EP4122503A1 - Device for dispensing volatile substances into the environment - Google Patents

Abstract

The present invention relates to a kit for producing a device for releasing an active substance into the environment, comprising or consisting of a) a composition consisting of or comprising a1) a water-miscible solvent, a2) one or more active substances and b) at least one diffusion stick consisting of or comprising i) fibers of plant origin and/or ii) fibers of animal origin and/or iii) a plastic. The present invention also relates to a device for releasing an active substance into the environment consisting of or comprising a) a liquid composition consisting of or comprising a1) a water-miscible solvent, a2) one or more active substances and a3) water, b) at least one Diffusion rods consisting of or comprising consisting of or comprising i) fibers of vegetable origin and/or ii) fibers of animal origin and/or iii) a plastic and c) a container which has at least one container opening and comprises the liquid composition. The present invention also relates to a method for producing a device for releasing an active substance, such as the use of diffusion rods consisting of or comprising i) fibers of plant origin and/or ii) fibers of animal origin in evaporator systems. The present invention also relates to the use of diffusion rods in devices (1) for releasing an active ingredient

Description

The present invention relates to a kit for producing a device for releasing an active substance into the environment, comprising or consisting of a) a composition consisting of or comprising a1) a water-miscible solvent, a2) one or more active substances and b) at least one diffusion stick consisting of or comprising i) fibers of plant origin and/or ii) fibers of animal origin and/or iii) a plastic. The present invention also relates to a device for releasing an active substance into the environment consisting of or comprising a) a liquid composition consisting of or comprising a1) a water-miscible solvent, a2) one or more active substances and a3) water, b) at least one Diffusion rods consisting of or comprising consisting of or comprising i) fibers of vegetable origin and/or ii) fibers of animal origin and/or iii) a plastic and c) a container which has at least one container opening and comprises the liquid composition. The present invention also relates to a method for producing a device for releasing an active substance, such as the use of diffusion rods consisting of or comprising i) fibers of plant origin and/or ii) fibers of animal origin in evaporator systems. The present invention also relates to the use of diffusion rods in devices (1) for releasing an active ingredient

In addition to spray systems, evaporation systems are often used to scent and refresh rooms. Compared to spray systems, these evaporation systems have the advantage that they produce an almost constant fragrance over the entire running time, while spray systems only produce an intensive fragrance after each spray burst, which gradually decreases.

Vaporization systems typically consist of a canister containing a fragrance dissolved in an organic solvent and a diffusor stick contained in the canister. The diffusion rods are designed in such a way that, due to capillary forces, they absorb the organic solvents and the fragrance dissolved in the solvent and transport them out of the container along the diffusion rod. The organic solvent along with the fragrance then evaporates on the surface of the diffusion rods and the fragrance (along with the solvent) is released into the environment.

The evaporation systems described in the prior art usually have the disadvantage that the composition containing the organic solvent and the fragrance dissolved in the organic solvent are always sold as a ready-to-use mixture. Namely, there is hardly any possibility that the consumer finalizes the evaporator device himself by obtaining the ready-to-use composition from a concentrate by dilution with an organic solvent. This is because the organic solvents required are not readily available to the consumer, so it has hitherto been customary to offer ready-to-use mixtures. As a result, the evaporation systems have a high weight (and pack size) and can have a negative impact on the ecological balance during manufacture, transport and storage.

In addition, the evaporation systems described in the prior art have the disadvantage that they have a high proportion of volatile organic compounds (VOC for short), ie organic substances which evaporate at room temperature or higher temperatures (colloquially "evaporate" ) pass into the gas phase, i.e. are volatile. While the evaporation of the flavorings or other active ingredients of the evaporation system is desirable, the evaporation of the solvents used has only been a necessary evil up to now. The mostly odorless or hardly odorous solvents do not contribute to the scenting and refreshment of rooms, but increase the proportion of volatile ones organic compounds in the air. In addition, the organic solvents are usually flammable and increase the risk of fire.

1. a) das Gewicht der Duftzusammensetzung reduziert werden kann, um die für die Herstellung, Lagerung und Transport benötigte Energie zu reduzieren und somit eine verbesserte Ökobilanz zu erreichen
   und/oder
2. b) den Anteil an flüchtigen organischen Verbindungen, die während der Verwendung der Verdampfervorrichtung freigesetzt werden zu reduzieren.

The object of the present invention was to provide an evaporation system in which

1. a) the weight of the fragrance composition can be reduced in order to reduce the energy required for production, storage and transport and thus achieve an improved ecological balance
   and or
2. b) reduce the level of volatile organic compounds released during use of the evaporator device.

1. a) eine Zusammensetzung bestehend aus oder umfassend
   • a1) ein mit Wasser mischbares Lösungsmittel und
   • a2) ein oder mehrere Wirkstoffe
2. b) mindestens ein Diffusionsstäbchen (3, 3', 3") bestehend aus oder umfassend
   1. i) Fasern pflanzlicher Herkunft
      und/oder
   2. ii) Fasern tierischer Herkunft
      und/oder
   3. iii) einen Kunststoff.

This object was achieved by a kit for producing a device (1) for releasing an active ingredient into the environment, consisting of or comprising

1. a) a composition consisting of or comprising
   • a1) a water-miscible solvent and
   • a2) one or more active ingredients
2. b) at least one diffusion rod (3, 3', 3") consisting of or comprising
   1. i) fibers of plant origin
      and or
   2. ii) fibers of animal origin
      and or
   3. iii) a plastic.

A device for releasing an active ingredient into the environment (also called vaporization systems) can be produced from a kit according to the invention by placing the composition of the kit in a container and adding a defined amount of water to this composition (5). Subsequently, the diffusing rods (3, 3', 3") must be inserted into the resulting water-containing composition such that one end of the diffusing rods are immersed in the composition and the other ends of the diffusing rods protrude from the Container containing the composition extend. In the resulting device for releasing an active substance, the composition (5) then consists of or comprises a1) a water-miscible solvent, a2) one or more active substances and a3) water. This offers the possibility that, by adding water from the composition of the kit according to the invention, the consumer obtains a ready-to-use composition which can be used in a device for releasing an active substance. Since the composition produced can usually contain up to 90% by weight of water, a weight and volume saving of up to 90% (sometimes even more) is possible. A device (1) for releasing an active ingredient from a kit according to the invention is thus produced by adding water, which is always available to the consumer. It is not necessary for the consumer to store and use organic solvents.

In addition, during use of the resulting evaporation system, the proportion of volatile organic compounds is significantly reduced, since instead of an organic solvent, up to 90% by weight of water is usually used.

In the context of the present invention, a water-miscible solvent is understood as meaning a solvent which can be mixed with water at a temperature of 25° C. in any ratio and in the process completely forms a homogeneous phase.

A kit according to the invention is particularly preferred which additionally comprises c) a container (2) which has at least one container opening (4). It is preferred according to the invention if the composition of the kit is already contained in the container (2). The consumer can then add water to the container to obtain a ready-to-use composition, preferably there being a corresponding mark in the container up to which the water must be topped up. Alternatively, of course, there is the possibility that no corresponding container is added to the kit and the consumer uses his own container or (re)uses a container contained in a previous kit. Unless the kit includes an appropriate container that has a container opening (4) and has sufficient internal volume to hold the composition plus water, the composition is preferably packaged in a smaller container, made of ceramic, metal, glass or plastic, or a sachet bottled.

1. a) eine flüssige Zusammensetzung (5) bestehend aus oder umfassend
   • a1) ein mit Wasser mischbares Lösungsmittel
   • a2) ein oder mehrere Wirkstoffe
     und
   • a3) Wasser
2. b) mindestens ein Diffusionsstäbchen (3, 3', 3") bestehend aus oder umfassend
   1. i) Fasern pflanzlicher Herkunft
      und/oder
   2. ii) Fasern tierischer Herkunft
      und/oder
   3. iii) einen Kunststoff.
   und
3. c) einen Behälter (2), der zumindest eine Behälteröffnung (4) aufweist und die flüssige Zusammensetzung (5) umfasst.

A further aspect of the present invention relates to a device (1) for releasing an active substance into the environment, preferably produced from a kit according to the invention, consisting of or comprising

1. a) a liquid composition (5) consisting of or comprising
   • a1) a water-miscible solvent
   • a2) one or more active substances
     and
   • a3) water
2. b) at least one diffusion rod (3, 3', 3") consisting of or comprising
   1. i) fibers of vegetable origin
      and or
   2. ii) fibers of animal origin
      and or
   3. iii) a plastic.
   and
3. c) a container (2) which has at least one container opening (4) and comprises the liquid composition (5).

It is preferred according to the invention if the container (2) is a glass container, ceramic container or metal container. These containers have the advantage that they can be washed and reused without absorbing odours. In addition, with these materials there is no risk of discolouration of the bottle. As an alternative to glass, there is also the—less preferred—possibility of using a container made of plastic, preferably transparent plastic. According to the invention, containers made of glass, ceramic, metal or plastic can thus be used. It is preferred according to the invention if the container has a filling volume (internal volume) in the range from 25 to 250 mL, preferably in the range from 40 to 220 mL. Usually, containers with a filling volume of 50 mL ± 15 mL, 90 mL ± 15 mL, 100 mL ± 15 mL, 120 mL ± 15 mL, 200 mL ± 15 mL or 250 mL ± 15 mL are used.

• a1) ein mit Wasser mischbares Lösungsmittel
• a2) ein oder mehrere Wirkstoffe
  und
• a3) optional Wasser.

Another aspect of the present invention relates to a composition consisting of or comprising

• a1) a water-miscible solvent
• a2) one or more active ingredients
  and
• a3) optionally water.

If only one composition is mentioned below, it can be a composition of the kit according to the invention, a liquid composition of the device (1) according to the invention or a composition according to the invention. Otherwise, a distinction is made between a composition of the kit according to the invention and a composition of the device (1) according to the invention.

It is preferred according to the invention if the composition additionally contains a4) a surfactant. In the case of a high water content in particular, it may be necessary to add a surfactant in order to produce an emulsion of active substance and solvent (a1) the water-miscible solvent and a3) water). Whether a surfactant has to be used depends on the solubility of the active ingredient in water.

