EP4182586A1 - Anode valve for a fuel cell automotive traction system - Google Patents
Anode valve for a fuel cell automotive traction systemInfo
- Publication number
- EP4182586A1 EP4182586A1 EP21752167.3A EP21752167A EP4182586A1 EP 4182586 A1 EP4182586 A1 EP 4182586A1 EP 21752167 A EP21752167 A EP 21752167A EP 4182586 A1 EP4182586 A1 EP 4182586A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- socket
- movable core
- valve
- anode valve
- inner casing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 10
- 238000004804 winding Methods 0.000 claims description 14
- 239000012530 fluid Substances 0.000 claims description 13
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 230000005291 magnetic effect Effects 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000007769 metal material Substances 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 230000005294 ferromagnetic effect Effects 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229910000975 Carbon steel Inorganic materials 0.000 description 2
- 229920002943 EPDM rubber Polymers 0.000 description 2
- 239000010962 carbon steel Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000000696 magnetic material Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- -1 Polytetrafluoroethylene Polymers 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000013037 co-molding Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16K—VALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
- F16K27/00—Construction of housing; Use of materials therefor
- F16K27/02—Construction of housing; Use of materials therefor of lift valves
- F16K27/029—Electromagnetically actuated valves
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16K—VALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
- F16K31/00—Actuating devices; Operating means; Releasing devices
- F16K31/02—Actuating devices; Operating means; Releasing devices electric; magnetic
- F16K31/06—Actuating devices; Operating means; Releasing devices electric; magnetic using a magnet, e.g. diaphragm valves, cutting off by means of a liquid
- F16K31/0644—One-way valve
- F16K31/0672—One-way valve the valve member being a diaphragm
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16K—VALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
- F16K31/00—Actuating devices; Operating means; Releasing devices
- F16K31/02—Actuating devices; Operating means; Releasing devices electric; magnetic
- F16K31/06—Actuating devices; Operating means; Releasing devices electric; magnetic using a magnet, e.g. diaphragm valves, cutting off by means of a liquid
- F16K31/0675—Electromagnet aspects, e.g. electric supply therefor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F7/00—Magnets
- H01F7/06—Electromagnets; Actuators including electromagnets
- H01F7/08—Electromagnets; Actuators including electromagnets with armatures
- H01F7/16—Rectilinearly-movable armatures
- H01F7/1607—Armatures entering the winding
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
- H01M8/04097—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with recycling of the reactants
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F7/00—Magnets
- H01F7/06—Electromagnets; Actuators including electromagnets
- H01F7/08—Electromagnets; Actuators including electromagnets with armatures
- H01F7/16—Rectilinearly-movable armatures
- H01F7/1607—Armatures entering the winding
- H01F2007/163—Armatures entering the winding with axial bearing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- the present invention is in the field of components for hydrogen fuel cell automotive systems; in particular, the present invention refers to an anode valve, i.e., a valve that intercepts the low-pressure branch of the system that feeds hydrogen to the fuel cells.
- anode valve i.e., a valve that intercepts the low-pressure branch of the system that feeds hydrogen to the fuel cells.
- ADV Anode Drain Valve
- ADVH Anode Drain Valve Header
- the object of the present invention is to provide an anode valve with high reliability.
- Fig. 1 depicts an anode valve according to an embodiment of the present invention, in separate parts;
- FIG. 2 depicts a cross section of the anode valve from Fig. 1;
- FIG. 3 shows an armature of a solenoid device of the anode valve according to the present invention.
- FIG. 4 illustrates an assembly comprising the armature and winding of the solenoid device of the anode valve according to the present invention.
- the reference 1 has been used to indicate an anode valve operating along a line downstream of fuel cells, supplied with a fluid which, depending on the uses of the valve, is primarily composed of gaseous components, such as hydrogen, nitrogen, and water vapor, or water.
- the anode valve 1 comprises a valve body 2, which is usually made in a single piece from aluminum, for example obtained from a bar by tooling.
- the valve body 2 has an inlet duct 4 for a fluid entering in the anode valve 1 and an outlet duct 6 for draining the fluid, which is connectable to the inlet duct 4.
- the valve body 2 also has a compartment 5 for containing some components; said compartment 5 has on its bottom, at the passage between the inlet duct 4 and the outlet duct 6, a support surface 16, which will be described hereinafter.
- At least partially elastically deformable shutter 8 is operational between the inlet duct 4 and the outlet duct 6; in a closed configuration, the shutter 8 sealingly closes the passage of the fluid from the inlet duct 4 to the outlet duct 6, while in an open configuration, the shutter 8 at least partially clears the passage allowing the fluid to pass from the inlet duct 4 to the outlet duct 6.
- the shutter 8 comprises a shutter body 10, which has at least one contact surface with a sealing surface of the valve body 2 for closing the passage between the inlet duct 4 and the outlet duct 6, and an elastically deformable shutter diaphragm 12 joined to the shutter body 10.
- the shutter body and shutter diaphragm are preferably made in one piece, for example of synthetic rubber, such as EPDM (Ethylene-Propylene Diene Monomer).
