EP4073012A1 - Filler mixture for chemical fastening systems and use thereof - Google Patents
Filler mixture for chemical fastening systems and use thereofInfo
- Publication number
- EP4073012A1 EP4073012A1 EP20812341.4A EP20812341A EP4073012A1 EP 4073012 A1 EP4073012 A1 EP 4073012A1 EP 20812341 A EP20812341 A EP 20812341A EP 4073012 A1 EP4073012 A1 EP 4073012A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- filler
- hardener
- hardener composition
- grain size
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000945 filler Substances 0.000 title claims abstract description 239
- 239000000203 mixture Substances 0.000 title claims abstract description 182
- 239000000126 substance Substances 0.000 title claims description 16
- 229920005989 resin Polymers 0.000 claims abstract description 178
- 239000011347 resin Substances 0.000 claims abstract description 178
- 150000001875 compounds Chemical class 0.000 claims abstract description 85
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000004848 polyfunctional curative Substances 0.000 claims description 135
- 238000006243 chemical reaction Methods 0.000 claims description 79
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- 239000003112 inhibitor Substances 0.000 claims description 25
- 239000000654 additive Substances 0.000 claims description 21
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 13
- 150000003839 salts Chemical class 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Chemical class 0.000 claims description 12
- 229910044991 metal oxide Inorganic materials 0.000 claims description 12
- 239000011342 resin composition Substances 0.000 claims description 10
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 9
- 150000004692 metal hydroxides Chemical class 0.000 claims description 9
- 150000004706 metal oxides Chemical class 0.000 claims description 9
- 238000006452 multicomponent reaction Methods 0.000 claims description 9
- 239000004593 Epoxy Substances 0.000 claims description 7
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- 229930185605 Bisphenol Natural products 0.000 claims description 2
- 239000002245 particle Substances 0.000 abstract description 40
- 150000002978 peroxides Chemical class 0.000 description 65
- -1 Acryl Chemical group 0.000 description 52
- 238000011049 filling Methods 0.000 description 52
- 238000001125 extrusion Methods 0.000 description 43
- 239000007787 solid Substances 0.000 description 36
- 235000013339 cereals Nutrition 0.000 description 27
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 21
- 238000005259 measurement Methods 0.000 description 20
- 239000003085 diluting agent Substances 0.000 description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 14
- 229920001567 vinyl ester resin Polymers 0.000 description 11
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- 239000011256 inorganic filler Substances 0.000 description 10
- 150000003254 radicals Chemical class 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- 239000004568 cement Substances 0.000 description 9
- 229910003475 inorganic filler Inorganic materials 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- 235000019400 benzoyl peroxide Nutrition 0.000 description 7
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 7
- 229940052303 ethers for general anesthesia Drugs 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- 229920006337 unsaturated polyester resin Polymers 0.000 description 7
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 6
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 6
- 229910010272 inorganic material Inorganic materials 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- 239000004570 mortar (masonry) Substances 0.000 description 6
- 239000006259 organic additive Substances 0.000 description 6
- 235000012239 silicon dioxide Nutrition 0.000 description 6
- 150000004992 toluidines Chemical class 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 150000002170 ethers Chemical class 0.000 description 5
- 239000001530 fumaric acid Substances 0.000 description 5
- 229910021485 fumed silica Inorganic materials 0.000 description 5
- 150000002334 glycols Chemical class 0.000 description 5
- 150000002440 hydroxy compounds Chemical class 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 150000002484 inorganic compounds Chemical class 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 229920000151 polyglycol Polymers 0.000 description 5
- 239000010695 polyglycol Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000010453 quartz Substances 0.000 description 5
- 239000002562 thickening agent Substances 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical group COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- PXKLMJQFEQBVLD-UHFFFAOYSA-N Bisphenol F Natural products C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 4
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- LNWBFIVSTXCJJG-UHFFFAOYSA-N [diisocyanato(phenyl)methyl]benzene Chemical compound C=1C=CC=CC=1C(N=C=O)(N=C=O)C1=CC=CC=C1 LNWBFIVSTXCJJG-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 239000007798 antifreeze agent Substances 0.000 description 4
- 239000000872 buffer Substances 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 150000007942 carboxylates Chemical class 0.000 description 4
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 4
- GGSUCNLOZRCGPQ-UHFFFAOYSA-N diethylaniline Chemical compound CCN(CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-N 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 239000012948 isocyanate Substances 0.000 description 4
- 150000002513 isocyanates Chemical class 0.000 description 4
- 125000005641 methacryl group Chemical group 0.000 description 4
- 235000010755 mineral Nutrition 0.000 description 4
- 239000001788 mono and diglycerides of fatty acids Chemical class 0.000 description 4
- 150000001451 organic peroxides Chemical class 0.000 description 4
- 150000002989 phenols Chemical class 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 4
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 4
- 239000006254 rheological additive Substances 0.000 description 4
- 238000000518 rheometry Methods 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 3
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- 239000011398 Portland cement Substances 0.000 description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 3
- 150000008064 anhydrides Chemical class 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 3
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- MHCLJIVVJQQNKQ-UHFFFAOYSA-N ethyl carbamate;2-methylprop-2-enoic acid Chemical class CCOC(N)=O.CC(=C)C(O)=O MHCLJIVVJQQNKQ-UHFFFAOYSA-N 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000010440 gypsum Substances 0.000 description 3
- 229910052602 gypsum Inorganic materials 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical class OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 3
- 229920001515 polyalkylene glycol Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 150000004760 silicates Chemical class 0.000 description 3
- 235000000346 sugar Nutrition 0.000 description 3
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- CSGAUKGQUCHWDP-UHFFFAOYSA-N 1-hydroxy-2,2,6,6-tetramethylpiperidin-4-ol Chemical compound CC1(C)CC(O)CC(C)(C)N1O CSGAUKGQUCHWDP-UHFFFAOYSA-N 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 2
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical class C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
- VUZNLSBZRVZGIK-UHFFFAOYSA-N 2,2,6,6-Tetramethyl-1-piperidinol Chemical compound CC1(C)CCCC(C)(C)N1O VUZNLSBZRVZGIK-UHFFFAOYSA-N 0.000 description 2
- ICKWICRCANNIBI-UHFFFAOYSA-N 2,4-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C(C(C)(C)C)=C1 ICKWICRCANNIBI-UHFFFAOYSA-N 0.000 description 2
- SGWZVZZVXOJRAQ-UHFFFAOYSA-N 2,6-Dimethyl-1,4-benzenediol Chemical compound CC1=CC(O)=CC(C)=C1O SGWZVZZVXOJRAQ-UHFFFAOYSA-N 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- SXGZJKUKBWWHRA-UHFFFAOYSA-N 2-(N-morpholiniumyl)ethanesulfonate Chemical compound [O-]S(=O)(=O)CC[NH+]1CCOCC1 SXGZJKUKBWWHRA-UHFFFAOYSA-N 0.000 description 2
- KZTWONRVIPPDKH-UHFFFAOYSA-N 2-(piperidin-1-yl)ethanol Chemical compound OCCN1CCCCC1 KZTWONRVIPPDKH-UHFFFAOYSA-N 0.000 description 2
- JKMHFZQWWAIEOD-UHFFFAOYSA-N 2-[4-(2-hydroxyethyl)piperazin-1-yl]ethanesulfonic acid Chemical compound OCC[NH+]1CCN(CCS([O-])(=O)=O)CC1 JKMHFZQWWAIEOD-UHFFFAOYSA-N 0.000 description 2
- LTHNHFOGQMKPOV-UHFFFAOYSA-N 2-ethylhexan-1-amine Chemical compound CCCCC(CC)CN LTHNHFOGQMKPOV-UHFFFAOYSA-N 0.000 description 2
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methylaniline Chemical compound CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 239000006004 Quartz sand Substances 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 2
- 150000001253 acrylic acids Chemical group 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
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- UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/0076—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials characterised by the grain distribution
- C04B20/0096—Fillers with bimodal grain size distribution
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
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- C04B14/06—Quartz; Sand
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- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
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- C04B14/04—Silica-rich materials; Silicates
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- C04B14/066—Precipitated or pyrogenic silica
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- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
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- C04B14/36—Inorganic materials not provided for in groups C04B14/022 and C04B14/04 - C04B14/34
- C04B14/368—Baryte
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- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/0076—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials characterised by the grain distribution
- C04B20/008—Micro- or nanosized fillers, e.g. micronised fillers with particle size smaller than that of the hydraulic binder
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/02—Alcohols; Phenols; Ethers
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- C—CHEMISTRY; METALLURGY
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
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- C04B24/121—Amines, polyamines
-
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- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
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- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/06—Acrylates
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- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
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- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/16—Polyurethanes
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- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/06—Inhibiting the setting, e.g. mortars of the deferred action type containing water in breakable containers ; Inhibiting the action of active ingredients
- C04B40/0641—Mechanical separation of ingredients, e.g. accelerator in breakable microcapsules
- C04B40/065—Two or more component mortars
-
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/02—Portland cement
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K3/22—Oxides; Hydroxides of metals
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K3/26—Carbonates; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0041—Non-polymeric ingredients chosen for their physico-chemical characteristics
- C04B2103/0043—Compounds chosen for their specific Moh's hardness
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- C—CHEMISTRY; METALLURGY
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00715—Uses not provided for elsewhere in C04B2111/00 for fixing bolts or the like
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/005—Additives being defined by their particle size in general
Definitions
- the invention relates to highly filled hardener compositions for use in injection mortars for chemical fastening technology, in particular highly filled hardener compositions based on peroxides for resin compositions based on free-radically curable compounds.
