EP4182034A1 - Products for treating keratinous fibers, containing complexing agent and amino acid and/or protein hydrolysate - Google Patents
Products for treating keratinous fibers, containing complexing agent and amino acid and/or protein hydrolysateInfo
- Publication number
- EP4182034A1 EP4182034A1 EP21728233.4A EP21728233A EP4182034A1 EP 4182034 A1 EP4182034 A1 EP 4182034A1 EP 21728233 A EP21728233 A EP 21728233A EP 4182034 A1 EP4182034 A1 EP 4182034A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- agent
- acid
- agents
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- 229920001542 oligosaccharide Polymers 0.000 description 1
- 150000002482 oligosaccharides Chemical class 0.000 description 1
- 239000003605 opacifier Chemical group 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229940101267 panthenol Drugs 0.000 description 1
- SERHXTVXHNVDKA-UHFFFAOYSA-N pantolactone Chemical compound CC1(C)COC(=O)C1O SERHXTVXHNVDKA-UHFFFAOYSA-N 0.000 description 1
- 229940115458 pantolactone Drugs 0.000 description 1
- SIEVQTNTRMBCHO-UHFFFAOYSA-N pantolactone Natural products CC1(C)OC(=O)CC1O SIEVQTNTRMBCHO-UHFFFAOYSA-N 0.000 description 1
- 235000019161 pantothenic acid Nutrition 0.000 description 1
- 239000011713 pantothenic acid Substances 0.000 description 1
- 229940055726 pantothenic acid Drugs 0.000 description 1
- 235000020957 pantothenol Nutrition 0.000 description 1
- 239000011619 pantothenol Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 125000005385 peroxodisulfate group Chemical group 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical group 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 description 1
- 229940081510 piroctone olamine Drugs 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- UQDJGEHQDNVPGU-UHFFFAOYSA-N serine phosphoethanolamine Chemical compound [NH3+]CCOP([O-])(=O)OCC([NH3+])C([O-])=O UQDJGEHQDNVPGU-UHFFFAOYSA-N 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910052722 tritium Inorganic materials 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/08—Preparations for bleaching the hair
Definitions
- the present invention is in the field of cosmetics and relates to agents for the treatment of keratin fibers, in particular human hair, which are particularly suitable for lightening or bleaching the keratin fibers.
- the oxidizing agents contained in bleaching agents are able to lighten the hair fiber through the oxidative destruction of the hair's own pigment, melanin.
- the use of hydrogen peroxide - optionally with the use of ammonia or other alkalizing agents - as the oxidizing agent alone is sufficient.
- a mixture of hydrogen peroxide and peroxodisulfate salts and/or peroxomonosulfate salts is usually used to achieve a stronger bleaching effect.
- complexing agents in the case of oxidative color changes in keratin fibers is known in the prior art.
- the complexing agents should, among other things, prevent the decomposition of the hydrogen peroxide by metal ions accumulated in the hair fibers.
- EP 1714634 A1 describes a hair treatment kit for coloring human hair, comprising a first compartment containing a complexing agent and a second compartment containing agents for coloring.
- HEDP etidronic acid
- EDTA ethylenediamine tetraacetate
- Both HEDP and EDTA stabilize hydrogen peroxide in an effective manner and complex existing metal ions so efficiently that an undesirable temperature increase occurring during use is almost completely avoided.
- the major disadvantage of HEDP and EDTA is their poor biodegradability.
- users have been paying increasing attention to the ecological profile of the cosmetic products they use. The user prefers cosmetics that are as sustainable as possible with biodegradable ingredients.
- EP 1462090 A1 describes agents for bleaching, coloring or shaping hair, which contain the combination of at least one oxidizing agent and at least one polyhydroxycarboxylic acid. Even if the polyhydroxycarboxylic acids of EP 1462090 A1 are readily biodegradable, the performance properties of the agents described in this document are still in need of improvement, and the bleaching performance in particular cannot yet be regarded as optimal.
- the object of the present invention to find bleaching agents with biodegradable complexing agents which, with regard to their bleaching performance, are superior to the bleaching or lightening agents known from the prior art. Furthermore, the bleaching agents should have a sufficiently high stability and should not heat up too much even when used on hair with a higher metal or heavy metal content. In addition, hair damage should be reduced when using the complexing agents in lightening or bleaching agents.
- an agent is used on the keratin fibers which, in addition to at least one special complexing agent (a) of the formula (I), also contains at least one amino acid and/or a protein hydrolyzate ( b) contains.
- a first subject matter of the present invention is a composition for treating keratin fibers, in particular human hair
- n is an integer from 1 to 6
- X1, X2 independently represent a hydrogen atom or an equivalent of an alkali, alkaline earth or metal ion, preferably sodium, potassium, 1 magnesium, 14 calcium, 14 zinc, or an ammonium ion (NhV), and (b) at least one Amino acid and/or a protein hydrolyzate.
- Keratin fibers or keratin fibers are to be understood as meaning fur, wool, feathers and, in particular, human hair. Although the agents are primarily suitable for treating or lightening keratin fibers, in principle there is nothing to prevent them from being used in other areas as well.
- treatment of keratin fibers includes in principle every possible form of treatment, i.e. shampoos, conditioners and styling agents as well as colorants, bleaching agents and permanent wave agents.
- the combination of ingredients (a) and (b) shows particularly good suitability in agents for lightening the keratin fibers.
- a lightening is to be understood as meaning any form of color change in the fibers in which the keratin fibers have a lighter color compared to the color present before the application of the agent.
- the color changes covered by the terms lightening, bleaching and bleaching are included.
