EP4058269A1 - Dispositif de préchauffage de matériau particulaire et son utilisation dans des procédés 3d - Google Patents

Dispositif de préchauffage de matériau particulaire et son utilisation dans des procédés 3d

Info

Publication number
EP4058269A1
EP4058269A1 EP20816386.5A EP20816386A EP4058269A1 EP 4058269 A1 EP4058269 A1 EP 4058269A1 EP 20816386 A EP20816386 A EP 20816386A EP 4058269 A1 EP4058269 A1 EP 4058269A1
Authority
EP
European Patent Office
Prior art keywords
particulate material
coater
container
preheating container
preheating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP20816386.5A
Other languages
German (de)
English (en)
Inventor
Christoph Hoppmann
Roman Scheller
Ingo Ederer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Voxeljet AG
Original Assignee
Voxeljet AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Voxeljet AG filed Critical Voxeljet AG
Publication of EP4058269A1 publication Critical patent/EP4058269A1/fr
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10—Processes of additive manufacturing
    • B29C64/159—Processes of additive manufacturing using only gaseous substances, e.g. vapour deposition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/20—Apparatus for additive manufacturing; Details thereof or accessories therefor
    • B29C64/205—Means for applying layers
    • B29C64/209—Heads; Nozzles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/20—Apparatus for additive manufacturing; Details thereof or accessories therefor
    • B29C64/205—Means for applying layers
    • B29C64/214—Doctor blades
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/20—Apparatus for additive manufacturing; Details thereof or accessories therefor
    • B29C64/255—Enclosures for the building material, e.g. powder containers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/20—Apparatus for additive manufacturing; Details thereof or accessories therefor
    • B29C64/295—Heating elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/30—Auxiliary operations or equipment
    • B29C64/307—Handling of material to be used in additive manufacturing
    • B29C64/314—Preparation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/30—Auxiliary operations or equipment
    • B29C64/307—Handling of material to be used in additive manufacturing
    • B29C64/321—Feeding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00—Processes of additive manufacturing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y30/00—Apparatus for additive manufacturing; Details thereof or accessories therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y40/00—Auxiliary operations or equipment, e.g. for material handling
    • B33Y40/10—Pre-treatment
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/25—Process efficiency

Definitions

  • the invention relates to a preheating container and a device and a method for producing 3-D molded parts that use a preheating container.
  • the European patent EP 0 431 924 B1 describes a method for producing three-dimensional objects from computer data.
  • a particle material is applied to a platform in a thin layer by means of a recoater and this is selectively printed with a binder material by means of a print head.
  • the particle area printed with the binder connects and solidifies under the influence of the binder and, if necessary, an additional hardener.
  • the construction platform is then lowered by a layer thickness or the coater / print head unit is raised and a new layer of particulate material is applied, which is also selectively printed as described above. These steps are repeated until the desired height of the object is reached.
  • a three-dimensional object (3D component, molded part) is created from the printed and solidified areas.
  • This object made of solidified particulate material is embedded in loose particulate material after its completion and is then freed from it. This is done, for example, by means of a suction device. Left over
  • powder-based rapid prototyping processes work in a similar way, such as selective laser sintering or electron beam sintering, in which a loose particle material is applied in layers and selectively solidified with the help of a controlled physical radiation source.
  • the particle materials in the 3D printer are heated to a predetermined temperature above the ambient temperature in order to bring about certain effects in the construction process.
  • Such a method is described, for example, in DE102005022308B4.
  • the particulate material is heated in the coater itself, with at least part of a heating element being at least partially integrated into the side walls or the coater blade. This has the disadvantage that the heat transfer has a gradient and is therefore not as efficient.
  • the retention time of the particulate material in the coater is relatively short, so that the target temperature is not or only partially reached and a temperature gradient also occurs in the particulate material, depending on whether the particulate material was close to the wall of the coater or further away from it.
  • a solution as described in the present application is neither disclosed nor suggested herein.
  • the method described in DE102013004940A1 uses, instead of a laser, an IR absorber that is printed onto the preheated particle material and another radiation source that selectively heats the areas of the particle material above the melting temperature that were previously printed.
  • a solution as described in the present application is neither disclosed nor suggested herein.
  • a liquid binder printed in fine droplets via a print head needs a certain temperature in order to harden and to form the desired molded parts in the particle bed.
  • This temperature is advantageously introduced into the binder via thermal conduction through the particulate material. Because the binder will harden with increasing temperature and thus increase the viscosity. Under no circumstances should this happen in the print head, since the hardening of the binder would lead to failure of the nozzles and thus possibly to failure of the print head.
  • the binder must therefore be dosed in the print head at as constant a temperature as possible, which is far enough away from the curing temperature. Once on the construction site, however, it must be ensured that the binder hardens sufficiently quickly.
  • the temperature is introduced into the particulate material in various ways.
  • One possibility is to irradiate the construction field with the particulate material freshly spread for a layer.