Our own investigations have shown that it is preferred according to the invention if the surfactant has an HLB value calculated according to Griffin in the range from 3 to 20, preferably in the range from 6 to 20, particularly preferably in the range from 9 to 20.

According to the invention, the surfactant is preferably a surfactant selected from the group consisting of nonionic surfactants, anionic surfactants, cationic surfactants and amphoteric surfactants.

According to the invention, the nonionic surfactant is particularly preferably a compound that has several alcohol groups, a compound that has one or more ether groups, or a compound that has both alcohol groups and ether groups (e.g. ethoxylates).

According to the invention, the anionic surfactant is particularly preferably a compound which has one or more carboxylate groups, a compound having one or more sulfonate groups, or a compound having one or more sulfate groups.

According to the invention, the cationic surfactant is particularly preferably a compound which has one or more quaternary ammonium groups.

According to the invention, the amphoteric surfactant is particularly preferably a compound which has both carboxylate groups and quaternary ammonium groups.

Typical examples of nonionic surfactants are fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, fatty acid polyglycol esters, fatty acid amide polyglycol ethers, fatty amine polyglycol ethers, alkoxylated triglycerides, mixed ethers or mixed formals, optionally partially oxidized alk(en)yl oligoglycosides or glucuronic acid derivatives, fatty acid N-alkyl glucamides, protein hydrolysates (especially wheat-based plant products) , polyol fatty acid esters, sugar esters, sorbitan esters, polysorbates and amine oxides. If the nonionic surfactants contain polyglycol ether chains, these can have a conventional, but preferably a narrow homolog distribution.

Typical examples of anionic surfactants are soaps, alkyl benzene sulfonates, alkane sulfonates, olefin sulfonates, alkyl ether sulfonates, glycerol ether sulfonates, α-methyl ester sulfonates, sulfofatty acids, alkyl sulfates, alkyl ether sulfates, glycerol ether sulfates, fatty acid ether sulfates, hydroxy mixed ether sulfates, monoglyceride (ether) sulfates, fatty acid amide (ether) sulfates, mono - and dialkyl sulfosuccinates, mono- and dialkyl sulfosuccinamates, sulfotriglycerides, amide soaps, ether carboxylic acids and their salts, fatty acid isethionates, fatty acid sarcosinates, fatty acid taurides, N-acylamino acids, such as acyl lactylates, acyl tartrates, acyl glutamates and acyl aspartates, alkyl oligoglucoside sulfates, protein fatty acid condensates (particularly wheat-based vegetable products) and alkyl (ether) phosphates, alkyl sulfates, alkyl ether sulfates, alkyl sulfonates, alkylaryl sulfonates, alkyl succinates, alkyl sulfosuccinates, N-alkoyl sarcosinates, acyl taurates, acyl isothionates, alkyl phosphates, alkyl ether phosphates, alkyl ether carbo xylates, alpha-olefin sulfonates, especially the alkali and alkaline earth metal salts, e.g. B. sodium, potassium, magnesium, calcium, and ammonium and triethanolamine salts. The alkyl ether sulfates, alkyl ether phosphates and alkyl ether carboxylates can have between 1 and 10 ethylene oxide or propylene oxide units, preferably 1 to 3 ethylene oxide units, in the molecule. These include e.g. B. sodium lauryl sulfate, ammonium tauryte sulfate, sodium lauryl ether sulfate, ammonium lauryl ether sulfate, sodium lauryl sarcosinate, sodium oleyl succinate, ammonium lauryl sulfosuccinate, sodium dodecylbenzene sulfonate, triethanolamine dodecylbenzene sulfonate.

If the anionic surfactants contain polyglycol ether chains, these can have a conventional, but preferably a narrow homolog distribution.

Typical examples of cationic surfactants are quaternary ammonium compounds, such as cetyltrimethylammonium chloride, dimethyldistearylammonium chloride, and ester quats, in particular quaternized fatty acid trialkanolamine ester salts.

Suitable amphoteric surfactants are e.g. B. aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetaines, alkyl betaines, alkylamidopropyl betaines, alkyl sulfobetaines, alkyl glycinates, alkyl carboxyglycinates, alkyl amphoacetates or propionates, alkyl amphodiacetates or dipropionates.

It is preferred according to the invention if the active ingredient or active ingredients are fragrances, antimicrobial active ingredients and/or insect repellents. However, it cannot be ruled out that, for example, some fragrances also have an effect against insects at the same time, as is the case with citronellol and geraniol, for example. According to the invention, the active substance is particularly preferably a fragrance.

In the context of this text, fragrances are understood to mean a substance or a mixture of substances that is perceived olfactorily.