- the hair is lightened by at least one oxidizing agent present in the composition.
- the agents according to the invention can also contain coloring components, such as oxidation dye precursors and/or substantive dyes, for the purpose of shading.
- the coloring components can be used to slightly modify the color of the resulting coloring.
- these coloring components are preferably present in the agent in such small amounts that the color impression of the keratin fibers treated with the agent is nevertheless lighter than their original color.
- Corresponding coloring techniques can be referred to as coloring bleaching or as nuanced bleaching.
- the agent contains the components (a) and (b) essential to the invention, preferably in a cosmetic carrier.
- a suitable aqueous, alcoholic or aqueous-alcoholic carrier can be used as a cosmetic carrier for the agent.
- a cosmetic carrier for the agent.
- such carriers are, for example, creams, emulsions, gels, pastes or foaming solutions containing surfactants, such as shampoos, foam aerosols, foam formulations or other preparations which are suitable for use on the hair.
- a composition for lightening keratinic fibers, in particular human hair, contained in a cosmetic carrier is therefore particularly preferred
- n is an integer from 1 to 6
- X1, X2 independently represent a hydrogen atom or an equivalent of an alkali, alkaline earth or metal ion, preferably sodium, potassium, magnesium, calcium, zinc, or an ammonium ion (NH 4 + ), and
- This agent according to the invention is a ready-to-use agent that can be applied in this form to the keratin fibers for the purpose of bleaching or lightening.
- the agent according to the invention contains at least one complexing agent (a) of the general formula (I),
- n is an integer from 1 to 6
- X1, X2 independently represent a hydrogen atom or an equivalent of an alkali, alkaline earth or metal ion, preferably sodium, potassium, magnesium, calcium, zinc, or an ammonium ion (NH 4 + ).
- the complexing agents of the formula (I) are described as being biodegradable and therefore represent an ecologically advantageous replacement for HEDP and EDTA in bleaching or lightening agents, the bleaching performance could also be greatly improved.
- the complexing agents of the formula (I) are alkane diacids which—depending on the number of structural units (CHOH) present in the middle part of the molecule—are substituted with one to six hydroxy groups.
- the number of structural units (CHOH) is given by the index number n, which stands for an integer from 1 to 6.
- n can stand for the numbers 1, 2, 3, 4, 5 or 6. However, a particularly strong improvement in bleaching performance was observed when n is an integer from 2 to 5, preferably an integer from 3 to 4 and very particularly preferably the number 4.
- an agent according to the invention is characterized in that it contains at least one complexing agent (a) of the general formula (I), where n is an integer from 2 to 5, preferably an integer from 3 to 4 and very particularly preferably the number 4.
- the radicals X1 and X2 independently represent a hydrogen atom or an equivalent of an alkali metal, alkaline earth metal or metal ion, preferably sodium, potassium, 1 magnesium, 14 calcium, 14 zinc, or an ammonium ion (NH 4 + ).
- the compound of formula (I) is in the form of its sodium salt, NaOOC-(CHOH) n -COONa.
- the compound of formula (I) is in the form of its potassium salt KOOC-(CHOH) n -COOK.
- the compound of formula (I) is in the form of its ammonium salt, (NH4)OOC-(CHOH) n -COO(NH4).
- radicals X1 and X2 can stand for different radicals from the group consisting of a hydrogen atom or the corresponding equivalent of an alkali metal, alkaline earth metal or metal ion.
- the complexing agents of the formula (I) can have one or more stereogenic centers. Both the D forms of the compounds and their L forms and mixtures thereof are encompassed by the present compound. The meso forms are also covered by the invention.
- an agent according to the invention is characterized in that it contains at least one complexing agent (a) of the general formula (I), which is selected from the group consisting of galactaric acid, glucaric acid, mannoic acid, altraric acid, idaric acid, talaric acid, gularic acid, allaric acid and its salts.
- the above compounds belong to the group of aldar acids, i.e. acids derived from sugars that carry two carboxy groups.
- galactaric acid is also referred to as mucic acid or mucic acid and is one of the polyhydroxy dicarboxylic acids.
- Other alternative names for galactaric acid are (2R,3S,4R,5S)-2,3,4,5-tetrahydroxyadipic acid, (2R,3S,4R,5S)-2,3,4,5-tetrahydroxyhexane-1,6-dioic acid , D-galactaric acid (IUPAC). It belongs to the sugar dicarboxylic acids (aldar acids). It shows no optical activity and has the CAS number 526-99-8.
- Galactaric acid can be purchased commercially, for example, in the form of the raw material Muciliance® Fruit; this raw material is galactaric acid or mucaric acid in powder form and is sold by the Givaudan company. Furthermore, galactaric acid can also be purchased commercially from fine chemical suppliers such as Sigma Aldrich or Merck.
- glucaric acid may also be referred to as D-glucaric acid or and is a polyhydroxy dicarboxylic acid.
- Other alternative names for glucaric acid are (2S,3S,4S,5R)-2,3,4,5-tetrahydroxyhexane-1,6-dioic acid and (2S,3S,4S,5R)-2,3,4,5-tetrahydroxyadipic acid .
- Glucaric acid has the CAS number 87-73-0.
- mannonic acid can also be referred to as D-mannonic acid or as (2S,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexane-1,6-dioic acid.
- an agent according to the invention is characterized in that it contains (a) galactaric acid.