  • the irradiation is usually carried out with infrared radiation, which is introduced, for example, via a heating coil radiator.
  • infrared radiation which is introduced, for example, via a heating coil radiator.
  • the particle material must guarantee good coupling of the wavelength.
  • Another disadvantage of the radiation heating is the possible shadowing of the radiation source by construction field tools moving in the process room.
  • the exposure time to a radiation source is usually shorter than the process time of a shift.
  • the power of a suitable radiation source must be correspondingly high and the energy losses are correspondingly high.
  • Another possibility is to heat contact surfaces with the powder, as shown in DE102005022308B4.
  • the particle material is then heated via the heat conduction, for example in the recoater.
  • Other components of the printer that carry particulate matter such as the construction platform and the job box, can also be heated.
  • Electrical resistance heaters can be used as heaters, but other types of construction, such as heating via the circulation of temperature-controlled liquids in fluid lines in the surfaces to be heated, are also possible.
  • the disadvantage here is that the bulk of particulate material generally has a significantly poorer thermal conductivity than the original material. This is due to the small contact area between the individual particles and the filling of the spaces in the powder with the little heat-conducting air.
  • particulate material in the recoater is problematic, since the retention time of the particulate material is generally short and only a few shift cycles long.
  • unheated particulate material can be discharged.
  • the disclosure relates to a preheating container for particulate material (building material) suitable for a 3D printing device, which has one or more heating means, wherein the heating means (s) are arranged in the area provided for receiving the particulate material and wherein the heating means (s) is substantially surrounded by the particulate material.
  • the disclosure relates to a method for producing a molded part by means of particle material application and selective solidification and all further process steps and process means necessary for this, the particle material being placed in a preheating container in a preheating container before being introduced into the coater and / or before being applied to the construction field Target temperature is heated.
  • FIG. 1 shows a device and a process sequence according to the prior art.
  • FIG. 2 shows an exemplary device according to the invention in
  • FIG. 3 shows an exemplary device according to the invention in
  • FIG. 4 shows an exemplary preheating container, a heating element being shown as an example.
  • the object on which the application is based is achieved by a preheating which is located in the interior of a particle material container - also referred to as a preheating container.
  • the preheater is surrounded by the particulate material and the particulate material flows around the preheater during the 3D printing process.
  • the particle material container is dimensioned in such a way that the average length of time the material remains in the container corresponds to a multiple of the shift time of the 3D printing process.
  • Storage containers which are provided for filling the coater have proven to be suitable containers in the context of the invention. Such storage containers hold a multiple of the particulate material required for a layer. In some cases, the storage bins also contain all of the particulate material required for a construction job.
  • the storage container can be located in the immediate vicinity of the coater. This means that it can be avoided that heated particulate material cools down again on the way to the application of the layer. It can be advantageous if the coater in turn has thermal insulation or a possibility of heating in order to effect "active" insulation. The same applies to the construction platform and the job box.
  • layer construction methods or “3D printing methods” or “3D methods” or “3D printing” are all methods known from the prior art that enable components to be built in three-dimensional shapes and with the methods used here Further described process components and devices are compatible.
  • Binder jetting in the sense of the disclosure means that powder is applied in layers to a building platform, the cross-sections of the component on this powder layer are printed with one or more liquids, the position of the building platform is changed by one layer thickness from the last position and these steps are repeated until the component is finished.Binder jetting is also to be understood here as layer construction processes that require a further process component such as exposure to layers, for example with IR or UV radiation. “3-D shapes”, “molded bodies” or “component” in the sense of the disclosure are all three-dimensional objects produced by means of the method according to the invention and / or the device according to the invention which have dimensional stability.
  • Construction space is the geometric location in which the particulate material fill grows during the construction process through repeated coating with particulate material or through which the fill passes with continuous principles.
  • the construction space is made up of a floor, the construction platform, walls and an open top surface, the Construction level, limited. With continuous principles there are usually a conveyor belt and delimiting side walls.
  • job box represents a unit that can be moved into and out of the device and allows batch production, with a job box being extended after the process has been completed and a new job box can be run into the device immediately, so that the production volume and thus the device performance is increased.
  • particulate material As “building material” or “particulate material” or “powder” or “bulk powder” in the sense of the disclosure, all flowable materials known for 3D printing can be used, in particular in powder form, as a slip or as a liquid. These can be, for example, sand, ceramic powder, glass powder, and other powders made of inorganic or organic materials such as metal powder, plastics, wood particles, fiber materials, celluloses and / or lactose powder and other types of organic, powdery materials.
  • the particulate material is preferably a dry, free-flowing powder, but a cohesive, cut-resistant powder can also be used. This cohesiveness can also result from the addition of a binder material or an auxiliary material such as a liquid. The addition of a liquid can result in the particulate material being able to flow freely in the form of a slip.
  • particulate material can also be referred to as fluids in the context of the disclosure.
  • particulate material and powder are used synonymously.