- Injection mortars based on free-radically hardenable compounds for chemical fastening technology are based on polymerizable resins that are usually hardened with peroxides as free-radical formers, also known as hardeners. These products are formulated as a multi-component, preferably two-component, and packaged in multi-compartment, preferably two-compartment containers to prevent reactions.
- the peroxide preferably used namely dibenzoyl peroxide
- phlegmatizing agents are used according to the prior art. These serve on the one hand as a diluent and on the other hand to avoid undesired decomposition of the radical formers.
- non-reactive plasticizers for example dicarboxylic acid esters, such as dioctyl phthalate, dioctyl adipate, have already been used as such phlegmatizers.
- liquid polyesters or polyalkylene glycol derivatives are used, as described, for example, in DE 3226602 A1, EP 0432087 A1 and EP 1371671 A1.
- an organic / inorganic hybrid system which contains hydraulically condensable compounds and thus enables water to be used as a phlegmatizer. After the components have been mixed, the water is bound by the existing hydraulically condensable compounds and therefore no longer has a softening function in the hardened mass.
- the hardener composition is therefore filled with fine fillers.
- the viscosity of the component also increases and thus the force with which such components can be pressed out.
- the coarser fillers are preferably present as the main filler in a larger amount, while the smaller fillers are used in a smaller amount compared to the amount of the main filler.
- injection mortars with high performance and good workability properties. This is particularly important when packaging is to be carried out in environmentally friendly foil packs, as it is difficult to achieve high mixing ratios (resin composition: hardener composition).
- Hardener compositions are mixed well with the resin composition in the static mixer and thus lead to stable curing of the injection mortar.
- reaction resin also called “base resin”, a usually solid or highly viscous “radically curable”, ie polymerizable compound which hardens through polymerization and forms a resin matrix;
- the reaction resin is the reaction product of a bulk reaction per se; this is also the reaction batch to produce the base resin after the reaction has ended, which is present without isolation of the product and therefore, in addition to the free-radically curable compound, can contain the reaction resin, a reactive diluent, a stabilizer and a catalyst, if used;
- Inhibitor a compound capable of inhibiting the polymerization reaction (hardening), which serves to avoid the polymerization reaction and thus an undesired premature polymerization of the polymerizable compound, the reaction resin, during storage (in this function often also referred to as a stabilizer) and / or to delay the start of the polymerization reaction immediately after the addition of the curing agent; the task of the inhibitor depends on the quantities in which it is used;
- Reactive thinners liquid or low-viscosity monomers and oligomers, which dilute the reaction resin and thereby give it the viscosity necessary for its application, contain one or more functional groups capable of reacting with the reaction resin and, during polymerization (curing), are predominantly part of the hardened ones Mass (resin matrix) become;
- Filler an organic or inorganic, in particular inorganic compound, which can be passive and / or reactive and / or functional;
- Passive means that the connection is surrounded unchanged by the hardening resin matrix;
- Reactive means that the compound polymerizes into the resin matrix and forms an expanded network with the reaction resin;
- Fluctional means that the compound is not polymerized into the resin matrix but fulfills a certain function in the formulation, in which case the term “additives” is also used;
- Resin composition a mixture of the polymerizable compound, the reaction resin, and inorganic and / or organic additives and fillers, such as an inhibitor and / or an accelerator;
- Hardener composition a mixture of the hardener and inorganic and / or organic fillers, such as a phlegmatizer, i.e. stabilizer for the hardener;
- highly filled hardener composition that the hardener composition has a predominant amount of fillers, in particular inorganic fillers and thus a high degree of filling of over 50% by volume of fillers;
- Total filling level the sum of all fillers or solids including any solid peroxides and including the first filler FS1 and the second filler FS2;
- Base fill level the sum of all fillers or solids including any solid peroxides, before the addition of the first filler FS1 and the second filler FS2;
- Maximum degree of filling is the degree of filling at which, after the addition of the first filler FS1 but before the addition of the second filler FS2, the squeezing force of the hardener composition has reached at least three times the squeezing force obtained with 2% by volume less filling level ;
- Two-component reaction resin system a reaction resin system that contains two components stored separately from one another, generally one Resin component containing the resin composition and a hardener component containing the hardener composition, so that curing of the reaction resin only takes place after the two components have been mixed;
- Multi-component reaction resin system a reaction resin system that comprises several components stored separately from one another, so that the reaction resin does not harden until all components have been mixed;
- this term means numerically “a”, “an”, “an”;
- a first object of the invention is a hardener composition for a reactive resin system with a reactive resin based on free-radically curable compounds, the hardener composition comprising a hardener for the reactive resin and a filler mixture, which is characterized in that the filler mixture consists of a first filler FS1 with a first middle Grain size d 50.1 and a second filler FS2 with a second mean grain size d 50.2, the first mean grain size d 50.1 of the first filler being larger than the second mean grain size d 50.2 of the second filler (d 50 , 1 > d 50, 2 ) and the ratio d 50.1 to d 50.2 (d 50.1 : d 50.2 ) is in the range from about 8: 1 to about 100: 1.
- the possible degree of filling of a hardener composition in particular a hardener composition based on a water- or solvent-based peroxide composition, while maintaining the flowability of the hardener composition by more than 5% by volume and depending on Filler mixture can even be increased by more than 8% by volume, based in each case on the hardener composition.
- the filler mixture consists of a first filler FS1 with a first mean grain size d 50.1 and a second filler FS2 with a second mean grain size d 50.2, the first mean grain size d 50.1 of the first filler FS1 being larger than the second average grain size d 50, 2 of the second filler is FS2 (d 50.1> 50 d, 2) and the ratio of d to 50.1 d 50, 2 (d 50.1 d 50, 2) in the range of 8: 1 to 100: 1.
- the first mean grain size d 50.1 of the first filler FS1 is preferably 16 ⁇ m to 130 ⁇ m.
- the second mean grain size d 50, 2 of the second filler FS2 is preferably 0.16 ⁇ m to 16 ⁇ m.
- the chemical composition of the fillers is of secondary importance. Natural or synthetic, inorganic materials are suitable, preferably of medium or higher hardness, in particular a Mohs hardness between 2 and 10. However, organic solids can also be used.
- Suitable fillers are, for example, metal oxides or semi-metal oxides such as aluminum oxide or titanium dioxide; Metal hydroxides such as aluminum hydroxide; Salts such as calcium carbonate or barium sulfate; mineral or mineral-like fillers such as various silicates or aluminates as well as mixtures of these, e.g. quartz, glass, sand, quartz sand, quartz powder, porcelain, corundum, ceramics, talc, silica (e.g.
- fumed silica silicates, clay, chalk, barite, Feldspar, basalt, granite or sandstone, glasses, ceramics, and natural stones such as basalt; hydraulically hardenable fillers, such as gypsum, quicklime or cement (e.g. high alumina or portland cement); Metals such as aluminum; Soot; polymer fillers such as thermosetting plastics.
- the first filler FS1 is preferably selected from semimetal oxides, metal oxides, semimetal oxides and metal hydroxides, such as silicon dioxide, in particular quartz, aluminum oxide and aluminum hydroxide.
- the second filler FS2 is more preferably selected from the group consisting of metal salts, such as calcium carbonate or barium sulfate.
- the coarser fillers are present as the main filler in a larger amount
- the smaller fillers are used in a smaller amount compared to the amount of the main filler.