- the performance properties of the agents according to the invention can be further optimized. If the combination of (a) and (b) is used in a composition for lightening keratin fibers, the lightening performance can be further improved by choosing suitable ranges of amounts. It is therefore particularly preferred if the agent - based on its total weight - contains one or more complexing agents (a) of the formula (I) in a total amount of from 0.01 to 10.0% by weight, preferably from 0.05 to 5 0.0% by weight, more preferably from 0.1 to 2.0% by weight and most preferably from 0.15 to 0.5% by weight.
- a composition according to the invention is characterized in that it contains one or more complexing agents (a) of the formula (I) in a total amount of from 0.01 to 10.0% by weight, based on the total weight of the composition. , preferably from 0.05 to 5.0% by weight, more preferably from 0.1 to 2.0% by weight and very particularly preferably from 0.15 to 0.5% by weight.
- the middle according to the invention contains at least one amino acid and/or a protein hydrolyzate (b) as the second essential component of the invention.
- An amino acid means a chemical compound with an amino group and a carboxylic acid group.
- the class of amino acids includes organic compounds that contain at least one amino group (-NH2 or substituted -NR2) and one carboxy group (-COOH) as functional groups, i.e. have structural features of amines and carboxylic acids. Chemically, they can be distinguished according to the position of their amino group in relation to the carboxy group - if the amino group on the C a atom is immediately adjacent to the terminal carboxy group, this is called the a position and is referred to as a-amino acids. Preference is given to using carboxylic acids having a total number of carbon atoms from C2-C20, more preferably from C2-C15, particularly preferably from C2-C10.
- an agent according to the invention is characterized in that it contains at least one amino acid (b) from the group consisting of lysine, arginine, histidine, asparagine, glutamine, cysteine, methionine, tryptophan, serine, alanine, aspartic acid, glutamic acid, glycine, Contains isoleucine, leucine, phenylalanine, proline, threonine, tyrosine and valine.
- amino acid (b) from the group consisting of lysine, arginine, histidine, asparagine, glutamine, cysteine, methionine, tryptophan, serine, alanine, aspartic acid, glutamic acid, glycine, Contains isoleucine, leucine, phenylalanine, proline, threonine, tyrosine and valine.
- Preferred amino acids are selected from lysine, arginine, histidine, asparagine, glutamine, cysteine, methionine, tryptophan, serine, alanine, aspartic acid, glutamic acid, glycine, isoleucine, leucine, phenylalanine, proline, threonine, tyrosine and valine and mixtures of these amino acids.
- Bleaching agents containing valine, glycine, serine and/or glutamic acid as amino acids also showed improved bleaching performance.
- Chiral amino acids have a sterogenic center and can exist in mirror-image forms.
- arginine occurs in the form of L-arginine and D-arginine. Both the L-form of an amino acid and its D-form and mixtures thereof are encompassed by the present invention. Accordingly, within the scope of the present invention, both possible enantiomers can be used equally as a specific compound or mixtures thereof, in particular as racemates. However, it is particularly advantageous to use the naturally occurring isomer form, usually in the L configuration.
- the amino acid(s) (b) are preferably used in specific quantity ranges. It has proven to be particularly advantageous if the agent - based on its total weight - contains one or more amino acids (b) in a total amount of 0.1 to 10.0% by weight, preferably 0.2 to 5.0% by weight. -% contains, more preferably from 0.3 to 2.5% by weight and very particularly preferably from 0.4 to 1.0% by weight.
- an agent according to the invention is characterized in that it contains one or more amino acids (b) in a total amount of from 0.1 to 10.0% by weight, preferably 0, based on the total weight of the agent. 2 to 5.0% by weight, more preferably from 0.3 to 2.5% by weight and very particularly preferably from 0.4 to 1.0% by weight.
- protein hydrolyzates are degradation products of proteins which are produced by acidic, basic or enzymatic reactions. Due to the manufacturing process, protein hydrolysates have a distribution of molecular weights. To those according to the invention Protein hydrolyzates also include oligopeptides, since these can also be produced from proteins by appropriate reactions. According to the invention, individual amino acids which are present as discrete individual compounds are not among the protein hydrolyzates in the context of this invention. According to the invention, protein hydrolyzates of both plant and animal or marine or synthetic origin can be used.
- protein hydrolyzates are understood to mean at most oligomeric compounds composed of a maximum of 10 amino acids.
- Animal protein hydrolysates are, for example, elastin, collagen, keratin, silk and milk protein hydrolysates, which can also be present in the form of salts.
- Such products are sold, for example, under the trademarks Dehylan ® (Cognis), Promois ® (Interorgana), Collapuron ® (Cognis), Nutrilan ® (Cognis), Gelita-Sol ® (Deutsche Gelatine Fabriken Stoess & Co), Lexein ® (Index), ProSina ® (Croda) and kerasol tm ® (Croda) sold.
- vegetable protein hydrolysates which are preferred according to the invention are, for example, soybean, almond, pea, moringa, potato and wheat protein hydrolysates.
- Such products are, for example, under the trademarks Gluadin ® (Cognis), diamine ® (Diamalt) ® (Index) Hydrosoy ® (Croda), hydro Lupine ® (Croda), hydro Sesame ® (Croda), Hydro tritium ® (Croda), Crotein ® (Croda) and Puricare ® LS 9658 from Laboratoires Serobi unanimouss.
- Further protein hydrolyzates preferred according to the invention are of maritime origin. These include, for example, collagen hydrolysates from fish or algae and protein hydrolysates from mussels or pearl hydrolysates.
- pearl extracts according to the invention are the commercial products Pearl Protein Extract BG ® or Crodarom ® Pearl.
