EP4233569A1 - Procédé de fabrication d'une source de chaleur combustible pour article à fumer, et article à fumer le comprenant - Google Patents

Procédé de fabrication d'une source de chaleur combustible pour article à fumer, et article à fumer le comprenant Download PDF

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Publication number
EP4233569A1
EP4233569A1 EP22893968.2A EP22893968A EP4233569A1 EP 4233569 A1 EP4233569 A1 EP 4233569A1 EP 22893968 A EP22893968 A EP 22893968A EP 4233569 A1 EP4233569 A1 EP 4233569A1
Authority
EP
European Patent Office
Prior art keywords
heat source
smoking article
combustible heat
combustion
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP22893968.2A
Other languages
German (de)
English (en)
Other versions
EP4233569A4 (fr
Inventor
Eunmi JEOUNG
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KT&G Corp
Original Assignee
KT&G Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KT&G Corp filed Critical KT&G Corp
Publication of EP4233569A1 publication Critical patent/EP4233569A1/fr
Publication of EP4233569A4 publication Critical patent/EP4233569A4/fr
Pending legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/10—Chemical features of tobacco products or tobacco substitutes
    • A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
    • A24B15/165—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes comprising as heat source a carbon fuel or an oxidized or thermally degraded carbonaceous fuel, e.g. carbohydrates, cellulosic material
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18—Treatment of tobacco products or tobacco substitutes
    • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/287—Treatment of tobacco products or tobacco substitutes by chemical substances by inorganic substances only
    • A24B15/288—Catalysts or catalytic material, e.g. included in the wrapping material
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18—Treatment of tobacco products or tobacco substitutes
    • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00—Cigars; Cigarettes
    • A24D1/22—Cigarettes with integrated combustible heat sources, e.g. with carbonaceous heat sources