- the proportion of the first filler FS1 is thus greater than the proportion of the second filler FS2.
- the proportion of fillers is expediently indicated as a volume proportion.
- the amount of first filler FS1 and second filler FS2 to be used depends on the fillers used in each case, more precisely on their grain size, and cannot be described across the board by a numerical value.
- the maximum amount of first filler is accordingly to be determined experimentally separately for each filler FS1.
- the maximum amount is the amount of first filler FS1, starting from which the second filler FS2 is added in a corresponding amount in order to obtain the filler mixture.
- the maximum amount of first filler FS1 is determined as follows: First, the amount (sum) of all solids including any solid peroxides and possibly other solids, such as solid additives, is determined before the addition of the first filler FS1 and the second filler FS2. This corresponds to the basic filling level. Starting from this basic filling level, the first filler FS1 is added step by step and the extrusion force is determined after each addition. If the extrusion force has risen exponentially for the first time by a multiple, roughly three times or more. No further addition of the first filler is required. The amount of first filler FS1 at which the exponential increase in the extrusion force is observed for the first time is referred to as the maximum degree of filling.
- the second filler FS2 is then added, the total fill level being able to exceed the amount of the maximum fill level without the extrusion forces increasing noticeably.
- the total filling level corresponds to the sum of the basic filling level and the filler mixture FS1 and FS2.
- the maximum amount of first filler FS1 with the mean particle size d 50.1 can be determined in particular by adding the filler FS1 to the hardener composition in steps of 2% by volume each until the press-out force of the hardener composition is greater than in the previous step ( previous addition), at least tripled for the first time. After each increase in the degree of filling, the extrusion force is determined at a given temperature (+ 23 ° C). The proportion of the first filler FS1 is increased until the extrusion force has risen three times the previous value. The degree of filling then achieved, possibly including the basic degree of filling due to the solid peroxide and possibly other solids, is referred to as the maximum degree of filling.
- the proportion of filler FS1 is already too high at this degree of filling to achieve or exhaust the maximum effect of the invention, the amount of first filler FS1 is reduced again, starting from the maximum degree of filling.
- a reduction in the proportion of the first filler FS1 in the hardener composition by about 5% by volume has been found to be expedient.
- filler FS1 FS2 To this amount of filler FS1 FS2 is the second filler having the average particle size d 50, optionally 2 to obtain the inventive fill composition.
- the amount of second filler FS2 is chosen so that the volume ratio of first filler to second filler (V FS1 : VFS2) is in the range from 1.5: 1 to 15: 1, preferably 2: 1 to 10: 1 and more preferably 2 , 5: 1 to 5: 1.
- the hardener composition contains a curing agent for the radically curable, ethylenically unsaturated compound.
- peroxides known to the person skilled in the art, which can be used for curing methacrylate resins, can be used.
- Such peroxides include organic and inorganic peroxides, either liquid or solid.
- suitable organic peroxides are peroxycarbonates (of the formula -OC (O) OO-), peroxyesters (of the formula -C (O) OO-), diacyl peroxides (of the formula -C (O) OOC (O) -), dialkyl peroxides ( of the formula -OO-) and the like. These can also be present as oligomers or polymers.
- a comprehensive series of examples of suitable peroxides is described, for example, in the application US 2002/0091214 A1, paragraph [0018].
- the peroxides are preferably selected from the group of organic peroxides.
- Suitable organic peroxides are: tertiary alkyl hydroperoxides, such as tert- Butyl hydroperoxide, and other hydroperoxides such as cumene hydroperoxide, peroxyesters or peracids such as tert-butyl perester (eg tert-butyl peroxybenzoate), dibenzoyl peroxide, peracetates and perbenzoates, dilauroyl peroxide, including (di) peroxyesters, perethers such as peroxydiethyl ether, perketones such as methyl ethyl ketone peroxide.
- the organic peroxides used as hardeners are often tertiary peresters or tertiary hydroperoxides, ie peroxide compounds with tertiary carbon atoms which are bonded directly to an -OO-acyl or -OOH group.
- tertiary peresters or tertiary hydroperoxides ie peroxide compounds with tertiary carbon atoms which are bonded directly to an -OO-acyl or -OOH group.
- mixtures of these peroxides with other peroxides can also be used according to the invention.
- the peroxides can also be mixed peroxides, ie peroxides which have two different peroxide-carrying units in one molecule.
- Dibenzoyl peroxide (BPO) or tert-butyl peroxybenzoate is preferably used for curing.
- Persulfates, perborates and / or perphosphates such as ammonium persulfate, potassium and sodium monopersulfates or potassium and sodium dipersulfates, can in particular be used as inorganic peroxides. But hydrogen peroxide can also be used.
- organically substituted ammonium persulfates for example N’N’N’N’-tetrabutylammonium or N‘N’N’-tricapryl-N‘-methylammonium persulfate is possible.
- the hardener composition according to the invention also contains a phlegmatizer to stabilize the peroxide.
- Corresponding phlegmatizers are known from DE 3226602 A1, EP 0432087 A1 and EP 1 371 671 A1.
- the hardener composition preferably contains water as a phlegmatizer.
- the hardener composition can also contain other phlegmatizing agents, water being preferred as the sole phlegmatizing agent in order not to introduce any compounds which have a softening effect.
- the peroxide is preferably present as a suspension together with the water.
- Corresponding suspensions are commercially available in different concentrations, such as, for example, the aqueous dibenzoyl peroxide suspensions from United Initiators (e.g. BP40SAQ), Perkadox 40L-W (Nouryon), Luperox® EZ-FLO (Arkema), Peroxan BP40W (Fa. Pergan).
- the peroxide can be contained in the reaction resin system in an amount of 0.25 to 35% by weight, preferably 1 to 30% by weight, particularly preferably 5 to 25% by weight, based on the hardener composition.
- the effect of the filler mixture described at the beginning comes into play in particular in the case of water-containing hardener compositions.
- the use of the filler mixture is particularly advantageous, since not only the proportion of low-viscosity components, but in particular the proportion of water, which has a disadvantageous effect on curing, can be reduced.
- peroxide dispersions In addition to water and the hardening agent, commercial peroxide dispersions contain other additives such as emulsifiers, antifreeze agents, buffers and rheological additives in an unpublished type and amount.
- the hardener composition can contain further additives, namely emulsifiers, antifreeze agents, buffers and / or rheological additives.
- the hardener composition according to the invention preferably contains no further organic or inorganic solids, in particular fillers. However, it is not excluded that additional organic and / or inorganic solids may be contained, provided that these do not adversely affect the effect according to the invention.
- Suitable emulsifiers are: ionic, nonionic or amphoteric surfactants; Soaps, wetting agents, detergents; Polyalkylene glycol ethers; Salts of fatty acids, mono- or diglycerides of fatty acids, sugar glycerides, lecithin; Alkanesulfonates, alkylbenzenesulfonates, fatty alcohol sulfates, fatty alcohol polyglycol ethers, Fatty alcohol ether sulfates, sulfonated fatty acid methyl esters; Fatty alcohol carboxylates; Alkyl polyglycosides, sorbitan esters, N-methylglucamides, sucrose esters; Alkylphenols, alkylphenol polyglycol ethers, alkylphenol carboxylates; Quaternary ammonium compounds, esterquats, carboxylates of quaternary ammonium compounds.
- Suitable antifreeze agents are: organic or inorganic, water-soluble additives that lower the freezing temperature of the water; Mono-, bi- or higher-functional alcohols, such as ethanol, n- or iso-propanol, n-, iso- or tert-butanol and the like; Ethylene glycol, 1,2- or 1,3-propylene glycol, glycerol, trimethylolpropane and the like; Oligo- or polyglycols such as dialkylene glycols, trialkylene glycols and the like; Sugars, especially mono- or disaccharides; Trioses, tetroses, pentoses and hexoses in their aldehyde or keto form as well as the analogous sugar alcohols. Examples, but not of limitation, are glyceraldehyde, fructose, glucose, sucrose, mannitol and the like.
- Suitable buffers are organic or inorganic acid / base pairs that stabilize the pH value of the hardener composition, such as acetic acid / alkali acetate, citric acid / monoalkali citrate, monoalkali / dialkali citrate, dialkali / trialkali citrate,
- Intramolecular, so-called Good buffers such as 4- (2-hydroxyethyl) -1-piperazineethanesulfonic acid (HEPES) or 2- (N-morpholino) ethanesulfonic acid (MES) as well as tris (hydroxymethyl) aminomethane (TRIS) and the like can also be used .