- cationized protein hydrolyzates are among the protein hydrolyzates, the underlying protein hydrolyzate from animals, for example from collagen, milk or keratin, from plants, for example from wheat, corn, rice, potatoes, soybeans or almonds, from marine life forms, for example from fish collagen or algae, or biotechnologically obtained protein hydrolyzates.
- inventive cationic protein hydrolysates and derivatives are under the INCI - th names in the "International Cosmetic Ingredient Dictionary and Handbook" (seventh edition 1997, The Cosmetic, Toiletry, and Fragrance Association 1101 17 Street, NW, Suite 300 , Washington, DC 20036-4702) and commercially available products.
- preparation (B) contained at least one protein hydrolyzate selected from elastin hydrolyzates, collagen hydrolyzates, of keratin, silk, milk protein, as well as soy, almond, pea, moringa, potato and wheat protein hydrolysates.
- an agent according to the invention is characterized in that it contains at least one protein hydrolyzate (b) selected from the group consisting of protein hydrolyzates of elastin, collagen, keratin, silk, milk protein, soybean, Almond, Pea, Moringa, Potato and Wheat Protein Hydrolysates.
- b protein hydrolyzate
- the protein hydrolyzates (b) are preferably used in specific quantity ranges. It has turned out to be particularly advantageous if the agent contains one or more protein hydrolyzates (c) in a total amount of 0.1 to 10.0% by weight, preferably 0.2 to 5.0% by weight preferably from 0.3 to 2.5% by weight and very particularly preferably from 0.4 to 1.0% by weight.
- an agent according to the invention is characterized in that it - based on its total weight - one or more protein hydrolyzates (c) in a total amount of 0.1 to 10.0 wt .-%, preferably 0.2 to 5.0% by weight, more preferably from 0.3 to 2.5% by weight and very particularly preferably from 0.4 to 1.0% by weight.
- Protein hydrolyzates according to the invention are also oligopeptides. Oligopeptides can be preferred in the hair treatment agents according to the invention because of their defined amino acid sequence.
- an oligopeptide having at least one amino acid sequence Glu-Glu-Glu has, where the amino group can be free or protonated and the carboxy groups can be free or deprotonated, can be particularly preferred according to the invention.
- the bracketed hydrogen atom of the amino group as well as the bracketed hydroxy group of the acid function means that the relevant groups can be present as such (then it is an oligopeptide with the relevant number of amino acids as in the above formula, or that the amino acid sequence in an oligopeptide is present which comprises further amino acids - depending on where the further amino acid(s) is/are bound, the components in brackets of the above formula are replaced by the further amino acid residue(s).
- oligopeptides are condensation products of amino acids linked by peptide bonds in the manner of acid amides, which comprise at least 3 and at most 25 amino acids.
- the oligopeptide comprises 5 to 15 amino acids, preferably 6 to 13 amino acids, particularly preferably 7 to 12 amino acids and in particular 8, 9 or 10 amino acids.
- the molar mass of the oligopeptide contained in the agents according to the invention can vary.
- Hair treatment agents preferred according to the invention are characterized in that the oligopeptide has a molar mass of 650 to 3000 Da, preferably 750 to 2500 Da, particularly preferably 850 to 2000 Da and in particular 1000 to 1600 Da.
- oligopeptides are preferably used which do not consist solely of the three glutamic acids but also have other amino acids bound to this sequence. These further amino acids are preferably selected from certain amino acids, while certain other representatives are less preferred according to the invention.
- a particularly preferred oligopeptide additionally contains tyrosine, which is preferably linked to the Glu-Glu-Glu sequence via its acid function.
- Hair treatment agents which are preferred according to the invention are therefore characterized in that the oligopeptide contained in them contains at least one amino acid sequence Tyr-Glu-Glu-Glu has, wherein the amino group can be free or protonated and the carboxy groups can be free or deprotonated.
- Another particularly preferred oligopeptide additionally contains isoleucine, which is preferably bound to the Glu-Glu-Glu sequence via its amino function.
- Hair treatment agents which are preferred according to the invention are therefore characterized in that the oligopeptide contained in them has at least one amino acid sequence Glu-Glu-Glu-Ile has, wherein the amino group can be free or protonated and the carboxy groups can be free or deprotonated.
- oligopeptides which contain both of the aforementioned amino acids (tyrosine and isoleucine).
- Hair treatment agents according to the invention in which the oligopeptide contained in them has at least one amino acid sequence Tyr-Glu-Glu-Glu-Ile has, wherein the amino group can be free or protonated and the carboxy groups can be free or deprotonated.
- oligopeptides additionally contain arginine, which is preferably present bound to isoleucine
- oligopeptides additionally contain valine, which is preferably bound to the arginine.
- Hair treatment agents that are further preferred according to the invention are therefore characterized in that the oligopeptide contained in them contains at least one amino acid sequence Tyr-Glu-Glu-Glu-Glu-Ile-Arg-Val has, wherein the amino
- oligopeptides can be free or protonated and the carboxy groups can be free or deprotonated. Even more preferred oligopeptides additionally contain leucine, which is preferably bound to the valine. Hair treatment agents which are further preferred according to the invention are characterized in that the oligopeptide contained in them contains at least one amino acid sequence Tyr- Glu-Glu-Glu-Ile-Arg-Val-Leu where the amino groups can be free or protonated and the carboxy groups can be free or deprotonated.
- Particularly preferred oligopeptides additionally contain leucine, which is preferably present bound to the tyrosine.
- Hair treatment agents which are further preferred according to the invention are characterized in that the oligopeptide contained in them contains at least one amino acid sequence Leu-Tyr-Glu-Glu-Glu-Ile-Arg-Val-Leu has, wherein the amino groups can be free or protonated and the carboxy groups can be free or deprotonated.