• der Kohlenwasserstoffe, dabei bevorzugt 3-Caren; α-Pinen; β-Pinen; α-Terpinen; γ-Terpinen; p-Cymol; Bisabolen; Camphen; Caryophyllen; Cedren; Farnesen; Limonen; Longifolen; Myrcen; Ocimen; Valencen; (E,Z)-1,3,5-Undecatrien; Styrol; Diphenylmethan;
• der aliphatischen Alkohole, dabei bevorzugt Hexanol; Octanol; 3-Octanol; 2,6-Dimethylheptanol; 2-Methyl-2-heptanol; 2-Methyl-2-octanol; (E)-2-Hexenol; (E)- und (Z)-3-Hexenol; 1-Octen-3-ol; Gemisch von 3,4,5,6,6-Pentamethyl-3/4-hepten-2-ol und 3,5,6,6-Tetramethyl-4-methyleneheptan-2-ol; (E,Z)-2,6-Nonadienol; 3,7-Dimethyl-7-methoxyoctan-2-ol; 9-Decenol; 10-Undecenol; 4-Methyl-3-decen-5-ol; 3,7-DIMETHYL-6-OCTEN-1-OL;
• der aliphatischen Aldehyde und deren Acetale, dabei bevorzugt Hexanal; Heptanal; Octanal; Nonanal; Decanal; Undecanal; Dodecanal; Tridecanal; 2-Methyloctanal; 2-Methylnonanal; (E)-2-Hexenal; (Z)-4-Heptenal; 2,6-Dimethyl-5-heptenal; 10-Undecenal; (E)-4-Decenal; 2-Dodecenal;2,6,10-Trimethyl-9-undecenal; 2,6,10-Trimethyl-5,9-undecadienal; Heptanaldiethylacetal; 1,1-Dimethoxy-2,2,5-trimethyl-4-hexen; Citronellyloxyacetaldehyd; 1-(1-Methoxy-propoxy)-(E/Z)-3-hexen;
• der aliphatischen Ketone und deren Oxime, dabei bevorzugt 2-Heptanon; 2-Octanon; 3-Octanon; 2-Nonanon; 5-Methyl-3-heptanon; 5-Methyl-3-heptanonoxim; 2,4,4,7-Tetramethyl-6-octen-3-on; 6-Methyl-5-hepten-2-on; 1-(1,2,3,4,5,6,7,8-OCTAHYDRO-2,3,8,8-TETRAMETHYL-2-NAPHTHYL)ETHAN-1-ONE; 3-METHYL-4-(2,6,6-TRIMETHYL-2-CYCLOHEXEN-1-YL)-3-BUTEN-2-ONE
• der aliphatischen schwefelhaltigen Verbindungen, dabei bevorzugt 3-Methylthio-hexanol; 3-Methylthiohexylacetat; 3-Mercaptohexanol; 3-Mercaptohexylacetat; 3-Mercaptohexylbutyrat; 3-Acetylthiohexylacetat; 1-Menthen-8-thiol;
• der aliphatischen Nitrile, dabei bevorzugt 2-Nonensäurenitril; 2-Undecensäurenitril; 2-Tridecensäurenitril; 3,12-Tridecadiensäurenitril; 3,7-Dimethyl-2,6-octadien-säurenitril; 3,7-Dimethyl-6-octensäurenitril;
• der Ester von aliphatischen Carbonsäuren, dabei bevorzugt (E)- und (Z)-3-Hexenylformiat; Ethylacetoacetat; Isoamylacetat; Hexylacetat; 3,5,5-Trimethylhexylacetat; 3-Methyl-2-butenylacetat; (E)-2-Hexenylacetat; (E)- und (Z)-3-Hexenylacetat; Octylacetat; 3-Octylacetat; 1-Octen-3-ylacetat; Ethylbutyrat; Butylbutyrat; Isoamylbutyrat; Hexylbutyrat; (E)- und (Z)-3-Hexenyl-isobutyrat; Hexylcrotonat; Ethylisovalerianat; Ethyl-2-methylpentanoat; Ethylhexanoat; Allylhexanoat; Ethylheptanoat; Allylheptanoat; Ethyloctanoat; Ethyl-(E,Z)-2,4-decadienoat; Methyl-2-octinat; Methyl-2-noninat; Allyl-2-isoamyloxyacetat; Methyl-3,7-dimethyl-2,6-octadienoat;4-Methyl-2-pentyl-crotonat;
• der acyclischen Terpenalkohole, dabei bevorzugt Citronellol; Geraniol; Nerol; Linalool; Lavadulol; Nerolidol; Farnesol; Tetrahydrolinalool; Tetrahydrogeraniol; 2,6-Dimethyl-7-octen-2-ol; 2,6-Dimethyloctan-2-ol; 2-Methyl-6-methylen-7-octen-2-ol; 2,6-Dimethyl-5,7-octadien-2-ol; 2,6-Dimethyl-3,5-octadien-2-ol; 3,7-Dimethyl-4,6-octadien-3-ol; 3,7-Dimethyl-1,5,7-octatrien-3-ol 2,6-Dimethyl-2,5,7-octatrien-1-ol; sowie deren Formiate, Acetate, Propionate, Isobutyrate, Butyrate, Isovalerianate, Pentanoate, Hexanoate, Crotonate, Tiglinate und 3-Methyl-2-butenoate;
• der acyclischen Terpenaldehyde und -ketone, dabei bevorzugt Geranial; Neral; Citronellal; 7-Hydroxy-3,7-dimethyloctanal; 7-Methoxy-3,7-dimethyloctanal; 2,6,10-Trimethyl-9-undecenal; Geranylaceton; sowie die Dimethyl- und Diethylacetale von Geranial, Neral, 7-Hydroxy-3,7-dimethyloctanal;
• der cyclischen Terpenalkohole, dabei bevorzugt Isopulegol; alpha-Terpineol; Terpinenol-4; Menthan-8-ol; Menthan-1-ol; Menthan-7-ol; Borneol; Isoborneol; Linalooloxid; Nopol; Cedrol; Ambrinol; Vetiverol; Guajol; sowie deren Formiate, Acetate, Propionate, Isobutyrate, Butyrate, Isovalerianate, Pentanoate, Hexanoate, Crotonate, Tiglinate und 3-Methyl-2-butenoate; Menthylformiat; Menthylpropionat; Menthylbutyrat; Menthylisobutyrat; Menthylisovalerianat; Menthylhexanoat; Menthylcrotonat; Menthyltiglinat;
• der cyclischen Terpenaldehyde und -ketone, dabei bevorzugt Menthon; Isomenthon; 8-Mercaptomenthan-3-on; Carvon; Campher; Fenchon; alpha-Ionon; beta-Ionon; beta-n-Methylionon; beta-Isomethylionon; alpha-lron; alpha-Damascon; beta-Damascon; beta-Damascenon; delta-Damascon; gamma-Damascon; 1-(2,4,4-Trimethyl-2-cyclohexen-1-yl)-2-buten-1-on; 1,3,4,6,7,8a-Hexahydro-1,1,5,5-tetramethyl-2H-2,4a-methanonaphthalen-8(5H)-on;2-Methyl-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-butenal; Nootkaton; Dihydro-nootkaton; 4,6,8-Megastigmatrien-3-on; alpha-Sinensal; beta-Sinensal; acetyliertes Ce-dernholzöl (Methylcedrylketon);
• der cyclischen Alkohole, dabei bevorzugt 4-tert.-Butylcyclohexanol; 3,3,5-Trimethylcyclohexanol; 3-Isocamphylcyclohexanol; 2,6,9-Trimethyl-Z2,Z5,E9-cyclododecatrien-1-ol; 2-Isobutyl-4-methyltetrahydro-2H-pyran-4-ol;
• der cycloaliphatischen Alkohole, dabei bevorzugt alpha,3,3-Trimethylcyclohexylmethanol; 1-(4-Isopropylcyclohexyl)ethanol; 2-Methyl-4-(2,2,3-trimethyl-3-cyclopent-1-yl)butanol; 2-Methyl-4-(2,2,3-trimethyl-3-cyclopent-1-yl)-2-buten-1-ol; 2-Ethyl-4-(2,2,3-trimethyl-3-cyclopent-1-yl)-2-buten-1-ol; 3-Methyl-5-(2,2,3-trimethyl-3-cyclopent-1-yl)-pentan-2-ol; 3-Methyl-5-(2,2,3-trimethyl-3-cyclopent-1-yl)-4-penten-2-ol; 3,3-Dimethyl-5-(2,2,3-trimethyl-3-cyclopent-1-yl)-4-penten-2-ol; 1-(2,2,6-Trimethylcyclohexyl)pentan-3-ol; 1-(2,2,6-Trimethylcyclohexyl)hexan-3-ol;
• der cyclischen und cycloaliphatischen Ether, dabei bevorzugt Cineol; Cedrylmethylether; Cyclododecylmethylether; 1,1-Dimethoxycyclododecan; (Ethoxymethoxy)cyclododecan; alpha-Cedrenepoxid; 3a,6,6,9a-Tetramethyldodecahydronaphtho[2,1-b]furan; 3a-Ethyl-6,6,9a-trimethyldodecahydronaphtho[2,1-b]furan; 1,5,9-Trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-dien; Rosenoxid; 2-(2,4-Dimethyl-3-cyclohexen-1-yl)-5-methyl-5-(1-methylpropyl)-1,3-dioxan;
• der cyclischen und makrocyclischen Ketone, dabei bevorzugt 4-tert.-Butylcyclohexanon; 2,2,5-Trimethyl-5-pentylcyclopentanon; 2-Heptylcyclopentanon; 2-Pentylcyclopentanon; 2-Hydroxy-3-methyl-2-cyclopenten-1-on; 3-Methyl-cis-2-penten-1-yl-2-cyclopenten-1-on; 3-Methyl-2-pentyl-2-cyclopenten-1-on; 3-Methyl-4-cyclopentadecenon; 3-Methyl-5-cyclopentadecenon; 3-Methylcyclopentadecanon; 4-(1-Ethoxyvinyl)-3,3,5,5-tetramethylcyclohexanon; 4-tert.-Pentylcyclohexanon; 5-Cyclohexadecen-1-on; 6,7-Dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanon; 8-Cyclohexadecen-1-on; 9-Cycloheptadecen-1-on; Cyclopentadecanon; Cyclohexadecanon;