- rheological additives are: sheet silicates such as Laponite, Bentone or montmorillonite, Neuburg Siliceous Earth, pyrogenic silicas, polysaccharides; Polyacrylate, polyurethane or polyurea thickeners and cellulose esters. Wetting and dispersing agents, surface additives, defoamers & deaerators, wax additives, adhesion promoters, viscosity reducers or process additives can also be added for optimization. Also for this applies that these are to be selected so that they do not adversely affect the effect according to the invention.
- the sum of the additives not already contained in the commercial products can be from 0% by weight to 30% by weight, preferably from 0% by weight to 25% by weight, particularly preferred from 0% by weight to 20% by weight, based in each case on the hardener composition.
- the filler mixture described above is advantageously used in a hardener composition for reactive resin composition with a reactive resin based on radically curable, ethylenically unsaturated compounds for chemical fastening in order to increase the filler content without negatively affecting the flowability of the hardener composition.
- This makes it possible to significantly reduce the proportion of liquid components in the hardener composition, in particular water, and to enable low extrusion forces despite the high proportion of fillers.
- a further object of the invention is the use of a filler mixture of a first filler FS1 with a first mean grain size d 50.1 and a second filler FS2 with a second mean grain size d 50.2, the first mean grain size d 50.1 des first filler FS1 is larger than the second mean grain size d 50, 2 of the second filler FS2 (d 50.1 > d 50, 2 ) and the ratio d 50.1 to d 50.2 (d 50.1 : d 50, 2 ) in the range from 8: 1 to 100: 1, in a hardener composition for reactive resin composition with a reactive resin based on radically curable, ethylenically unsaturated compounds for chemical fastening to increase the filler content while maintaining the flowability of the hardener composition.
- the hardener composition according to the invention can advantageously be used as the hardener component in a multi-component reaction resin system, which also includes two-component reaction resin systems.
- the invention accordingly also relates to a multicomponent reaction resin system comprising a resin component and the hardener composition described above as the hardener component.
- the resin component contains at least one free-radically curable unsaturated compound.
- the radically curable unsaturated compound can be a reaction resin.
- the one radical curable unsaturated compound can be a reactive diluent.
- the free-radically curable unsaturated compound can also comprise a mixture of at least one reaction resin and at least one reactive diluent, a reaction resin mixture.
- Suitable free-radically curable unsaturated compounds as reaction resin are ethylenically unsaturated compounds, compounds with carbon-carbon triple bonds and thiol-Yn / ene resins, as are known to the person skilled in the art.
- the free-radically curable, ethylenically unsaturated compound the reaction resin, a compound based on urethane (meth) acrylate, epoxy (meth) acrylate, a methacrylate of an alkoxylated bisphenol or based on other ethylenically unsaturated compounds.
- the group of ethylenically unsaturated compounds is preferred, which includes styrene and derivatives thereof, (meth) acrylates, vinyl esters, unsaturated polyesters, vinyl ethers, allyl ethers, itaconates, dicyclopentadiene compounds and unsaturated fats, of which unsaturated polyester resins and vinyl ester resins are particularly suitable are described, for example, in the applications EP 1 935 860 A1, DE 195 31 649 A1, WO 02/051903 A1 and WO 10/108939 A1.
- Vinyl ester resins (synonym: (meth) acrylate resins) are most preferred because of their hydrolytic resistance and excellent mechanical properties.
- Vinyl ester urethane resins in particular urethane methacrylates, are very particularly preferred. These include, as preferred resins, the urethane methacrylate resins described in DE 102011 017 626 B4. In this regard, reference is made to DE 102011 017 626 B4, and above all to the description of the composition of these resins, in particular in the examples of DE 102011 017626 B4.
- Ortho resins are based on phthalic anhydride, maleic anhydride or fumaric acid and glycols, such as 1,2-propylene glycol, ethylene glycol, diethylene glycol, triethylene glycol, 1,3-propylene glycol, dipropylene glycol, tripropylene glycol, neopentyl glycol or hydrogenated bisphenyl glycol;
- Iso-resins these are made from isophthalic acid, maleic anhydride or fumaric acid and glycols. These resins can contain higher proportions of reactive thinners than the ortho resins;
- HET acid resins are resins obtained from anhydrides or phenols containing chlorine / bromine in the production of unsaturated polyester resins.
- DCPD resins can also be distinguished as unsaturated polyester resins.
- the class of DCPD resins is obtained either by modifying one of the above resin types by Diels-Alder reaction with cyclopentadiene, or alternatively they are obtained by a first reaction of a dicarboxylic acid, e.g. maleic acid, with dicyclopentadienyl, and then by a second reaction, the conventional production of an unsaturated polyester resin, the latter being referred to as a DCPD maleate resin.
- a dicarboxylic acid e.g. maleic acid
- the unsaturated polyester resin preferably has a molecular weight Mn in the range from 500 to 10,000 Dalton, more preferably in the range from 500 to 5000 and even more preferably in the range from 750 to 4000 (according to ISO 13885-1).
- the unsaturated polyester resin has an acid value in the range from 0 to 80 mg KOH / g resin, preferably in the range from 5 to 70 mg KOH / g resin (according to ISO 2114-2000). If a DCPD resin is used as the unsaturated polyester resin, the acid value is preferably 0 to 50 mg KOH / g resin.
- vinyl ester resins are oligomers, prepolymers or polymers with at least one (meth) acrylate end group, so-called (meth) acrylate-functionalized resins, which also include urethane (meth) acrylate resins and epoxy (meth) acrylates.
- Vinyl ester resins which only have unsaturated groups in the terminal position are, for example, by reacting epoxy oligomers or polymers (e.g. bisphenol A digylcidyl ether, epoxies of the phenol novolak type or epoxy oligomers based on tetrabromobisphenol A) with, for example (Meth) acrylic acid or (meth) acrylamide obtained.
- Preferred vinyl ester resins are (meth) acrylate-functionalized resins and resins obtained by reacting an epoxy oligomer or polymer with methacrylic acid or methacrylamide, preferably with methacrylic acid, and optionally with a chain extender such as diethylene glycol or dipropylene glycol. Examples of such compounds are known from the applications US 3297745 A, US 3772404 A, US 4618658 A, GB 2217722 A1, DE 3744390 A1 and DE 4131457 A1.
- Particularly suitable and preferred vinyl ester resins are (meth) acrylate-functionalized resins, which are produced, for example, by reacting di- and / or higher-functional isocyanates with suitable acrylic compounds, optionally with the help of hydroxy compounds that contain at least two hydroxyl groups, as described, for example, in DE 3940309 A1 can be obtained.
- the urethane methacrylate resins described in DE 102011017626 B4 (which are also referred to as vinyl ester urethane resins) are very particularly suitable and preferred.
- Aliphatic (cyclic or linear) and / or aromatic di- or higher-functional isocyanates or prepolymers thereof can be used as isocyanates.
- aromatic difunctional or higher-functional isocyanates or prepolymers thereof Preference is given to aromatic difunctional or higher-functional isocyanates or prepolymers thereof, with aromatic difunctional or higher-functional prepolymers being particularly preferred.
- Toluylene diisocyanate (TDI), diisocyanatodiphenylmethane (MDI) and polymeric diisocyanatodiphenylmethane (pMDl) to increase chain stiffening and hexane diisocyanate (HDI) and isophorone diisocyanate (IPDI), which improve flexibility, may be mentioned (among which polymeric diisocyanatodiphenylmethane is particularly preferred) .
- Acrylic compounds are acrylic acid and acrylic acids substituted on the hydrocarbon radical, such as methacrylic acid, esters of acrylic or methacrylic acid containing hydroxyl groups with polyhydric alcohols, pentaerythritol tri (meth) acrylate, glycerol di (meth) acrylate, such as trimethylolpropane di (meth) acrylate, and neopentyl glycol mono (meth) acrylate suitable.
- methacrylic acid esters of acrylic or methacrylic acid containing hydroxyl groups with polyhydric alcohols
- pentaerythritol tri (meth) acrylate such as pentaerythritol tri (meth) acrylate
- glycerol di (meth) acrylate such as trimethylolpropane di (meth) acrylate
- neopentyl glycol mono (meth) acrylate suitable such as methacrylic acid, esters of acrylic or methacrylic acid
- Acrylic or methacrylic acid hydroxyalkyl esters such as hydroxyethyl (meth) acrylate, hydroxypropyl (meth) acrylate, polyoxyethylene (meth) acrylate, polyoxypropylene (meth) acrylate, are preferred, especially since such compounds serve to sterically prevent the saponification reaction. Because of its lower alkali stability, acrylic acid is less preferred than acrylic acids substituted on the hydrocarbon radical.