- the weight ratio of all complexing agents (a) of the formula (I) contained in the agent to all compounds from the group of amino acids and protein hydrolyzates (b) contained in the agent i.e. the Weight ratio (a)/(b), at a value from 0.1 to 10, preferably from 0.2 to 5, more preferably from 0.25 to 4.0, and very particularly preferably from 0.3 to 1.0 located.
- a composition according to the invention is characterized in that the weight ratio of all complexing agents (a) contained in the composition to all compounds from the group of amino acids and protein hydrolyzates (b) contained in the composition, ie the weight ratio (a)/(b ), at a value from 0.1 to 10, preferably from 0.2 to 5, more preferably from 0.25 to 4.0, and very particularly preferably from 0.3 to 1.0.
- a composition according to the invention is characterized in that the weight ratio of all complexing agents (a) contained in the composition to all compounds from the group of amino acids (b) contained in the composition, ie the weight ratio (a)/(b), is from 0.1 to 10, preferably from 0.2 to 5, more preferably from 0.25 to 4.0, and very particularly preferably from 0.3 to 1.0.
- composition for lightening keratin fibers with oxidizing agent (c)
- ingredients (a) and (b) shows its potential particularly when used in agents for lightening or bleaching hair.
- hydrogen peroxide is the oxidizing agent of choice.
- bleaching and bleaching agents preferred agents are further characterized in that they contain hydrogen peroxide and/or one of its solid adducts with organic or inorganic compounds.
- hydrogen peroxide is used together with stronger oxidizing agents such as persulphates (sodium persulphate, potassium persulphate or ammonium persulphate).
- an agent according to the invention is characterized in that it
- (c) contains at least one oxidizing agent from the group consisting of hydrogen peroxide, ammonium peroxodisulphate, potassium peroxodisulphate and sodium peroxodisulphate.
- composition for lightening keratinic fibers, in particular human hair, contained in a cosmetic carrier is therefore particularly preferred
- X1, X2 independently represent a hydrogen atom or an equivalent of an alkali, alkaline earth or metal ion, preferably sodium, potassium, 1 magnesium, 14 calcium, 14 zinc, or an ammonium ion (NH 4 + ), and
- At least one oxidizing agent from the group consisting of hydrogen peroxide, ammonium peroxodisulphate, potassium peroxodisulphate and sodium peroxodisulphate.
- Ammonium peroxodisulfate which can alternatively also be referred to as ammonium persulfate, is understood as meaning the persulfate with the empirical formula (NH 4 ) 2 S 2 O 8 .
- Potassium peroxodisulfate which can alternatively also be referred to as potassium persulfate, means the persulfate with the molecular formula K2S2O8.
- Sodium peroxodisulfate which can alternatively also be referred to as sodium persulfate, is understood as meaning the persulfate with the molecular formula Na 2 S 2 Os.
- an agent according to the invention is characterized in that it contains (c1) hydrogen peroxide and
- (c2) at least one persulphate from the group consisting of ammonium persulphate, potassium persulphate and sodium persulphate.
- hydrogen peroxide itself is used as an aqueous solution.
- concentration of a hydrogen peroxide solution in the agent according to the invention is determined on the one hand by the legal requirements and on the other hand by the desired effect; preferably 3 to 12% by weight solutions in water are used.
- Agents preferred according to the invention of the first subject matter of the invention are characterized in that, based on the total weight of the agent, they contain (a) 0.1 to 12.0% by weight, preferably 0.5 to 10.5% by weight, more preferably 1 0 to 8.5% by weight, more preferably from 1.5 to 7.0% by weight and very particularly preferably 1.5 to 6.0% by weight, of hydrogen peroxide.
- a composition according to the invention is characterized in that it contains (c) 0.1 to 12.0% by weight, preferably 0.5 to 10.5% by weight, based on the total weight of the composition preferably 1.0 to 8.5% by weight, even more preferably from 1.5 to 7.0% by weight and very particularly preferably 1.5 to 6.0% by weight hydrogen peroxide.
- the persulfate or persulfates are also preferably used in specific quantity ranges in the agent according to the invention. It turned out to be preferable if the means - based on the total weight of the agent - (c) one or more persulfates from the group consisting of ammonium peroxodisulfate, potassium peroxodisulfate and sodium peroxodisulfate in a total amount of 2.0 to 40.0% by weight, preferably 4.0 to 30.0% by weight. -%, more preferably from 6.0 to 20.0% by weight and most preferably from 8.0 to 15.0% by weight.
- an agent according to the invention is characterized in that - based on the total weight of the agent - (c) one or more persulfates from the group consisting of ammonium peroxodisulfate, potassium peroxodisulfate and sodium peroxodisulfate in a total amount of 2.0 to 40.0 % by weight, preferably from 4.0 to 30.0% by weight, more preferably from 6.0 to 20.0% by weight and very particularly from 8.0 to 15.0% by weight.
- a composition for lightening keratinic fibers, in particular human hair, contained in a cosmetic carrier is therefore particularly preferred
- n is an integer from 1 to 6
- X1, X2 independently represent a hydrogen atom or an equivalent of an alkali, alkaline earth or metal ion, preferably sodium, potassium, 1 magnesium, 14 calcium, 14 zinc, or an ammonium ion (NH 4 + ), and
- (c2) at least one persulphate from the group consisting of ammonium persulphate, potassium persulphate and sodium persulphate.
- the agent according to the first subject matter of the invention is a ready-to-use agent for lightening or bleaching keratin fibers.
