EP4153807A1 - Airbag fabrics - Google Patents
Airbag fabricsInfo
- Publication number
- EP4153807A1 EP4153807A1 EP21728640.0A EP21728640A EP4153807A1 EP 4153807 A1 EP4153807 A1 EP 4153807A1 EP 21728640 A EP21728640 A EP 21728640A EP 4153807 A1 EP4153807 A1 EP 4153807A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- woven fabric
- yarn
- fabric
- halide
- fabric according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims description 136
- 239000002759 woven fabric Substances 0.000 claims abstract description 95
- 150000004820 halides Chemical class 0.000 claims abstract description 50
- 239000004952 Polyamide Substances 0.000 claims abstract description 45
- 229920002647 polyamide Polymers 0.000 claims abstract description 45
- 239000010949 copper Substances 0.000 claims abstract description 43
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 35
- 239000011734 sodium Substances 0.000 claims abstract description 35
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 34
- 229910052802 copper Inorganic materials 0.000 claims abstract description 34
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 28
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims abstract description 9
- 235000019253 formic acid Nutrition 0.000 claims abstract description 9
- 238000009991 scouring Methods 0.000 claims description 57
- 238000000034 method Methods 0.000 claims description 39
- 238000009941 weaving Methods 0.000 claims description 30
- 230000008569 process Effects 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 230000035699 permeability Effects 0.000 claims description 17
- -1 halide salt Chemical class 0.000 claims description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 238000011282 treatment Methods 0.000 claims description 12
- 238000011068 loading method Methods 0.000 claims description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- 229910001415 sodium ion Inorganic materials 0.000 claims description 8
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 7
- 230000003068 static effect Effects 0.000 claims description 6
- 238000001223 reverse osmosis Methods 0.000 claims description 5
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 claims description 4
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Inorganic materials [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 claims description 4
- 239000010409 thin film Substances 0.000 claims description 4
- ODWXUNBKCRECNW-UHFFFAOYSA-M bromocopper(1+) Chemical compound Br[Cu+] ODWXUNBKCRECNW-UHFFFAOYSA-M 0.000 claims description 3
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 3
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims 1
- 239000000155 melt Substances 0.000 claims 1
- 238000012360 testing method Methods 0.000 description 33
- 239000000835 fiber Substances 0.000 description 10
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
- 238000010276 construction Methods 0.000 description 8
- 230000001276 controlling effect Effects 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 239000003981 vehicle Substances 0.000 description 7
- 239000005749 Copper compound Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 150000001880 copper compounds Chemical class 0.000 description 6
- 239000000314 lubricant Substances 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000001143 conditioned effect Effects 0.000 description 3
- 230000000670 limiting effect Effects 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- 239000012209 synthetic fiber Substances 0.000 description 3
- 239000013585 weight reducing agent Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- YEOCHZFPBYUXMC-UHFFFAOYSA-L copper benzoate Chemical compound [Cu+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 YEOCHZFPBYUXMC-UHFFFAOYSA-L 0.000 description 2
- GBRBMTNGQBKBQE-UHFFFAOYSA-L copper;diiodide Chemical compound I[Cu]I GBRBMTNGQBKBQE-UHFFFAOYSA-L 0.000 description 2
- 230000000875 corresponding effect Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000000921 elemental analysis Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- XBTRYWRVOBZSGM-UHFFFAOYSA-N (4-methylphenyl)methanediamine Chemical compound CC1=CC=C(C(N)N)C=C1 XBTRYWRVOBZSGM-UHFFFAOYSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- JXSRRBVHLUJJFC-UHFFFAOYSA-N 7-amino-2-methylsulfanyl-[1,2,4]triazolo[1,5-a]pyrimidine-6-carbonitrile Chemical compound N1=CC(C#N)=C(N)N2N=C(SC)N=C21 JXSRRBVHLUJJFC-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920003189 Nylon 4,6 Polymers 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- RAOSIAYCXKBGFE-UHFFFAOYSA-K [Cu+3].[O-]P([O-])([O-])=O Chemical compound [Cu+3].[O-]P([O-])([O-])=O RAOSIAYCXKBGFE-UHFFFAOYSA-K 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000004320 controlled atmosphere Methods 0.000 description 1
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 1
- CMRVDFLZXRTMTH-UHFFFAOYSA-L copper;2-carboxyphenolate Chemical compound [Cu+2].OC1=CC=CC=C1C([O-])=O.OC1=CC=CC=C1C([O-])=O CMRVDFLZXRTMTH-UHFFFAOYSA-L 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000009986 fabric formation Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000003947 neutron activation analysis Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006124 polyolefin elastomer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
- D06L1/14—De-sizing
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D1/00—Woven fabrics designed to make specified articles
- D03D1/02—Inflatable articles
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/573—Tensile strength
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
Definitions
- the present invention relates to finished woven fabrics comprising spun synthetic polyamide yarn which are suitable as improved airbag fabrics, and a method of making said fabrics.
