EP4225688A1 - Distributeur d'eau et procédé de fonctionnement - Google Patents
Distributeur d'eau et procédé de fonctionnementInfo
- Publication number
- EP4225688A1 EP4225688A1 EP21787470.0A EP21787470A EP4225688A1 EP 4225688 A1 EP4225688 A1 EP 4225688A1 EP 21787470 A EP21787470 A EP 21787470A EP 4225688 A1 EP4225688 A1 EP 4225688A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- water
- water dispenser
- heater
- carbon dioxide
- boiler
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 161
- 238000000034 method Methods 0.000 title claims description 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 116
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 54
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 47
- 239000007789 gas Substances 0.000 claims description 14
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 10
- 235000012171 hot beverage Nutrition 0.000 claims description 10
- 239000011777 magnesium Substances 0.000 claims description 10
- 229910052749 magnesium Inorganic materials 0.000 claims description 10
- 238000005342 ion exchange Methods 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- 239000011701 zinc Substances 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 235000014171 carbonated beverage Nutrition 0.000 claims description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 6
- 235000013361 beverage Nutrition 0.000 description 6
- 229910052791 calcium Inorganic materials 0.000 description 6
- 239000011575 calcium Substances 0.000 description 5
- 235000010755 mineral Nutrition 0.000 description 4
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 229910001425 magnesium ion Inorganic materials 0.000 description 3
- 235000010216 calcium carbonate Nutrition 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical class [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- 235000011160 magnesium carbonates Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 206010013911 Dysgeusia Diseases 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000020965 cold beverage Nutrition 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- -1 hydrogen ions Chemical class 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000014214 soft drink Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67D—DISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
- B67D1/00—Apparatus or devices for dispensing beverages on draught
- B67D1/0003—Apparatus or devices for dispensing beverages on draught the beverage being a single liquid
- B67D1/0014—Apparatus or devices for dispensing beverages on draught the beverage being a single liquid the beverage being supplied from water mains
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/236—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids specially adapted for aerating or carbonating beverages
- B01F23/2362—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids specially adapted for aerating or carbonating beverages for aerating or carbonating within receptacles or tanks, e.g. distribution machines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67D—DISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
- B67D1/00—Apparatus or devices for dispensing beverages on draught
- B67D1/0003—Apparatus or devices for dispensing beverages on draught the beverage being a single liquid
- B67D1/0009—Apparatus or devices for dispensing beverages on draught the beverage being a single liquid the beverage being stored in an intermediate container connected to a supply
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67D—DISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
- B67D1/00—Apparatus or devices for dispensing beverages on draught
- B67D1/08—Details
- B67D1/0895—Heating arrangements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67D—DISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
- B67D3/00—Apparatus or devices for controlling flow of liquids under gravity from storage containers for dispensing purposes
- B67D3/0022—Apparatus or devices for controlling flow of liquids under gravity from storage containers for dispensing purposes provided with heating arrangements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67D—DISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
- B67D2210/00—Indexing scheme relating to aspects and details of apparatus or devices for dispensing beverages on draught or for controlling flow of liquids under gravity from storage containers for dispensing purposes
- B67D2210/00028—Constructional details
- B67D2210/00099—Temperature control
- B67D2210/00102—Heating only
Definitions
- Water dispenser or Beverage making machines may include a refrigerated carbonator through which carbonated water may be dispensed.
- the carbonator comprises a cooled pressure vessel which is connected to a compressed gas cylinder which is filled with carbon dioxide.
- a water dispenser can on the other hand have a boiler or flow heater, the so-called.
- Thermoblock include, over the hot water or. hot drinks are provided .
- a softening system can be used in an installation system, which exchanges calcium and magnesium for sodium via an ion exchanger and thus reduces the degree of hardness of the water.
- Such a system is sold, for example, by the applicant under the trade name "BestMax®".
- EP 2 094 611 B1 (BWT AG).
- EP 3 507 247 B1 describes a method and a device for enriching water with zinc ions.
- magnesium carbonates are still formed in the boiler. Furthermore, a sufficiently high removal of calcium is required to avoid scale in the boiler, which in turn is not necessary or not necessary for the cold water part of the water dispenser. would not be desirable at all, since calcium is also a physiologically important mineral.