  • the "particle material application” is the process in which a defined layer of powder is generated. This can be done either on the construction platform (construction field) or on an inclined plane relative to a conveyor belt using continuous principles Called “Recoaten”.
  • “Selective application of liquid” or “selective application of binder” in the sense of the disclosure can take place after each application of particulate material or, depending on the requirements of the molded body and to optimize the production of the molded body, it can also take place irregularly, for example several times based on an application of particulate material. A sectional image is printed through the desired body.
  • any known 3D printing device that contains the required components can be used as the “device” for carrying out a method according to the disclosure.
  • Usual components include coater, construction field, means for moving the construction field or other components in continuous processes, job boxes, metering devices and heat and radiation means and other components known to the person skilled in the art, which are therefore not detailed here.
  • the building material according to the disclosure is always applied in a “defined layer” or “layer thickness”, which is set individually depending on the building material and process conditions. It is, for example, 0.05 to 5 mm, preferably 0.07 to 2 mm.
  • a "coater” or “recoater” in the sense of the disclosure is a device part that can absorb fluid, for example particle material such as mineral or metallic materials or plastics, wood in the form of particles or mixtures thereof, and is controlled on a building platform of a 3D Device releases or applies in layers.
  • the application device can be designed to be elongated and the particulate material is located in a storage container above an outlet opening.
  • the coater can also consist of a stationary blade or a counter-rotating roller, which spreads a certain amount of powder in front of the blade or roller on the construction field.
  • a “coater blade” in the sense of the disclosure is an essentially flat metallic component or component made from another suitable material, which is located at the outlet opening of the coater and via which the fluid is released onto the construction platform and is smoothed or two or more coater blades.
  • a coater blade can be an oscillating blade which oscillates in the sense of a rotary movement when it is excited. Furthermore, this oscillation can be switched on and off by a means for generating oscillations.
  • the coating blade is arranged “essentially horizontally” or “essentially vertically” in the sense of the disclosure.
  • the “storage container” or “preheating container” in the sense of the disclosure is a container that contains particulate material and releases a quantity thereof to the coater after each layer or after any number of layers.
  • the storage container can advantageously extend over the entire width of a coater.
  • the storage container has a closure at the lower end that prevents the particulate material from accidentally escaping.
  • the closure can be designed, for example, as a rotary valve, a simple slide or other suitable mechanisms according to the prior art.
  • a storage container in the sense of the disclosure may contain particulate material for more than one layer.
  • the storage container preferably even contains particulate material for the application of 20 or more layers.
  • the particulate material either comes from a larger supply in the form of a silo or a big bag via a conveyor or is filled into the container by hand.
  • the filling is preferably carried out through an opening on the upper edge.
  • the storage container may also have vibrating mechanisms that prevent the particulate material in the container from bridging.
  • the storage container has an area which receives the particulate material, which is usually located between the side walls and the closure. According to the disclosure, it is advantageous if a heating means is arranged in the area that receives the particulate material.
  • the heating means is arranged in such a way that the particulate material flows around the heating means and thus the heating of the particulate material is improved.
  • the storage container can be arranged in a stationary manner, in which case it can then be arranged, for example, above the holding position of the coater or above the construction field. The refilling can then take place, depending on requirements and / or control of the volume, with pre-tempered particulate material by a method of the coater on or below the storage container.
  • the storage container can, however, also be connected to the coater in a detachable or non-detachable manner. It can also be advantageous, for reasons of construction and / or cost, that the coater cannot be heated.
  • the coater can then have passive insulation.
  • the coater can also not be heated at all and also not provided with insulation if the preheated particulate material is delivered to the coater in a volume that essentially corresponds to a layer volume or 1.2 to 2 times that, and so it is can be applied to the construction field with practically no dwell time in the coater and thus essentially without heat loss.
  • "Emitter unit” in the sense of the disclosure is an arrangement of emitter units.
  • emitter unit in the sense of the disclosure is a unit that emits light of a specific spectrum.
  • Coupled in the sense of the disclosure is an agent that can cool a radiator unit, such as water or another liquid or a fan flow.
  • Heating means in the sense of the disclosure is a means that serves to heat the particulate material in the storage container to a desired temperature.
  • a heating means can be any known heating unit compatible with the other parts of the device, which are known to the person skilled in the art and are therefore not described in detail here
  • the heating means is not or not at least partially integrated in the storage container or coater, but is only arranged in the area that receives the particulate material. It can be advantageous if the surface of the heating means is enlarged by suitable means in order to reduce the To optimize heat conduction into the particle material that flows around the heating medium. Conceivable are, for example, ribs or fins, a serpentine or spiral design of the heating medium, etc.
  • Edge area in the sense of the disclosure is the area of a radiator unit that is located at the edge of the radiator unit and can be delimited from the interior area.
  • the edge area and interior area form the total area of the radiator unit in terms of its area on which the radiator units are attached.
  • Outside area in the sense of the disclosure is the area of a radiator unit that is located inside the radiator unit and can be delimited from the edge area.