Definitions

  • the following description relates to a method for manufacturing a combustible heat source for a smoking article, a combustible heat source manufactured by the manufacturing method, and a smoking article comprising the combustible heat source.
  • a number of smoking articles which are heated rather than combusted have recently been proposed. Unlike conventional smoking articles, these non-combustion type smoking articles are used by sucking an aerosol generated by heating the smoking article medium without burning the smoking article medium. As one of these types of heating-type smoking articles, there is a smoking article product to which a carbon heat source is applied.
  • a smoking article to which the carbon heat source is applied generates an aerosol by heat transfer from the carbon heat source to a smoking article medium located downstream of the carbon heat source.
  • the smoking article to which the carbon heat source is applied has a smoking form similar to that of a traditional smoking article, unlike general heating-type electronic smoking articles using a dedicated device, so that consumers' smoking convenience and satisfaction can be expected to be improved.
  • Patent Document 1 Korean Patent Publication No. 2020-0030364
  • An object of the present disclosure is to provide a method for manufacturing a combustible heat source having reduced flame generation or surface cracking phenomenon during combustion and at the same time excellent ignitability and combustion persistency, and a smoking article comprising the heat source.
  • the present disclosure provides a method for manufacturing a combustible heat source for a smoking article, the method comprising the steps of:
  • the aqueous sugar solution may be contained in the composition in an amount of 5 to 15% by weight.
  • the aqueous sugar solution may be prepared by mixing sugar and water at a weight ratio of 7: 3 to 5: 5.
  • the sugar may be one or more sugar alcohols selected from the group consisting of sorbitol, xylitol, mannitol, maltitol, lactitol, erythritol, reduced palatinose, and reduced starch syrup.
  • the composition may further comprise potassium nitrate.
  • the carbon powder may include charcoal and graphite.
  • the organic binder may be one or more selected from the group consisting of carboxymethylcellulose (CMC), guar gum, methylcellulose (MC), and hydroxypropyl methylcellulose (HPMC).
  • CMC carboxymethylcellulose
  • MC methylcellulose
  • HPMC hydroxypropyl methylcellulose
  • the heat source may be ignited within 30 seconds, and combustion may last for 140 seconds or more.
  • the present disclosure provides a smoking article comprising a combustible heat source comprised of the composition.
  • the present disclosure uses an aqueous sugar solution to facilitate the ignition of the combustible heat source, and the heat source consisting of the composition according to the present disclosure is characterized by having improved ignitability and combustibility compared to the conventional heat sources.
  • Most heating-type electronic smoking articles have a device in the structure of [device + dedicated stick].
  • a product having a smoking form similar to those of general smoking articles is being developed by applying a carbon-based heat source to the tip of the smoking article.
  • the present disclosure has attempted to develop a combustible heat source that can have a smoking form (ignition, smoking start point) similar to those of the general smoking articles.
  • an ignition accelerator composed of potassium nitrate/sugar was used in the present disclosure.
  • a small amount of potassium nitrate/sugar in a powder form was not evenly mixed compared to the main used carbon powder, causing problems during combustion.
  • a small amount of oil/moisture is applied to the carbon heat source, and sugar is applied in the form of an aqueous sugar solution to promote an even distribution inside the combustion body, and it is confirmed that problems occurring during combustion are solved, completed the present disclosure.
  • the present disclosure seeks to present a method for manufacturing a combustible heat source, which has excellent ignitability and combustion persistency at the same time by adding sugar and enables stable combustion without a phenomenon such as flying flame by being evenly mixed with sugar, a combustible heat source manufactured through this, and a smoking article comprising the combustible heat source.
  • the present disclosure provides a method for manufacturing a combustible heat source for a smoking article, the method comprising the steps of:
  • the present disclosure may provide a combustible heat source for a smoking article, which is manufactured by the above method.
  • the present disclosure may provide a smoking article comprising the combustible heat source.
  • the combustible heat source composition according to the present disclosure is characterized in that it comprises a carbon powder and an organic binder, and is used by adding an aqueous sugar solution to the composition.
  • aqueous sugar solution is used in general heat source manufacturing so that sugar is evenly dispersed in the heat source, thereby enabling stable combustion transition due to this.
  • the aqueous sugar solution in the composition may be contained in an amount of 5 to 15% by weight, more preferably 5 to 10% by weight so as to have an ignition time of within 30 seconds and a combustion duration time of about 3 minutes.
  • the aqueous sugar solution is prepared by mixing sugar and water at a weight ratio of 7:3 to 5:5, and it is preferable to use sugar in an amount greater than or equal to that of water. More preferably, an aqueous sugar solution prepared by mixing them at a weight ratio of 6:4 in which sugar and water can be evenly dispersed may be used.
  • the sugar is a sugar alcohol, and may include sorbitol, xylitol, mannitol, maltitol, lactitol, erythritol, reduced palatinose, reduced starch syrup, or the like.