- such agents are usually made highly alkaline, with the pH preferably being between 9 and 10.5.
- Such high pH values are necessary in order to ensure that the outer cuticle layer (cuticle) opens and thus allows penetration of the active species (hydrogen peroxide and persulphates) into the hair.
- the agent according to the invention additionally contains at least one alkalizing agent.
- an agent according to the invention is characterized in that it contains at least one alkalizing agent.
- Preferred alkalizing agents are, for example, ammonia, alkanolamines, basic amino acids, and inorganic alkalizing agents such as (earth) alkali metal hydroxides (earth) - alkali metal metasilicates (earth) alkali metal silicates (earth) alkali metal phosphates and (earth) - alkali metal hydrogen phosphates.
- Lithium, sodium and/or potassium preferably serve as metal ions.
- Preferred alkalizing agents are (earth) alkali metal metasilicates and (earth) alkali metal silicates.
- Suitable inorganic alkalizing agents are preferably selected from sodium hydroxide, potassium hydroxide, calcium hydroxide, barium hydroxide, sodium phosphate, potassium phosphate, sodium silicate, potassium silicate, magnesium silicate, sodium carbonate and potassium carbonate.
- Sodium hydroxide and/or potassium hydroxide are particularly preferred.
- Alkanolamines used as alkalizing agents are preferably selected from primary, secondary or tertiary amines with a C2-C6-alkyl skeleton which carries at least one hydroxyl group.
- Particularly preferred alkanolamines are selected from the group formed from 2-aminoethan-1-ol (monoethanolamine), 3-aminopropan-1-ol, 4-aminobutan-1-ol, 5-aminopentan-1-ol, 1 -aminopropan-2-ol (monoisopropanolamine), 1-aminobutan-2-ol, 1-aminopentan-2-ol, 1-aminopentan-3-ol, 1-aminopentan-4-ol, 2-amino-2-methyl- propanol, 2-amino-2-methylbutanol, 3-amino-2-methylpropan-1-ol, 1-amino-2-methylpropan-2-ol, 3-aminopropan-1,2-diol
- Basic amino acids as alkalizing agents are preferably selected from the group consisting of L-arginine, D-arginine, D/L-arginine, L-lysine, D-lysine, D/L-lysine, L-ornithine, D-ornithine , D/L-ornithine, L-histidine, D-histidine and/or D/L-histidine.
- L-arginine, D-arginine and/or D/L-arginine are particularly preferably used as an alkalizing agent.
- the agents according to the invention preferably contain these two complexing agents in particularly small amounts.
- the agents are very particularly preferably free of these two substances.
- the agent is also essentially free of the salts of HEDP and EDTA.
- an agent according to the invention is characterized in that - based on the total weight of the agent - the total content of the etidronic acid and the salts of etidronic acid contained in the agent is below 0.2% by weight, preferably below 0.1% by weight %, more preferably below 0.05% by weight and very particularly preferably below 0.001% by weight.
- an agent according to the invention is characterized in that - based on the total weight of the agent - the total content of the EDTA contained in the agent and the salts of EDTA is less than 0.2% by weight, preferably less than 0.1% by weight %, more preferably below 0.05% by weight and very particularly preferably below 0.001% by weight
- Etidronic acid is alternatively also referred to as hydroxyethane-1,1-diphosphonic acid and has the CAS number 2809-21-4.
- EDTA is alternatively referred to as ethylenediamine tetraacetate and has CAS numbers 6381-92-6 and 139-33-3 (anhydrous).
- the agent according to the invention can also contain other active ingredients and auxiliaries as optional ingredients. These are described below.
- the agents can also contain other active ingredients, auxiliaries and additives, such as solvents, fatty components such as Cs-Cso fatty alcohols, C8-C30 fatty acid triglycerides, C8-C30 fatty acid monoglycerides, C8-C30 fatty acid diglycerides and/or hydrocarbons; nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric and/or zwitterionic surfactants, polymers; structurants such as glucose, maleic acid and lactic acid, hair conditioning compounds such as phospholipids, e.g.
- auxiliaries and additives such as solvents, fatty components such as Cs-Cso fatty alcohols, C8-C30 fatty acid triglycerides, C8-C30 fatty acid monoglycerides, C8-C30 fatty acid diglycerides and/or hydrocarbons; nonionic surfactants, anionic surfactants, cationic surfactants, ampho
- lecithin and cephalins perfume oils, dimethylisosorbide and cyclodextrins; fiber structure-improving active ingredients, in particular mono-, di- and oligosaccharides such as glucose, galactose, fructose, fructose and lactose; dyes for coloring the agent; anti-dandruff agents such as Piroctone Olamine, Zinc Omadine and Climbazole; amino acids and oligopeptides; Protein hydrolyzates based on animals and/or plants, and in the form of their fatty acid condensation products or optionally anionically or cationically modified derivatives; vegetable oils; sunscreens and UV blockers; Active ingredients such as panthenol, pantothenic acid, pantolactone, allantoin, pyrrolidinone carboxylic acids and their salts, and bisabolol; Polyphenols, in particular hydroxycinnamic acids, 6,7-dihydroxycoumarins, hydroxybenzoic acids, plant extracts; fat
- the person skilled in the art will select these further substances in accordance with the desired properties of the agents. With regard to other optional components and the amounts of these components used, express reference is made to the relevant handbooks known to those skilled in the art.
- the additional active ingredients and auxiliaries are preferably used in the preparations according to the invention in amounts of 0.0001 to 25% by weight, in particular 0.0005 to 15% by weight, based on the total weight of the respective composition.