  • 3D printer or “printer” in the sense of the disclosure refers to the device in which a 3D printing process can take place.
  • a 3D printer within the meaning of the disclosure has an application means for building material, e.g. a fluid such as a particulate material, and a solidification unit, e.g. a print head or an energy input means such as a laser or a heat lamp.
  • building material e.g. a fluid such as a particulate material
  • solidification unit e.g. a print head or an energy input means such as a laser or a heat lamp.
  • Further machine components known to the person skilled in the art and components known in 3D printing are combined with the above-mentioned machine components depending on the special requirements in the individual case.
  • Construction field is the level or, in a broader sense, the geometric location on which or in which a bed of particulate material grows during the construction process through repeated coating with particulate material.
  • the construction field is often made up of a floor, the "construction platform”, walls and an open top surface , the building level.
  • the “printing” or “3D printing” process in the sense of the disclosure denotes the summary of the processes of material application, selective solidification or also printing and adjusting the working height and takes place in an open or closed process space.
  • a “receiving plane” in the sense of the disclosure is to be understood as the plane onto which the building material is applied. According to the disclosure, the receiving plane is always freely accessible in one spatial direction by means of a linear movement.
  • Construction field tool or “functional unit” in the sense of the disclosure are all means or device parts that are used for the application of fluid, for example particulate material, and the selective solidification during the production of Moldings are used. All material application means and layer treatment means are also construction site tools or functional units.
  • “Spreading” or “applying” within the meaning of the disclosure means any manner in which the particulate material is distributed. For example, at the starting position of a coating run, a larger amount of powder can be presented and distributed or spread into the layer volume by a blade or a rotating roller.
  • “Coater” or “recoater” or “material application means” in the sense of the disclosure is the unit by means of which a fluid is applied to the construction field.
  • This can consist of a fluid storage container and a fluid application unit, wherein according to the present invention the fluid application unit has a fluid outlet and a "Squeegee device” includes.
  • This doctor blade device could be a coater blade.
  • any other conceivable suitable doctor blade device could also be used.
  • rotating rollers or a nozzle are also conceivable.
  • the material supply can flow freely via storage containers or extruder screws, pressurization or other
  • Warping refers to the bending of printed layers due to the shrinkage occurring at different times when the bound particles solidify. This can lead to layer defects if structures rise from the construction site level due to warping and are possibly carried away by the coater during the next coating.
  • the “print head” or means for selective solidification within the meaning of the disclosure is usually composed of various components. Among other things, these can be print modules.
  • the print modules have a large number of nozzles, from which the “binder” in Droplet form is ejected in a controlled manner onto the construction field.
  • the print modules are aligned relative to the print head.
  • the printhead is oriented relative to the machine. This means that the position of a nozzle can be assigned to the machine coordinate system.
  • the plane in which the nozzles are located is usually referred to as the nozzle plate.
  • Another means for selective solidification can also be one or more lasers or other radiation sources or a heat lamp. Arrays of such radiation sources, such as laser diode arrays, can also be considered.
  • the selectivity is introduced separately from the solidification reaction.
  • a print head or one or more lasers can be used for selective treatment of the layer and solidification can be started with other layer treatment agents.
  • the particulate material is printed with an IR absorber and then solidified with an infrared source.
  • Layer treatment agents in the sense of the disclosure are all agents that are suitable to achieve a certain effect in the layer. This can include the aforementioned units such as print head or laser, but also heat sources in the form of IR radiators or other radiation sources such as UV radiation. Means for de- or ionization of the layer are also conceivable. What all layer treatment agents have in common is that their zone of action is linearly distributed over the layer and that, like the other layer units such as print head or coater, they have to be guided over the construction field to cover the entire area Layer to achieve.
  • the object on which the application is based is achieved by a preheating container for particulate material (building material) suitable for a 3D printing device, which has one or more heating means, the heating means (s) being arranged in the area provided for receiving the particulate material and where the or the heating means is substantially surrounded by the particulate material.
  • the object on which the application is based is further achieved by a device suitable for a 3D printing method, the device having one or more preheating containers for particulate material which have one or more heating means that are essentially surrounded by the particulate material.
  • the solution of the present disclosure has the advantage that an advantageous heat transfer takes place from the heating element in the storage container into the particulate material to be preheated. This is achieved on the one hand by the fact that the particle material flows around the heating element and thus a good temperature transfer is achieved.
  • the retention time of the particulate material in the storage container is relatively long in the overall view of a printing process and a print job or a print batch, but also in continuous processes, whereby a good result of the preheating of the particulate material can be achieved.
  • the temperature control of the particle material is shifted away from the installation space and can be upstream.
  • the one or more heating means can have a surface enlargement on their surface facing the particulate material and be designed as ribbing, lamella or other suitable structure. This can be advantageous in order to further improve the heat transfer rate to the particulate material and to achieve a uniform heat distribution.
  • the preheating container can be stationary, the preheating container can be arranged in a stationary manner above the construction field and / or laterally above the construction field, or the preheating container can be coupled to the coater.