  • mannitol with low hygroscopicity is used since it is suitable for being used in the heat source.
  • the ignition accelerator may be used by adding potassium nitrate to sugar.
  • the potassium nitrate may be contained in an amount of 5 to 15% by weight.
  • the charcoal is used as a fuel that is ignited as a main material of a heat source and maintains combustion.
  • the charcoal is preferably contained in an amount of 40% by weight or more based on 100% by weight of the solid content, and may maintain the temperature necessary for smoking for 3 minutes or more by being contained in an amount of 40% by weight or more.
  • a heat source may be manufactured by adding a polyhydric alcohol as oil to the composition. Since the polyhydric alcohol is added, combustible vaporization may be possible after ignition of the heat source, and thus ignitability and combustion persistency may be improved.
  • the polyhydric alcohol assists combustion, and may be glycerin or propylene glycol.
  • the polyhydric alcohol may be used in an amount of 1 to 5 parts by weight based on 100 parts by weight of the solid content. It has excellent ignitability and combustion persistency within the above range, and more preferably, when used in an amount of 1 to 3 parts by weight, rapid ignition and stable combustion progress are possible.
  • the heat source may be ignited within 30 seconds, and combustion may last for 140 seconds or more.
  • the heat source having the ignition time and the combustion time may have a diameter of 5 to 10 mm and a length of 8 to 15 nm, but is not limited thereto.
  • one or more binders may be combined in the heat source.
  • one or more binders are organic binders.
  • suitable organic binders are not limited thereto, but include carboxymethylcellulose (CMC), guar gum, methylcellulose (MC), hydroxypropyl methylcellulose (HPMC), and combinations thereof.
  • a combustible heat source for use in a smoking article may comprise one or more additives to enhance the properties of the combustible heat source.
  • suitable additives include additives that promote consolidation of the combustible heat source (e.g., sintering aids), additives that promote ignition of the combustible heat source (e.g., oxidizers such as perchlorates, chlorates, nitrates, peroxides, permanganates, zirconium, and combinations thereof), additives that promote combustion of the combustible heat source (e.g., potassium, and potassium salts such as potassium citrate), and additives that promote decomposition of one or more gases produced by combustion of the combustible heat source (e.g., catalysts such as CuO, Fe 2 O 3 , and Al 2 O 3 ).
  • the combustible heat source may further comprise an ignition aid.
  • ignition aid is used to denote a substance that releases one or both of energy and oxygen during ignition of a combustible heat source, wherein the rate of release of one or both of the energy and oxygen by the substance is not limited by ambient oxygen diffusion. That is, during ignition of a combustible heat source, the rate of release of one or both of energy and oxygen by the substance is almost independent of the rate at which ambient oxygen can reach the substance.
  • the term 'ignition aid' is also used to denote an elemental metal that releases energy during ignition of a combustible heat source, wherein the ignition temperature of the elemental metal is lower than about 500°C, and the combustion heat of the elemental metal is at least about 5 kJ/g.
  • the ignition aid is an alkali metal salt of carboxylic acid (an alkali metal citrate salt, an alkali metal acetate salt, an alkali metal succinate salt, or the like), an alkali metal halide salt (an alkali metal chloride salt or the like), an alkali metal carbonate salt, or an alkali metal phosphate salt, which is believed to modify carbon combustion.
  • nitrates such as, for example, potassium nitrate, calcium nitrate, strontium nitrate, sodium nitrate, barium nitrate, lithium nitrate, aluminum nitrate, and iron nitrate; nitrite; other organic and inorganic nitro compounds; chlorates such as, for example, sodium chlorate, and potassium chlorate; perchlorates such as, for example, sodium perchlorate; chlorites; bromates such as, for example, sodium bromate and potassium bromate; perbromates; bromites; borates such as, for example, sodium borate and potassium borate; ferrates such as, for example, barium ferrate; ferrites; manganates such as, for example, potassium manganate; permanganates such as, for example, potassium permanganate; organic peroxides such as, for example, benzoyl peroxide and acetone peroxide; inorganic peroxides such as,
  • the ignition and combustion performances of the combustible heat source are advantageously improved, but undesirable decomposition and reaction products during the use of a smoking article may be produced by comprising ignition and combustion additives.
  • ignition and combustion additives For example, nitrates contained in the combustible heat source to assist ignition are decomposed so that nitrogen oxides may be formed.
  • Containing a combustible heat source in a smoking article according to the present disclosure advantageously substantially prevents or suppresses decomposition and reaction products from entering the air drawn through the smoking article according to the present disclosure during its use.
  • Combustible carbonaceous heat sources for use in a smoking article according to the present disclosure may be manufactured as described in the conventional art known to those skilled in the art.
  • a combustible carbonaceous heat source for use in a smoking article according to the present disclosure is preferably formed by mixing one or more carbon-containing materials with one or more binders and other additives (if contained), and preforming the mixture into the desired shape.