- Inflatable airbags are a key component of vehicle safety systems and are installed in virtually every vehicle produced globally.
- inflatable airbags are made from woven fabric of nylon or polyester yarns.
- airbag fabric must meet certain tensile strength requirements and have the ability to resist the passage of air, and it is therefore desirable for airbags to have a very low air permeability.
- airbag means inflatable passive safety restraints for automobiles and many other forms of transportation, including aviation applications. In recent years, the number of airbags, and the area of coverage for these airbags within various types of vehicular cabins has increased.
- airbags for the front seating area, for side impact protection, for rear seat use, for use in headliner area inflatable curtains, and for use in inflatable seat belts or pedestrian airbags.
- airbags for the front seating area, for side impact protection, for rear seat use, for use in headliner area inflatable curtains, and for use in inflatable seat belts or pedestrian airbags.
- a woven fabric comprising spun synthetic polyamide yarn, wherein said fabric is made from polyamide yarn woven in the warp direction and weft direction wherein the polyamide yarn in the woven fabric exhibits a formic acid relative viscosity of at least 60, a halide:copper molar ratio of at least 2.0 and a sodium content of no more than 25 ppm (preferably no more than 20 ppm, preferably no more than 15 ppm, preferably no more than 10 ppm), and wherein the woven fabric exhibits a melt-through resistance at 450°C of least 2.10 seconds.
- the formic acid relative viscosity (also referred to herein as “relative viscosity”) of the scoured yarn is a key influence on the melt-through resistance of the finished fabric, and that yarns which exhibit a higher relative viscosity exhibit greater melt-through resistance.
- relative viscosity also referred to herein as “relative viscosity”
- an effective concentration of copper halide in the polymer of the fabric is desirable to maintain the effect provided by the higher relative viscosity, even though neither relative viscosity nor copper halide concentration has a measurable effect on the melting point of the fiber or fabric at the levels described herein.
- the inventors have found that, surprisingly, the molar ratio of halide to copper in the finished fabric is desirably maintained above an effective level to maintain the effect which increased polymer relative viscosity has on melt-through resistance.
- an article preferably an airbag, made from the woven fabric of the first aspect.
- a method of making the woven fabric of the first aspect comprising the steps of weaving a spun synthetic polyamide yarn and scouring said yarn before, during or after weaving such that the polyamide yarn in the woven fabric exhibits a formic acid relative viscosity of at least 60, a halide:copper molar ratio of at least 2.0 and a sodium content of no more than 25 ppm (preferably no more than 20 ppm, preferably no more than 15 ppm, preferably no more than 10 ppm).
- a fourth aspect of the present invention there is provided the use of a woven fabric according to the first aspect of the invention to improve the resistance to pinhole failure of an airbag made therefrom.
- the woven fabrics of the present invention are composed of high tenacity spun synthetic polyamide yarns.
- the yarns are made from fibers which are in the form of continuous filaments. Such filaments are formed by extrusion of molten polymer through spinnerets at high temperatures and pressures, and subsequently quenched in air, coated with spin finish lubricant, drawn between pairs of godets, lightly textured to provide enough entanglement to make a coherent yarn, and then wound up on cardboard tubes, as bobbins.
- the spin finish on the filaments facilitates the processing of yarn during its production and is subsequently removed to provide the finished woven fabric.