- the agent of the first subject matter of the invention is an agent for treating keratin fibers.
- the agent is very particularly preferably a lightening or bleaching agent.
- Bleaching agent is a ready-to-use agent.
- the agents can be used in a method for treating, in particular for lightening, the keratin fibers.
- a second subject of the present invention is a method for treating keratin fibers, in which an agent, as disclosed in detail in the description of the first subject of the invention, is applied to the keratin fibers and rinsed out again after an exposure time.
- the method is characterized in that it is a method for lightening keratin fibers.
- Oxidizing agents such as hydrogen oxide and persulfates are highly reactive compounds that have only limited stability, especially in an alkaline environment. For this reason, the ready-to-use bleaching agent is usually produced shortly before use by mixing two or more separately packaged preparations.
- the oxidizing agent (a) and the alkalizing agent are usually made up separately from one another.
- Various types of packaging are now conceivable for the complexing agent (a) and the amino acid and/or a protein hydrolyzate (b).
- complexing agent (a) and amino acid/protein hydrolyzate (b) can be formulated together with one or more persulfates and separately from the hydrogen peroxide. This embodiment is particularly preferred when only two different preparations are to be mixed together to produce the ready-to-use agent.
- a method for lightening keratin fibers characterized in that at least two separately packaged preparations (A) and (B) are mixed to form an application mixture, which is applied to the fibers and rinsed off again after an exposure time, wherein
- the preparation (A) contains hydrogen peroxide (c1), and
- persulfate (c2) from the group consisting of ammonium peroxodisulfate, potassium peroxodisulfate and sodium peroxodisulfate, the complexing agent (a) and the amino acid/protein hydrolyzate (b) having already been disclosed in detail in the description of the first subject of the invention.
- the preparations (A) and (B) can be mixed either with each other or with other separately packaged preparations immediately before use to form an application mixture.
- first oxidizing agent hydrogen peroxide separately in a first preparation (A)
- second preparation B
- third preparation C which comprises complexing agent (a) and amino acid/protein hydrolyzate (b).
- a method for lightening keratinic fibers is characterized in that at least three separately packaged preparations (A) and (B) and (C) are mixed to form an application mixture, which is applied to the fibers and rinsed off again after an exposure time will, where
- the preparation (A) contains hydrogen peroxide (c1), and
- the preparation (B) contains at least one persulfate (c2) from the group consisting of ammonium peroxodisulfate, potassium peroxodisulfate and sodium peroxodisulfate, and
- the preparation (C) contains at least one complexing agent (a) of the general formula (I) and contains at least one amino acid and/or a protein hydrolyzate (b), wherein the complexing agent (a) and the amino acid/protein hydrolyzate (b) have already been disclosed in detail in the description of the first subject of the invention.
- the preparations (B) containing the persulfates are preferably in powder form. Powders made from solid components with different particle sizes can be used here. However, it can usually be preferred if the powders have a particle size which is as homogeneous as possible, in particular in order to facilitate uniform dispersion or dissolution of the powders in the preparations (B).
- the preparations (B) can also contain the persulfates in a solid cosmetic carrier.
- a solid cosmetic carrier can contain salts of silicic acid, in particular salts of silicates and metasilicates with ammonium, alkali metals and alkaline earth metals.
- metasilicates which are characterized according to formula (Si0 2 ) n (M 2 0) m , where M is an ammonium ion, an alkali metal or a half stoichiometry equivalent of an alkaline earth metal, by the ratio between n and m of ⁇ 1 and as chain-like polymeric structures of the anion [SiC>3] 2 can be used with preference.
- Sodium metasilicate of the formula [Na 2 SiO 3 ]- is particularly preferred.
- silicates which are formed from a silicate of the formula (Si0 2 )n(Na 2 0) m (K 2 0) P , where n is a positive rational number and m and p are independently positive rational numbers or 0, with the proviso that at least one of m or p is different from 0 and the ratio of n to the sum of m and p is between 2:1 and 4:1.
- the solid preparations (B) can contain so-called flow aids, which are intended to prevent the powder components from clumping or caking.
- flow aids are preferably water-insoluble, hydrophobic or moisture-absorbing powders of kieselguhr, pyrogenic silica, calcium phosphate, calcium silicates, aluminum oxide, magnesium oxide, magnesium carbonate, zinc oxide, stearates, fatty amines and the like.
- preparations (B) can additionally contain a dedusting agent, which prevents the formation of dust from the pulverulent components.
- a dedusting agent which prevents the formation of dust from the pulverulent components.
- inert oils can be used for this purpose.
- the solid cosmetic carriers preferably contain ester oils or mineral oils, preferably hydrocarbon oils, such as liquid paraffin oil, as dust-removing agents.
- the ready-to-use agents are prepared immediately before use on the hair by mixing the two preparations (A) and (B) or by mixing the three preparations (A) and (B) and (C).
- ready-to-use agents that are mixed from more than two preparations to form a ready-to-use mixture, it may be irrelevant whether two preparations are first mixed together and then the third preparation is added and mixed in, or whether all preparations are combined together and then mixed.
- Mixing can be accomplished by stirring in a bowl or beaker, or by shaking in a sealable container.
- immediately is to be understood as a period of a few seconds to an hour, preferably up to 30 minutes, in particular up to 15 minutes.
- the preparations (A), (B) and optionally (C) are used in a method for lightening keratin fibers, in particular human hair, in which the agent is applied to the keratin-containing fibers for an exposure time of 10 to 60 minutes on the Leave the fiber and then rinse it out with water or wash it out with a shampoo.