  • the mixture of one or more carbon-containing materials, one or more binders, and optional other additives may be pre-formed into a desired shape by using any suitable known ceramic forming methods such as, for example, slip casting, extrusion, injection molding, and mold compression.
  • the mixture is pre-formed into a desired shape by pressurization, extrusion, or a combination thereof.
  • the mixture of one or more carbon-containing materials, one or more binders, and other additives is pre-formed into an elongate rod.
  • the mixture of one or more carbon-containing materials, one or more binders, and other additives may be pre-formed into other desired shapes.
  • the combustible heat source may preferably have a porosity between about 20% and about 80%, more preferably between about 20% and about 60%. More preferably, the combustible heat source may have a porosity between about 50% and about 70% when measured, for example, by mercury porosimetry or helium pycnometry. The required porosity may be easily achieved while the method for manufacturing the heat source is being performed using conventional methods and techniques.
  • a combustible heat source for use in a smoking article according to the present disclosure have an apparent density between about 0.6 g/cm 3 and about 1 g/cm 3 .
  • the combustible heat source has a mass between about 300 mg and about 500 mg, more preferably between about 400 mg and about 450 mg.
  • the combustible heat source has a length between about 7 mm and about 17 mm, more preferably between about 7 mm and about 15 mm, and most preferably between about 7 mm and about 13 mm.
  • the combustible heat source has a diameter between about 5 mm and about 9 mm, more preferably between about 7 mm and about 8 mm.
  • the combustible heat source has a substantially uniform diameter.
  • the combustible heat source is alternatively tapered so that the diameter of the rear portion of the combustible heat source is greater than the diameter of the front portion thereof.
  • the rear portion of the combustible heat source has a widthwise directional cross-sectional area of at least about 60% of the widthwise directional cross-sectional area of the smoking article.
  • the combustible heat source is substantially cylindrical.
  • the combustible heat source may be, for example, a substantially circular cross-sectional cylinder or tapered cylinder shape, or a substantially elliptical cross-sectional cylinder or tapered cylinder shape.
  • the combustible heat source may be used in a combustible heat source-applied smoking article.
  • the "smoking article” may mean any smokeable product or any product that can provide a smoking experience regardless of whether or not it is based on tobacco, tobacco derivatives, expanded tobacco, reconstituted tobacco, or tobacco substitutes.
  • the smoking article may mean a smokeable article capable of generating an aerosol, such as a cigarette, cigar, cigarillo, or the like.
  • the smoking article may comprise a combustible heat source composed of the composition, a medium part, a thermally conductive wrapper, cigarette paper, a cooling part, a filter part, etc., and the combustible heat source; the medium part; the cooling part; and the filter part may be aligned in order based on the longitudinal direction, but the order can be freely changed except for the case where the combustible heat source is located upstream.
  • additional configurations may be further included or one or more of the above-described configurations may be omitted.
  • the smoking article may have a diameter of, for example, 4 mm to 10 mm, and a circumference of 14 mm to 29 mm.
  • the smoking article may have a length of 45 mm to 100 mm.
  • the medium part may include, for example, at least one of cut tobacco, cut reconstituted tobacco leaves, cigarette leaves, expanded tobacco, and nicotine extract.
  • the medium part may contain a nicotine component.
  • an aerosol-generating material may be further contained.
  • the aerosol-generating material may include polyhydric alcohols, esters of polyhydric alcohols such as glycerol mono-, di- or triacetate, and aliphatic esters of mono-, di- or esters of polycarboxylic acids such as dimethyl dodecanedioate and dimethyl tetradecanedioate.
  • the aerosol-generating material may include, for example, at least one of glycerin, propylene glycol, ethylene glycol, dipropylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, and oleyl alcohol.
  • the medium part may include cut reconstituted tobacco leaves immersed in glycerin.
  • this is an example and the present disclosure is not necessarily limited to the description described above.
  • the medium part may have a length between about 5 mm and about 20 mm, more preferably between about 8 mm and about 12 mm.
  • the medium part is surrounded by paper or other wrapper and may be in the form of a plug or part containing a material capable of releasing volatile compounds in response to heating. As described above, when the medium part is in the form of a plug or part, the entire plug or part including any wrapper is considered to be the medium part.
  • the cooling part may contain a cooling material.
  • the cooling part includes a tubular hollow body with an open end, and may cool airflow passing through the heat source and the medium part.
  • the cooling part may be made of a polymer material or a biodegradable polymer material and may have a cooling function.
  • the cooling part may be paper, cardboard, plastic, and may be, for example, cellulose acetate, ceramic, and a combination thereof.
  • the cooling part may include a corrugated sheet of material selected from the group consisting of metal foil, polymeric material, and substantially non-porous paper or cardboard.
  • the aerosol cooling element may also include a corrugated sheet of material selected from the group consisting of polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), polyethylene terephthalate (PET), polylactic acid (PLA), cellulose acetate (CA), and aluminum foil.