- Removal of the spin finish, such as lubricants or oils, as well as anti-static substances, dust, contaminants and the like, from yarn is typically effected by a scouring treatment as conventionally used in the art, for instance by rinsing or soaking with using conventional agents such as water (optionally with defined pH levels), surfactants, detergents, alkalis, sequestrants, emulsifying agents and the like.
- scouring treatments are typically effected during and/or after weaving.
- said substances may be removed in the course of the weaving process used to manufacture the woven fabric, for instance a waterjet-weaving process.
- the polyamide yarn in the woven fabric of the present invention is a scoured yarn.
- scoured yarn refers to a yarn from which spin finish or other lubricants or oils have been removed.
- the relative viscosity of the yarn is defined herein as the relative viscosity after removal of spin finish from the yarn. Removal of the spin finish may be effected prior to, during or after weaving (preferably during or after weaving).
- removal of the spin finish may be effected either by a conventional scouring process of the yarn prior to weaving or effected during weaving, and preferably during weaving, for instance in a waterjet-weaving process.
- removal of the spin finish may be effected after the yarn has been woven into the fabric.
- the relative viscosity of the yarn refers to the relative viscosity of the scoured yarn present in the finished woven fabric, which is preferably the same as the relative viscosity of the yarn supplied to the weaving process.
- At least a majority (and preferably all) of the yarn used in the warp direction of fabric is preferably formed from synthetic fiber made from a single polyamide composition.
- at least a majority (and preferably all) of the yarn used in the weft direction of fabric is preferably formed from synthetic fiber made from a single polyamide composition.
- at least a majority (and preferably all) of the yarn used in the warp direction and weft direction of fabric is formed from synthetic fiber formed from a single polyamide composition.
- a single polyamide is used in each of the warp and weft directions and preferably the same polyamide is used in both the warp and weft directions.
- Suitable polyamide fibers are preferably selected from those formed from nylon 6,6, nylon 6, nylon 6,12, nylon 7, nylon 12, nylon 4,6 or copolymers or blends thereof.
- the polyamide is nylon 6,6.
- the relative viscosity of the yarn is preferably at least 70, preferably at least 78, preferably at least 85, preferably at least 90, and typically no more than 150, typically no more than 110, typically no more than 100.
- the relative viscosity is in the range of from 60 to 110, preferably 70 to 110, preferably from 85 to 100.
- the inventors observed no evident relationship between melt-through resistance and the melting point of the polyamide in either the base yarn or the fabric.
- the positive correlation observed by the inventors between melt- though resistance and relative viscosity is surprising given that the melting point of the higher-RV polyamide yarn is effectively indistinguishable from the melting point of a corresponding lower- RV polyamide yarn over the relevant relative viscosity range.
- Polyamide yarns which exhibit such relative viscosity values may be prepared by means conventional in the art.
- relative viscosity may be increased by increasing the degree of polymerization, i.e. the molecular weight, of the polyamide as is known in the art.
- the molecular weight and relative viscosity may be increased by a solid state polymerization step, typically conducted under dry nitrogen at elevated temperature (for instance about 180°C).
- At least a majority (and preferably all) of the yarn in the warp direction is yarn having a tenacity from 6.8 to 10.1 g/den.
- at least a majority (and preferably all) of the yarn in the weft direction is yarn having a tenacity from 6.8 to 10.1 g/den.
- at least a majority (and preferably all) of the yarn in the warp and weft directions is yarn having a tenacity from 6.8 to 10.1 g/den.
- the yarn used in the present invention preferably has a linear mass density in the range from about 100 to about 2000 decitex, preferably from about 150 to about 1000 decitex, preferably from about 150 to about 940 decitex, preferably from about 150 to about 750 decitex.
- the linear mass density of fiber which constitutes the yarn is preferably in the range from about 1 to about 25 decitex per filament (DPF), or from about 2 to about 12 decitex per filament (DPF).
- the woven fabric of the present invention is preferably made from yarn having from 90 to 300 ends/dm, preferably from 160 to 240 ends/dm.
- the woven fabric exhibits a symmetrical construction.
- the ends/dm of the warp yarn is preferably the same as the ends/dm of the weft yarn.
- the yarn used in the present invention may also comprise various additives used in the production and processing of fibers.