  • the preheating container can advantageously be arranged in such a way that the coater can easily be moved to the preheating container and the preheated particulate material can be dispensed and transferred to the coater in a desired volume.
  • the device or the preheating container according to the disclosure can advantageously be designed so that the heating means (s) are not and not at least partially integrated in the preheating container and / or not and not at least partially in the side walls, the bottom part and / and a coating blade of the preheating container are integrated.
  • the heating element in the preheating container improved heat conduction into the particulate material is achieved and a substantially uniform temperature distribution can be achieved in the particulate material to be heated or at least the heat input into the particulate material can be improved compared to known solutions of the prior art Technology.
  • the preheating container can have a particulate material dispensing means (closure) and the particulate material dispensing means for dispensing a defined one
  • the volume of particulate material can be adjusted, optionally for delivery into the coater (s) or directly onto the construction field, the particulate material delivery means preferably not being designed as a blade.
  • any volume of particulate material can be dosed into the coater or onto the construction field. It can be advantageous if the defined volume essentially corresponds to the volume of a particle material layer on the construction field or 1.2 to 1.9 times the volume of a particle material layer on the construction field or the 2, 3, 4, 5, 6, 7 , Corresponds to 8, 9 or 10 to 12 times the volume of a particulate material layer on the construction field.
  • this particulate material also essentially retains the temperature to which it was brought in the preheating container without cooling down significantly. This means that practically no further heating is required on the construction site, so that the construction of the 3D components with constant temperatures and in high quality is possible.
  • the preheating container can be arranged in a manner that is advantageous for the device and its overall structure, for example outside the complex of coater and construction field or above the construction field or near a reversal point of the coater.
  • the preheating container can also be connected upstream of one or more coaters.
  • a heat source for example in the form of an electrically operated resistance heater, can be integrated directly into the heating means or means.
  • the heating means (s) can be designed as heat conductors which conduct heat from a source located outside the container into the interior. For example as a heated liquid or gas. The heat can also be conducted into the interior of the container via a heat conducting body. In the form of a guide body constructed with ribs, which is heated from the outside via one or more heating means.
  • the heat source in the device according to the disclosure can be designed as an electrically operated resistance heater or as a fuel operated heater.
  • the heating means are arranged in the space for receiving the particulate material, the heating means (s) essentially not touching the container wall and / or the bottom and / or the closure. It can be advantageous if a distance of 2 to 5 mm or 1 to 5 cm is maintained.
  • the disclosure relates to a method for the production of a molded part by means of particle material application and selective solidification and all other necessary process steps and process means, wherein the particle material before being introduced into the coater and / or before being applied to the construction field in a preheating container Target temperature is heated.
  • Target temperature can be set variably and even changed during the process, for example after a certain number of layer applications, the target temperature being 50 ° C to 190 ° C, preferably 50 ° C to 80 ° C or 90 ° C to 120 ° C ° C or 120 ° C to 190 ° C.
  • the preheating container can have a particulate material dispensing means (closure) and the particulate material dispensing means can be adjusted to dispense a defined volume of particulate material.
  • the volumes that are advantageous for this have already been described above and are also used here.
  • any particulate material suitable for 3D printing can be used in the method according to the disclosure, the particulate material preferably being a sand, a coated sand, a ceramic powder, a metal powder, a polymer or a cellulose-based material.
  • the process according to the disclosure can be any known 3D printing process, for example the process can be a phenolic resin process, a high-speed sintering process or an inorganic process.
  • the installation space and / or the installation field can also be set to a defined temperature.
  • the temperature can be set to 50 ° C to 190 ° C, preferably 50 ° C to 80 ° C or 90 ° C to 120 ° C or 120 ° C to 190 ° C.
  • a device in one aspect comprises a 3D printer according to the prior art with the components well known to the person skilled in the art, e.g. with a particulate material supply, a coater, a print head for the dosage of binder, a construction platform of a controller and optionally at least one Heat source for heating and / or tempering the particulate material above ambient temperature and, according to the disclosure, a preheating container.
  • the storage container has a structure inside that has the largest possible contact surface with the particle material.
  • the particle material moves following the force of gravity from the upper edge of the storage container to the bottom, where a
  • the outflowing particulate material moves past the internal structure and absorbs heat through contact with the structure.
  • the structure itself can consist, for example, of elongated electrically operated heating rods that have additional fins to improve the heat transfer.
  • the heating rods advantageously have a surface made of a material that conducts heat well, such as steel.
  • the lamellas can also advantageously be formed from such a material.
  • the structure should be designed in such a way that the particulate material can move around it, but there are no constrictions at which the flow of particulate material can come to a standstill. This means that the The distances between the lamellae and the rods to one another but also to the storage container wall are sufficiently dimensioned.
  • the heatable length of such containers is as long as the coater is wide, in the present case e.g. 1000mm.
  • the depth of the container is 60 mm and the height is 250 mm.