- hydroxy compounds are suitable dihydric or higher alcohols, such as derivatives of ethylene or propylene oxide, such as ethanediol, di- or triethylene glycol, propanediol, dipropylene glycol, other diols, such as 1,4-butanediol, 1,6-hexanediol, Neopentyl glycol, diethanolamine, further bisphenol A or F or their ethox / propoxylation and / or hydrogenation or halogenation products, higher alcohols such as glycerol, trimethylolpropane, hexanetriol and pentaerythritol, hydroxyl-containing polyethers, for example oligomers of aliphatic or aromatic oxiranes and / or higher cyclic ethers, such as ethylene oxide, propylene oxide, styrene oxide and furan, polyethers which contain aromatic structural units in the main chain, such as those of bisphenol A or
- hydroxy compounds with aromatic structural units to reinforce the chain of the resin hydroxy compounds that contain unsaturated structural units, such as fumaric acid, to increase the crosslinking density
- hydroxy compounds that contain unsaturated structural units, such as fumaric acid to increase the crosslinking density
- branched or star-shaped hydroxy compounds in particular trihydric or higher-valent alcohols and / or polyethers or polyesters
- the Structural units contain branched or star-shaped urethane (meth) acrylates to achieve lower viscosity of the resins or their solutions in reactive diluents and higher reactivity and crosslinking density.
- the vinyl ester resin preferably has a molecular weight Mn in the range from 500 to 3000 Dalton, more preferably from 500 to 1500 Dalton (according to ISO 13885-1).
- the vinyl ester resin has an acid value in the range from 0 to 50 mg KOH / g resin, preferably in the range from 0 to 30 mg KOH / g resin (according to ISO 2114-2000).
- reaction resin can also contain other reactive groups which can be polymerized with a radical initiator such as peroxides, for example reactive groups which are derived from itaconic acid, citraconic acid and allylic groups and the like.
- the resin component of the reaction resin system contains, in addition to the reaction resin, at least one further low-viscosity, free-radically polymerizable, ethylenically unsaturated compound as a reactive diluent.
- This is expediently added to the reaction resin and is therefore contained in the resin component.
- Suitable, in particular low-viscosity, free-radically curable, ethylenically unsaturated compounds as reactive diluents are described in the applications EP 1935860 A1 and DE 19531649 A1.
- the reaction resin system preferably contains a (meth) acrylic acid ester as reactive diluent, with (meth) acrylic acid esters being particularly preferably selected from the group consisting of hydroxypropyl (meth) acrylate, propanediol-1,3-di (meth) acrylate, butanediol-1,2- di (meth) acrylate, trimethylolpropane tri (meth) acrylate, 2-ethylhexyl (meth) acrylate, phenylethyl (meth) acrylate, tetrahydrofurfuryl (meth) acrylate, ethyl triglycol (meth) acrylate, N, N-dimethylaminoethyl (meth) acrylate, N, N-dimethylaminomethyl (meth) acrylate,
- Biogenic reactive diluents such as tetrahydrofurfuryl (meth) acrylate, isobornyl (meth) acrylate or isosorbide di (meth) acrylate are preferred.
- the reactive diluent can be used alone or as a mixture of two or more reactive diluents.
- customary free-radically polymerizable compounds alone or in a mixture with the (meth) acrylic acid esters described in the preceding paragraph, can be used, for example styrene, ⁇ -methylstyrene, alkylated styrenes such as tert-butylstyrene, divinylbenzene and vinyl and allyl compounds.
- vinyl or allyl compounds examples include hydroxybutyl vinyl ether, ethylene glycol divinyl ether, 1,4-butanediol divinyl ether, trimethylolpropane divinyl ether, trimethylolpropane trivinyl ether, mono-, di-, tri-, tetra- and polyalkylene glycol vinyl ether, Mono-, di-, tri-, tetra- and polyalkylene glycol allyl ethers, divinyl adipate, trimethylolpropane diallyl ether and trimethylolpropane triallyl ether.
- Particularly preferred reactive thinners are the reactive thinners used in the examples.
- Compounds which have various reactive or functional groups can also be used as free-radically curable compounds. These can, for example, both be ethylenically unsaturated, such as, for example, (meth) acrylates with an additional allyl ether function. But compounds with two different reactive / functional groups that react with different reaction mechanisms can be used. Examples of this are (meth) acrylates with a silane or siloxane group, such as 3-trimethoxysilylpropyl methacrylate. Compounds with more than two reactive / functional groups can also be used.
- the free-radically curable unsaturated compound can be contained in the reaction resin system in an amount of 10 to 99.99% by weight, preferably 15 to 97% by weight, particularly preferably 30 to 95% by weight, based on the resin component.
- the free-radically curable compound can either be a reaction resin based on a free-radically curable compound or a reactive diluent or a mixture of a reaction resin with one, two or more reactive diluents.
- the amount of the mixture that can be contained in the reaction resin system corresponds to the amount of the free-radically curable compound, namely from 10 to 99.99% by weight, preferably 15 to 97% by weight, particularly preferably 30 to 95% by weight, based on the resin component, with the proportion of the reaction resin being 0 to 100% by weight, preferably 30 to 70% by weight and based on the reaction resin mixture the proportion of the reactive diluent or a mixture of several reactive diluents is 0 to 100% by weight, preferably 30 to 70% by weight.
- the total amount of the free-radically curable compound depends on the degree of filling, that is to say the amount of inorganic fillers, including those listed below Fillers, in particular the hydrophilic fillers, the other inorganic additives and the hydraulically setting or polycondensable compounds.
- reaction resin system also contains at least one accelerator. This accelerates the hardening reaction.
- Suitable accelerators are known to the person skilled in the art. These are conveniently amines.
- Suitable amines are selected from the following compounds, which are described, for example, in application US 2011071234 A1: dimethylamine, trimethylamine, ethylamine, diethylamine, triethylamine, n-propylamine, di-n-propylamine, tri-n-propylamine, isopropylamine, diisopropylamine, triisopropylamine , n-butylamine, isobutylamine, tert-butylamine, di-n-butylamine, diisobutylamine, tri-isobutylamine, pentylamine, isopentylamine, diisopentylamine, hexylamine, octylamine, dodecylamine, laurylamine, stearylamine, aminoethanol, diethanolamine, triethanolamine (2-chloroethyl) amine, 2-ethylhexylamine, bis (2-chloroethy
- Diethylaminoethoxy) ethanol bis (2-hydroxyethyl) oleylamine, tris- [2- (2-hydroxy-ethoxy) ethyl] amine, 3-amino-1-propanol, methyl (3-aminopropyl) ether, ethyl (3- aminopropyl) ether, 1,4-butanediol bis (3-aminopropyl) ether, 3-dimethylamino-1-propanol, 1-amino-2-propanol, 1-diethylamino-2-propanol, diisopropanolamine, methyl bis (2- hydroxypropyl) amine, tris (2-hydroxypropyl) amine, 4-amino-2-butanol, 2-amino-2-methylpropanol, 2-amino-2-methyl-propanediol, 2-amino-2-hydroxymethylpropanediol, 5-diethylamino 2-pentanone,
- Preferred amines are symmetrically or asymmetrically substituted aniline and toluidine derivatives and N, N-bis (hydroxy) alkylarylamines, such as N, N, -dimethylaniline, N, N-diethylaniline, N, N-dimethyl-p-toluidine, N, N-bis (hydroxyalkyl) arylamine, N, N-bis (2-hydroxyethyl) aniline, N, N-bis (2-hydroxyethyl) toluidine, N, N-bis (2-hydroxypropyl) aniline, N, N-bis ( 2-hydroxypropyl) toluidine, N, N-bis (3-methacryloyl-2-hydroxypropyl) -p-toluidine, N, N-dibutoxyhydroxypropyl-p-toluidine, N-methyl-N-hydroxyethyl-p-toluidine, N-ethyl -N-hydroxyethyl-p-toluidine and
- Polymeric amines such as those obtained by polycondensation of N, N-bis (hydroxyalkyl) aniline with dicarboxylic acids or by polyaddition of ethylene oxide and these amines, are also suitable as accelerators.
- Preferred accelerators are N, N-bis (2-hydroxypropyl) toluidine, N, N-bis (2-hydroxyethyl) toluidine and para-toluidine ethoxylate (Bisomer ® PTE).