- the exposure time of the ready-to-use lightening agent is preferably 10 to 60 minutes, in particular 15 to 50 minutes, particularly preferably 20 to 45 minutes. While the agent is acting on the fiber, it can be advantageous to support the lightening process by applying little heat.
- the heat can be supplied by an external heat source, such as with the aid of a warm air blower, and also, particularly in the case of hair lightening on living subjects, by the subject's body temperature. With the latter option, the area to be lightened is usually covered with a hood. An exposure phase at room temperature is preferred.
- the remaining lightening preparation is rinsed out of the hair with water or a cleaning agent.
- commercial shampoo can be used as the cleaning agent, in which case the cleaning agent can be dispensed with and the rinsing process can be carried out with tap water if the lightening agent has a carrier with a high surfactant content.
- Hair tresses were colorimetrically measured (Datacolor Spectraflash SF 450), preshampooed and dried.
- the previously prepared, ready-to-use bleaching agents were applied to the strands of hair, left there for 45 minutes and then rinsed out again with water.
- the hair tresses were then measured colorimetrically again.
- Each formulation was colored on two tresses of hair and these were measured. The average value was calculated from the measured values.
- the bleaching performance is the better, the higher the DE value and in particular the AL value.
- Strands with a high metal content were used to measure the temperatures occurring during bleaching. To produce this hair, strands of hair were treated as follows: strands of hair (Kerling, European natural hair white, 6-0) were pre-shampooed and then pre-bleached once with a commercially available bleaching agent. The pre-bleaching was done to increase the copper uptake in the hair. The pre-bleached strand was doped with copper:
- 1 g strand was dipped into 40 g of a copper solution (50 ppm copper in water, 16.8° dH) and left there for 1 minute. Then the tress was taken out of the solution, squeezed out slightly and dried at room temperature. This dipping process was repeated three times for each tress.
- a copper solution 50 ppm copper in water, 16.8° dH
- the copper content of each strand of hair was determined analytically. The determination was made after mineralization of the sample (one strand each) in the microwave digestion system HN03/HCL by atomic emission spectrometry (ICP-OES). The average was formed from 12 measurements. The average copper content of each strand of hair was 3900 mg/kg.
- the previously prepared, ready-to-use bleaching agents 1 to 8 were applied to the hair treated in this way.
- the strands were fitted with a Pt100 sensor and wrapped in aluminum foil.
- the reaction temperature was measured and documented every minute.
- Bleaching agents which are produced by mixing three preparations (A), (Bf and (Q).
- preparation (A) were mixed with 20 g of preparation (B) and 60 g each of preparations (C1) to (C10).
- a ready-to-use bleaching agent was produced by mixing preparation (A) with one of each of preparations (B1) to (B8).
- a ready-to-use bleaching agent was produced by mixing preparation (A) with one of each of preparations (B1) to (B4).
- Preparation (A) was mixed with preparation (B) in a ratio of 1:1 in each case.
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Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DE102020209041.6A DE102020209041A1 (en) | 2020-07-20 | 2020-07-20 | "Means for the treatment of keratin fibers with complexing agent and amino acid and/or protein hydrolyzate" |
PCT/EP2021/064042 WO2022017665A1 (en) | 2020-07-20 | 2021-05-26 | Products for treating keratinous fibers, containing complexing agent and amino acid and/or protein hydrolysate |
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EP4182034A1 true EP4182034A1 (en) | 2023-05-24 |
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EP21728233.4A Pending EP4182034A1 (en) | 2020-07-20 | 2021-05-26 | Products for treating keratinous fibers, containing complexing agent and amino acid and/or protein hydrolysate |
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EP (1) | EP4182034A1 (en) |
DE (1) | DE102020209041A1 (en) |
WO (1) | WO2022017665A1 (en) |
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FR3137278A1 (en) * | 2022-06-29 | 2024-01-05 | L'oreal | Composition comprising a peroxygen salt, a fatty substance in a particular content, an amino acid type compound and a (poly) carboxylic acid. |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
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FR2852834B1 (en) | 2003-03-25 | 2008-02-15 | Oreal | OXIDIZING COMPOSITION COMPRISING HYDROXYCARBOXYLIC ACIDS AND THEIR SALTS AS COMPLEXANTS FOR PERMANENT COLORING, DECOLORATION OR DEFORMATION OF KERATINIC FIBERS |
FR2852836B1 (en) * | 2003-03-25 | 2008-02-15 | Oreal | USE OF HYDROXYCARBOXYLIC ACIDS AND THEIR SALTS AS COMPLEXING AGENTS IN REDUCING COMPOSITIONS FOR THE PERMANENT DECOLORATION OR DEFORMATION OF KERATIN FIBERS |
FR2852828A1 (en) * | 2003-03-25 | 2004-10-01 | Oreal | COMPOSITION FOR TREATING KERATINIC MATERIALS COMPRISING A HYDROXYCARBOXYLIC ACID AND A PROTECTIVE AGENT OR CONDITIONER |
DE102005013438A1 (en) | 2005-03-21 | 2006-09-28 | Henkel Kgaa | Hair treatment kit, useful in cosmetic product e.g. hair shampoo, comprises a compartment containing a complex binder; and a color compartment for coloring the keratin fibers (preferably human hairs) |
-
2020
- 2020-07-20 DE DE102020209041.6A patent/DE102020209041A1/en not_active Withdrawn
-
2021
- 2021-05-26 EP EP21728233.4A patent/EP4182034A1/en active Pending
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DE102020209041A1 (en) | 2022-01-20 |
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