• der cycloaliphatischen Aldehyde, dabei bevorzugt 2,4-Dimethyl-3-cyclohexencarbaldehyd; 2-Methyl-4-(2,2,6-trimethyl-cyclohexen-1-yl)-2-butenal; 4-(4-Hydroxy-4-methylpentyl)-3-cyclohexencarbaldehyd; 4-(4-Methyl-3-penten-1-yl)-3-cyclohexencarbaldehyd;
• der cycloaliphatischen Ketone, dabei bevorzugt 1-(3,3-Dimethylcyclohexyl)-4-penten-1-on; 2,2-Dimethyl-1-(2,4-dimethyl-3-cyclohexen-1-yl)-1-propanon; 1-(5,5-Dimethyl-1-cyclohexen-1-yl)-4-penten-1-on; 2,3,8,8-Tetramethyl-1,2,3,4,5,6,7,8-octahydro-2-naphtalenylmethylketon; Methyl-2,6,10-trimethyl-2,5,9-cyclododecatrienylketon; tert.-Butyl-(2,4-dimethyl-3-cyclohexen-1-yl)keton;
• der Ester cyclischer Alkohole, dabei bevorzugt 2-tert-Butylcyclohexylacetat; 4-tert-Butylcyclohexylacetat; 2-tert-Pentylcyclohexylacetat; 4-tert-Pentylcyclohexylacetat; 3,3,5-Trimethylcyclohexylacetat; Decahydro-2-naphthylacetat; 2-Cyclopentylcyclopentylcrotonat; 3-Pentyltetrahydro-2H-pyran-4-ylacetat; Decahydro-2,5,5,8a-tetramethyl-2-naphthylacetat; 4,7-Methano-3a,4,5,6,7,7a-hexahydro-5, bzw. 6-indenylacetat; 4,7-Methano-3a,4,5,6,7,7a-hexahydro-5, bzw. 6-indenylpropionat; 4,7-Methano-3a,4,5,6,7,7a-hexahydro-5, bzw. 6-indenylisobutyrat; 4,7-Methanooctahydro-5, bzw. 6-indenylacetat;
• der Ester cycloaliphatischer Alkohole, vorzugsweise 1-Cyclohexylethylcrotonat;
• der Ester cycloaliphatischer Carbonsäuren, dabei bevorzugt Allyl-3-cyclohexylpropionat; Allylcyclohexyloxyacetat; cis- und trans-Methyldihydrojasmonat; cis- und trans-Methyljasmonat; Methyl-2-hexyl-3-oxocyclopentancarboxylat; Ethyl-2-ethyl-6,6-dimethyl-2-cyclohexencarboxylat; Ethyl-2,3,6,6-tetramethyl-2-cyclohexencarboxylat; Ethyl-2-methyl-1,3-dioxolan-2-acetat;
• der araliphatischen Alkohole, dabei bevorzugt Benzylalkohol; 1-Phenylethylalkohol; 2-Phenylethylalkohol; 3-Phenylpropanol; 2-Phenylpropanol; 2-Phenoxyethanol; 2,2-Dimethyl-3-phenylpropanol; 2,2-Dimethyl-3-(3-methylphenyl)propanol; 1,1-Dimethyl-2-phenylethylalkohol; 1,1-Dimethyl-3-phenylpropanol; 1-Ethyl-1-methyl-3-phenylpropanol; 2-Methyl-5-phenylpentan-1-ol; 3-Methyl-5-phenylpentanol; 3-Phenyl-2-propen-1-ol; 4-Methoxybenzylalkohol; 1-(4-Isopropylphenyl)ethanol;
• der Ester von araliphatischen Alkoholen und aliphatischen Carbonsäuren, dabei bevorzugt Benzylacetat; Benzylpropionat; Benzylisobutyrat; Benzylisovalerianat; 2-Phenylethylacetat; 2-Phenylethylpropionat; 2-Phenylethylisobutyrat; 2-Phenylethylisovalerianat; 1-Phenylethylacetat; alpha-Trichlormethylbenzylacetat; alpha,alpha-Dimethylphenylethylacetat; alpha,alpha-Dimethylphenylethylbutyrat; Cinnamylacetat; 2-Phenoxyethylisobutyrat; 4-Methoxybenzylacetat;
• der araliphatischen Ether, dabei bevorzugt 2-Phenylethylmethylether; 2-Phenylethylisoamylether; 2-Phenylethyl-1-ethoxyethylether; Phenylacetaldehyddimethylacetal; Phenylacetaldehyddiethylacetal; Hydratropaaldehyddimethylacetal; Phenylacetaldehydglycerinacetal; 2,4,6-Trimethyl-4-phenyl-1,3-dioxan; 4,4a,5,9b-Tetrahydroindeno[1,2-d]-m-dioxin; 4,4a,5,9b-Tetrahydro-2,4-dimethylindeno[1,2-d]-m-dioxin;
• der aromatischen und araliphatischen Aldehyde, dabei bevorzugt Benzaldehyd; Phenylacetaldehyd; 3-Phenylpropanal; Hydratropaaldehyd; 4-Methylbenzaldehyd; 4-Methylphenylacetaldehyd; 3-(4-Ethylphenyl)-2,2-dimethylpropanal; 2-Methyl-3-(4-isopropylphenyl)propanal; 2-Methyl-3-(4-tert.-butylphenyl)propanal; 2-Methyl-3-(4-isobutylphenyl)propanal; 3-(4-tert.-Butylphenyl)propanal; Zimtaldehyd; alpha-Butylzimtaldehyd; alpha-Amylzimtaldehyd; alpha-Hexylzimtaldehyd; 3-Methyl-5-phenylpentanal; 4-Methoxybenzaldehyd; 4-Hydroxy-3-ethoxybenzaldehyd; 3,4-Methylendioxybenzaldehyd; 3,4-Dimethoxybenzaldehyd; 2-Methyl-3-(4-methoxyphenyl)propanal; 2-Methyl-3-(4-methylendioxyphenyl)propanal;
• der aromatischen und araliphatischen Ketone, dabei bevorzugt Acetophenon; 4-Methylacetophenon; 4-Methoxyacetophenon; 4-tert.-Butyl-2,6-dimethylacetophenon; 4-Phenyl-2-butanon; 4-(4-Hydroxyphenyl)-2-butanon; 1-(2-Naphthalenyl)ethanon;2-Benzofuranylethanon;(3-Methyl-2-benzofuranyl)ethanon; Benzophenon; 1,1,2,3,3,6-Hexamethyl-5-indanylmethylketon; 6-tert.-Butyl-1,1-dimethyl-4-indanylmethylketon; 1-[2,3-dihydro-1,1,2,6-tetramethyl-3-(1-methylethyl)-1H-5-indenyl]ethanon; 5',6',7',8'-Tetrahydro-3',5',5',6',8',8'-hexamethyl-2-acetonaphthon;
• der aromatischen und araliphatischen Carbonsäuren und deren Ester, dabei bevorzugt Benzoesäure; Phenylessigsäure; Methylbenzoat; Ethylbenzoat; Hexylbenzoat; Methylphenylacetat; Ethylphenylacetat; Geranylphenylacetat; Phenylethyl-phenylacetat; Methylcinnmat; Ethylcinnamat; Benzylcinnamat; Phenylethylcinnamat; Cinnamylcinnamat; Allylphenoxyacetat; Methylsalicylat; Isoamylsalicylat; Hexylsalicylat; Cyclohexylsalicylat; Cis-3-Hexenylsalicylat; Benzylsalicylat; Phenylethylsalicylat; Methyl-2,4-dihydroxy-3,6-dimethylbenzoat; Ethyl-3-phenylglycidat; Ethyl-3-methyl-3-phenylglycidat;
• der stickstoffhaltigen aromatischen Verbindungen, dabei bevorzugt 2,4,6-Trinitro-1,3-dimethyl-5-tert.-butylbenzol; 3,5-Dinitro-2,6-dimethyl-4-tert.-butylacetophenon; Zimtsäurenitril; 3-Methyl-5-phenyl-2-pentensäurenitril; 3-Methyl-5-phenylpentansäurenitril; Methylanthranilat; Methy-N-methylanthranilat; Schiff'sche Basen von Methylanthranilat mit 7-Hydroxy-3,7-dimethyloctanal, 2-Methyl-3-(4-tert.-butylphenyl)propanal oder 2,4-Dimethyl-3-cyclohexencarbaldehyd; 6-Isopropylchinolin; 6-Isobutylchinolin; 6-sec.-Butylchinolin;2-(3-Phenylpropyl)pyridin; Indol; Skatol; 2-Methoxy-3-isopropylpyrazin; 2-lsobutyl-3-methoxypyrazin;
• der Phenole, Phenylether und Phenylester, dabei bevorzugt Estragol; Anethol; Eugenol; Eugenylmethylether; Isoeugenol; Isoeugenylmethylether; Thymol; Carvacrol; Diphenylether; beta-Naphthylmethylether; beta-Naphthylethylether; beta-Naphthylisobutylether; 1,4-Dimethoxybenzol; Eugenylacetat; 2-Methoxy-4-methylphenol; 2-Ethoxy-5-(1-propenyl)phenol; p-Kresylphenylacetat;
• der heterocyclischen Verbindungen, dabei bevorzugt 2,5-Dimethyl-4-hydroxy-2H-furan-3-on; 2-Ethyl-4-hydroxy-5-methyl-2H-furan-3-on; 3-Hydroxy-2-methyl-4H-pyran-4-on; 2-Ethyl-3-hydroxy-4H-pyran-4-on;
• der Lactone, dabei bevorzugt 1,4-Octanolid; 3-Methyl-1,4-octanolid; 1,4-Nonanolid; 1,4-Decanolid; 8-Decen-1,4-olid; 1,4-Undecanolid; 1,4-Dodecanolid; 1,5-Decanolid; 1,5-Dodecanolid;4-Methyl-1,4-decanolid; 1,15-Pentadecanolid; cis- und trans-11-Pentadecen-1,15-olid; cis- und trans-12-Pentadecen-1,15-olid; 1,16-Hexadecanolid; 9-Hexadecen-1,16-olid; 10-Oxa-1,16-hexadecanolid; 11-Oxa-1,16-hexadecanolid; 12-Oxa-1,16-hexadecanolid; Ethylen-1,13-tridecandioat; Cumarin; 2,3-Dihydrocumarin; Octahydrocumarin.