  • Two 3.6 m long four heating rods with 3 bends each are installed in the container, which extend over the entire length and are held in position in a support structure.
  • FIG. 1 shows a device and a process sequence according to the prior art, the particulate material (5) - also referred to as bulk material - being filled from a powder reservoir (1) (storage container) into a coater (2); the delivery of the particulate material can be controlled via a closure (10).
  • the particle material is dispensed here, for example, by means of a coater blade (3), with particle material layers (6, 61, 6.2) being created in a defined thickness on the construction field (not shown).
  • the particle material is applied by moving the coater (2) over the construction field in the direction of travel (4) and the opposite direction (4.1). After each application of the particle material layer, the construction field is lowered by a desired height or the application device (2) is raised.
  • FIG. 2 shows an exemplary device according to the invention in a side view, with a coater as shown in FIG. 1, which is filled via a preheating container (7).
  • the preheating container (7) has heating elements (8, 8.1, 8.2) around which particulate material (5) flows and can thus be heated to a predetermined temperature.
  • a defined amount (volume) of particulate material can be dispensed into the coater by means of a closure (10).
  • the closure (10) can be designed as a slide, by means of vibration and bridging or in another suitable manner.
  • the particulate material (5) can also be delivered directly to the construction field when working without a coater to create a particle layer, but by means of a particle material feed quantity, which is then applied by means of a so-called roller over a roller or a slide on the construction field to create a defined particle material layer is achieved.
  • FIG. 3 shows an exemplary device according to the invention in side view, the components essentially corresponding to those of FIG. 2, with two heating elements being arranged in the preheating container (7), which are designed as finned tube heating (9, 9.1) and are also surrounded by particulate material . Due to the contact and a relatively long dwell time, effective and targeted heating of the particulate material (5) can be achieved, so that heating in the coater and / or on the construction field is essentially no longer necessary.
  • the heating element can have a surface enlargement such as ribs, which further simplify the heating of the particulate material. It is now possible to select the loading of the preheating container (7) according to the material requirements.
  • the preheating container can be fully loaded, while in the case of more heat-sensitive materials such as plastics, a shorter dwell time is achieved in that less particulate material (5) is presented and this is thus released into the coater (2) more quickly.
  • a specifically defined one can also be used Amount that essentially corresponds to one layer thickness, for example, or 1.2 to 1.9, or 2, 3, 4, 5, 6, 7, 8, 9, 10 or 11-12 layer thicknesses
  • Particulate material (5) corresponds to being dispensed into the coater (2) via the closure (10).
  • an even more precise temperature control of the particulate material can advantageously be achieved by further shortening the dwell time in the coater (2) and thus the cooling in the
  • Coater (2) is reduced.
  • better temperature control can be achieved overall and there is no need to heat the particulate material (5) on the construction field itself. This is particularly advantageous if the components in the installation space are to be exposed to as short as possible or not exposed to elevated temperatures.
  • FIG. 4 shows an exemplary preheating container (7), a heating element (8) being shown as an example.
  • a preheating container (7) with a heating element is shown schematically in a plan view, the heating element being designed as a finned tube heater (9).
  • the heating element has ribs (11) as surface enlargements.
  • Binder jetting processes with thermosetting binders are known from the prior art.
  • the temperature necessary to harden the binder is either entered into the particulate material bed after the construction process, for example via microwave treatment or other oven treatment, or the temperature is introduced into the particle material bed in layers during construction.
  • This is typically done by means of IR radiation heating, which is designed, for example, as a line-shaped radiator, which in turn is, for example, on the Coater is located in the immediate vicinity of the construction site.
  • the particulate material can be deposited in a new layer and at the same time brought to the required temperature.
  • the disadvantage here is that the coupling of the IR radiation energy into typical particle materials such as quartz sand or ceramic materials is relatively poor and a lot of energy is lost to the surrounding space.
  • several layers of building material are applied one after the other and treated with IR radiation until the desired temperature is reached on the building site.
  • this preheating phase lasts up to 90 minutes, which are part of the actual construction process and reduce the productivity of the device.
  • the usable overall height is reduced by the amount of the unprinted starter layers, in the specific example that is around 20 mm.
  • a particulate material e.g. quartz sand with an average grain size of 90 to 210 ⁇ m or more specifically 140 ⁇ m
  • a transport route e.g. a screw conveyor into a preheating container of a VX2000 3D printer from voxeljet AG.
  • the preheating container holds about 8 kg of particulate matter.
  • several heating rods are attached lengthways. The heating rods are arranged so that the particulate material must flow around the heating rods.
  • the heating rods have an electrical connection power of 6 kW and heat the particulate material from an ambient temperature of around 22 ° C to a temperature of over 170 ° C.
  • the hot particulate material is poured into a coater hopper in batches. The process takes place about every 2nd shift.
  • the coater funnel has on its outside electrically heated mats to minimize heat loss from the particulate material through a cold coater hopper wall.