  • the cooling part may have a length between about 5 mm and about 30 mm, more preferably between about 8 mm and about 25 mm, but the length may be freely adjusted in consideration of the temperature of heat generated from a heatable heat source.
  • the filter part contains a filter material, and the shape of the filter part is not limited.
  • the filter part may be a cylinder-type rod or a tube-type rod including a hollow therein.
  • the filter part may be a recess-type rod. If the filter part is composed of a plurality of segments, at least one of the plurality of segments may be manufactured in a different shape.
  • the filter part may include a fibrous phase, a filament phase, or a filter tow including both thereof, containing at least one of polymer, paper, cellulose acetate, activated carbon, and carbon, but is not limited thereto.
  • the filter part for example, may have a length of 5 to 20 mm.
  • the filter may further comprise a tipping paper in contact with the mouth, which surrounds the filter material.
  • the tipping paper may have one or more perforations formed therein.
  • the filter part may be manufactured to generate flavor.
  • a flavoring liquid may be sprayed onto the filter material, and a separate fiber coated with the flavoring liquid may be inserted into the filter part.
  • the cooling part and the filter part may contain an aerosol modifier.
  • one or more of the cooling part, filter part, and tipping paper of the smoking article according to the present disclosure may contain one or more aerosol modifiers.
  • Suitable aerosol modifiers may not be limited thereto, but may include a flavoring agent and a chemesthetic agent.
  • the flavoring agent is used to describe any substance that, when used, imparts taste, aroma, or both thereof to aerosols generated by a tobacco material and an aerosol-generating material of the smoking article.
  • the cigarette paper is composed of cellulose fibers obtained from wood, flax, or other materials, and may be wrapped around a medium part, wrapped around the entire smoking article comprising the medium part, or wrapped around a part except for the filter part.
  • the base paper of the cigarette paper may have a thickness of about 30 ⁇ m to about 100 ⁇ m, and the base paper may have a basis weight of about 15 g/m 2 to about 80 g/m 2 .
  • the smoking article according to the present disclosure may also comprise downstream one or more aerosol modifiers that are both a flavoring agent and a chemesthetic agent.
  • one or more of the cooling part and filter part of the smoking article according to the present disclosure may contain menthol or another flavoring agent that provides a cooling object sensory effect.
  • the smoking article comprising the combustible heat source may comprise a thermally conductive wrapper surrounding the combustible heat source and the medium part.
  • the thermally conductive wrapper may completely surround the heat source and the medium part, partially surround a portion of the heat source and the medium part, or entirely surround a portion of the heat source and the medium part.
  • the thermally conductive wrapper transfers heat generated from a combustible heat source to a smoking article material, and the wrapper may include metal foil wrappers such as an aluminum foil wrapper, a steel wrapper, an iron foil wrapper, and a copper foil wrapper; and metal alloy foil wrappers, and is not limited to the material as long as it is a material capable of efficiently transferring heat.
  • a metal barrier may be formed between the heatable heat source and the medium part.
  • the metal barrier may prevent direct contact of a combustible heat source part with the medium part, and may prevent some out of components generated in the combustible heat source part from moving to the medium part.
  • the thickness of the barrier may be appropriately adjusted to obtain good smoking performance.
  • the barrier may have a thickness between about 10 microns and about 500 microns.
  • the barrier may include one or more metallic materials that are substantially thermally stable and non-combustible at the temperatures obtained by the combustible heat source upon ignition and combustion. Suitable materials are known in the art and are not limited thereto, but they include aluminum, copper, stainless steel, and combinations thereof.
  • combustible heat source compositions comprising charcoal, binder, potassium nitrate, and sugar were prepared.
  • the heat sources were manufactured in the form of a cylinder with a diameter of 7 mm and a height of about 11 mm.
  • Materials for manufacturing heat sources were prepared according to the mixing ratios and then mixed using an atmospheric pressure mixer (ARE-310 from THINKY). When mixing, each material was mixed at 1,500 RPM for 1 minute each time it was added.
  • Comparative Embodiment 2 using an aqueous sugar solution having a high water content, good combustion was performed, but the start of combustion was late, and the surface combustion time took an excessively long time.
  • Comparative Embodiment 3 using 3% by weight of an aqueous sugar solution, the start of combustion was late, and surface combustion lasted for a long time, and in Comparative Embodiment 4 using 20% by weight of an aqueous sugar solution, ignition was good, but sugar boiling and explosion phenomena were confirmed.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacture Of Tobacco Products (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
EP22893968.2A 2021-12-30 2022-11-28 Procédé de fabrication d'une source de chaleur combustible pour article à fumer, et article à fumer le comprenant Pending EP4233569A4 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020210192018A KR102696082B1 (ko) 2021-12-30 2021-12-30 흡연 물품용 가연성 열원의 제조방법 및 이를 포함하는 흡연 물품
PCT/KR2022/019004 WO2023128317A1 (fr) 2021-12-30 2022-11-28 Procédé de fabrication d'une source de chaleur combustible pour article à fumer, et article à fumer le comprenant