The selection of fragrances is very extensive; Corresponding fragrances that can be used according to the invention can be found, for. Am " S. Arctander, Perfume and Flavor Chemicals, Vols. I and II, Montclair, NJ, 1969, self-published " or " H. Surburg and J. Panten, Common Fragrance and Flavor Materials, 6th ed., Wiley-VCH, Weinheim, 2016 ". In detail, fragrances are mentioned below, selected from the group

• the hydrocarbons, preferably 3-carene; α-pinene; β-pinene; α-terpinene; γ-terpinene; p-cymene; bisabolene; camphene; caryophyllene; cedren; farnese; limonene; longifolia; myrcene; ocimene; valencene; (E,Z)-1,3,5-undecatriene; styrene; diphenylmethane;
• of aliphatic alcohols, preferably hexanol; octanol; 3-octanol; 2,6-dimethylheptanol; 2-methyl-2-heptanol; 2-methyl-2-octanol; (E)-2-hexenol; (E)- and (Z)-3-hexenol; 1-octen-3-ol; mixture of 3,4,5,6,6-pentamethyl-3/4-hepten-2-ol and 3,5,6,6-tetramethyl-4-methyleneheptan-2-ol; (E,Z)-2,6-nonadienol; 3,7-dimethyl-7-methoxyoctan-2-ol; 9-decenol; 10-undecenol; 4-methyl-3-decen-5-ol; 3,7-DIMETHYL-6-OCTEN-1-OL;
• the aliphatic aldehydes and their acetals, preferably hexanal; heptanal; octanal; nonanal; decanal; undecanal; dodecanal; tridecanal; 2-methyloctanal; 2-methylnonanal; (E)-2-hexenal; (Z)-4-heptenal; 2,6-dimethyl-5-heptenal; 10-undecenal; (E)-4-decenal; 2-dodecenal; 2,6,10-trimethyl-9-undecenal; 2,6,10-trimethyl-5,9-undecadienal; heptanal diethyl acetal; 1,1-dimethoxy-2,2,5-trimethyl-4-hexene; citronellyloxyacetaldehyde; 1-(1-methoxypropoxy)-(E/Z)-3-hexene;
• of aliphatic ketones and their oximes, preferably 2-heptanone; 2-octanone; 3-octanone; 2-nonanone; 5-methyl-3-heptanone; 5-methyl-3-heptanone oxime; 2,4,4,7-tetramethyl-6-octen-3-one; 6-methyl-5-hepten-2-one; 1-(1,2,3,4,5,6,7,8-OCTAHYDRO-2,3,8,8-TETRAMETHYL-2-NAPHTHYL)ETHANE-1-ONE; 3-METHYL-4-(2,6,6-TRIMETHYL-2-CYCLOHEXEN-1-YL)-3-BUTEN-2-ONE
• the aliphatic sulfur-containing compounds, preferably 3-methylthiohexanol; 3-methylthiohexyl acetate; 3-mercaptohexanol; 3-mercaptohexyl acetate; 3-mercaptohexyl butyrate; 3-acetylthiohexyl acetate; 1-menthene-8-thiol;
• of aliphatic nitriles, preferably 2-nonenonitrile; 2-undecenonitrile; 2-tridecenonitrile; 3,12-tridecadienonitrile; 3,7-dimethyl-2,6-octadienonitrile; 3,7-dimethyl-6-octenonitrile;
• the ester of aliphatic carboxylic acids, preferably (E)- and (Z)-3-hexenyl formate; ethyl acetoacetate; isoamyl acetate; hexyl acetate; 3,5,5-trimethylhexyl acetate; 3-methyl-2-butenyl acetate; (E)-2-hexenyl acetate; (E)- and (Z)-3-hexenyl acetate; octyl acetate; 3-octyl acetate; 1-octen-3-yl acetate; ethyl butyrate; butyl butyrate; isoamyl butyrate; hexyl butyrate; (E)- and (Z)-3-hexenyl isobutyrate; hexyl crotonate; ethyl isovalerate; ethyl 2-methylpentanoate; ethyl hexanoate; allyl hexanoate; ethyl heptanoate; allyl heptanoate; ethyl octanoate; ethyl (E,Z)-2,4-decadienoate; methyl 2-octinate; methyl 2-noninate; allyl 2-isoamyloxyacetate; methyl 3,7-dimethyl-2,6-octadienoate; 4-methyl-2-pentyl crotonate;
• the acyclic terpene alcohols, preferably citronellol; geraniol; nerol; linalool; lavadulol; nerolidol; farnesol; tetrahydrolinalool; tetrahydrogeraniol; 2,6-dimethyl-7-octen-2-ol; 2,6-dimethyloctan-2-ol; 2-methyl-6-methylene-7-octen-2-ol; 2,6-dimethyl-5,7-octadien-2-ol; 2,6-dimethyl-3,5-octadien-2-ol; 3,7-dimethyl-4,6-octadien-3-ol; 3,7-dimethyl-1,5,7-octatrien-3-ol 2,6-dimethyl-2,5,7-octatrien-1-ol; and their formates, acetates, propionates, isobutyrates, butyrates, isovalerianates, pentanoates, hexanoates, crotonates, tiglinates and 3-methyl-2-butenoates;
• the acyclic terpene aldehydes and ketones, preferably geranial; neral; citronellal; 7-hydroxy-3,7-dimethyloctanal; 7-methoxy-3,7-dimethyloctanal; 2,6,10-trimethyl-9-undecenal; geranylacetone; as well as the dimethyl and diethyl acetals of geranial, neral, 7-hydroxy-3,7-dimethyloctanal;
• the cyclic terpene alcohols, preferably isopulegol; alpha-terpineol; terpinenol-4; menthan-8-ol; menthan-1-ol; menthan-7-ol; borneol; isoborneol; linalool oxide; nopole; cedrol; ambrinol; vetiverol; guajol; and their formates, acetates, propionates, isobutyrates, butyrates, isovalerianates, pentanoates, hexanoates, crotonates, tiglinates and 3-methyl-2-butenoates; menthyl formate; menthyl propionate; menthyl butyrate; menthyl isobutyrate; menthyl isovalerianate; menthyl hexanoate; menthyl crotonate; menthyl tiglinate;
• the cyclic terpene aldehydes and ketones, preferably menthone; isomenthone; 8-mercaptomenthan-3-one; carvone; camphor; fenchone; alpha ionone; beta-ionone; beta-n-methyl ionone; beta-isomethylionone; alpha iron; alpha damascone; beta-damascone; beta-damascenone; delta damascone; gamma damascone; 1-(2,4,4-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one; 1,3,4,6,7,8a-hexahydro-1,1,5,5-tetramethyl-2H-2,4a-methanonaphthalen-8(5H)-one; 2-methyl-4-(2,6, 6-trimethyl-1-cyclohexen-1-yl)-2-butenal; nootkatone; dihydro-nootkatone; 4,6,8-megastigmatrien-3-one; alpha-sinensal; beta-sinensal; acetylated cedarwood oil (methyl cedryl ketone);
• of cyclic alcohols, preferably 4-tert-butylcyclohexanol; 3,3,5-trimethylcyclohexanol; 3-isocamphylcyclohexanol; 2,6,9-trimethyl-Z2,Z5,E9-cyclododecatrien-1-ol; 2-isobutyl-4-methyltetrahydro-2H-pyran-4-ol;
• of cycloaliphatic alcohols, preferably alpha,3,3-trimethylcyclohexylmethanol; 1-(4-isopropylcyclohexyl)ethanol; 2-methyl-4-(2,2,3-trimethyl-3-cyclopent-1-yl)butanol; 2-methyl-4-(2,2,3-trimethyl-3-cyclopent-1-yl)-2-buten-1-ol; 2-ethyl-4-(2,2,3-trimethyl-3-cyclopent-1-yl)-2-buten-1-ol; 3-methyl-5-(2,2,3-trimethyl-3-cyclopent-1-yl)pentan-2-ol; 3-methyl-5-(2,2,3-trimethyl-3-cyclopent-1-yl)-4-penten-2-ol; 3,3-dimethyl-5-(2,2,3-trimethyl-3-cyclopent-1-yl)-4-penten-2-ol; 1-(2,2,6-trimethylcyclohexyl)pentan-3-ol; 1-(2,2,6-trimethylcyclohexyl)hexan-3-ol;
• the cyclic and cycloaliphatic ethers, preferably cineole; cedryl methyl ether; cyclododecyl methyl ether; 1,1-dimethoxycyclododecane; (ethoxymethoxy)cyclododecane; alpha-cedrene epoxide; 3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan; 3a-ethyl-6,6,9a-trimethyldodecahydronaphtho[2,1-b]furan; 1,5,9-trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-diene; rose oxide; 2-(2,4-dimethyl-3-cyclohexen-1-yl)-5-methyl-5-(1-methylpropyl)-1,3-dioxane;
• the cyclic and macrocyclic ketones, preferably 4-tert-butylcyclohexanone; 2,2,5-trimethyl-5-pentylcyclopentanone; 2-heptylcyclopentanone; 2-pentylcyclopentanone; 2-hydroxy-3-methyl-2-cyclopenten-1-one; 3-methyl-cis-2-penten-1-yl-2-cyclopenten-1-one; 3-methyl-2-pentyl-2-cyclopenten-1-one; 3-methyl-4-cyclopentadecenone; 3-methyl-5-cyclopentadecenone; 3-methylcyclopentadecanone; 4-(1-ethoxyvinyl)-3,3,5,5-tetramethylcyclohexanone; 4-tert-pentylcyclohexanone; 5-cyclohexadecen-1-one; 6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone; 8-cyclohexadecen-1-one; 9-cycloheptadecen-1-one; cyclopentadecanone; cyclohexadecanone;
• the cycloaliphatic aldehydes, preferably 2,4-dimethyl-3-cyclohexenecarbaldehyde; 2-methyl-4-(2,2,6-trimethyl-cyclohexen-1-yl)-2-butenal; 4-(4-hydroxy-4-methylpentyl)-3-cyclohexenecarbaldehyde; 4-(4-methyl-3-penten-1-yl)-3-cyclohexenecarbaldehyde;
• the cycloaliphatic ketones, preferably 1-(3,3-dimethylcyclohexyl)-4-penten-1-one; 2,2-dimethyl-1-(2,4-dimethyl-3-cyclohexen-1-yl)-1-propanone; 1-(5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one; 2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydro-2-naphthalenyl methyl ketone; methyl 2,6,10-trimethyl-2,5,9-cyclododecatrienyl ketone; tert -butyl (2,4-dimethyl-3-cyclohexen-1-yl) ketone;
• the ester of cyclic alcohols, preferably 2-tert-butylcyclohexyl acetate; 4-tert-butylcyclohexyl acetate; 2-tert-pentylcyclohexyl acetate; 4-tert-pentylcyclohexyl acetate; 3,3,5-trimethylcyclohexyl acetate; decahydro-2-naphthyl acetate; 2-cyclopentylcyclopentylcrotonate; 3-pentyltetrahydro-2H-pyran-4-yl acetate; decahydro-2,5,5,8a-tetramethyl-2-naphthyl acetate; 4,7-methano-3a,4,5,6,7,7a-hexahydro-5 or 6-indenyl acetate; 4,7-methano-3a,4,5,6,7,7a-hexahydro-5 or 6-indenylpropionate; 4,7-methano-3a,4,5,6,7,7a-hexahydro-5 or 6-indenyl isobutyrate; 4,7-methanooctahydro-5 or 6-indenyl acetate;
• the ester of cycloaliphatic alcohols, preferably 1-cyclohexylethyl crotonate;
• the ester of cycloaliphatic carboxylic acids, preferably allyl 3-cyclohexylpropionate; allylcyclohexyloxyacetate; cis and trans methyl dihydrojasmonate; cis and trans methyl jasmonate; methyl 2-hexyl-3-oxocyclopentanecarboxylate; ethyl 2-ethyl-6,6-dimethyl-2-cyclohexenecarboxylate; ethyl 2,3,6,6-tetramethyl-2-cyclohexenecarboxylate; ethyl 2-methyl-1,3-dioxolane-2-acetate;
• the araliphatic alcohols, preferably benzyl alcohol; 1-phenylethyl alcohol; 2-phenylethyl alcohol; 3-phenylpropanol; 2-phenylpropanol; 2-phenoxyethanol; 2,2-dimethyl-3-phenylpropanol; 2,2-dimethyl-3-(3-methylphenyl)propanol; 1,1-dimethyl-2-phenylethyl alcohol; 1,1-dimethyl-3-phenylpropanol; 1-ethyl-1-methyl-3-phenylpropanol; 2-methyl-5-phenylpentan-1-ol; 3-methyl-5-phenylpentanol; 3-phenyl-2-propen-1-ol; 4-methoxybenzyl alcohol; 1-(4-isopropylphenyl)ethanol;
• the ester of araliphatic alcohols and aliphatic carboxylic acids, preferably benzyl acetate; benzyl propionate; benzyl isobutyrate; benzyl isovalerianate; 2-phenylethyl acetate; 2-phenylethyl propionate; 2-phenylethyl isobutyrate; 2-phenylethyl isovalerianate; 1-phenylethyl acetate; alpha-trichloromethylbenzyl acetate; alpha,alpha-dimethylphenylethyl acetate; alpha,alpha-dimethylphenylethyl butyrate; cinnamyl acetate; 2-phenoxyethyl isobutyrate; 4-methoxybenzyl acetate;
• the araliphatic ether, preferably 2-phenylethyl methyl ether; 2-phenylethyl isoamyl ether; 2-phenylethyl-1-ethoxyethyl ether; phenylacetaldehyde dimethyl acetal; phenylacetaldehyde diethyl acetal; hydratropaaldehyde dimethyl acetal; phenylacetaldehyde glycerol acetal; 2,4,6-trimethyl-4-phenyl-1,3-dioxane; 4,4a,5,9b-tetrahydroindeno[1,2-d]-m-dioxin; 4,4a,5,9b-tetrahydro-2,4-dimethylindeno[1,2-d]-m-dioxin;
• the aromatic and araliphatic aldehydes, preferably benzaldehyde; phenylacetaldehyde; 3-phenylpropanal; hydratropaaldehyde; 4-methylbenzaldehyde; 4-methylphenylacetaldehyde; 3-(4-ethylphenyl)-2,2-dimethylpropanal; 2-methyl-3-(4-isopropylphenyl)propanal; 2-methyl-3-(4-tert-butylphenyl)propanal; 2-methyl-3-(4-isobutylphenyl)propanal; 3-(4-tert-butylphenyl)propanal; cinnamaldehyde; alpha-butylcinnamaldehyde; alpha-amylcinnamaldehyde; alpha-hexylcinnamaldehyde; 3-methyl-5-phenylpentanal; 4-methoxybenzaldehyde; 4-hydroxy-3-ethoxybenzaldehyde; 3,4-methylenedioxybenzaldehyde; 3,4-dimethoxybenzaldehyde; 2-methyl-3-(4-methoxyphenyl)propanal; 2-methyl-3-(4-methylenedioxyphenyl)propanal;
• the aromatic and araliphatic ketones, preferably acetophenone; 4-methylacetophenone; 4-methoxyacetophenone; 4-tert-butyl-2,6-dimethylacetophenone; 4-phenyl-2-butanone; 4-(4-hydroxyphenyl)-2-butanone; 1-(2-naphthalenyl)ethanone; 2-benzofuranylethanone; (3-methyl-2-benzofuranyl)ethanone; benzophenone; 1,1,2,3,3,6-hexamethyl-5-indanyl methyl ketone; 6-tert-butyl 1,1-dimethyl-4-indanyl methyl ketone; 1-[2,3-dihydro-1,1,2,6-tetramethyl-3-(1-methylethyl)-1H-5-indenyl]ethanone; 5',6',7',8'-tetrahydro-3',5',5',6',8',8'-hexamethyl-2-acetonaphthone;
• of aromatic and araliphatic carboxylic acids and their esters, preferably benzoic acid; phenylacetic acid; methyl benzoate; ethyl benzoate; hexyl benzoate; methyl phenyl acetate; ethyl phenyl acetate; geranyl phenyl acetate; phenylethyl phenylacetate; methyl cinnmate; ethyl cinnamate; benzyl cinnamate; phenylethyl cinnamate; cinnamyl cinnamate; allylphenoxy acetate; methyl salicylate; isoamyl salicylate; hexyl salicylate; cyclohexyl salicylate; cis-3-hexenyl salicylate; benzyl salicylate; phenylethyl salicylate; methyl 2,4-dihydroxy-3,6-dimethylbenzoate; ethyl 3-phenylglycidate; ethyl 3-methyl-3-phenylglycidate;
• the nitrogen-containing aromatic compounds, preferably 2,4,6-trinitro-1,3-dimethyl-5-tert-butylbenzene; 3,5-dinitro-2,6-dimethyl-4-tert-butylacetophenone; cinnamonitrile; 3-methyl-5-phenyl-2-pentenonitrile; 3-methyl-5-phenylpentanonitrile; methyl anthranilate; methyl N-methyl anthranilate; Schiff's bases of methyl anthranilate with 7-hydroxy-3,7-dimethyloctanal, 2-methyl-3-(4-tert-butylphenyl)propanal or 2,4-dimethyl-3-cyclohexenecarbaldehyde; 6-isopropylquinoline; 6-isobutylquinoline; 6-sec-butylquinoline; 2-(3-phenylpropyl)pyridine; indole; skatole; 2-methoxy-3-isopropylpyrazine; 2-isobutyl-3-methoxypyrazine;
• of phenols, phenyl ethers and phenyl esters, preferably estragol; anethole; eugenol; eugenyl methyl ether; isoeugenol; isoeugenyl methyl ether; thymol; carvacrol; diphenyl ether; beta-naphthyl methyl ether; beta-naphthyl ethyl ether; beta-naphthyl isobutyl ether; 1,4-dimethoxybenzene; eugenyl acetate; 2-methoxy-4-methylphenol; 2-ethoxy-5-(1-propenyl)phenol; p-cresylphenyl acetate;
• of heterocyclic compounds, preferably 2,5-dimethyl-4-hydroxy-2H-furan-3-one; 2-ethyl-4-hydroxy-5-methyl-2H-furan-3-one; 3-hydroxy-2-methyl-4H-pyran-4-one; 2-ethyl-3-hydroxy-4H-pyran-4-one;
• the lactones, preferably 1,4-octanolide; 3-methyl-1,4-octanolide; 1,4-nonanolide; 1,4-decanolide; 8-decene-1,4-olide; 1,4-undecanolide; 1,4-dodecanolide; 1,5-decanolide; 1,5-dodecanolide; 4-methyl-1,4-decanolide; 1,15-pentadecanolide; cis and trans 11-pentadecene-1,15-olide; cis and trans 12-pentadecene-1,15-olide; 1,16-hexadecanolide; 9-hexadecene-1,16-olide; 10-oxa-1,16-hexadecanolide; 11-oxa-1,16-hexadecanolide; 12-oxa-1,16-hexadecanolide; ethylene 1,13-tridecanedioate; coumarin; 2,3-dihydrocoumarin; octahydrocoumarin.

