EP4075205A1 - Verfahren zur herstellung einer uhrentriebfeder und durch dieses verfahren erhaltene uhrentriebfeder - Google Patents
Verfahren zur herstellung einer uhrentriebfeder und durch dieses verfahren erhaltene uhrentriebfeder Download PDFInfo
- Publication number
- EP4075205A1 EP4075205A1 EP21168779.3A EP21168779A EP4075205A1 EP 4075205 A1 EP4075205 A1 EP 4075205A1 EP 21168779 A EP21168779 A EP 21168779A EP 4075205 A1 EP4075205 A1 EP 4075205A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- thin layer
- phosphorus
- intermediate layer
- nickel
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 29
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 56
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000000463 material Substances 0.000 claims abstract description 44
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 43
- 239000011574 phosphorus Substances 0.000 claims abstract description 43
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 28
- 230000008021 deposition Effects 0.000 claims abstract description 13
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 5
- 229910052796 boron Inorganic materials 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- 230000007423 decrease Effects 0.000 claims description 3
- 230000000750 progressive effect Effects 0.000 claims description 2
- 238000000151 deposition Methods 0.000 abstract description 13
- 230000005291 magnetic effect Effects 0.000 description 8
- OFNHPGDEEMZPFG-UHFFFAOYSA-N phosphanylidynenickel Chemical compound [P].[Ni] OFNHPGDEEMZPFG-UHFFFAOYSA-N 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000010979 ruby Substances 0.000 description 2
- 229910001750 ruby Inorganic materials 0.000 description 2
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910003271 Ni-Fe Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- QDWJUBJKEHXSMT-UHFFFAOYSA-N boranylidynenickel Chemical compound [Ni]#B QDWJUBJKEHXSMT-UHFFFAOYSA-N 0.000 description 1
- 230000005294 ferromagnetic effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000001459 lithography Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007425 progressive decline Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G04—HOROLOGY
- G04D—APPARATUS OR TOOLS SPECIALLY DESIGNED FOR MAKING OR MAINTAINING CLOCKS OR WATCHES
- G04D3/00—Watchmakers' or watch-repairers' machines or tools for working materials
- G04D3/0069—Watchmakers' or watch-repairers' machines or tools for working materials for working with non-mechanical means, e.g. chemical, electrochemical, metallising, vapourising; with electron beams, laser beams
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B15/00—Escapements
- G04B15/14—Component parts or constructional details, e.g. construction of the lever or the escape wheel
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B17/00—Mechanisms for stabilising frequency
- G04B17/20—Compensation of mechanisms for stabilising frequency
- G04B17/22—Compensation of mechanisms for stabilising frequency for the effect of variations of temperature
- G04B17/227—Compensation of mechanisms for stabilising frequency for the effect of variations of temperature composition and manufacture of the material used
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B17/00—Mechanisms for stabilising frequency
- G04B17/20—Compensation of mechanisms for stabilising frequency
- G04B17/26—Compensation of mechanisms for stabilising frequency for the effect of variations of the impulses
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B31/00—Bearings; Point suspensions or counter-point suspensions; Pivot bearings; Single parts therefor
- G04B31/08—Lubrication
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B43/00—Protecting clockworks by shields or other means against external influences, e.g. magnetic fields
- G04B43/007—Antimagnetic alloys
Definitions
- the first thin layer 11, the intermediate layer 12 and the second thin layer 13 are deposited so that the watchmaking wheel set 10 formed comprises, in the sense and the direction of growth of deposition of said layers, a phosphorus concentration gradient defined for example by a progressive growth through the first thin layer 11, a stable state through the intermediate layer 12 and a progressive decrease through the second layer thin 13.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Optics & Photonics (AREA)
- Plasma & Fusion (AREA)
- Manufacturing & Machinery (AREA)
- Gears, Cams (AREA)