- Suitable additives include, but are not limited to a thermal stabilizer, antioxidant, photo stabilizer, smoothing agent, antistatic agent, plasticizer, thickening agent, pigment, flame retarder, filler, binder, fixing agent, softening agent or combinations thereof.
- Copper compounds have conventionally been added to polyamide yarn, typically either before or during fiber spinning (and preferably added to the polyamide prior to spinning), in order to improve long-term oxidative degradation of the airbag fabric over long periods of storage. The effectiveness of these additives has conventionally been measured by retention of fabric strength (tenacity) over long storage intervals at elevated temperatures.
- Suitable copper compounds include copper halides (preferably copper bromide and/or copper iodide), copper acetate, copper phosphate, copper salicylate, copper stearate and copper benzoate, as well as copper compounds with xylenediamine, mercaptobenzimidazole or benzimidazole.
- the copper compound may be in oxidation state I or II.
- the copper compound is preferably present in the range of 10-500 ppm, preferably 50-150 ppm, preferably 60-120 ppm (calculated as elemental copper) by weight of the polyamide yarn in the finished fabric. Copper bromide and/or copper iodide are particularly preferred.
- the inventors have determined that the effectiveness of copper in improving the melt- through resistance of woven fabric correlates with the halide:copper molar ratio in the yarn.
- the halide:copper molar ratio in the yarn of the woven fabric of the present invention i.e.
- the halide:copper molar ratio in the finished fabric is at least 2.0:1, preferably at least 3.0:1, preferably at least 4.0:1 , preferably at least 6.0:1.
- the inventors have found that such halide- copper molar ratios unexpectedly improve the melt-through resistance.
- the halide:copper molar ratio in the finished fabric is no more than 25.0:1 , preferably no more than 20.0:1.
- the halide:copper ratio is in the range of 2.0:1 to 25.0:1 , preferably 3.0:1 to 25.0:1, preferably 4.0:1 to 25.0:1 , preferably 6.0:1 to 25.0:1.
- halide in particular bromide and/or iodide
- Exposing fiber or finished fabric to water tends to remove halides, with the rate of loss depending upon a number of factors, including the volume of water, temperature, pH and the identity of the base used in the scouring process.
- Such yarn and fabric processing typically use scouring agents such as potassium hydroxide or sodium hydroxide.
- scouring processes typically, about 15-50% of the halide content of the yarn is lost during such yarn and fabric processing (which are collectively referred to herein in this context as “scouring processes”), and 80% or more in a harsh scouring process.
- the halide:copper molar ratio is maintained in the present invention by controlling the harshness of the scouring process in order to minimize halide loss and to ensure a sufficiently high molar ratio in the finished fabric.
- Scouring treatments to remove spin finishes can be achieved by various means and are well understood in the art, and hence can be modulated accordingly by the skilled person, for instance by controlling one or more of the volume of water, temperature, pH, residence time, and the identity and/or concentration of the base used in the process. Scouring treatments are also sometimes employed to finalize construction or dimensions of the final fabric; for instance, a mild scouring treatment employed for that purpose is typically conducted by rinsing in water at elevated temperatures.
- the temperature in the scouring process is less than 95°C, preferably less than 75°C.
- the final pH of a scouring bath is at least 10, preferably at least 11.
- the residence time in a scouring bath is no more than 5 min/m 2 , preferably no more than 3 min/m 2 , preferably no more than 2 min/m 2 of fabric.
- the concentration of sodium ion in the scouring bath or fluid is less than 35 ppm, preferably less than 10 ppm.
- the scouring bath contains potassium hydroxide rather than sodium hydroxide as the base to control pH.
- the harshness of the scouring process is suitably determined by measurement of the residual sodium content of the finished fabric, a lower residual sodium content corresponding to a less harsh scouring process.
- the residual sodium content is no more than 25 ppm, preferably no more than 20 ppm, preferably no more than 15 ppm, preferably no more than 10 ppm (as elemental sodium) by total weight of the finished woven fabric (i.e. after weaving and scouring).
- the halide:copper molar ratio in the yarn of the woven fabric may be controlled by controlling the halide loading in the base fiber or yarn in order to ensure a halide:copper molar ratio of at least 2.0:1 (preferably at least 4.0:1, preferably at least 6.0:1) in the finished woven fabric.