The fragrances used according to the invention can also be essential oils, concretes, absolutes, resins, resinoids, balms and/or tinctures. Preferred essential oils, concretes, absolutes, resins, resinoids, balms and/or tinctures are preferably to be selected from the group consisting of:
amber tincture; amyris oil; angelica seed oil; angelica root oil; anise oil; valerian oil; basil oil; tree moss absolute; bay oil; mugwort oil; benzoeresin; bergamot oil; beeswax absolute; birch tar oil; bitter almond oil; savory oil; buckwheat oil; cabreuva oil; cade oil; Calmus oil; camphor oil; cananga oil; cardamom oil; cascarilla oil; cassia oil; cassie absolute; castoreum absolute; cedar leaf oil; cedarwood oil; cistus oil; citronella oil; lemon oil; copaiva balm; copaiva balm oil; coriander oil; costus root oil; cumin oil; cypress oil; davana oil; dill weed oil; dill seed oil; eau de brouts absolute; oakmoss absolute; elemi oil; tarragon oil; Eucalyptus citriodora oil; eucalyptus oil; fennel oil; spruce needle oil; galbanum oil; galbanum resin; geranium oil; grapefruit oil; guaiac wood oil; gurjun balm; gurjun balm oil; helichrysum absolute; helichrysum oil; ginger oil; orris root absolute; orris root oil; jasmine absolute; calamus oil; chamomile oil blue; chamomile oil roman; carrot seed oil; cascarilla oil; pine needle oil; spearmint oil; cumin oil; labdanum oil; labdanum absolute; labdanum resin; lavandin absolute; lavandin oil; lavender absolute; lavender oil; lemongrass oil; lovage oil; lime oil distilled; squeezed lime oil; linaloe oil; litseacubeba oil; bay leaf oil; mace oil; marjoram oil; tangerine oil; massoi bark oil; mimosa absolute; musk seed oil; musk tincture; clary sage oil; nutmeg oil; myrrh absolute; myrrh oil; myrtle oil; clove leaf oil; clove flower oil; neroli oil; olibanum absolute; olibanum oil; opoponax oil; orange blossom absolute; orange oil; origanum oil; palmarosa oil; patchouli oil; perilla oil; Peru balsam oil; parsley leaf oil; parsley seed oil; petitgrain oil; Peppermint oil; pepper oil; allspice oil; pine oil; poley oil; rose absolute; rosewood oil; rose oil; rosemary oil; sage oil Dalmatian; sage oil spanish; sandalwood oil; celery seed oil; spilavender oil; star anise oil; styrax oil; marigold oil; pine needle oil; tea tree oil; turpentine oil; thyme oil; tolu balsam; tonka absolute; tuberose absolute; vanilla extract; violet leaf absolute; verbena oil; vetiver oil; juniper berry oil; wine yeast oil; wormwood oil; oil of wintergreen; ylang oil; hyssop oil; civet absolute; cinnamon leaf oil; cinnamon bark oil.

A kit according to the invention is particularly preferred if d) additionally comprises a packaging which comprises or accommodates components a, b and, if applicable, c. In sales in particular, it is advantageous if the individual components are packaged appropriately. The packaging preferably consists of paper, cardboard or cardboard or includes these substances.

It is preferred according to the invention if the water-miscible solvent is an alcohol or an ether, preferably ethanol or dipropylene glycol methyl ether. Our own investigations have shown that the use of alcohols or ethers, in particular ethanol or dipropylene glycol methyl ether, has particularly good properties in devices according to the invention. Both ethanol and dipropylene glycol methyl ether are miscible with water and have sufficient vapor pressure at room temperature.

In a kit according to the invention, it is preferred if the composition of the kit according to the invention is liquid and all components of the composition are dissolved, ie a homogeneous phase is formed. It is also possible - although less preferred - if individual components of the composition of the Kits according to the invention are not or only partially dissolved and (partly) are present as a solid. In this case, however, it is preferred if, after the addition of water to the composition of the kit according to the invention, all solids are dissolved during the production of the composition of the device according to the invention and a homogeneous phase is formed. In a device according to the invention, it is preferred if the composition of the device according to the invention is liquid and all components of the composition are dissolved, ie a homogeneous phase is formed. Depending on the fragrances used, there is also the possibility that the fragrances or active ingredients are emulsified in the mixture of water and the water-miscible solvent or some of the fragrances or active ingredients are emulsified and some are dissolved. In this case, it is preferred according to the invention if a heterogeneous mixture is present.

According to the invention, diffusion rods are preferred in which the fibers of plant origin are selected from the group consisting of cellulose fibers, seed fibers, bast fibers and hard fibers. It is particularly preferred here if the fibers of plant origin are cellulose fibers.

The use of diffusion sticks that comprise fibers of vegetable origin or consist of fibers of vegetable origin has the advantage that the diffusion sticks can be added to paper recycling after use and can be completely biodegraded. So there is even the possibility that corresponding diffusion sticks can be added to the compost. Unlike the use of diffusing sticks that include plastics, the diffusing sticks that include vegetable fibers break down into their component parts and are therefore biodegradable and do not pollute the environment.

According to the invention, diffusion rods are preferred which comprise fibers of vegetable origin and no plastics.

In the context of the present invention, wood or other parts of plants is not understood to mean any material that comprises or consists of plant fibers or cellulose fibers. In the context of the present invention, plant fibers or cellulose fibers are understood as meaning a fiber which results from mechanical and/or chemical processing of wood or other parts of plants, as is customary in papermaking, for example.

According to the invention, it is preferred here if the mass fraction of cellulose fibers is greater than or equal to 60.0%, preferably greater than or equal to 70.0%, particularly is preferably greater than 75.0%, based on the total mass of the diffusion rod and determined as the air-dry mass fraction (air dry).

It is also preferred according to the invention if the mass fraction of cellulose fibers is less than or equal to 90.0%, preferably less than or equal to 85%, particularly preferably less than or equal to 80.0%, based on the total mass of the diffusion rod and determined as the air-dry mass fraction (air dry) .

It is preferred according to the invention if the mass fraction of cellulose fibers is in the range from 60.0% to 90.0%, preferably in the range from 70.0% to 85.0%, particularly preferably in the range from 75.0% to 80 .0% is based on the total mass of the diffusion stick and determined as the air-dry mass fraction (air dry).

The water content in air-dried diffusion sticks is usually in the range from 1 to 7% by weight.