- the accelerator can be contained in the reaction resin system in an amount of 0.01 to 10% by weight, preferably 0.5 to 5% by weight, particularly preferably 0.5 to 3% by weight, based on the resin component .
- the resin component also contains an inhibitor both for the storage stability of the reaction resin and the resin component and for setting the gel time.
- the inhibitor can be contained in the reaction resin system alone or together with the accelerator.
- a suitably coordinated accelerator-inhibitor combination is preferably used to set the processing time or gel time.
- the inhibitors usually used for free-radically polymerizable compounds are suitable as inhibitors.
- the inhibitors are preferably selected from phenolic compounds and non-phenolic compounds, such as stable radicals and / or phenothiazines.
- Phenols such as 2-methoxyphenol, 4-methoxyphenol, 2,6-di-tert-butyl-4-methylphenol, 2,4-di-tert-butylphenol, 2,6-di-tert-butylphenol, 2 , 4,6-trimethylphenol, 2,4,6-tris (dimethylaminomethyl) phenol, 4,4'-thio-bis (3-methyl-6-tert-butylphenol), 4,4'-isopropylidenediphenol, 6,6 '-Di-tert-butyl-4,4'-bis (2,6-di-tert-butylphenol), 1,3,5-trimethyl-2,4,6-tris (3,5-di-tert-butyl -4-hydroxybenzyl) benzene, 2,2'-methylene-di-p-cresol, pyrocatechol and butylpyrocatechol, such as 4-tert-butylpyrocatechol, 4,6-di-tert-buty
- Suitable non-phenolic or anaerobic inhibitors ie, in contrast to the phenolic inhibitors, also without oxygen, are preferably phenothiazines, such as phenothiazine and / or derivatives or combinations thereof, or stable organic radicals, such as galvinoxyl and N-oxyl radicals.
- N-oxyl radicals examples include those described in DE 199 56 509.
- Suitable stable N-oxyl radicals can be selected from 1-oxyl-2,2,6,6-tetramethylpiperidine, 1-oxyl-2,2,6,6-tetramethylpiperidin-4-ol (also referred to as TEMPOL), 1-oxyl-2,2,6,6-tetramethylpiperidin-4-one (also referred to as TEMPON), 1-oxyl-2,2,6,6-tetramethyl-4-carboxyl-piperidine (also known as 4-carboxy- TEMPO), 1-oxyl-2,2,5,5-tetramethylpyrrolidine, 1-oxyl-2, 2,5,5-tetramethyl-3-carboxylpyrrolidine (also referred to as 3-carboxy-PROXYL), aluminum-N- nitrosophenylhydroxylamine, diethylhydroxylamine can be selected.
- TEMPOL 1-oxyl-2,2,6,6-tetramethylpiperidin-4-ol
- N-oxyl compounds are oximes, such as acetaldoxime, acetone oxime, methyl ethyl ketoxime, salicyloxime, benzoxime, glyoximes, dimethylglyoxime, acetone-O- (benzyloxycarbonyl) oxime and the like.
- UV stability and, in particular, the storage stability can thus be increased considerably.
- pyrimidinol or pyridinol compounds substituted in the para position to the hydroxyl group can be used as inhibitors.
- Preferred inhibitors are 1-oxyl-2,2,6,6-tetramethylpiperidine (TEMPO) and 1-oxyl-2,2,6,6-tetramethylpiperidin-4-ol (TEMPOL), catechols, particularly preferably tert-butyl pyrocatechol and catechol, BHT and phenothiazine.
- the inhibitors can, depending on the desired properties of the reaction resin system, be used either alone or as a combination of two or more thereof.
- the combination of the phenolic and the non-phenolic Inhibitors enable a synergistic effect, as is also shown by the setting of an essentially drift-free setting of the gel time of the reaction resin composition.
- the inhibitor can be contained in the reaction resin system in an amount of 0.001 to 5% by weight, preferably 0.01 to 3% by weight, particularly preferably 0.05 to 1% by weight, based on the resin component. If several inhibitors are included, the amount just mentioned corresponds to the total amount of inhibitors.
- the resin component contains inorganic additives, such as fillers and / or further additives.
- the fillers are customary fillers, preferably mineral or mineral-like fillers, such as quartz, glass, sand, quartz sand, quartz powder, porcelain, corundum, ceramics, talc, silica (e.g. fumed silica), silicates, clay, titanium dioxide, chalk, barite , Feldspar, basalt, aluminum hydroxide, granite or sandstone, polymeric fillers such as thermosets, hydraulically hardenable fillers such as gypsum, quicklime or cement (e.g.
- alumina or Portland cement alumina or Portland cement
- metals such as aluminum, carbon black, and also wood, mineral or organic fibers, or the like, or mixtures of two or more thereof, which can be added as powder, in granular form or in the form of shaped bodies, use.
- the fillers can be in any form, for example as powder or flour or as shaped bodies, e.g. B. in cylinder, ring, ball, plate, rod, saddle or crystal form, or also in fiber form (fibrillar fillers), and the corresponding particles preferably have a maximum diameter of 10 mm.
- the globular, inert substances spherical shape
- Fillers are preferably present in the resin component in an amount of 20 to 90, in particular 40 to 80, in particular 50 to 80% by weight.
- additives are also rheology additives, such as, if necessary, organically aftertreated pyrogenic silica, bentonites, alkyl and methyl celluloses, Castor oil derivatives or the like, plasticizers, such as phthalic acid or sebacic acid esters, stabilizers, antistatic agents, thickeners, flexibilizers, curing catalysts, rheological aids, wetting agents, coloring additives such as dyes or especially pigments, for example for different coloring of the components for better control of their mixing, or the like , or mixtures of two or more thereof, are possible.
- plasticizers such as phthalic acid or sebacic acid esters, stabilizers, antistatic agents, thickeners, flexibilizers, curing catalysts, rheological aids, wetting agents
- coloring additives such as dyes or especially pigments, for example for different coloring of the components for better control of their mixing, or the like , or mixtures of two or more thereof, are possible.
- agents for regulating the pH such as inorganic and / or organic acids according to DE102010008971A1, in particular copolymers with acidic groups, for example esters of phosphoric acid
- Non-reactive diluents can also be present, preferably in an amount of up to 30% by weight, based on the respective component (reaction resin mortar, hardener), for example from 1 to 20% by weight, such as lower alkyl ketones, e.g. acetone, Di-lower alkyl lower alkanoylamides, such as dimethylacetamide, lower alkylbenzenes, such as xylenes or toluene, phthalic acid esters or paraffins, or water.
- lower alkyl ketones e.g. acetone
- Di-lower alkyl lower alkanoylamides such as dimethylacetamide
- lower alkylbenzenes such as xylenes or toluene
- means for improving the compatibility between resin and hardener components such as ionic, nonionic or amphoteric surfactants; Soaps, wetting agents, detergents; Polyalkylene glycol ethers; Salts of fatty acids, mono- or diglycerides of fatty acids, sugar glycerides, lecithin; Alkanesulfonates, alkylbenzenesulfonates, fatty alcohol sulfates, fatty alcohol polyglycol ethers, fatty alcohol ether sulfates, sulfonated fatty acid methyl esters; Fatty alcohol carboxylates; Alkyl polyglycosides, sorbitan esters, N-methylglucamides, sucrose esters; Alkylphenols, alkylphenol polyglycol ethers, alkylphenol carboxylates; quaternary ammonium compounds, esterquats, carboxylates of quaternary ammonium compounds can be used.
- the resin component in addition to the free-radically curable compound present, also contains a hydraulically setting or polycondensable inorganic compound, in particular cement.
- a hydraulically setting or polycondensable inorganic compound for example Portland cement or aluminate cement, cements free of transition metal oxides or low in transition metal being particularly preferred.
- Gypsum as such or mixed with the cement can also be used as the hydraulically setting inorganic compound become.
- the resin component can also comprise silicate, polycondensable compounds, in particular substances containing soluble, dissolved and / or amorphous silicon dioxide, such as, for example, pyrogenic silica.
- the hydraulically setting or polycondensable compound can be present in the reaction resin system in an amount of 0 to 40% by weight, preferably 5 to 30% by weight, particularly preferably 10 to 30% by weight, based on the resin component. If the reaction system contains hydraulically setting or polycondensable compounds, the total amount of fillers is in the range mentioned above. Accordingly, the total amount of fillers, including the hydraulically setting and polycondensable compounds, is 20 to 90, in particular 40 to 80, especially 50 to 80% by weight, based on the resin component.