- the halide loading in the base yarn is defined herein as the halide loading in the fiber or yarn prior to removal of any spin finish from the yarn.
- the halide loading in the base yarn is preferably such that the halide:copper molar ratio in the base yarn is at least 4.0:1 , preferably, at least 8.0:1 , preferably at least 10.0:1, preferably at least 12.0:1.
- the appropriate halide loading in the base yarn is preferably determined with knowledge of the subsequent scouring process. However, for mild scouring processes (i.e. in which no more than 50% of the halide content is lost), a halide:copper molar ratio in the base yarn of at least 4.0:1 , preferably, at least 8.0:1 or at least 10.0:1 or at least 12.0:1 will suffice to achieve the object of the invention.
- the halide content in the base yarn may be increased accordingly, for instance to at least 15.0: 1 or at least 20.0: 1 , albeit with increasing manufacturing costs.
- the halide content in the base yarn may be increased accordingly, for instance to at least 15.0: 1 or at least 20.0: 1 , albeit with increasing manufacturing costs.
- even high levels of halide are subject to nearly quantitative removal, and resultant loss of melt-through resistance.
- a halide salt (other than a copper halide), such as a potassium halide may be added to the yarn in addition to the copper compound, preferably potassium bromide or potassium iodide.
- said halide salt is added to the polyamide prior to spinning. It will be appreciated that in the present invention this halide salt is not a sodium salt.
- the concentration of sodium in the final fabric is minimised to the desirable levels described herein by controlling the sodium content in the water used in the weaving and/or scouring treatment steps, for instance by a treatment system for the feed water.
- the sodium content of the weaving water may be controlled, for instance by a thin-film reverse-osmosis system capable of rejecting at least 90% of sodium ions in the feed water.
- the sodium content of water used in the scouring treatment may be controlled, for instance by a thin film reverse osmosis system capable of rejecting at least 90% of sodium ions in the feed water.
- the water in either the weaving or the scouring step may be recycled.
- Spin finishes are typically rich in oils and fats, and in order to avoid degrading the performance of the water treatment system by blocking the reverse-osmosis system, it is preferred to utilise an ultrafilter membrane system to screen out any fats or oils prior to removal of the sodium.
- the woven fabric of the present invention may be formed from warp and weft yarns using weaving techniques known in the art.
- Suitable weaving techniques include, but are not limited to a plain weave, twill weave, satin weave, modified weaves of these types, one piece woven (OPW) weave, or a multi-axial weave.
- Suitable looms that can be used for weaving include a waterjet loom, airjet loom or rapier loom, and preferably the loom is a waterjet loom. These looms can also be used in conjunction with a jacquard in order to create an OPW structure.
- the fabrics may be finished according to any methods known in the art, including drying on loom, scouring, can drying and heat setting.
- the woven fabric of the present invention is a waterjet woven fabric which is dried on loom, or dried by a separate process.
- waterjet weaving the dissolution of spin finish in water, and the rubbing of yarns against one another and the heddles and reed of the loom, causes removal of the spin finish lubricant from the yarn.
- the woven fabrics of the present invention preferably exhibit a total fabric weight of from 50 to 500 g/m 2 , preferably no more than 300 g/m 2 , preferably no more than 260 g/m 2 , preferably no more than 225 g/m 2 , and preferably at least about 80 g/m 2 , preferably at least about 100 g/m 2 , preferably at least about 150 g/m 2 , and typically at least 170 g/m 2 .
- the woven fabrics of the present invention exhibit a total fabric weight of from 150 to 260 g/m 2 , preferably from 170 to 225 g/m 2 .
- the woven fabrics of the present invention preferably exhibit a fabric density of no more than 750 kg/m 3 , preferably no more than 725 kg/m 3 , typically no more than 700 kg/m 3 .
- the total thickness of the woven fabrics of the present invention is preferably no more than 0.40 mm.
- the melt-through resistance of the woven fabrics of the present invention at 450°C, measured as described herein, is preferably at least 2.10 seconds, preferably at least 2.20 seconds, preferably at least 2.30 seconds, preferably at least 2.40 seconds, preferably at least 2.50 seconds, preferably at least 2.60 seconds.