It is preferred according to the invention if the at least one diffusion bar (3, 3', 3") or all of the diffusion bars comprises a binder, the binder preferably being starch. The starch can be starch selected from the group consisting of natural starch, anionic starch, cationic starch, peroxidized starch, etherified starch, esterified starch, oxidized starch, hydrolyzed starch, dextrinated starch, hydroxyethylated starch and acetylated starch The use of natural starch is particularly preferred according to the invention.

It is preferred according to the invention if the mass fraction of binder is in the range from 1.0% to 10.0%, preferably in the range from 2.0% to 8.0%, particularly preferably in the range from 3.0% to 5.0%, based on the total mass of the diffusion stick and determined as the air-dry mass fraction (air dry).

Our own investigations have surprisingly shown that diffusion rods comprising cellulose fibers and starch as binders have particularly good transport properties for the compositions of the device. Normally, the person skilled in the art would have assumed that diffusion rods based on cellulose fibers would swell when they came into contact with compositions with a high water content and would no longer be functional within a short time. Our own investigations have shown that diffusion sticks made of cellulose fibers and starch are very compatible with aqueous compositions.

It is preferred according to the invention that the at least one diffusion rod (3, 3′, 3″) or all of the diffusion rods comprises one or more fillers, the fillers preferably being carbonates.

It is preferred according to the invention if the carbonate or carbonates are selected from the group consisting of magnesium carbonate, calcium carbonate, beryllium carbonate, lithium carbonate, sodium carbonate, potassium carbonate and calcium-magnesium carbonate, preferably selected from the group consisting of magnesium carbonate, calcium carbonate and calcium magnesium carbonate.

It is preferred according to the invention if the mass fraction of filler is in the range from 3.0% to 25.0%, preferably in the range from 5.0% to 20.0%, particularly preferably in the range from 10.0% to 15.0%, based on the total mass of the diffusion stick and determined as the air-dry mass fraction (air dry).

Our own investigations have shown that when using fillers and especially when using carbonates, the physical properties of the diffusion rods can be further improved. This enables the diffusing rods to be used for a long period of time even if they are mainly made of pulp fibers.

It is preferred according to the invention if the cellulose fibers are softwood, hardwood, straw cellulose fibers or mixtures thereof. It is particularly preferred here if the cellulose fibers are fibers made from pine, birch, poplar, spruce, beech or eucalyptus wood. Our own investigations have shown that these cellulose fibers have particularly good properties when transporting the composition of the device according to the invention.

It is preferred according to the invention if the diffusion rod comprises fresh fibers as the cellulose fibers and the mass fraction of fresh fibers is greater than or equal to 80%, preferably greater than or equal to 90%, particularly preferably greater than or equal to 95%, based on the total mass of the cellulose fibers and determined as the air-dry mass fraction (air dry) .

It is preferred according to the invention if all the cellulose fibers in the paper substrate are fresh fibres, i.e. the mass fraction of fresh fibers is 100%, based on the total mass of the cellulose fibers and determined as air-dry mass fraction (air dry).

It is preferred according to the invention if the diffusion rod comprises recycled fibers as cellulose fibers and the mass fraction of recycled fibers is greater than or equal to 40% is preferably greater than or equal to 50%, particularly preferably greater than or equal to 60%, based on the total mass of the cellulose fibers and determined as the air-dry mass fraction (air dry).

According to the invention, it is preferred if the diffusion rods additionally comprise auxiliary substances selected from the group consisting of inorganic fillers, binders (preferably starch), alum and/or glue.

In an alternative embodiment, diffusion sticks are preferred in which the fibers of animal origin are selected from the group consisting of wool, fine animal hair, coarse animal hair and silk.

In an alternative embodiment, diffusion sticks are preferred in which the fibers of animal origin are selected from the group consisting of wool, fine animal hair, coarse animal hair and silk.

In an alternative embodiment, diffusion rods are preferred in which at least one diffusion rod (3, 3', 3") consists of plastic or includes plastic, the polymer preferably being a polyester, particularly preferably the polyester is polyethylene terephthalate.

In the context of the present invention, a polymer or plastic is understood to mean a chemical substance that consists of macromolecules. It is particularly preferred according to the invention if the polymer is a synthetic polymer, i.e. a macromolecule that has been produced industrially or on a laboratory scale. According to the invention, the polymer is preferably not cellulose or lignin.

Also preferably according to the invention, the diffusion rod is not a diffusion rod that includes or consists of rattan, bamboo, balsa wood, Pedding cane or another wood.

It is preferred according to the invention if the at least one diffusion rod (3, 3′, 3″) is made of plastic or includes plastic and is a fiber diffusion rod. In the context of the present invention, a fiber diffusion rod is a diffusion rod that consists of individual Fibers are formed that run parallel to the length of the diffusion rod. To produce the fiber diffusion rods, the individual fibers can be, for example, glued together or thermally and/or bonded together by the application of pressure so that they form a solid fiber diffusion rod. Through the individual fibers form within of the diffusion rod from capillary spaces that are suitable for absorbing liquids and promoting them through the acting capillary forces.

It is preferred according to the invention if the at least one small diffusion rod (3, 3′, 3″) consists of plastic or comprises plastic and is a fiber diffusion rod and the at least one small diffusion rod comprises or consists of a polyethylene terephthalate.

Also preferably according to the invention, the diffusion rod is not a diffusion rod that comprises or consists of glass or glass fibers (glass fiber diffusion rods).

The diffusion rods can be colored with a dye. It is important to ensure that the dye is bound in the material of the diffusion rod and that the dye does not bleed into the liquid composition. Corresponding dyes are known to those skilled in the art. In order to improve the appearance of the device according to the invention, it is possible to use differently colored diffusion rods. In the context of the present invention, differently colored or designed diffusion rods are understood to belong to a single type, provided that the basic material from which the diffusion rods are formed is identical. For example, diffusion rods made of polyethylene terephthalate, which are only colored differently or contain other customary polymer additives, but are otherwise identical in design, are to be regarded as a single type of diffusion rod.

According to the invention, the diffusion rods are preferably of cylindrical design. However, there is also the possibility that other shapes are formed, such as cuboids. The rods can also have other cross-sections, such as hearts, stars, snowflakes.

It is preferred according to the invention if the diffusion rods have a diameter in the range from 2 to 10 mm, preferably in the range from 3 to 7 mm, particularly preferably in the range from 3 to 5 mm. Diffusion rods with a diameter of 4 mm ± 0.5 mm are usually used.

It is preferred according to the invention if the diffusion rods have a length in the range from 50 to 240 mm, preferably in the range from 80 to 220 mm, particularly preferably in the range from 90 to 200 mm. Diffusion rods with a length of 170 mm ± 20 mm, 200 mm ± 20 mm or 240 mm ± 20 mm are usually used.

The diffusion and evaporation rate of the composition can be controlled via the length, the diameter and the number of the diffusion rods. Usually three, four, five, six, seven, eight or nine diffusion sticks are used and are present in a kit according to the invention. In addition, the number, length and diameter are also adapted to the quantity or container size.

According to the invention, it is preferred if the diffusion rods were produced by rolling up paper.

It is preferred according to the invention if the diffusion rods have a hollow core along their axis. In this embodiment, the diffusion rod is a hollow cylinder with an (outside) diameter, a diameter of the core (inside diameter) and a wall thickness.

Surprisingly, it has been shown that diffusion rods that have a core along their axis have a higher evaporation rate. Without wishing to be bound by theory, it is assumed that the core acts as a capillary and further improves the transport of the composition. As is well known, the capillary action of a tube depends on the diameter of the capillary. Our own investigations have shown that with a diameter of less than 0.60 mm, the capillarity is so high that the entire core is filled with the composition. With a core diameter of more than 4.0 mm, on the other hand, the capillary action of the core is often only slightly pronounced.

Within the scope of the present invention, diffusion rods with a core diameter of less than or equal to 0.50 mm are regarded as diffusion rods without a core.

It is preferred according to the invention if the core is open at the ends of the diffusion rods and the diameter at the ends is at most 50% less than the average diameter of the core along the diffusion rod, preferably at most 25% less, more preferably at most 10% less. After the paper has been rolled up into a diffusion rod, the diffusion rods usually have to be cut to length, and the cut can result in the diameter of the core being smaller at the ends than along the diffusion rod. According to the invention, it is not preferred and should be avoided that the ends of the diffusion rod are closed, although a core is formed inside the diffusion rod.

According to the invention, a use is preferred in which the core has a diameter of at least 0.50 mm, preferably at least 0.60 mm, more preferably at least 0.70 mm.

According to the invention, a use is preferred in which the core has a maximum diameter of 3.5 mm, preferably a maximum of 2.5 mm, more preferably a maximum of 2.0 mm.

A use is preferred according to the invention, wherein the core has a diameter in the range of 0.50 mm to 3.5 mm, preferably in the range of 0.60 mm to 3.0 mm, more preferably in the range of 0.70 mm to 2.0mm.

Our own investigations have shown that with a diameter of the diffusion rods of 4 mm 50 mL of the composition the best vaporization properties are obtained when four diffusion rods with a length of 170 mm are used. With a 4 mm diameter diffusion rod for 100 mL of composition, the best vaporization properties are obtained when four 200 mm long diffusion rods are used. With a 4mm diameter diffusion rod for 120mL of composition, the best vaporization properties are obtained when four 240mm long diffusion rods are used. With a 4 mm diameter diffusion rod for 200 mL of composition, the best vaporization properties are obtained when eight 240 mm long diffusion rods are used. However, there is the possibility of using shorter diffusion rods and at the same time increasing the number and/or the diameter of the diffusion rods.

According to the invention, it is preferred if all of the diffusion rods are configured identically and no further diffusion rods are included. Alternatively, different diffusion sticks can also be mixed with one another, for example diffusion sticks that include or consist of fibers of plant origin can be mixed with diffusion sticks that include or consist of fibers of animal origin.