- the object of the invention is to reduce the stated disadvantages of the prior art.
- the object of the invention is already achieved by a water dispenser and by a method for operating a water dispenser according to one of the independent claims.
- the invention also relates to water dispensers in the broadest sense.
- the invention further relates to water dispensers with or without a tank, which dispense hot and cold water.
- the invention also relates to machines that use the water for the production of hot drinks, e.g. B. Tea or coffee, use and/or with which so-called soft drinks can be produced, i.e. carbonated sweetened drinks.
- hot drinks e.g. B. Tea or coffee
- soft drinks i.e. carbonated sweetened drinks.
- the water dispenser includes a heater.
- the heater is electrically operated.
- this is also referred to as a thermal block.
- the thermal block can be designed in particular as a boiler. According to another embodiment, an embodiment as a flow heater is also conceivable.
- the invention is based on the finding that the carbon dioxide can be used to increase the carbon dioxide content and thus the carbon dioxide concentration in the boiler.
- the water dispenser comprises a carbonator for dispensing carbonated water.
- the carbonator is designed in particular as a cooled pressure vessel.
- the carbonator can be connected to a CO2 compressed gas tank. About the compressed gas tank is possibly. Carbon dioxide is fed to the carbonator via a pressure reducer.
- the carbon dioxide partly dissolves in the water present in the carbonator, partly the carbon dioxide forms carbonic acid, which lowers the pH value of the water.
- the pressurized gas tank used for the carbonator can be used to supply carbon dioxide to the heater.
- the carbon dioxide is introduced into the heater as a gas, in particular starting from the compressed gas container via a pressure reducer.
- the carbon dioxide dissolved in water (together with dissociated, dissolved carbonic acid) is introduced into the heater. This can allow for easier dosing via a single dosing valve.
- the metering valve is preferably designed as a switching valve.
- the water dispenser therefore preferably includes a control device that regulates the introduction of carbon dioxide via the metering valve.
- This refinement of the invention enables particularly simple control. For example, no separate water meter is required to measure the flow rate through the boiler, but this can be determined indirectly via the number of hot drinks taken.
- the carbon dioxide metering can take place as a function of the heating of the thermal block.
- a boiler is temperature controlled, i. H . if the machine is in stand-by mode, the boiler is heated so that a hot drink can be dispensed.
- the controller clocks and thus counteracts cooling. If a hot beverage is dispensed, the water in the boiler cools down due to the inflowing water and the boiler has to be heated more via the control .
- Control to change the amount of carbon dioxide per elapsed time unit and/or based on volume.
- the setting is preferably based on the degree of hardness of the input water.
- the water dispenser according to the invention includes adjustment means, such as a rotary wheel or a display, via which the degree of hardness of the water can be entered at the respective point of use.
- adjustment means such as a rotary wheel or a display
- an electronic control system calculates how much carbon dioxide is required and then adjusts the CC ⁇ release into the thermal block.
- the water dispenser comprises two switching valves arranged in series, which can be controlled alternately.
- the switching valves are designed in particular as solenoid valves.
- a small amount of carbon dioxide can also be added to the thermal block in a very simple manner via two such switching valves.
- An intermediate piece located between the switching valves is pressurized as soon as the switching valve located on the inlet side after the CO2 pressure tank opens.
- a pressure-dependent amount of CO2 is introduced into this line section and when the output switching valve opens, a small amount of carbon dioxide is introduced depending on the volume of the line section and depending on the pressure in the thermal block and the carbon dioxide pressure present.
- Compressed gas tanks and the two switching valves thus form a metering pump of very simple construction.
- the arrangement also includes a cartridge for water treatment, via which water is supplied to the water dispenser.
- Such cartridges are mostly cartridges that are used inline in a filter cartridge head, such as in the above system.
- the filter candle head is usually located outside of the water dispenser. An integration of the cartridge in the water dispenser is also possible.
- the ion exchange material can be loaded with magnesium or zinc with at least 30%, preferably at least 50%, of its total capacity.
- the ion exchange material is preferably loaded with less than 60%, particularly preferably with less than 20%, of its capacity with hydrogen and/or sodium.
- the ion exchanger can be completely loaded with magnesium.