Publications (2)

Publication Number Publication Date
EP4233569A1 true EP4233569A1 (fr) 2023-08-30
EP4233569A4 EP4233569A4 (fr) 2024-05-01

Family

ID=86999481

Family Applications (1)

Application Number Title Priority Date Filing Date
EP22893968.2A Pending EP4233569A4 (fr) 2021-12-30 2022-11-28 Procédé de fabrication d'une source de chaleur combustible pour article à fumer, et article à fumer le comprenant

Country Status (5)

Country Link
EP (1) EP4233569A4 (fr)
JP (1) JP2024504232A (fr)
KR (1) KR102696082B1 (fr)
CN (1) CN116829006A (fr)
WO (1) WO2023128317A1 (fr)

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5076296A (en) * 1988-07-22 1991-12-31 Philip Morris Incorporated Carbon heat source
US9775376B2 (en) * 2010-12-01 2017-10-03 R.J. Reynolds Tobacco Company Smokeless tobacco pastille and moulding process for forming smokeless tobacco products
UA112440C2 (uk) * 2011-06-02 2016-09-12 Філіп Морріс Продактс С.А. Спалиме джерело тепла для курильного виробу
US9717273B2 (en) * 2012-04-02 2017-08-01 Philip Morris Products S.A. Method of manufacturing a combustible heat source
TW201417729A (zh) * 2012-09-04 2014-05-16 Philip Morris Products Sa 絕熱熱源
KR20200030365A (ko) * 2018-09-12 2020-03-20 주식회사 케이티앤지 열원을 포함하는 에어로졸 생성 물품
KR102385863B1 (ko) 2018-09-12 2022-04-12 주식회사 케이티앤지 복합 열원 및 이를 포함하는 흡연 물품

Also Published As

Publication number Publication date
JP2024504232A (ja) 2024-01-31
KR20230102130A (ko) 2023-07-07
WO2023128317A1 (fr) 2023-07-06
CN116829006A (zh) 2023-09-29
KR102696082B1 (ko) 2024-08-19
EP4233569A4 (fr) 2024-05-01

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