- the quantitative data relate in each case to the individual components, that is to say the resin component and the hardener component, unless otherwise stated.
- the actual amounts are such that the weight percent on the respective component adds up to 100.
- the hardener composition according to the invention contains: at least one peroxide as hardener,
- a filler composed of a first filler FS1 having a first average particle size d 16 and 130 microns 50.1 and interlocutory a second filler FS2 having a second average particle size d 50, 2 microns 0.16 to 16, wherein the ratio d 50 , 1 to d 50, 2 (d 50,1 : d 50, 2 ) is in the range from 8: 1 to 100: 1.
- the peroxide is solid and suspended in the water.
- the hardener composition according to the invention it contains: at least one peroxide as hardener,
- a filler composed of a first filler FS1 having a first average particle size d 16 and 130 microns 50.1 and interlocutory a second filler FS2 having a second average particle size d 50, 2 microns 0.16 to 16, wherein the ratio d 50 , 1 to d 50, 2 (d 50,1 : d 50, 2 ) is in the range from 8: 1 to 100: 1 and the fillers are selected from the group consisting of metal oxides, semi-metal oxides, metal hydroxides, metal salts, mineral or mineral-like fillers, hydraulically hardenable fillers, metals, carbon black and polymeric fillers, preferably metal oxides, metal hydroxides and metal salts.
- the peroxide is solid and suspended in the water.
- this contains: at least one solid peroxide as hardener,
- Metal hydroxides and metal salts and inorganic and / or organic additives.
- the peroxide is suspended in the water.
- this contains: a solid peroxide as hardener,
- the peroxide is suspended in the water.
- this contains: a solid peroxide
- V FS2 is in the range from 2.5: 1 to 5: 1, o the fill level is between 55 and 75% by volume, and inorganic and / or organic additives.
- the peroxide is suspended in the water.
- the hardener composition according to the invention is particularly suitable as a hardener component for a two-component reaction resin system for chemical fastening with a resin component and a hardener component. Preferred embodiments of such a two-component reaction resin system are described below.
- the resin component contains:
- the hardener component contains: at least one peroxide as hardener,
- a filler composed of a first filler FS1 having a first average particle size d 16 and 130 microns 50.1 and interlocutory a second filler FS2 having a second average particle size d 50, 2 microns 0.16 to 16, wherein the ratio d 50 , 1 to d 50, 2 (d 50,1 : d 50, 2 ) is in the range from 8: 1 to 100: 1.
- the peroxide is suspended in the water.
- the resin component contains:
- the hardener component contains: the first filler FS1 first filler FS1 with a first mean grain size d 50.1 and the second filler FS2 with a second mean grain size d 50.2 in a volume ratio of the first filler to the second filler (V FS1 : V FS2 ) in the range from 1.5: 1 to 15: 1,
- the resin component contains:
- the hardener component contains: at least one peroxide as hardener,
- a filler composed of a first filler FS1 having a first average particle size d 16 and 130 microns 50.1 and interlocutory a second filler FS2 having a second average particle size d 50, 2 microns 0.16 to 16, wherein the ratio d 50 , 1 to d 50, 2 (d 50,1 : d 50, 2 ) is in the range from 8: 1 to 100: 1.
- the peroxide is suspended in the water.
- the resin component contains:
- the hardener component contains: the first filler FS1 first filler FS1 with a first mean grain size d 50.1 and the second filler FS2 with a first mean grain size d 50.2 in a volume ratio of first filler to second filler (V FS1 : V FS2 ) in the range from 1.5: 1 to 15: 1,
- the resin component contains:
- reaction resin mixture of at least one reaction resin based on urethane (meth) acrylate and at least one reactive thinner based on (meth) acrylate, as a free-radically curable compound
- At least one inorganic filler in particular a silica
- the hardener component contains:
- the peroxide is suspended in the water.
- the reaction resin system contains the constituents in the amounts specified in the second aspect.
- the resin component contains:
- reaction resin mixture of at least one reaction resin based on urethane (meth) acrylate and at least one reactive thinner based on (meth) acrylate, as a free-radically curable compound
- the hardener component contains:
- the peroxide is suspended in the water.
- the resin component contains:
- the hardener component contains: the first filler FS1 first filler FS1 with a first mean grain size d 50.1 and the second filler FS2 with a first mean grain size dso , 2 in a volume ratio of first filler to second filler (V FS1 : VFS2) in the range from 1.5: 1 to 15: 1,
- hardener compositions were produced in which the overall filling level was increased by adding a further filler.
- the basic fill level which indicates the content of solid peroxide and other solids before the addition of the fillers FS1 and FS2, must also be taken into account in this determination.
- a premix V1 composed of 48% by weight of a 40% strength aqueous dibenzoyl peroxide dispersion (LUPEROX® EZ-FLO; Arkema Inc.), 42.7% by weight of water, 5.8% by weight of sodium hydrogen citrate was first used (Na 2 H citrate, Sigma Aldrich) and 3.5% by weight of a rheology additive based on an activated phyllosilicate (OPTIGEL-CK; BYK-Chemie GmbH).
- OPIGEL-CK activated phyllosilicate
- the mixture was stirred briefly by hand using a spatula and the premix was sheared in a dissolver (1 L, PC Laboratory System; dissolver disc 3.5 cm) for 10 minutes at a speed of 3500 rpm.
- Premix V2 was prepared analogously by mixing 87% by weight of BP 40SAQ with 10.14% by weight of water, 0.75% by weight of potassium dihydrogen phosphate, 0.11% by weight of sodium hydroxide and 2% by weight of OPTIGEL-CK were.
- the maximum fill level was first determined by gradually increasing the maximum amount of first filler FS1, based on a 52% fill level, the proportion of first filler FS1 so that the fill level of the hardener composition increased by 2 vol. -% elevated.
- the extrusion force was measured after each addition. Filler FS1 was added until the extrusion force tripled for the first time.
- the increase in the extrusion force was calculated from the ratio of the extrusion force of a mixture with a given volume% of filler FS 1 (x volume% FS 1) to the extrusion force of the mixture with 2 volume% less filler FS 1 (x- 2 Vol .-% FS 1) calculated.
- Table 3 The results are shown in Table 3.
- Table 1 Weights of the filler FS1 in g per 100 g premix
- hardener compositions were prepared from premix 1, in which filler mixtures of a first filler and a second filler were used, the particle size of the second Filler was varied. In addition, the amount of filler was increased by adding other fillers.
- the fillers used in each case and the corresponding amounts are given in Table 4.
- the extrusion forces of the hardener compositions obtained in each case were measured after heating at 23 ° C. overnight. The results of the measurements are shown in Table 4.
- Hardener compositions with the ingredients indicated in Table 5 in the amounts also indicated in Table 5 were used. From this, too, the extrusion forces of the hardener compositions obtained were measured after heating overnight at 23 ° C. The results of the measurements are shown in Table 5.
- the mixture of hardener compositions in the examples shown in Table 5 were prepared analogously to premix 1. When using Axilat RH23 as a rheology additive, the premix was left to stand overnight in the dissolver before the composition was completed in order to swell the thickener.
- Table 4 Results of the measurements of the extrusion force of the hardener composition according to the invention and the comparison hardener compositions as a function of the degree of filling and the particle size
- Table 4 (cont. 1): Results of the measurements of the extrusion force of the hardener composition according to the invention and the comparative hardener compositions as a function of the degree of filling and the particle size
- Table 4 (cont. 2): Results of the measurements of the extrusion force of the hardener composition according to the invention and the 5 comparative hardener compositions of the extrusion force as a function of the degree of filling and the particle size
- Table 4 (cont. 3): Results of the measurements of the extrusion force of the hardener composition according to the invention and the comparison hardener compositions as a function of the degree of filling and the particle size
- Table 5 (cont. 1): Results of the measurements of the extrusion force of the hardener composition according to the invention and the comparative hardener compositions as a function of the degree of filling and the particle size (proportions by weight)
- Table 5 (cont. 2): Results of the measurements of the extrusion force of the hardener composition according to the invention and the comparative hardener compositions as a function of the degree of filling and the particle size (proportions by mass)
- Table 5 (cont. 3): Results of the measurements of the extrusion force of the hardener composition according to the invention and the comparative hardener compositions as a function of the degree of filling and the particle size (proportions by mass)
- Table 5 (cont. 4): Results of the measurements of the extrusion force of the hardener composition according to the invention and the comparative hardener compositions as a function of the degree of filling and the particle size (proportions by mass)
- Table 5 (cont. 5): Results of the measurements of the extrusion force of the hardener composition according to the invention and the comparative hardener compositions as a function of the degree of filling and the particle size
- Table 5 (cont. 6): Results of the measurements of the extrusion force of the hardener composition according to the invention and the comparison hardener compositions as a function of the degree of filling and the particle size
- Table 5 (cont. 7): Results of the measurements of the extrusion force of the hardener composition according to the invention and the comparison hardener compositions as a function of the degree of filling and the particle size
- Table 5 (cont. 8): Results of the measurements of the extrusion force of the hardener composition according to the invention and the comparative hardener compositions as a function of the degree of filling and the particle size
- the results of the measurement of the extrusion forces shown in Tables 4 and 5 clearly show that when using a filler mixture of a first and a second filler, the particle size of the second filler has a significant influence on the extrusion forces. If the second filler selected such that the ratio d 50.1 d 50, 2 is between 8 and 100, increase the press-out forces and the measured values hardly be in the range of or less than 100 N. When the second filler is selected so that the ratio d 50.1 d 50, 2 outside the range of 8 to 100, to increase the press-out forces and significantly increase part ten-fold to.