- the inventors have observed that melt-through resistance increases with increasing fabric weight.
- the woven fabric of the present invention preferably exhibits a static air permeability (SAP) of no more than 6.0, preferably no more than 5.0, preferably no more than 4.0, preferably no more than 3.0, preferably no more than 2.0 l/dm 2 /min when the fabric is unaged.
- SAP static air permeability
- the woven fabric of the present invention preferably exhibits a dynamic air permeability (DAP) of no more than 700, preferably no more than 600, preferably no more than 500, preferably no more than 400, preferably no more than 300, preferably no more than 200 mm/s when the fabric is unaged.
- DAP dynamic air permeability
- the tear strength of the fabric in both the warp and weft directions is at least 120 N, preferably at least 150 N, preferably at least 170 N when the fabric is unaged.
- the woven fabrics of the present invention are preferably uncoated.
- coated woven fabrics which comprise layers or coatings applied to the surface of the woven fabric for the purpose of reducing air permeability.
- Such prior art woven fabrics containing additional layers or coatings are referred to herein as “coated woven fabrics”, and take the form of any coating, web, net, laminate or film, which may have been used, for instance, to impart a reduction in air permeability or improvement in thermal resistance.
- the preferred uncoated woven fabrics of the present invention are not “coated woven fabrics” as defined herein.
- the woven fabrics of the present invention are further processed by applying said layers or coatings to the surface of the woven fabric to further improve the fabric resistance to pinhole creation by excessively hot gas and/or hot particulates in the process of high energy (hot) inflation.
- the present invention further provides an article made from the woven fabric described herein, wherein the article is selected from an airbag, sailcloth, inflatable slides, temporary shelters, tents, ducts, coverings and printed media, and particularly wherein the article is an airbag.
- airbags includes airbag cushions. Airbag cushions are typically formed from multiple panels of fabrics and can be rapidly inflated. Fabric of the present invention can be used in airbags sewn from multiple pieces of fabric or from a one piece woven (OPW) fabric. One Piece Woven (OPW) fabric can be made from any method known to those skilled in the art.
- a method of making a woven fabric as described herein comprising the steps of weaving a spun synthetic polyamide yarn and scouring said yarn before, during or after weaving such that the polyamide yarn in the woven fabric exhibits a formic acid relative viscosity of at least 60, a halide:copper molar ratio of at least 2.0 and a sodium content of no more than 25 ppm.
- the method of making the woven fabric preferably comprises controlling the harshness of the scouring treatment.
- the method of making the woven fabric comprises controlling the halide loading in the base yarn from which the woven fabric is made in order to ensure a halide:copper molar ratio of at least 2.0:1 (preferably at least 4.0:1, preferably at least 6.0:1) in the finished woven fabric, preferably wherein the halide loading in the base yarn is such that the halide:copper molar ratio in the base yarn is at least 4.0:1, preferably, at least 8.0:1 , preferably at least 10.0:1 , preferably at least 12.0:1.
- the method comprises controlling the concentration of sodium in the woven fabric by controlling the sodium content in the feed-water used in the weaving and/or scouring treatment steps, for instance by a thin-film reverse-osmosis system capable of rejecting at least 90% of sodium ions in the feed water.
- a woven fabric according to the first aspect of the invention to improve the resistance to pinhole failure of an airbag made therefrom, particularly to the levels of melt-through resistance described herein.
- the relative viscosity (RV) was measured on the fabric according to ASTM D789-19 using a 90% formic acid solution.
- One 20-gram fabric sample is required for each replicate of this analysis.
- each sample was treated to remove any remaining fiber lubricant oil, also known as spin finish.
- spin finish To remove the lubricant, each piece of fabric is soaked in enough methylene chloride to fully cover the sample. The sample is allowed to soak in a covered extraction funnel for twenty minutes with stirring. This procedure is then repeated.
- the second methylene chloride rinse is complete, the fabric is soaked in enough 1:1 methanol:methylene chloride to fully cover the sample. The sample is allowed to soak in a covered extraction funnel for twenty minutes with stirring. This procedure is repeated twice more.