  • the particulate material is then applied by means of a coater in a layer thickness of 0.1 to 0.5 mm, usually 0.3 mm, onto the construction area of 2 ⁇ 1 m.
  • the deposited amount for this type of machine is approx. 800g or 1400g.
  • the particle material then forms the new construction area and, after coating, has a temperature in the range of 90 - 110 ° C. This process is repeated for the initial shifts before the start of a print job. Due to the uniform heating of the particulate material, the heat loss of the first layers in the construction area is relatively low, so that the desired temperature on the sand surface can be reached and stabilized after 15 unprinted starting layers.
  • the print head follows, which is computer-controlled and selectively doses a thermosetting phenolic resin onto the construction field according to the predetermined shift data. The dosage is about 5 - 8% by weight. In this version, the process room atmosphere has an average temperature of 45 ° C.
  • the coater moves to the start position and guides an IR radiator over the construction field, which increases the construction field temperature further to 110 ° C.
  • the heater is set to a power of 3 kW.
  • the necessary energy input at the IR radiator can be reduced from 18 kW to 3 kW.
  • the power requirement for heating the sand to the required temperature on the construction site has decreased so that the speed during the irradiation run of the coater from 100 mm / s to 500 mm / s and that of the coating run from 80 mm / s to 130 mm / s can be increased.
  • the shift duration is thus significantly reduced from 70 s to less than 40 s.
  • the temperature of the process room atmosphere is kept constant at 45 ° C and that no air conditioning unit is required for this at an ambient temperature of 25 ° C.
  • the heating phase of the device decreases when the starting shifts are taken off around 80 minutes to around 20 minutes and the usable overall height is only reduced by around 5 mm instead of around 20 mm.
  • the process of layer application, printing and irradiation is repeated until the desired molded part is built up.
  • the filled job box is removed from the 3D printer and cools down for a few hours under ambient conditions before the unprinted sand is removed using a vacuum suction device and the printed structures can be removed.
  • Standard bending bars that are oriented in the direction of pressure have a bending strength of 350-400 N / cm 2 with an LOI of 2.2-2.4% by weight.
  • a particulate material for example a quartz sand with an average grain size of 90 to 210 ⁇ m or, more specifically, 140 ⁇ m.
  • the particulate material can be premixed with a so-called promoter.
  • the material is dosed into a storage container (preheating container) of a VX1000 3D printer from voxeljet AG via a transport route, e.g. a screw conveyor.
  • the preheating container holds about 8 kg of particulate matter.
  • several heating rods are attached lengthways. The heating rods are arranged so that the particulate material must flow around the heating rods.
  • the heating rods have an electrical connection power of 6 kW and heat the particulate material from an ambient temperature of around 22 ° C to a temperature of over 80 ° C.
  • the hot particulate material is poured into a coater hopper in batches. The process takes place about every 3rd shift.
  • the coating hopper has electrically heated mats on its outside in order to minimize heat loss from the particulate material via a cold coating hopper wall.
  • the particle material is then applied by means of a coater in a layer thickness of 0.1 to 0.5 mm, usually 0.3 mm, onto the construction field of 0.6 ⁇ 1 m. The deposited amount is around 240 g for this type of machine.
  • the particulate material then forms the new construction area and, after coating, has a temperature in the range of 40 - 50 ° C.
  • the print head follows, which is computer-controlled and selectively doses an inorganic binder onto the construction field according to the predetermined layer data.
  • This binder consists of a mixture of dissolved water glasses and other solvents, which builds strength when dry. The dosage is about 2 - 5% by weight.
  • the increase in the temperature in the particulate material leads to faster drying of the binder and thus to less undesirable penetration into the unprinted areas.
  • the necessary energy input during the layer build-up can take place entirely via the preheating container. No other heat source such as an IR radiator is necessary.
  • the filled job box is removed from the 3D printer and can be sent to a post process, which can include heat treatment, among other things.
  • Standard bending bars which are oriented in the direction of pressure, have a bending strength of 200-300 N / cm 2 with a residual moisture content of 0.1-0.35% by weight after the post process.
  • Another process in additive manufacturing is the high-speed sintering process.
  • a polymer powder eg polyamide 12 - PA12 for short - with an average grain size of 55 ⁇ m is processed.
  • the material is bonded by selective melting.
  • the particulate material is applied to the construction area for this purpose.
  • the layer thickness in this case is typically 80 ⁇ m.
  • the fresh layer is now brought to a temperature of preferably 165-178 ° C. from the free upper side by means of radiation and from the previously applied layer underneath by means of heat conduction.
  • a print head then selectively doses an absorber on the areas to be consolidated before the entire construction field is passed over with another radiation source.
  • the unprinted parts of the construction area are largely reflective or transparent for the selected radiation, retain the previously set temperature and thus remain loose.
  • the desired component can be removed from the construction container and cleaned of the unprinted particulate material.
  • the component will have material properties typical for PA12.
  • the challenge in this process is temperature control.