• 5 bis 90 Gew.-%, vorzugsweise 6 bis 70 Gew.-%, besonders bevorzugt 8 bis 65 Gew.-% des mit Wasser mischbaren Lösungsmittels
• 1 bis 25 Gew.-% vorzugsweise 2 bis 20 Gew.-%, besonders bevorzugt 4 bis 10 Gew.-% ein oder mehrere Wirkstoffe
• 10 bis 90 Gew.-%, vorzugsweise 20 bis 85 Gew.-%, besonders bevorzugt 25 bis 85 Gew.-% Wasser
  und
• 0 bis 20 Gew.-% vorzugsweise 0,5 bis 15 Gew.-%, besonders bevorzugt 1,0 bis 10 Gew.-% Tensid

umfasst oder daraus besteht, jeweils bezogen auf das Gesamtgewicht der Zusammensetzung.A device according to the invention is preferred, wherein the liquid composition

• 5 to 90% by weight, preferably 6 to 70% by weight, particularly preferably 8 to 65% by weight of the water-miscible solvent
• 1 to 25% by weight, preferably 2 to 20% by weight, particularly preferably 4 to 10% by weight, of one or more active ingredients
• 10 to 90% by weight, preferably 20 to 85% by weight, particularly preferably 25 to 85% by weight, water
  and
• 0 to 20% by weight, preferably 0.5 to 15% by weight, particularly preferably 1.0 to 10% by weight, of surfactant

comprises or consists of, in each case based on the total weight of the composition.

Our own investigations have shown that it is preferable if the ratio between all active ingredients and the surfactant is in the range between 1:2 and 2:1.

1. a) eine flüssige Zusammensetzung (5) bestehend aus oder umfassend
   • a1) 10 bis 90 Gew.-% Ethanol und/oder Dipropylenglycolmethylether
   • a2) 1 bis 25 Gew.-% eines oder mehrerer Wirkstoffe,
   • a3) 10 bis 90 Gew.-% Wasser und
     und
   • a4) 0 bis 10 Gew.-% Tensid, das einen nach Griffin berechneten HLB-Wert im Bereich von 3 bis 20 aufweist,
   bezogen auf das Gesamtgewicht der flüssigen Zusammensetzung
2. b) mindestens ein Diffusionsstäbchen (3, 3', 3") bestehend aus oder umfassend Zellstofffasern, natürlicher Stärke und ein oder mehrere Carbonate
   und
3. c) einen Behälter (2), der zumindest eine Behälteröffnung (4) aufweist und die flüssige Zusammensetzung (5) umfasst.

A device (1) for releasing an active ingredient into the environment is particularly preferred consisting of or comprising

1. a) a liquid composition (5) consisting of or comprising
   • a1) 10 to 90% by weight of ethanol and/or dipropylene glycol methyl ether
   • a2) 1 to 25% by weight of one or more active ingredients,
   • a3) 10 to 90% by weight of water and
     and
   • a4) 0 to 10% by weight of surfactant which has an HLB value calculated according to Griffin in the range from 3 to 20,
   based on the total weight of the liquid composition
2. b) at least one diffusion rod (3, 3', 3") consisting of or comprising cellulose fibers, natural starch and one or more carbonates
   and
3. c) a container (2) which has at least one container opening (4) and comprises the liquid composition (5).

1. i) Herstellen oder Bereitstellen eines erfindungsgemäßen Kits,
2. ii) Überführen sämtlicher Komponenten der Zusammensetzung in einen Behälter, der zumindest eine Behälteröffnung (4) aufweist, und optionales Vermischen sämtlicher Komponenten,
   und
3. iii) Hinzufügen der Diffusionsstäbchen (3, 3', 3") durch die Behälteröffnung, sodass ein Teil der jeweiligen Diffusionsstäbchen (3, 3', 3") in Kontakt mit der Zusammensetzung befindet und ein Teil der jeweiligen Diffusionsstäbchen (3, 3', 3") sich durch die Behälteröffnung (4) aus dem Behälter erstreckt.

A further aspect of the present invention relates to a method for producing a device (1) for releasing an active substance, comprising the following steps:

1. i) producing or providing a kit according to the invention,
2. ii) transferring all components of the composition into a container which has at least one container opening (4) and optionally mixing all components,
   and
3. iii) adding the diffusing rods (3, 3', 3") through the container opening so that part of the respective diffusing rods (3, 3', 3") is in contact with the composition and part of the respective diffusing rods (3, 3' , 3") extends out of the container through the container opening (4).

• a1) ein mit Wasser mischbares Lösungsmittel,
• a2) ein oder mehrere Wirkstoffe,
• a3) Wasser
  und
• optional a4) ein Tensid

umfasst oder daraus besteht
und wobei die Diffusionsstäbchen aus

1. i) Fasern pflanzlicher Herkunft
   und/oder
2. ii) Fasern tierischer Herkunft

bestehen oder diese umfassen.A further aspect of the present invention relates to the use of diffusion rods in devices (1) for releasing an active substance, in which the composition comprising the active substance

• a1) a water-miscible solvent,
• a2) one or more active substances,
• a3) water
  and
• optionally a4) a surfactant

includes or consists of
and wherein the diffusion rods from

1. i) fibers of plant origin
   and or
2. ii) fibers of animal origin

exist or include.

The design of the kit according to the invention or the device according to the invention, in particular with regard to the diffusion rods and the composition, apply analogously to the use according to the invention. This applies in particular to the embodiments marked as preferred and particularly preferred.

The invention is explained below by way of example with reference to a drawing. This shows in Fig.1 a device (1) according to the invention for releasing an active substance into the environment in a schematic representation. A liquid composition (5) is located in a container (2) which has a container opening (4). The liquid composition (5) comprises water, a water-miscible solvent (ethanol or dipropylene glycol methyl ether) and one or more active ingredients (here fragrances). Three diffusion rods (3, 3', 3") are arranged in the container, which are in contact with the liquid composition (5) in the container and extend out of the container (2) through the container opening (4). Diffusion rods (3, 3', 3") are diffusion rods which mainly comprise cellulose fibers and additional natural starch and carbonates as fillers.

Example 1:

A composition is prepared comprising 60% by weight dipropylene glycol methyl ether, 30% by weight water and 10% by weight fragrance. This composition is transferred to a cylindrical glass bottle. Four diffusing rods made of cellulose fibers are inserted through the opening of the glass bottle, so that the liquid composition can be transported out of the glass bottle via the diffusing rods and evaporate on the surface of the diffusing rods.

The fragrance intensity is very good over the entire term.

Example 2:

A composition is prepared comprising 10% by weight ethanol, 80% by weight water, 5% by weight surfactant and 5% by weight fragrance. This composition is transferred to a cylindrical glass bottle. Four diffusing rods made of cellulose fibers are inserted through the opening of the glass bottle, so that the liquid composition can be transported out of the glass bottle via the diffusing rods and evaporate on the surface of the diffusing rods.

The fragrance intensity is very good over the entire term.

Claims (15)

Kit for the manufacture of a device (1) for releasing an active substance into the environment, comprising or consisting of a) a composition consisting of or comprising a1) a water-miscible solvent a2) one or more active ingredients b) at least one diffusion rod (3, 3', 3") consisting of or comprising i) fibers of plant origin
and or ii) fibers of animal origin. A kit according to claim 1, wherein the water-miscible solvent is an alcohol or an ether, preferably ethanol or dipropylene glycol methyl ether. A kit according to any one of the preceding claims, wherein the composition is liquid and all components are dissolved therein. Kit according to one of the preceding claims, wherein the fibers of plant origin are selected from the group consisting of pulp fibers, seed fibers, bast fibers and hard fibers. Kit according to one of the preceding claims, wherein the at least one diffusion rod (3, 3', 3") or all diffusion rods consist of fibers of vegetable origin, preferably of cellulose fibers. Kit according to one of claims 4 or 5, wherein the mass fraction of cellulose fibers is in the range from 60.0% to 90.0%, preferably in the range from 70.0% to 85.0%, particularly preferably in the range of 75 0% to 80.0%, based on the total mass of the diffusion stick and determined as an air-dry mass fraction (air dry). Kit according to one of the preceding claims, wherein the at least one diffusion rod (3, 3', 3") or all of the diffusion rods comprises a binder, the binder preferably being starch. A kit according to any one of claims 4 to 7, wherein the pulp fibers are softwood, hardwood, grass, straw pulp fibers or mixtures thereof. Kit according to one of Claims 4 to 8, in which the cellulose fibers are fibers from pine, birch, poplar, spruce, beech or eucalyptus wood. Kit according to one of the preceding claims, wherein the diffusion rods have a diameter in the range from 2 to 10 mm, preferably in the range from 3 to 7 mm, particularly preferably in the range from 3 to 5 mm. A kit according to any one of the preceding claims, wherein the diffusion sticks are made by rolling paper. A kit according to any one of the preceding claims, wherein the diffusing rod (1) has a hollow core (5) along its axis. A device (1) for releasing an active ingredient into the environment, preferably made from a kit according to any one of claims 1 to 29, consisting of or comprising a) a liquid composition (5) consisting of or comprising a1) a water-miscible solvent a2) one or more active substances
and a3) water b) at least one diffusion rod (3, 3', 3") consisting of or comprising i) fibers of vegetable origin and/or ii) fibers of animal origin and/or iii) a plastic
and c) a container (2) which has at least one container opening (4) and comprises the liquid composition (5). Use of diffusion rods in devices (1) for releasing an active substance, in which the active substance is contained in a composition which comprises or consists of the following components a1) a water-miscible solvent, a2) one or more active substances, a3) water,
and optionally a4) a surfactant and wherein the diffusion rods from i) fibers of plant origin
and or ii) fibers of animal origin exist or comprise these fibers. Diffusion rod (1), the diffusing rod being made by rolling paper and having a hollow core (5) along its axis, wherein the core has a diameter (d) in the range from 0.20 mm to 3.0 mm, preferably in the range from 0.25 mm to 3.0 mm, more preferably in the range from 0.30 mm to 2.0 mm wherein the diffusion rod has a wall thickness (W) in the range of 0.4 to 3.4 mm, preferably in the range of 0.5 to 2.0, more preferably in the range of 0.7 to 2.5 mm and wherein the diffusion rod has a length (L) in the range from 80 to 300 mm, preferably in the range from 80 to 260 mm, particularly preferably in the range from 90 to 240 mm, more preferably in the range from 170 to 240 mm.

Images