- a “hot rod” test was used. Each fabric piece is 75 mm wide (warp direction) and 100 cm long (weft direction). Three fabric pieces are required per fabric sample (one per test temperature). Prior to testing, the fabric pieces are conditioned in a controlled atmosphere (20 ⁇ 2°C and 65 ⁇ 4% RH) for at least 24 hours before testing.
- This test uses a 12L14 carbon steel cylindrical rod, which is 50 mm in length, 11 mm in diameter and each end being rounded at its edges with a 2mm radius giving a flat end which is 7mm in diameter, and weighing 36.5 g, with a specific heat capacity of 502.4J/(kg°K).
- the rod is heated to a controlled temperature in a muffle furnace for at least one hour to ensure temperature stabilization before testing.
- the hot rod is transferred to a delivery tube and brought into contact with a fabric piece which is mounted horizontally below the delivery tube.
- the fabric pieces are tested at 450°C, 550°C and 650°C.
- the first test site must be at least 20 cm from the fabric selvedge.
- a light-sensor in the delivery tube and a piezo-electric sensor attached to the catch tray positioned underneath the fabric allow a precise measurement of the time required for the rod to penetrate through the fabric once contact is made.
- the recorded time in the test is the total time (seconds) between the rod breaking the light beam and hitting the catch tray, wherein the total time equals the residence time of the rod on the fabric plus 0.19 seconds (which is the free-fall time it takes for the rod to pass between the light beam and the catch tray with no fabric present).
- the time required for the rod to melt through the fabric i.e. the residence time of the rod on the fabric
- this time period is defined as the melt-through resistance. Longer melt-through times indicate increased thermal resistance.
- Each test is repeated 10 times at each temperature to characterize the time required to melt through the fabric sample in seconds. [00057] (iii) Elemental Analysis
- Thickness testing is conducted on fabric specimens which have been conditioned to standard laboratory conditions of 20 ⁇ 2°C & 65 ⁇ 4% RH for at least 24hrs.
- the specimens are cut from the fabric in such a way that no two specimens possess any common warp or weft yarns.
- Specimens are not cut within 20cm of either selvedge or at any creased, obviously damaged or dirty fabric regions.
- Specimens are suitably cut using a cutter die with a hydraulic press.
- the thickness of five specimens is measured with an electronic micrometer of testing range 0-25mm by 0.001mm (with 6.5mm diameter jaw faces) and the result recorded.
- the reported result in units of mm is the mean average of five individual specimen results.
- Fabric weight was measured according to ISO 3801 (1977) with EASC amendments, and in accordance with EASC instruction 99040180 covering fabric testing (sections 3.05 & 4.01). Weight testing is conducted on samples of fabric which have been conditioned to standard laboratory conditions of 20 ⁇ 2°C & 65 ⁇ 4% RH for at least 24hrs. Five square specimens of size 10x10cm are cut (each orientated on the bias at 45° to the warp direction) from the sample in a diagonal line pattern across the fabric in such a way that no two specimens possess any common warp or weft yarns. Specimens are not cut within 10cm of either selvedge or at any creased, obviously damaged or dirty fabric regions.
- Specimens are cut using a 10x10cm cutter die with a hydraulic press. Once cut, the five specimens are weighed in a 3 decimal place balance in units of grams & the result recorded. Each result is multiplied by 100 to give the fabric weight in g/m 2 . The reported fabric weight result is the mean average of five results.
- Static Air Permeability SAP was measured according to ISO 9237 (1995) but with the following amendments:
- test area is 100cm 2 .
- test pressure (partial vacuum) is 500 Pa.
- Static Air Permeability testing is conducted at six sites on a test fabric in a sampling pattern across and along the fabric in order to test 6 separate areas of warp and weft threadlines within the fabric.
- Dynamic Air Permeability is defined as the average velocity (mm/s) of air or gas in the selected test pressure range of 30-70kPa, converted to a pressure of 100kPa (14.2 psi) and a temperature of 20°C. Dynamic Air Permeability is measured according to test standard ASTM D6476-12 but with the following amendments:
- the start pressure (as set on the test instrument) is adjusted to achieve a peak pressure of 100 ⁇ 5kPa.
