper function layer. The transitional layer acts as an intermediate layer with a hardness and Young’s modulus that lies between the softer pure metal layer and the harder functional layer. This structure provides for a more robust
coating that is better able to withstand any force or stresses that might occur on the functional layer.
Fig. 5 shows an example of a coated periodical rectangular grating structure introduced into the body 101 of the device. As can be seen from Fig. 5, the structured body 101 , comprises a periodical rectangular grating structure (with a grating period of 500 nm and a fillfactor of 0.5). The body is coated with a metallic coating 103. Because auf shadowing effects the coating thickness on top of the grating is thicker as compared to the metallic coating in the area of the grooves. As Fig. 5 shows, the openings of the gratings are narrowed due to the coating. This has the effect that the ceramic overcoat 105 (shown in Fig. 5 as crossed area) is not reaching the bottom of the grooves. In effect in depth region indicated as hm in the Fig. 5 only the metallic coating exists. The openings to the grooves are narrowed down to “d”. This prevents the etching plasma from entering into the grooves and the ceramic coating 105 will fully protect the device. As an additional effect, due to the structuring the adhesion of the coating to the structured body 101 is increased.
Chemical removal of the coating is also easier in comparison to homogenous type ceramic films covered in the prior art. This is primarily due to the ability of the stripping chemical to attack the metallic adhesion layer through the coating thus causing coating detachment.
In order to demonstrate the positive effect of stripping when a metallic interlayer is applied, two AI2O3 substrates were coated with a circular shaped AION ceramic film. On one substrate, a thick AION ceramic film was directly deposited onto the ceramic substrate AI2O3 while, on the other sample, a metallic layer was first deposited onto the sample, followed by a transitional gradient layer and finally the deposition of the thick ceramic AION film, as previously described.
After deposition of the coating, it was tried to strip the ceramic films with the help of 10% NaOH alkaline solution at room temperature for 90 minutes. Fig. 6 shows the sample with the AION film directly coated on the substrate before stripping and Fig. 7 shows the sample after stripping. As can be seen in Fig. 7, the circular ceramic film is attacked, however not completely removed. Fig. 8 shows the sample with the AION
film coated on the metallic interlayer and Fig. 9 shows the sample after stripping. As can be seen, the circular ceramic film is completely removed. Very interestingly, no damages (pitting, cracks) were observed at the surface of the freshly uncoated AI2O3 substrate after stripping.
Other solutions could be used for the stripping. For example a KOH solution is expected to do a good job as well.
Claims
1 . Method for producing a device to be used within a plasma etching chamber for the manufacturing of semiconductor components, comprising:
- providing a body forming the substrate of the device,
- applying a first coating on the surface of the body, wherein the first coating comprises a metal and/or a metal alloy thin film coating layer in order to form a metal coated body,
- applying a second coating on the metal coated body, wherein the second coating comprises a ceramic coating layer, wherein the second coating at least partially overlaps with the first coating.
2. Method according to claim 1 , wherein the method comprises manufacturing the body, wherein the manufacturing comprises uncoating the body, preferably by polishing and cleaning the surface of the body, wherein in particular plasma methods and/or ion bombardment is used for cleaning and/or activating the surface.
3. Method according to claim 1 or 2, wherein the manufacturing comprises treating the body with an alkaline or oxidizing substance to dissolve existing coatings from the surface of the body.
4. Method according to one of the previous claims, wherein an intermediate coating comprising metallic and ceramic components is applied between the first coating and the second coating, wherein the intermediate coating is applied preferably by using a controlled feed of reactive gases forming the ceramic components while continuously decreasing the addition of metallic components in order to create a gradient of the metallic component within the intermediate coating starting with a higher amount of the metallic compound at the interface to the first coating and finishing with a lower amount of the metallic compound at the interface to the second coating, wherein in particular the feed of the reactive gases forming the ceramic components and/or the addition of the metallic compound is variated at least partially stepwise and/or at least partially continuously.
5. Method according to one of the previous claims, wherein the method comprises a step of micro- and/or nanostructuring the device, wherein the structures being introduced by micro- and/or nanostructuring preferably are made in form of grating structures, in particular introduced into the body of the device.
6. Method according to one of the previous claims, wherein vacuum coating methods are used for applying the first coating and/or the second coating and/or the intermediate coating, wherein preferably CVD- or PVD-techniques, in particular magnetron sputtering techniques are used.