- Information on the loading of the ion exchanger always refers to its delivery status.
- the invention also relates to a method for operating a water dispenser, in particular the water dispenser as described above.
- the water dispenser includes a thermal block, in particular a boiler, for heating the water, carbon dioxide being supplied to the thermal block.
- the carbon dioxide is preferably supplied from a compressed gas tank, via which a carbonator of the water dispenser is also supplied with carbon dioxide.
- the pH in the thermal block is preferably adjusted to below 7.5, preferably to 6.0 to 7.5, particularly preferably from 6.5 to 7.0, by supplying carbon dioxide.
- the pH value is not measured directly using a measuring device, but rather the metering in of carbon dioxide takes place based on time and/or volume, as described above.
- a control device can dose the carbon dioxide in such a way that the pH values mentioned above are maintained.
- the thermal block is preferably heated to at least 60° C., particularly preferably to at least 80° C., particularly preferably up to the boiling point.
- the metering of carbon dioxide takes place preferably via two switching valves clocked in opposite directions, which are designed in particular as solenoid valves.
- the invention also relates to a system for dispensing hot drinks and cold carbonated drinks, which includes the water dispenser described above and/or is designed to carry out the method described above.
- Fig. 1 is a schematic view of a beverage dispensing system according to the invention, comprising a water dispenser according to the invention.
- Fig. 3 shows another alternative embodiment.
- Fig. 4 is a schematic view of an embodiment in which the water dispenser includes a faucet and a water heater.
- FIG. 1 shows a schematic view of a system for dispensing hot and cold carbonated beverages.
- Water is supplied to the water dispenser 1 via a water pipe 2 provided by the customer.
- the water is routed through a water filter, which includes a filter candle head 3 installed inline in the water pipe 2 by the customer and a filter candle 4 inserted into the filter candle head 3 .
- the water can also include an ion exchanger, for example, which releases magnesium ions in particular to the water to be prepared.
- the water dispenser 1 includes a pump 5 via which the desired water can be pumped to an outlet 10 .
- the line 2 branches into the flow paths 6a to 6c downstream of the pump 5.
- the flow path 6a is designed for the delivery of hot water.
- the water is routed via the boiler 7 and from there it reaches the outlet 10 .
- the flow path 6b leads through a carbonator 8 .
- the water present in the carbonator 8 is thus pressurized and, depending on the pressure, enriched with a different amount of carbonic acid (and correspondingly dissolved CO2).
- the water present in the boiler 7 is also supplied with carbonic acid.
- the carbon dioxide is supplied via the same compressed gas tank 11 from which the carbonator 8 is supplied with CO 2 .
- the carbonic acid can be fed directly into the boiler 7 via the line 13 .
- control device 14 These are controlled alternately via a control device 14 .
- the line section 13a between the switching valves 15a and 15b serves as a pressure accumulator.
- the switching valve 15a opens and the line section 13a fills with carbon dioxide.
- the first switching valve 15a is then closed and the switching valve 15a downstream on the flow side is opened by the control device 14 .
- the dosing is preferably based on the opening times of the switching valve 9a and/or time-controlled.
- Fig. 2 shows an alternative embodiment of the invention. As shown here, the carbon dioxide from the CO2 compressed gas tank 11 does not have to be fed directly to the boiler 7 either.
- the line 13 for supplying carbon dioxide runs directly to the line 2 in front of the pump 5 .
- the amount of carbon dioxide introduced is as shown in FIG. 1 controlled by two switching valves.
- the water is already enriched with a small amount of carbon dioxide when it is fed into the carbonator 8 .
- the dosing preferably takes place within the water dispenser 1 .
- Z. B. metering can also take place in the line path 6a (not shown).
- Fig. 3 is a schematic view of another embodiment of the invention.
- the carbon dioxide is not introduced directly, but rather dissolved in the water, or initiated in the form of carbonic acid.
- a single switching valve 17 can easily be used in one of these embodiments to carry out the dosage.
- the disadvantage is that water that has been cooled in the carbonator 8 has to be heated again.
- Fig. 4 is a schematic representation of a water dispenser 1 which includes a faucet 19 and a water heater 18 .
- the faucet can B. be designed as a mixer tap, as used in the household.
- the line section 2b supplies the faucet 19 with cold water.