- the test head volume is 400cm 3 unless the specified start pressure cannot be achieved with this head, in which case an interchangeable test head of volume 100, 200, 800 or 1600cm 3 is used, as appropriate for the fabric under test.
- the tear force (also known as tear strength) of the fabric, expressed in Newtons (N), is determined according to standard ISO 13937-2 (2000) with the amendments as listed below:
- the fabric specimen size is 150mm x 200mm (with a 100mm slit extending from the midpoint of the narrow end to the center.
- Warp direction tear results are obtained from tested specimens where the tear is made across the warp (i.e. warp threadlines are torn) whilst weft direction results are obtained from tested specimens where the tear is made across the weft (i.e. weft threadlines are torn).
- the fabric density is calculated by dividing the fabric weight per unit area (g/m 2 ) by the fabric thickness measurement (mm) with a conversion to units of kg/m 3 .
- a further series of woven fabrics was manufactured with a construction of 209x209 ends/dm, using each using a nylon 6,6 yarn of differing halide:Cu molar ratios.
- the warp yarn was the same as the weft yarn, and the yarns in the finished fabric exhibited a relative viscosity of 66 and a residual sodium content of less than 10 ppm.
- Melt-through resistance of each fabric was tested at 450°C, 550°C and 650°C. The results, shown in Figure 2, demonstrate that melt-through resistance for a fabric with a relatively higher halide:Cu molar ratio was superior to a fabric with a relatively lower halide:Cu molar ratio.
- melt-through resistance performance was achieved at a halide:Cu molar ratio of at least 4.0:1, preferably at least 6.0:1.
- the fabric should preferably maintain at least 302 ppm bromine or at least 480 ppm iodine for effective melt-through resistance.
- a further series of woven fabrics was manufactured from nylon 6,6 yarn, similar to those described above, and using different scouring conditions in order to assess the effect on the halide:Cu molar ratio of (i) residence time in the scouring process, (ii) pH of the scouring bath, and (iii) temperature of the scouring bath.
- the inventors observed that halide:Cu molar ratio is inversely related to fabric dwell time in the scouring process, as shown in Figure 4.
- the inventors also observed that halide:Cu molar ratio in the scoured fabric is correlated with the pH of the scouring bath, as shown in Figure 5.
- the inventors also observed that halide losses observed as a result of exposure to alkaline scouring were not mitigated by pH neutralization of the scouring bath composition with weak acids. Surprisingly, weak acids were found to exacerbate halide leaching from the yarn or fabric in such neutralized bath compositions. The inventors further observed that the halide:Cu molar ratio in the fabric is also inversely related to the scouring bath temperature, as shown in Figure 6.
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Abstract
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Application Number | Priority Date | Filing Date | Title |
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GBGB2007599.0A GB202007599D0 (en) | 2020-05-21 | 2020-05-21 | Airbag fabrics |
GBGB2017564.2A GB202017564D0 (en) | 2020-11-06 | 2020-11-06 | Airbag fabrics |
PCT/IB2021/054393 WO2021234636A1 (en) | 2020-05-21 | 2021-05-20 | Airbag fabrics |
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EP (1) | EP4153807A1 (en) |
KR (1) | KR20230013071A (en) |
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WO2001009416A1 (en) * | 1999-08-02 | 2001-02-08 | Asahi Kasei Kabushiki Kaisha | Base cloth for air bag |
JP4723735B2 (en) * | 2001-02-26 | 2011-07-13 | 旭化成せんい株式会社 | Fabric and airbag |
KR101109042B1 (en) * | 2005-08-30 | 2012-01-31 | 코오롱인더스트리 주식회사 | Fabric for airbag, and method of preparing the same |
JP2007162187A (en) * | 2005-12-16 | 2007-06-28 | Toray Ind Inc | Non-coated woven fabric for airbag, coated woven fabric, method for producing the same and inflatable curtain airbag |
JP5425563B2 (en) * | 2009-09-01 | 2014-02-26 | 旭化成せんい株式会社 | Airbag fabrics and airbags |
PT3279378T (en) * | 2015-04-03 | 2021-06-21 | Toyo Boseki | Airbag-use woven fabric and airbag |
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