7. Method according to one of the previous claims, wherein as the first coating a pure metal layer and/or a pure metal alloy is applied to the surface of the body, wherein the metal layer and/or the metal alloy comprises at least one of the following metals: Al, V, Ti, Hf, Y, Er, Sc, Ce, La.
8. Method according to one of the previous claims, wherein as the second coating a pure ceramic layer is applied to the surface of the body, wherein the ceramic layer preferably comprises at least one of the following: oxides, nitrides, oxynitrides, silicates, fluorides, carbides, oxyfluorides, wherein the reactive gases to form the ceramics in particular are fed slowly and ramped.
9. Device to be used within a plasma etching chamber for the manufacturing of semiconductor components, preferably produced by a method according to one of the previous claims, comprising:
- a body forming the substrate of the device,
- a first coating applied on the surface of the body, wherein the first coating comprises a metal and/or metal alloy thin film coating layer,
- a second coating on the metal coated body, wherein the second coating comprises a ceramic coating layer, wherein the second coating at least partially overlaps with the first coating.
10. Device according to claim 9, wherein the device comprises additionally an intermediate coating, wherein the intermediate coating comprises metallic and ceramic components, which are preferably inhomogeneously distributed within the layer.
19
11. Device according to claim 10, wherein the metallic portion within the intermediate coating continuously decreases starting from the interface between the intermediate coating and the first coating to the interface between the intermediate coating and the second coating and wherein at the same time the ceramic portion within the layer continuously increases starting from the interface between the intermediate coating and the first coating to the interface between the intermediate coating and the second coating, wherein the ratio of the metallic component and the ceramic component to each other preferably changes at least partially stepwise and/or at least continuously.
12. Device according to one of claims 9 to 11 , wherein the second coating and if given the intermediate coating comprises pores, wherein the pores preferably have a different pore diameter at a pore inlet and a pore outlet, wherein the diameter of the pores at the pore inlet adjacent to the second coating is in particular smaller than at the pore outlet adjacent to the first coating.
13. Device, according to one of claims 9 to 12, wherein the device comprises micro- and/or nanostructured parts, wherein the micro- and/or nanostructured parts preferably are made in form of grid structures, in particular introduced into the body of the device.
14. The device of claim 13, wherein the grid structures comprise protrusions and apertures disposed between two neighbouring protrusions, wherein the apertures preferably comprising a constriction disposed between two neighbouring protrusions adjacent to the second coating, wherein the diameter of the apertures in particular increases continuously from the constriction to the bottom of the grid within the apertures.
15. Device according to claim 13 or 14, wherein the ceramic top layer is applied partially on the surface of the body, wherein the ceramic top layer preferably does not extend to the bottom of the grid within the apertures, wherein the bottom of the grid is only coated with a metallic coating.
16. Device according to one of the claims 9 to 15, wherein the first coating is a pure metal and/or metal alloy thin film, preferably comprising at least one of the following metals: Al, V, Ti, Hf, Y, Er, Sc, Ce, La.
20
17. Device according to one of the claims 9 to 16, wherein the second coating is a pure ceramic layer, preferably comprising at least one of the following: oxides, nitrides, oxynitrides, silicates, fluorides, carbides, oxyfluorides.
18. Device according to one of the claims 9 to 17, wherein the micro- and/or nanostructured parts are designed in the form of a periodic grid structure, wherein the distances between two adjacent protrusions are preferably at least 200 nm in width, in particular at least 400 nm in width.
19. Device according to one of the claims 9 to 18, wherein the device is inhomogeneously coated along its surface, wherein the layer thickness of the first and/or second coating and/or the intermediate coating being thinner at some points than at other points at the surface.