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Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP19214397.2A EP3835279A1 (en) | 2019-12-09 | 2019-12-09 | Filler mixture for chemical fastening systems and use thereof |
PCT/EP2020/083839 WO2021115808A1 (en) | 2019-12-09 | 2020-11-30 | Filler mixture for chemical fastening systems and use thereof |
Publications (1)
Publication Number | Publication Date |
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EP4073012A1 true EP4073012A1 (en) | 2022-10-19 |
Family
ID=68835111
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19214397.2A Withdrawn EP3835279A1 (en) | 2019-12-09 | 2019-12-09 | Filler mixture for chemical fastening systems and use thereof |
EP20812341.4A Withdrawn EP4073012A1 (en) | 2019-12-09 | 2020-11-30 | Filler mixture for chemical fastening systems and use thereof |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
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EP19214397.2A Withdrawn EP3835279A1 (en) | 2019-12-09 | 2019-12-09 | Filler mixture for chemical fastening systems and use thereof |
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US (1) | US20220380571A1 (en) |
EP (2) | EP3835279A1 (en) |
JP (1) | JP2023505542A (en) |
KR (1) | KR20220113361A (en) |
CN (1) | CN114641461B (en) |
AU (1) | AU2020403372A1 (en) |
CA (1) | CA3155531A1 (en) |
WO (1) | WO2021115808A1 (en) |
Family Cites Families (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3297745A (en) | 1962-04-05 | 1967-01-10 | Robertson Co H H | Ethylenically unsaturated di-and tetra-urethane monomers |
GB1352063A (en) | 1971-01-08 | 1974-05-15 | Ici Ltd | Polymerisable compositions and resins derived thererom |
DE3226602A1 (en) | 1982-07-16 | 1984-01-19 | Hilti AG, 9494 Schaan | HARDENABLE RESIN MATERIALS AND THEIR USE |
US4618658A (en) | 1985-05-16 | 1986-10-21 | The Dow Chemical Company | Polymer modified epoxy resin compositions |
DE3744390A1 (en) | 1987-12-29 | 1989-07-13 | Basf Ag | Fibre composite materials based on modified vinyl ester urethane resins |
GB8810299D0 (en) | 1988-04-29 | 1988-06-02 | Scott Bader Co | Vinyl terminated urethane containing resins |
DE3940309A1 (en) | 1989-12-06 | 1991-06-13 | Hilti Ag | MOERTELMASSE |
DE4131457A1 (en) | 1991-09-21 | 1993-03-25 | Basf Ag | CARTRIDGE OR CARTRIDGE FOR CHEMICAL FASTENING TECHNOLOGY |
DE4231161A1 (en) | 1992-09-17 | 1994-03-24 | Hilti Ag | Mortar and device for fixing anchoring means in boreholes |
DE4337264A1 (en) | 1993-11-02 | 1995-05-04 | Upat Max Langensiepen Kg | Mortar for two-component systems |
DE19531649A1 (en) | 1995-08-29 | 1997-03-06 | Basf Ag | Dowel compound for chemical fastening technology |
DE19956509A1 (en) | 1999-11-24 | 2001-01-18 | Basf Ag | Inhibitor composition for (meth)acrylic acid stabilization comprises nitroxyl radical(s) (derivative) and a phenothiazine(s) and/or phenothiazine derivative(s) |
EP1221452A1 (en) | 2000-12-22 | 2002-07-10 | Dsm N.V. | Vinyl ether resins for structural applications |
EP1216991A1 (en) | 2000-12-22 | 2002-06-26 | Akzo Nobel N.V. | Transportable and safely packaged organic peroxide formulations comprising reactive phlegmatizers |
DE10226613B4 (en) | 2002-06-14 | 2007-05-16 | Hilti Ag | Hardener component for an at least two-component mortar composition and process for their preparation |
DE10345139A1 (en) * | 2003-09-29 | 2005-04-21 | Bosch Gmbh Robert | Thermosetting reaction resin system, useful e.g. for impregnating electrical coils and sealing diodes, comprises resin component (containing dispersed polymer particles) and mineral fillers (containing nanoparticles) |
CN100547028C (en) * | 2004-06-21 | 2009-10-07 | 积水化学工业株式会社 | Adhesive resin composition, paste and raw cook |
CN1982255A (en) * | 2005-12-15 | 2007-06-20 | Pci奥格斯堡有限责任公司 | Hydraulic hardening adhesive mortar |
CA2614050C (en) | 2006-12-21 | 2015-04-21 | Hilti Aktiengesellschaft | Two-component reaction resin and method of fastening using the resin |
ES2498722T3 (en) | 2009-03-25 | 2014-09-25 | Dsm Ip Assets B.V. | Composition of vinyl ester resin |
US9119774B2 (en) | 2009-09-18 | 2015-09-01 | Premier Dental Products Company | Self-healing dental restorative formulations and related methods |
DE102010008971B4 (en) | 2010-02-24 | 2013-10-10 | Hilti Aktiengesellschaft | Use of a two-component mortar composition |
DE102010051818B3 (en) * | 2010-11-18 | 2012-02-16 | Hilti Aktiengesellschaft | Two-component mortar compound and its use |
DE102011017626B4 (en) | 2011-04-27 | 2013-01-03 | Hilti Aktiengesellschaft | Method for stabilizing a reaction resin mortar and its precursor mixtures, resin mixture, reaction resin mortar, multi - component mortar system, its use and cartridge, cartridge or foil bag comprising the multi - component mortar system |
DE102011017619B4 (en) * | 2011-04-27 | 2014-10-16 | Hilti Aktiengesellschaft | Accelerator mixture for peroxide hardener and containing two-component mortar system and use of the mortar system |
DE102011077248B3 (en) | 2011-06-09 | 2012-09-27 | Hilti Aktiengesellschaft | Use of an inhibitor, resin mixture, reaction resin mortar, two - component mortar system and its use, and cartridge, cartridge or foil bag containing a two - component mortar system |
EP2784036A1 (en) * | 2013-03-26 | 2014-10-01 | Basf Se | Quickly suspending powder-form compound |
EP2829525A1 (en) * | 2013-07-24 | 2015-01-28 | HILTI Aktiengesellschaft | Reaction resin mortar, multi-component mortar system and their use |
EP3034520A1 (en) * | 2014-12-19 | 2016-06-22 | HILTI Aktiengesellschaft | Reaction resin composition and its use |
-
2019
- 2019-12-09 EP EP19214397.2A patent/EP3835279A1/en not_active Withdrawn
-
2020
- 2020-11-30 JP JP2022534859A patent/JP2023505542A/en active Pending
- 2020-11-30 US US17/755,859 patent/US20220380571A1/en active Pending
- 2020-11-30 EP EP20812341.4A patent/EP4073012A1/en not_active Withdrawn
- 2020-11-30 CA CA3155531A patent/CA3155531A1/en active Pending
- 2020-11-30 CN CN202080072577.7A patent/CN114641461B/en active Active
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JP2023505542A (en) | 2023-02-09 |
WO2021115808A1 (en) | 2021-06-17 |
US20220380571A1 (en) | 2022-12-01 |
CN114641461A (en) | 2022-06-17 |
AU2020403372A1 (en) | 2022-05-19 |
EP3835279A1 (en) | 2021-06-16 |
KR20220113361A (en) | 2022-08-12 |
CA3155531A1 (en) | 2021-06-17 |
CN114641461B (en) | 2023-06-16 |
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