- the line section 2a supplies the water tap 19 with hot water and runs via the water heater 18 .
- the water heater comprises a boiler 7 and can in particular be designed as an under-sink unit.
- carbon dioxide is introduced into the boiler 7 via two switching valves 15a, 15b arranged in series. Due to the reduced formation of scale as a result, the ion exchange material can be loaded with less hydrogen or sodium.
- the existing capacity in the filter cartridge 4 can be used for dosing other ions, e.g. B. magnesium.
- a softening system (not shown) is used, which is regenerated with a common salt solution, a higher degree of hardness of the treated water can be set without increased scale formation occurring.
- the sodium content of the treated water can be reduced in this way.
- the invention made it possible to improve the formation of scale in the thermal block of a water dispenser, in particular the water dispenser of a machine for preparing cold and hot drinks, in a very simple manner.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Devices For Dispensing Beverages (AREA)
Abstract
La divulgation concerne un distributeur d'eau, comprenant un carbonateur de préférence refroidi destiné à distribuer de l'eau gazeuse. Le distributeur d'eau comprend un Thermoblock, notamment une bouilloire, destiné à distribuer de l'eau chaude. Le carbonateur peut être relié à un cylindre à gaz comprimé CO2. Le distributeur d'eau comprend au moins une valve de dosage, notamment une valve de commande, qui permet d'acheminer du dioxyde de carbone dans le Thermoblock.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102020126392.9A DE102020126392A1 (de) | 2020-10-08 | 2020-10-08 | Wasserspender sowie Verfahren zu dessen Betrieb |
PCT/EP2021/077860 WO2022074193A1 (fr) | 2020-10-08 | 2021-10-08 | Distributeur d'eau et procédé de fonctionnement |
Publications (1)
Publication Number | Publication Date |
---|---|
EP4225688A1 true EP4225688A1 (fr) | 2023-08-16 |
Family
ID=78085716
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP21787470.0A Pending EP4225688A1 (fr) | 2020-10-08 | 2021-10-08 | Distributeur d'eau et procédé de fonctionnement |
Country Status (4)
Country | Link |
---|---|
US (1) | US20240017981A1 (fr) |
EP (1) | EP4225688A1 (fr) |
DE (1) | DE102020126392A1 (fr) |
WO (1) | WO2022074193A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102022134233A1 (de) | 2022-12-20 | 2024-06-20 | ACLARIS GmbH, Lindau, Zweigniederlassung Rebstein | Volumenstromabhängige Mineralisierung in Getränkebereitern |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2536400A (en) * | 1946-10-30 | 1951-01-02 | Automatic Canteen Co | Apparatus for treating and dispensing liquids |
EP0102401B1 (fr) | 1982-08-27 | 1987-07-22 | Guldager Electrolyse International & Cie. | Procédé pour la prévention de dépôts calcaires dans les systèmes aqueux |
DE102006058223A1 (de) | 2006-12-01 | 2008-06-05 | Wp Engineering Ltd. | Verfahren und Vorrichtung zur Anreicherung von Wasser mit Magnesium-Ionen |
US10899645B2 (en) | 2011-03-04 | 2021-01-26 | Aquis Wasser-Luft-Systeme Gmbh, Lindau, Zweigniederlassung Rebstein | Water conditioner for preventing or reducing mineral precipitation |
DE102016116140A1 (de) | 2016-08-30 | 2018-03-01 | Bwt Ag | Vorrichtung und Verfahren zur Aufbereitung von Trinkwasser sowie Verfahren zur Beladung eines Ionenaustauschermaterials mit Zinkionen |
-
2020
- 2020-10-08 DE DE102020126392.9A patent/DE102020126392A1/de active Pending
-
2021
- 2021-10-08 US US18/030,524 patent/US20240017981A1/en active Pending
- 2021-10-08 EP EP21787470.0A patent/EP4225688A1/fr active Pending
- 2021-10-08 WO PCT/EP2021/077860 patent/WO2022074193A1/fr active Application Filing
Also Published As
Publication number | Publication date |
---|---|
WO2022074193A1 (fr) | 2022-04-14 |
US20240017981A1 (en) | 2024-01-18 |
DE102020126392A1 (de) | 2022-04-14 |
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