20. Device according to one of claims 9 to 19, wherein the device is an electrostatic chuck or a hard shadow masking device.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US202063120497P | 2020-12-02 | 2020-12-02 | |
PCT/EP2021/084017 WO2022117746A1 (en) | 2020-12-02 | 2021-12-02 | Improved plasma resistant coatings for electrostatic chucks |
Publications (1)
Publication Number | Publication Date |
---|---|
EP4256100A1 true EP4256100A1 (en) | 2023-10-11 |
Family
ID=86486815
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP21824529.8A Pending EP4256100A1 (en) | 2020-12-02 | 2021-12-02 | Improved plasma resistant coatings for electrostatic chucks |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP4256100A1 (en) |
JP (1) | JP2023551725A (en) |
KR (1) | KR20230116776A (en) |
CN (1) | CN116529415A (en) |
IL (1) | IL301981A (en) |
WO (1) | WO2022117746A1 (en) |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7077918B2 (en) | 2004-01-29 | 2006-07-18 | Unaxis Balzers Ltd. | Stripping apparatus and method for removal of coatings on metal surfaces |
US7732056B2 (en) | 2005-01-18 | 2010-06-08 | Applied Materials, Inc. | Corrosion-resistant aluminum component having multi-layer coating |
US7642205B2 (en) * | 2005-04-08 | 2010-01-05 | Mattson Technology, Inc. | Rapid thermal processing using energy transfer layers |
US20070221132A1 (en) * | 2006-03-24 | 2007-09-27 | General Electric Company | Composition, coating, coated article, and method |
US20080141938A1 (en) * | 2006-12-13 | 2008-06-19 | General Electric Company | Processing apparatus, coated article and method |
US8206829B2 (en) | 2008-11-10 | 2012-06-26 | Applied Materials, Inc. | Plasma resistant coatings for plasma chamber components |
EP2614518A4 (en) * | 2010-09-10 | 2016-02-10 | VerLASE TECHNOLOGIES LLC | Methods of fabricating optoelectronic devices using layers detached from semiconductor donors and devices made thereby |
CN103918065A (en) | 2011-08-10 | 2014-07-09 | 恩特格林斯公司 | Aion coated substrate with optional yttria overlayer |
CN103794445B (en) | 2012-10-29 | 2016-03-16 | 中微半导体设备(上海)有限公司 | For electrostatic chuck assembly and the manufacture method of plasma process chamber |
JP6527524B2 (en) * | 2014-02-07 | 2019-06-05 | インテグリス・インコーポレーテッド | Electrostatic chuck and method of manufacturing the same |
US10020218B2 (en) * | 2015-11-17 | 2018-07-10 | Applied Materials, Inc. | Substrate support assembly with deposited surface features |
JP6698168B2 (en) | 2016-02-10 | 2020-05-27 | インテグリス・インコーポレーテッド | Wafer contact surface protrusion profile with improved particle performance |
-
2021
- 2021-12-02 KR KR1020237015850A patent/KR20230116776A/en unknown
- 2021-12-02 WO PCT/EP2021/084017 patent/WO2022117746A1/en active Application Filing
- 2021-12-02 CN CN202180081950.XA patent/CN116529415A/en active Pending
- 2021-12-02 JP JP2023533721A patent/JP2023551725A/en active Pending
- 2021-12-02 EP EP21824529.8A patent/EP4256100A1/en active Pending
- 2021-12-02 IL IL301981A patent/IL301981A/en unknown
Also Published As
Publication number | Publication date |
---|---|
WO2022117746A8 (en) | 2023-05-25 |
WO2022117746A1 (en) | 2022-06-09 |
CN116529415A (en) | 2023-08-01 |
JP2023551725A (en) | 2023-12-12 |
KR20230116776A (en) | 2023-08-04 |
IL301981A (en) | 2023-06-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US11680308B2 (en) | Plasma erosion resistant rare-earth oxide based thin film coatings | |
JP6956774B2 (en) | Ion-assisted vapor deposition topcoat of rare earth oxides | |
JP6596060B2 (en) | Ion-assisted deposition for rare earth oxide coatings on lids and nozzles | |
US9460898B2 (en) | Plasma generation chamber with smooth plasma resistant coating | |
US20150311043A1 (en) | Chamber component with fluorinated thin film coating | |
TWI545650B (en) | A method for manufacturing a gas sprinkler for a plasma processing chamber and a method for forming the same | |
TW201417211A (en) | Performance enhancement of coating packaged esc for semiconductor apparatus | |
TW201417151A (en) | Coating for performance enhancement of semiconductor apparatus | |
US20240006216A1 (en) | Improved plasma resistant coatings for electrostatic chucks | |
WO2022117746A1 (en) | Improved plasma resistant coatings for electrostatic chucks | |
US20240017299A1 (en) | Methods for removing deposits on the surface of a chamber component | |
US20230290616A1 (en) | Semiconductor chamber components with multi-layer coating | |
US20230223240A1 (en) | Matched chemistry component body and coating for semiconductor processing chamber | |
CN116635565A (en) | Carbon doped metal oxyfluoride (C: M-0-F) layer as a protective layer during fluorine plasma etching |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: UNKNOWN |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE |
|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
17P | Request for examination filed |
Effective date: 20230628 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
DAV | Request for validation of the european patent (deleted) | ||
DAX | Request for extension of the european patent (deleted) |