  • the particle material on the construction field should have a temperature that is as constant as possible within the sintering window of the material.
  • the printhead must not be exposed to excessive temperatures, as this could otherwise be damaged.
  • the operating temperature of the printhead is typically below 60 ° C.
  • the process room temperature should therefore not exceed 50 ° C.
  • a prior art HSS printer therefore usually has various systems for heating and cooling.
  • the particle material can, for example, be brought to temperature using a surface heater above the construction field.
  • the sintering temperature can be achieved on the printed surfaces by passing a heater over them.
  • the process room temperature on the other hand, can be implemented using a passive exhaust air concept or active cooling using an air conditioning unit.
  • particulate material at ambient temperature has a disadvantageous effect on the hot construction field. In the worst case, so much heat is withdrawn from the previous layer that the printed powder areas solidify and shrink and thereby become so-called warping stops. In this respect, it is advantageous that the particulate material to be applied already has a temperature which is close to the construction field temperature, if possible beforehand. It is obvious that the entire particle material supply should be tempered accordingly. However, this is tedious and, on the other hand, it stresses the particulate material for the duration of the entire construction process as well as the times for heating and cooling. For this reason, it is more effective and gentler on the particle material if the material is brought to the appropriate temperature shortly before application. Devices according to the prior art use, inter alia, heated coaters.
  • the disadvantage here is that the time to heat up the particulate material is limited, because a coater advantageously carries along a supply of particulate material that is only sufficient for a few layers. Accordingly, the particulate material newly filled into the coater is applied to the construction site in a few minutes. In addition, it can hardly be prevented that, due to the mixing in the coater, even non-tempered particle material is released onto the construction field.
  • a limited supply of particulate material in the storage container can be safely pre-tempered with low energy losses and a desired temperature can be set in the particulate material.
  • the material is in large quantities in a silo at ambient temperature and is conveyed to a storage container on demand via a conveyor line, eg a screw conveyor.
  • the request takes place when a defined fill level in the container, which is detected by means of a sensor, is not reached.
  • the storage container is equipped with the device according to the invention, with which the particulate material is heated to 90-140 ° C. when it is metered into the coater at the lower outlet.
  • the coater itself has, for example, active insulation through electrically heated mats attached to the outer surfaces, which ensure that the temperature of the particulate material does not drop during coating.
  • the new one will arrive at the construction site Layer brought to the desired temperature from below through the previous layer and on the free upper side by the surface heater.
  • the device leads to a more uniform construction field temperature than is possible with a device according to the prior art.
  • the zones at the edge of the construction site have an overall better temperature uniformity.
  • Powder reservoir coater (recoater) Coater blade 4.1 direction of travel (direction and opposite direction) particle material (particle material pouring) particle material layers on construction field .1 particle material layers on construction field .2 particle material layers on construction field preheating container heating element .1 further heating element .2 further heating element, 9.1 finned tube heating 0 closure (particle material release means) 1 Surface enlargement (ribs) on the heating element

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Abstract

L'invention concerne un dispositif et un procédé pour fabriquer des pièces façonnées en 3D, un récipient de préchauffage étant utilisé.
EP20816386.5A 2019-11-13 2020-11-11 Dispositif de préchauffage de matériau particulaire et son utilisation dans des procédés 3d Pending EP4058269A1 (fr)

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DE102019007863.2A DE102019007863A1 (de) 2019-11-13 2019-11-13 Partikelmaterialvorwärmvorrichtung und Verwendung in 3D-Verfahren
PCT/DE2020/000278 WO2021093911A1 (fr) 2019-11-13 2020-11-11 Dispositif de préchauffage de matériau particulaire et son utilisation dans des procédés 3d

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WO (1) WO2021093911A1 (fr)

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US5204055A (en) 1989-12-08 1993-04-20 Massachusetts Institute Of Technology Three-dimensional printing techniques
DE102005022308B4 (de) 2005-05-13 2007-03-22 Eos Gmbh Electro Optical Systems Vorrichtung und Verfahren zum Herstellen eines dreidimensionalen Objekts mit einem beheizten Beschichter für pulverförmiges Aufbaumaterial
DE102013004940A1 (de) 2012-10-15 2014-04-17 Voxeljet Ag Verfahren und Vorrichtung zum Herstellen von dreidimensionalen Modellen mit temperiertem Druckkopf
DE102015006363A1 (de) 2015-05-20 2016-12-15 Voxeljet Ag Phenolharzverfahren
DE102015219355A1 (de) * 2015-10-07 2017-04-13 Siemens Aktiengesellschaft Vorrichtung und Verfahren zu einer additiven Fertigung
WO2018075035A1 (fr) * 2016-10-19 2018-04-26 Hewlett-Packard Development Company, L.P. Production d'objet tridimensionnel
JP6866931B2 (ja) * 2017-10-31 2021-04-28 株式会社Ihi 三次元造形装置及び三次元造形方法

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WO2021093911A1 (fr) 2021-05-20

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