- EPDM Ethylene-Propylene Diene Monomer
- the shutter diaphragm 12 has peripherally an annular enlargement 14 to improve its sealing characteristics.
- the shutter diaphragm 12 rests on the support surface 16.
- the anode valve 1 further comprises a pressure element 18, for example annular, usually made of a metal material, accommodated in the body compartment 5 of the valve body 2 and suitable for pressing on the shutter diaphragm 12 so as to achieve a fluid seal between the pressure element 18 and the shutter diaphragm 12 and between the shutter diaphragm 12 and the support surface 16 of the valve body 2. [0015]Consequently, the body compartment 5 is hermetically sealed off from the inlet duct 4 and the outlet duct 6. [0016]The anode valve 1 further comprises an inner casing 20, for example tubular, accommodated at least partially in the body compartment 5.
- the inner casing 20 comprises a first portion 22, accommodated in the body compartment 5, in contact with the pressure element 18, comprising a first tubular wall 24 surrounding a first chamber 26.
- a nut 28 operates, which, screwed to the valve body 2 at the mouth of the body compartment 5, operates with thrust on the first portion 22, whereby the thrust action is transmitted to the pressure element 18.
- the inner casing 20 further comprises a second portion 30, which extends axially from the first portion 22 to exit the body compartment 5 through the nut 28; the second portion 30 comprises a second tubular wall 32 surrounding a second chamber 34.
- the second wall 32, terminating in a wall end 32a is made of a ferromagnetic metal material, for example carbon steel, such as llSMn37.
- the inner casing 20 comprises a third portion 36 joined to the second portion 30 outside of the body compartment 5, which closes the second chamber 34.
- said third portion 36 further comprises a fixed core 36' of a solenoid device suitable for moving the shutter body 10 of the shutter 8 by electromagnetic actuation.
- the third portion 36 is made of a ferromagnetic metal material, for example carbon steel, such as H SMn37 steel.
- the inner casing 20 further comprises an annular band 38, made of a non-magnetic material, for example a copper alloy such as CuA18 or generically of bronze, applied to the wall end 32a, interrupting the magnetic continuity with the third portion 36 or fixed core 36'.
- the band 38 comprises the remaining portion of a weld made between the second wall 32 and the third portion 36 or fixed core 36'.
- the anode valve 1 further comprises a fixed guide 40 accommodated in the second chamber 34; the guide 40 comprises a foot 42 fixed to the third portion 36, a stem 44 extending along a major axis X from the foot 42, and a head 46 joined to the end of the stem 44 opposite the foot 42.
- the anode valve 1 further comprises a movable core 48 of the solenoid device, made of a ferromagnetic metal material, accommodated in the second chamber 34 and slidably mounted on the stem 44 of the guide 40.
- the movable core 48 extends along the main axis X between a first end 50, facing the third portion 36 (fixed core), and a second end 52, facing the head 46, which forms an abutment.
- the anode valve 1 further comprises a socket 54 integral with the movable core 48, for example applied to said movable core 48 at the second end 52;
- the socket 54 comprises an annular socket wall 56 and a socket base 58 which delimit, together with the movable core 48, a socket compartment 60, in the head 46 of which the guide 40 is located.
- the anode valve 1 further comprises elastic return means suitable for operating permanently on the socket 54 to bring it toward the closed configuration.
- said return means comprise a spring 62 accommodated in the socket compartment 60, in compression between the guide 40, and in particular applied to the head 46, and the socket base 58.
- the socket 54 is connected to the shutter 8, whereby translation of the socket 54 results in a displacement of the shutter body 10 between the closed configuration and the open configuration.
- the shutter 8 comprises a peg 64 integral with the shutter body 10, e.g., made by co- molding or co-injection with the shutter body 10; the peg 64, extending along said main axis X, is engaged, e.g., screwed, to the socket base 58.
- the anode valve 1 further comprises guiding means accommodated in the inner casing 20, and in particular in the first chamber 26, integral with the movable core 48, and in particular applied to the socket 54, and suitable for guiding said socket 54 translationally on the inner casing 20.
- said guiding means comprise at least one skid 65 supported by the socket 54 and slidable on the inner side surface 24a of the first wall 24 to guide the translation of said socket 54.
- the skid 65 is made of PTFE (Polytetrafluoroethylene) or PUR (Polyurethane).
- the solenoid device further comprises a fixed armature 68 that supports an electrically powerable winding 70 to generate a magnetic field; within the winding 70 is contained at least partially the fixed core 36' and, within the fixed core, at least partially the movable core 48.
- the band 38 made of non-magnetic metal material is arranged between the winding 70 and the second chamber 34, to deflect the magnetic field and convey it into the movable core 48.
- the armature 68 preferably made of steel, is C- shaped and comprises a main wall 69, facing the side surface 70a of the winding 70, and a pair of base walls 71, projecting from the main wall 69, between which the winding 70 is held.
- the solenoid device preferably comprises an outer casing 72, which encloses the armature 68 with the winding 70 and the fixed core 36'.