- Electroplating Methods And Accessories (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Chemically Coating (AREA)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP21168779.3A EP4075205A1 (de) | 2021-04-16 | 2021-04-16 | Verfahren zur herstellung einer uhrentriebfeder und durch dieses verfahren erhaltene uhrentriebfeder |
JP2022031472A JP7378523B2 (ja) | 2021-04-16 | 2022-03-02 | 時計可動体を製造するための方法および方法を実施することにより得られる時計可動体 |
US17/692,303 US20220334539A1 (en) | 2021-04-16 | 2022-03-11 | Method for manufacturing a horological disc and horological disc obtained by its implementation |
CN202210413895.6A CN115220325A (zh) | 2021-04-16 | 2022-04-14 | 制造钟表运动件的方法和由实施该方法获得的钟表运动件 |
KR1020220047071A KR20220143605A (ko) | 2021-04-16 | 2022-04-15 | 시계 모빌을 제조하기 위한 방법 및 그 구현에 의해 획득된 시계 모빌 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP21168779.3A EP4075205A1 (de) | 2021-04-16 | 2021-04-16 | Verfahren zur herstellung einer uhrentriebfeder und durch dieses verfahren erhaltene uhrentriebfeder |
Publications (1)
Publication Number | Publication Date |
---|---|
EP4075205A1 true EP4075205A1 (de) | 2022-10-19 |
Family
ID=75562576
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP21168779.3A Pending EP4075205A1 (de) | 2021-04-16 | 2021-04-16 | Verfahren zur herstellung einer uhrentriebfeder und durch dieses verfahren erhaltene uhrentriebfeder |
Country Status (5)
Country | Link |
---|---|
US (1) | US20220334539A1 (de) |
EP (1) | EP4075205A1 (de) |
JP (1) | JP7378523B2 (de) |
KR (1) | KR20220143605A (de) |
CN (1) | CN115220325A (de) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH514873A (fr) * | 1969-07-11 | 1971-07-15 | Far Fab Assortiments Reunies | Procédé de fabrication d'une ancre d'horlogerie |
EP1927648A1 (de) * | 2006-12-01 | 2008-06-04 | Rolex Sa | Hydrophobe und oleophobe ultradünne Schicht, Herstellungsverfahren und Anwendung beim Uhrenbau als Epilame |
CH698230B1 (fr) * | 2006-11-02 | 2011-01-14 | Rolex Sa | Montre. |
CH707562A2 (fr) * | 2013-02-13 | 2014-08-15 | Nivarox Sa | Procédé de fabrication d'une pièce de micromécanique monobloc comportant au moins deux niveaux distincts. |
EP3432079A1 (de) * | 2017-07-12 | 2019-01-23 | Société anonyme de la Manufacture d'Horlogerie Audemars Piguet & Cie | Uhrenteil aus nichtmagnetischer binärer cuni-legierung |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH681370A5 (en) * | 1992-02-25 | 1993-03-15 | Estoppey Reber S A | Solid lubricant coating prodn. for reducing friction between soft parts - by applying nickel@-phosphorus@ layer and gold@ layer and then heat treating |
JP5113687B2 (ja) | 2008-02-25 | 2013-01-09 | セイコーインスツル株式会社 | 摺動部品およびそれを用いた時計 |
EP2263971A1 (de) * | 2009-06-09 | 2010-12-22 | Nivarox-FAR S.A. | Mikromechanisches Verbundbauteil und sein Herstellungsverfahren |
EP3273306A1 (de) * | 2016-07-19 | 2018-01-24 | Nivarox-FAR S.A. | Bauteil für uhrwerk |
-
2021
- 2021-04-16 EP EP21168779.3A patent/EP4075205A1/de active Pending
-
2022
- 2022-03-02 JP JP2022031472A patent/JP7378523B2/ja active Active
- 2022-03-11 US US17/692,303 patent/US20220334539A1/en active Pending
- 2022-04-14 CN CN202210413895.6A patent/CN115220325A/zh active Pending
- 2022-04-15 KR KR1020220047071A patent/KR20220143605A/ko not_active Application Discontinuation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH514873A (fr) * | 1969-07-11 | 1971-07-15 | Far Fab Assortiments Reunies | Procédé de fabrication d'une ancre d'horlogerie |
CH698230B1 (fr) * | 2006-11-02 | 2011-01-14 | Rolex Sa | Montre. |
EP1927648A1 (de) * | 2006-12-01 | 2008-06-04 | Rolex Sa | Hydrophobe und oleophobe ultradünne Schicht, Herstellungsverfahren und Anwendung beim Uhrenbau als Epilame |
CH707562A2 (fr) * | 2013-02-13 | 2014-08-15 | Nivarox Sa | Procédé de fabrication d'une pièce de micromécanique monobloc comportant au moins deux niveaux distincts. |
EP3432079A1 (de) * | 2017-07-12 | 2019-01-23 | Société anonyme de la Manufacture d'Horlogerie Audemars Piguet & Cie | Uhrenteil aus nichtmagnetischer binärer cuni-legierung |
Also Published As
Publication number | Publication date |
---|---|
JP2022164565A (ja) | 2022-10-27 |
US20220334539A1 (en) | 2022-10-20 |
KR20220143605A (ko) | 2022-10-25 |
CN115220325A (zh) | 2022-10-21 |
JP7378523B2 (ja) | 2023-11-13 |
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RIC1 | Information provided on ipc code assigned before grant |
Ipc: G04B 43/00 20060101ALI20240828BHEP Ipc: G04B 17/26 20060101ALI20240828BHEP Ipc: G04B 17/22 20060101ALI20240828BHEP Ipc: G04B 15/14 20060101AFI20240828BHEP |