- the anode valve 1 comprises at least one heater 74, electrically powerable, to heat the valve body 2 and melt any ice deposits formed at low temperatures.
- said anode valve In the normal operation of the anode valve 1, said anode valve is initially in the closed configuration wherein the solenoid device is in a deactivated state in which the winding 70 is not electrically powered; consequently, there are no magnetic actions of attraction between the fixed core 36' and the movable core 48, and the action of the return means, particularly the spring 62, causes the shutter body to obstruct the passage of fluid from the inlet duct 4 to the outlet duct 6.
- the movable core 48 In said configuration, the movable core 48 is in a closed position wherein the first end 50 forms a gap G with the fixed core 36'.
- the fluid When the anode valve 1 is in the closed configuration, the fluid accumulates in the inlet duct 4 and exerts a pressure on the shutter that tends to lift it, bringing it into the open configuration. The action of the return means must therefore be particularly energetic in order to keep the shutter in the closed configuration .
- the winding 70 When the system requires the fluid to be discharged, the winding 70 is electrically powered so that the solenoid device goes into an activated state. The action of attraction between the movable and fixed cores generated by the magnetic field attracts the movable core 48 toward the fixed core 36'; the movable core 48 then moves to an open position wherein the gap G is reduced to the minimum. Accordingly, the shutter body 10 clears the passage between the inlet duct 4 and the outlet duct 6.
- the valve 1 thus assumes the open configuration and the fluid may be discharged downstream.
- the action of the spring 62 must be very energetic to ensure closure in the closed configuration, the action of attraction between the movable and fixed cores must be equally energetic to pass into the open configuration.
- the band 38 allows the magnetic flux from the winding to the movable core to be properly channeled, preventing it from being channeled into the inner casing and thereby increasing the attractive action between the fixed core and the movable core.
- the shutter provided with a diaphragm allows the body compartment 5 to be isolated from the inlet duct 4, whereby hydrogen or other components of the pressurized fluid in the inlet duct may not travel up the inner casing to the band 38, the material of which is particularly deteriorable when in contact with such gases.
- the inlet duct 4 and the outlet duct 6 are hermetically separated from the body compartment and from the second chamber which faces the band 38 made of non-magnetic material.
- the presence of the C-shaped armature causes an asymmetry of the actions acting on the movable core, which therefore pushes on the stem 44 with off-axis actions that, in the long run, would cause wear to the stem and the jamming of the movable core.
- the anode valve provides for the guiding means to guide the movable core during translation.
- the skid and in particular the material and the special geometry, advantageously prevents the sliding of the movable core, made of steel, on the surface of the inner casing wall, also made of steel, thus reducing friction and limiting force dissipation; consequently, with the same size of the solenoid device, it is possible to pass the valve into the open configuration under more critical temperature or power supply conditions.
- the anode valve according to the present invention enables the aforementioned reliability requirements to be met.
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Electromagnetism (AREA)
- Physics & Mathematics (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Sustainable Energy (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Power Engineering (AREA)
- Magnetically Actuated Valves (AREA)
- Fuel Cell (AREA)
- Electromagnets (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT102020000017065A IT202000017065A1 (en) | 2020-07-14 | 2020-07-14 | ANODE VALVE FOR A FUEL CELL AUTOMOTIVE SYSTEM |
PCT/IB2021/056186 WO2022013694A1 (en) | 2020-07-14 | 2021-07-09 | Anode valve for a fuel cell automotive traction system |
Publications (1)
Publication Number | Publication Date |
---|---|
EP4182586A1 true EP4182586A1 (en) | 2023-05-24 |
Family
ID=72561903
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP21752167.3A Pending EP4182586A1 (en) | 2020-07-14 | 2021-07-09 | Anode valve for a fuel cell automotive traction system |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP4182586A1 (en) |
JP (1) | JP2023538986A (en) |
IT (1) | IT202000017065A1 (en) |
WO (1) | WO2022013694A1 (en) |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2872241B1 (en) * | 2004-06-23 | 2008-02-22 | Asco Joucomatic | SOLENOID VALVE, IN PARTICULAR TO BE INSTALLED ON A LIQUID RESERVOIR UNDER GAS PRESSURE |
WO2009049625A1 (en) * | 2007-10-18 | 2009-04-23 | Danfoss A/S | A magnetic actuator and a valve comprising such an actuator |
US20150034180A1 (en) * | 2013-08-02 | 2015-02-05 | Continental Automotive Systems, Inc. | Tank pressure control solenoid with passive tank vacuum relief |
-
2020
- 2020-07-14 IT IT102020000017065A patent/IT202000017065A1/en unknown
-
2021
- 2021-07-09 EP EP21752167.3A patent/EP4182586A1/en active Pending
- 2021-07-09 JP JP2022564778A patent/JP2023538986A/en active Pending
- 2021-07-09 WO PCT/IB2021/056186 patent/WO2022013694A1/en active Search and Examination
Also Published As
Publication number | Publication date |
---|---|
WO2022013694A1 (en) | 2022-01-20 |
IT202000017065A1 (en) | 2022-01-14 |
JP2023538986A (en) | 2023-09-13 |
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